Search Documents

By Gaom M. W.

The Mount Isa copper concentrator started operation in 1973. Its secondary grinding circuit consisted of two 5 meters diameter ball mills in closed circuit with 505 mm cyclones. At the design throughput of 800 t/h, the 80% passing size of the circuit product (P80) was about 140 µm. The then Mount Isa Mines Limited (?MIM?) installed two autogenous grinding (?AG?) mills in 1991 to replace two stages of crushing, a rod milling stage and one primary ball milling stage. One of the AG mills was later converted to semi-autogenous grinding (?SAG?) operation by the addition of a steel grinding medium to achieve the designed plant throughput of 800 t/h. The cyclone over-flow P80of the secondary ball mill circuit was reduced to 120 µm by the increased operating power in the AG/SAG mill circuits. The two secondary balls mills had a grinding power of 5.2 MW. A mineralogical study of the milled products indicated that half of this grinding power was sufficient for adequate chalcopyrite liberation. Eliminating one of the secondary ball mills could reduce energy and operating costs by more than A$2 million dollars per year. An optimisation project team was established to achieve the predicted power saving. Grinding circuit simulations were conducted for different circuit configurations. Ball mill parameters such as ball size, ball charge and feed slurry density were optimised. Cyclone body diameter, spigot and vortex finder sizes, and cyclone types were tested. The secondary ball mill circuit was redesigned and several proposed circuits were run as trial production campaigns to determine their operability and efficiency. The plant trials confirmed that one of the secondary ball mills could be decommissioned. Significant cost savings were achieved as a result. The success of the project demonstrates optimising grinding circuits can not only deliver the plant performance, but also a much lower unit operating cost through energy and maintenance savings.

Jan 1, 2014

By Polezhaev S. Yu, I. V. Ukraintsev, Boduen A. Ya, Saburbayeva L. Yu

"Comparison studies of different technologies are performed when selecting optimum option for gold ore and concentrate processing. Methods of ultrafine grinding, oxidizing roasting, bacterial leaching and pressure oxidation are used to extract gold from refractory ores and concentrates. Refractory gold flotation concentrate produced from pyrite-arsenopyrite ores of Bestobe deposit is a case study in this paper. The results of the experimental tests of the direct leaching of flotation concentrate and pre-oxidation products using different methods (oxidizing roasting cinder, pressure oxidation and bacterial leaching cakes) are the following: - cyanidation of original flotation concentrate provides recovery of Au at 46.6 %; - oxidizing roasting increases gold recovery from 46.6 % to 85 %; - BIOX increases gold recovery up to 86 %; - preliminary pressure oxidation of flotation concentrate ensures steadily high Au extraction in the follow-up cyanidation at 94.9-96.5 %. Pressure oxidation and bio-oxidation has changed dramatically the strategy of refractory gold ore processing. These solutions provided for development of ore deposits that considered earlier non-commercial. However, refractory ore processing has a complex character in terms of developing process flowsheet and requires large amount of studies to be performed for each new project. Gold extraction is the basic but not the only criteria to technology selection for gold ore and concentrate processing. Opex and capex, ore reserves, regional geography, developed infrastructure and skill personnel should be considered. Process studies and feasibility study of the developed technology shall be provided for each specific gold ore deposit. INTRODUCTION Due to changes in available feedstock and depletion of easy-to-process ores, refractory ores containing finely disseminated gold and silver in sulphides (primarily, in pyrites and arsenopyrites) are more and more involved into processing. Experts say that such ores amount above 40 % of the world’s gold reserves. Conventional technologies of gold extraction from refractory ores include flotation, roasting and cinder cyanidation (Fraser etal., 1991). However, today’s best available practice for refractory gold ore processing are bacterial (BIOX) and pressure (POX) oxidation."

Jan 1, 2018

By S. N. Shahcheraghi

Bioleaching method makes use of bacteria in solving metallic sulphides, so that these bacteria tend to convert insoluble metal sulphides into soluble sulphates. Since the kinetics description of this process is inevitable for better interpretation of relation between metabolism and growth of live organisms, as well as optimization of metals extraction processes, in this paper, this description is represented and designed in mathematic (kinetics) model for copper sulphide minerals based on Monod kinetics model. According to this model, special growth rate of bacteria (?) is a hyperbola function of restrictive substrate concentration (S). By Solving and developing of Monod kinetics model, a comprehensive kinetics model for bioleaching of copper sulphide minerals results. The designed is also applicable for other metal sulphides.

Sep 1, 2012

By E. R. Bobicki

"Low-grade ultramafic nickel ores, while representing a large potential nickel resource, are difficult to process due to their serpentine content. Microwave treatment is proposed as a technique to improve the beneficiation of ultramafic nickel ores by converting the constituent serpentine to olivine. The present paper reviews the microwave heating response of ultramafic nickel ores and resultant changes in mineralogy, as well as effects on grinding and slurry rheology. Beyond nickel extraction, microwave treatment improves the mineral carbon storage capacity of ultramafic ore tailings, providing a potential source of additional revenue via the sale of carbon credits. The combined positive effects, considered in the context of the whole operation, suggest an economically viable process is possible.INTRODUCTIONAs high-grade deposits become depleted, the processing of low-grade ores has become increasingly important. One such resource is low-grade ultramafic nickel ores. While representing a large source of nickel, these ores are difficult to process due to their serpentine content. Serpentine is a phyllosilicate mineral consisting of 1:1 stacked sheets of silica tetrahedra and magnesium hydroxide octahedra. There are three primary polymorphs: lizardite (platy), antigorite (corrugated) and chrysotile (coiled, fibrous). The anisotropic nature and non-spherical morphology of serpentine particles leads to complex rheology. Suspensions of serpentine minerals, especially those of chrysotile, exhibit high viscosity and yield stress, which can have a negative effect on comminution, flotation and dewatering operations. In flotation, serpentine is known to slime-coat pentlandite, a valuable nickel mineral, and form bubble-fibre aggregates that report to the froth, reducing nickel concentrate grade and recovery. Methods used to counteract the effects of serpentine in processing include desliming, the addition of chemical dispersants, salts or acid, and dilution (Bobicki et al., 2014a). Microwave pre-treatment has been proposed as an alternative way to eliminate the deleterious effects of serpentine in ultramafic nickel ore processing by converting the serpentine to olivine via dehydroxylation, which occurs at 600-700oC (Reaction 1). Olivine is isotropic, consisting of isolated silica tetrahedra linked by octahedrally coordinated magnesium ions, and has the same surface potential as pentlandite at the pH of flotation (~pH 9). Furthermore, since olivine is more reactive to CO2 than serpentine, microwave pre-treatment creates an opportunity to store more CO2 in tailings, an attractive option for mining operations looking to increase their bottom line where carbon pricing exists."

Jan 1, 2018

By S. Sarioglan

The bleaching of edible oils, industrial oils, and some chemicals may be achieved using natural and acid-activated clays. These materials remove impurities and pigments from the oils. In this work, a bentonite clay from Turkey (Somas bentonite) was activated with different concentration of H2SO4 and HCl at 70~90°C and 5~8 hours. Under these conditions several cations were removed from natural bentonite (Al, Mg, and Fe) and DTA-TGA, FT-IR curves of the solids obtained after acid treatment were examined. Treatment time and acid concentration increased the degree of destruction of the bentonite structure which was determined by ICP. Activated samples were tested in order to verify their capacity to bleach soybean oil and compared to standard commercial bleaching clays. The experimental results indicate that treated samples with H2SO4 have the same efficient in bleaching crude soybean oil with the standards and treated sample with HCl is more efficient in bleaching than the commercial products.

Jan 1, 2014

By Bruce Mathema, Steven Huynh, Terry Cheng, Gerry Gomez

"The use of PM40N, a specialty precious metals promoter in conjunction with a standard Xanthate based collector was extensively investigated in the flotation of a complex, silver-bearing, lead-zinc ore containing naturally occurring graphitic gangue. The ore, considered difficult to treat with conventional reagents, was tested at plant scale to determine the impact of the promoter on silver recovery, lead grade and also on the amount of zinc misplaced to the final lead concentrate.Initial laboratory-scale rougher flotation testing implied significant improvements in the recovery of silver and lead with a marginal amount of zinc displaced. Subsequent mini pilot flotation tests further revealed that a gain in selectivity and recovery could be achieved by adjusting PM40N promoter dosage and incorporating a cleaner flotation step, further improving rejection of sphalerite. Plant trials resulted in an improvement of 3% in Silver recovery coupled with a 2% increase in recovered lead whilst maintaining lead grade in the lead circuit.To date, the use of PM40N as a promoter has enabled the processing operation to significantly increase its plant economics. The partial replacement of the standard Xanthate based collector has also reduced the overall quantity of Xanthate required in the standard circuit by approximately 10% - which is a positive impact on the environment. It is envisaged that further optimization of plant parameters will favor stable operation and continue to boost revenues generated by subsequent improvements in silver metallurgy."

Jan 1, 2014

By Ventsislav Stoilov, Angel Angelov, Ivan Korolev, Antti Remes, Todor Pukov, Stoyan Gaydardzhiev

"The process modeling and simulation studies aim for better process operation and favorable environmental impact. The objective of this work is to set up a simulation model of the Assarel copper flotation circuit for planning and optimization of the process with the aim of increased metal recovery. The model is parameterized based on laboratory flotation tests of ore samples from the Assarel mine together with mineralogical studies by X-ray diffraction (XRD) and Mineral Liberation Analysis (MLA). A combination of several techniques allows reliable identification of mineralogical composition of the selected samples. The changes in the proportion between sulfide minerals in various products along the circuit have been also documented. Further, this information is used in the simulation model and in data reconciliation procedures for establishing mass balance. The simulation accuracy is studied by comparing the simulations with the plant survey based mass balance. Constructed simulation model can be used to run alternative process scenarios. As an example, the flotation circuit performance with different reagent regimes is simulated based on data from batch flotation tests. Two reagents were considered for this purpose, dithiocarbamate-based one and xanthogen formate/mercaptan blend. It has been revealed that these reagents do not have the same influence on the selective flotation. The one improves flotation of gold and overall recovery but without notable selective action. In contrast, the other showed better selectivity towards copper, rejecting more gangue and lowering gold recovery. The model is also applicable for process optimization studies with different feed compositions, flowrates and circuit configurations. INTRODUCTION In the pursuit for elevated technological indicators, finding an optimal set of process parameters fully utilizing the potential of the equipment is a key factor to success. Over the past decades, there has been a substantial development in flotation circuit optimization through performance benchmarking using metallurgical modelling and steady-state computer simulation. Practical simulation engineering tools are based on experimental data obtained from laboratory tests and from plant surveys and operation data. With the help of flotation models, it is possible to study grade-recovery response with different feed compositions and throughputs, and with various cell-operating parameters, as well as to evaluate and design different flowsheet configurations. Outotec’s HSC Chemistry® software, which incorporates simulation and mass balancing modules alongside with several other tools, can assist with this optimization (Mattsson et al., 2015)."

Jan 1, 2018

By E. Ashirbaeva

"Ores of ferrous metals traditionally make up the bulk of recoverable reserves of solid minerals, and iron ore concentrates - in the processing and consumption. To obtain concentrates, three main methods are used: dry and wet magnetic separation, gravity and flotation. But even their integration into complex developed schemes with finishing operations often do not solve the problem of obtaining high-quality concentrates, which are necessary for powder metallurgy and electric steelmaking. Increasing the iron content in the concentrate by removing harmful impurities is the goal of this work. The possibility of reducing the operations of wet magnetic separation twice and completely eliminating concentrating operations in ball mills from the scheme of operations has been established. Selective leaching agents for each type of iron ores have been created, allowing to obtain concentrates with an iron content of not less than 68-69% and negligible concentrations of harmful impurities. Methodical recommendations for long-term storage of bioreagents in the active state, their immobilization and preparation in industrial conditions at the enterprise Nedropolzovatelja are developed. The proposed biotechnology, which allows to obtain high quality iron and conditional concentrates for harmful impurities, is protected by patents (RU 2537684 ""Method for fine-tuning of high-sulfur magnetite concentrate"" for magnetite ores and Pat. RU 2599068. For the industrial implementation of the new technology, organizational and technological measures have been developed in the system with Road maps for types of ores. The developed technology makes it possible to condition noble metal, tin, tungsten, nickel and other concentrates in harmful impurities such as arsenic, antimony, mercury, sulfur, copper, zinc, iron, phosphorus, manganese, in total 30 components that pass into solution under the influence of bioreagents.INTRODUCTION Consumption of various metals is steadily increasing every year, the volume of mining is constantly increasing. Ores of ferrous metals traditionally make up the bulk of the recoverable reserves of solid minerals. Enrichment technologies for iron-containing ores are reduced to the combination of three main methods: wet and dry magnetic separation, gravity and flotation. But even the use of complex advanced technological schemes often does not lead to the production of high-quality concentrates suitable for metallurgical processing. In this case, either lapping operations or effective technical and technological solutions are used in the main enrichment cycle. Widely used in practice methods for improving the quality of iron ore concentrates include the use of finishing operations (fine screening, reverse cation flotation), staging of concentrates, the use of more sophisticated equipment (separators with running magnetic field, magnetic gravity classifiers, column flotation machines)."

Jan 1, 2018

By S. A. Kondratyev

"The present research work aims at disclosing the dependence of flotation concentrate recovery and its grade on the physically adsorbed collecting reagent properties, viz., surface pressure in the reagent film at gas-liquid interface, velocity of reagent species spreading over the said interface, relation between interaction energies of collector molecules within a film and with water dipoles.When using a single collecting reagent it is possible to improve the flotation concentrate grade in two ways, namely, by reducing collector consumption rate or using a weaker reagent. According to the proposed mechanism, a decrease in the physically sorbed species of the collector leads to a decrease in the rate of removal of the kinetic restriction of a flotation contact formation. As a result, the recovery of the useful component is reduced and the content of valuable components in the flotation concentrate is increased. The relationship between the spreading velocity of physically sorbed species at the gas-liquid interface and the recovery and quality of the flotation concentrate has been experimentally proved. Reduction in collector consumption lowered the valuable component recovery at a higher grade of the concentrate.The reasons were established for a rise of valuable content in the flotation concentrate if a weaker collector was used. It is justified that the use of a weaker collecting reagent with a shorter hydrocarbon fragment declines physically sorbed species of collector. The spreading velocity of collector derivatives at gas-liquid interface tends to lower along with less participation physically sorbed species of collector in formation of a flotation aggregate. The spreading velocity is determined for products of interaction between butyl-and ethyl-xanthates and lead nitrate at gas-liquid interface. It is found that the spreading velocity of butyl-xanthate derivatives is higher than that of ethylxanthate derivatives.The research work gets insight into the nature of relation between useful component content in the flotation concentrate and the useful component recovery. It is pointed out that adjusting the collecting activity of a collector makes it possible to influence a useful component content in the froth product thus gaining a compromise between wanted grade and recovery parameters."

Jan 1, 2018

By Leon Lorenzen, Nursen Guresin, Harald Muller

The development of mining projects from discovery, exploration to actual production is a complex and time consuming process. Often poor process plant performance can be attributed to the use of non-representative samples and inadequate and/or unsuitable metallurgical test work when designing flow sheets during project feasibility study stages and specifying process equipment. Samples not representing the ore deposit and inadequate test work may lead to increased project development costs, since expensive test work and engineering may have to be repeated. It should be noted that for higher level engineering studies, larger scale test work is recommended and is a requirement for feasibility level studies. This would apply even if the technology is considered mature and well proven, as each ore body may have its own unique characteristics that, if untested at a larger scale, could result in significant design shortcomings, which will have to be rectified at later stages of the project, usually at significant additional costs

Jan 1, 2014

By M. Saghaeian, R. Hejazi, H. Abedini, M. Zare

Water recovery in mineral processing plants is one of the most important subjects because water supply is a critical matter economically and environmentally, especially in desert areas. In this paper, the filtration behaviour of two iron ore tailing sample has been investigated using laboratory scale vacuum and pressure filtration units. These samples including tailing from Sirjan and Zarand concentrate production plants with the d80 of 94 and 41 micron, respectively. The results show that by using vacuum filtration the cake moisture content of Sirjan sample would be about 24%. But the filtration time is too long and vacuum belt filter cannot be used in industrial scale. Adding about 40 g/ton of flocculant would decrease the filtration time by about 30% and make the vacuum belt filter appropriate for dewatering of this sample. For Zarand tailing sample, the vacuum filtration would produce a wet cake by about 31% moisture content. Filtration time is too long and adding flocculant would not improve the results very much. So pressure filtration must be used for dewatering of this sample. The results of laboratory tests show that using pressure filter would reduce the cake moisture content to 21%. The filtration time is logical, so this process can be used for Zarand tailing dewatering.

Jan 1, 2014

By V. F. Bannikov, A. P. Kozlov

"The purpose of this study was to develop a theoretical and technology framework for designing new combined technologies for processing tailings containing non-ferrous and noble metals using dry separation. The main goals of the study were: identifying the distribution patterns of valuable components in various fractions in dry separation processes; examining the patterns identified for different types of non-ferrous and noble metal tailings; developing a theoretical and technology foundation for the development of innovative technologies for the efficient processing of tailings with minimal process water consumption. To examine the possibility of efficient recovery of valuable components from refractory tailings using dry separation, an experimental laboratory unit was designed and built, composed of novel or modified lab equipment: plasma unit for increasing the magnetic susceptibility of Fe - containing minerals; magnetic separator supporting isodynamic and polygradient fields; pneumatic separator for the dry separation of finely dispersed mineral mixtures; dielectric separator using the resonant frequency of the electric field. The laboratory unit supports various modifications and combinations of the lab equipment. The experimental studies led to the development of a unified process scheme for lab tests of mature and non-ferrous smelter tailings using dry separation methods.INTRODUCTION The huge amount of waste from mining and processing of mineral resources Russia inherited from the extensive use of mineral resources in the Soviet Union and amount of waste continue to grow. Often the content of valuable non - ferrous, rare and noble metals in waste exceeds the balance contents in natural ores of the developed deposits. The availability of a rich scientific reserve for the creation highly effective innovative technologies for waste processing determines the necessity of the acceleration in the resolution of problems of the complex assessment, capitalization and involvement in the processing of technogenic resources in Russia (Chanturiya and Kozlov, 2014.)."

Jan 1, 2018

By J. Quinteros-Riquelme

Despite increasing demand, the supply of silver is limited by its inadequate recovery from ores. Due to its scarcity in nature, its high ore variability and complex mineralogy of current silver deposits, its recovery by mineral froth flotation presents a real challenge for process engineers. A silver ore often contains significant amounts of five to ten different silver minerals and knowledge of the mineralogy is a necessary precursor to flotation testing. In this work, a complex silver ore was treated by using batch laboratory flotation, in an effort to find the best experimental conditions to obtain the optimal silver recovery. Mineralogical characterization of feed samples was conducted using a combination of tools, namely the mineral liberation analyzer (MLA) and inductively-coupled plasma mass spectrometry (LA-ICP-MS), which indicated that most of the silver occurred as ?invisible? silver in pyrite. The pyrite assay of the ore was approximately 4%. The ore was processed in two flotation stages. The first stage, sulphide flotation, aimed to collect a sulphide mineral rich concentrate; then a non-sulphide flotation stage was performed by adding sodium sulphide and collectors to the remaining material in the cell, with the objective of obtaining a pyrite rich concentrate. To reach the target recovery of silver from this ore, various variables were altered. In the first stage: mixed collectors, activators, dispersants, and mainstream inert grinding were assessed. In the second stage, the conditions for sulphidization and subsequent flotation were both investigated. From the grade recovery curves for silver and sulphur it was possible to observe a similar metallurgical behavior for both elements, supporting the results given by the mineralogical characterization. Keywords: silver oxide, froth flotation, sulphidization, mig

Sep 1, 2012

By S. Saha

Minerals in coals cause operational problems in various coal utilization technology as well as act as diluents towards its heat value. Indian coals contain higher percentage of mineral matter compared to foreign coals due to its formation through drift origin. Efficient utilization of high ash coal in environment friendly manner is the driving force for the development of clean coal technology. Coal gasification offers practical means meeting stringent environment controlled parameters for producing power, chemicals, liquid fuels and clean energy on a single platform. It is well accepted that gasification technology has sufficient potential for sustainable development of clean coal technology. Gasification reactivity depends on the coal properties and operational parameters as well as minerals present in coal. Minerals not only create operational problems but on the other side also catalyze the gasification and combustion reaction. Therefore to understand the effect of minerals on the gasification reactivity, present paper proposes to study the variation of gasification reactivity with various gravity cuts such as, 1.4-1.5; 1.6-1.7; and 1.8-1.9 of a selected coal. Gasification reactivity has been studied by thermo gravimetric analyzer (TGA) using CO2 as gasifying agent. Surface properties such as, true density, apparent density, porosity, surface area of different gravity cut samples have also been measured to find out the effect of gravity separation on gasification reactivity. Keywords: gasification, reactivity, mineral matter, gravity separation

Sep 1, 2012

By H. Mengbing, A. Potokin, A. Usov

"Revealed and analyzed in the study are the ways of significant perfection of specific characteristics of the equipment, such as use of high-frequency voltage transformation to create a charger; use of pulse transformers, with core made of materials with high magnetic permeability, in pulse generating circuits; as well as use of special ways to produce voltage pulses with a short front. The experiments have proved the possibility to adapt these technological solutions for electric-pulse installations, and suggested on this base is a strategy of further development and application of electric-pulse technologies. The different applications joint work schemes of voltage sources with two levels voltage and energy in electric pulse technologies are investigated. The possibility of increasing energy efficiency of destruction is shown."

Jan 1, 2014

By Y. M. Zhu, G. C. Gong

"The influences of citric acid (CA) on the flotation behavior of cassiterite using styrene phosphonic acid (SPA) as the collector were studied via single mineral flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations in this paper. The results of single mineral flotation tests revealed under the conditions that pH=4 and the dosage of SPA 100 mg/L, the recovery of cassiterite reached 76.78%. The addition of 20 mg/L AC decreased the recovery by 12.42% at pH=4. Contact angle measurements demonstrated the adsorption of CA prior to SPA made the cassiterite more hydrophilic. The results of zeta potential determinations and solution chemistry calculations indicated the chemisorption of C6H7O7- and C6H6O72- filled parts of the Sn site on cassiterite surface and prevented the SPA from getting adsorbed. The hydrophilic effect of AC was stronger than the hydrophobic effect of SPA and the flotation of cassiterite was crippled. INTRODUCTION Tin is an important metal which is widely used in medical instruments, marine engineering materials, electronic and electrical devices, welding, weapon manufacturing and organotin compounds industries (Angadi et al., 2015). Cassiterite is the only mineral from which the tin can be extracted, thus it is of great importance to efficiently exploit the cassiterite mineral. Flotation is an indispensable method for the recovery of cassiterite (Li et al., 2015). However, cassiterite is usually in association with many other gangue minerals which are of similar floatability, such as quartz, calcite, fluorite, iron oxide, wolframite, scheelite and tourmaline (Sreevinas, 1997). So some modifiers are necessary in the cassiterite flotation process. The amounts of the modifiers used in the flotation must be judicious and the overmuch modifiers may cripple the recovery of cassiterite (Parsonage et al., 1987). Nevertheless, the research about the effects of the modifiers on the flotation behavior of cassiterite has been rarely reported. In this paper, the influences of citric acid (CA) on the flotation of cassiterite using styrene phosphonic acid (SPA) as the collector were investigated by flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations."

Jan 1, 2018

By R. Roufail

In this paper, the effect of different operating parameters of high speed stirred mill on the particle breakage mode is addressed. Morphological features of broken particles is investigated and related to the types of forces generated in the mill using Discrete Element Method (DEM). The stress intensities generated in the mill are varied by changing the agitator speed. The investigated agitator speeds were 1000, 1500, and 2000 revolution per minute (rpm). The minerals considered in this study are hard minerals (quartz) and soft, sulphide minerals (galena). The morphological features examined are roughness, roundness and elongation, which shed light on the mode of breakage during the grinding process. Particles that are rough, less round and elongated would imply that they broke via fracture, along their grain boundaries. On the other hand, the smooth, less elongated particles would mean breakage occurred across the grain, which is abrasion mod. DEM study complemented the understanding of particle breakage mechanism via tracking the types of forces applied on the particles. Normal forces imply compressive loading, which is presumed to impose fracture breakage along the grain boundaries, whereas tangential forces imply abrasion loading. Stirred mill grinding has been regarded as an attrition/abrasion process, whereas, this study showed that about 60% of total particles that are morphologically analyzed for both minerals were rough particles. Such an observation indicates that the fine product, which contain a significant amount of progeny from the coarse fractions are consistently broken via fracture. The morphology results agreed with the DEM findings, which indicated that the agitator speed, mineral type, and residence time would dictate the type and mode of particle breakage. Keywords: DEM, high speed stirred mill

Sep 1, 2012

By Chiharu Tokoro

Acid Mine Drainage (AMD), high acid water containing heavy metals discharged from mines, has been recognized as major cause of mine pollution. In Japan, the government spends billions of yen every year to prevent pollution caused by AMD in about 80 abandoned mines. It is widely recognized that the treatment could continue for long decades or an even century. However, costs and environmental loads are uncertain during the treatment because a predictive model for the quality of AMD, the dosage of neutralizer, and the amount of sludge that is applicable for abandoned mines with limited data has not yet been established. In this study, a two-steps predictive model for solution composition and neutralization chemical requirements of AMD in future was constructed based on the geochemical modeling. Requisite input data of the model was the past historical water quality data from AMD monitoring, such as metal concentration and pH in the solution, instead of the sample rocks as other conventional prediction methods. In the first step, solution composition of AMD in the future was extrapolated from the available historical data using geochemical simulation considering the first order kinetics for the mineral dissolution. In the second step, neutralizer dosage and sludge generation in the future was predicted based on the geochemical simulation supposing the chemical equilibrium and oxidation state for all of elements in the solution. Based on case studies of two abandoned mines in Japan, solution composition, neutralizer dosage and sludge generation were estimated. The results of this study demonstrate the effectiveness of our model for the prediction of AMD quality and chemical requirements of neutralization treatment after mine closing. The model is useful for the estimation of the neutralizer dosage and the sludge volume in abandoned mines with limited data. Keywords: acid mine drainage, predictive model, geochemical modeling, first order kinetics, water monitoring

Sep 1, 2012

By Q. W. Jiang

This paper presents a new process for producing industrial magnesium sulphate using waste water from titanium white plant and magnesium oxide from calcinations of magnesite ore as raw materials. With the laboratory experimental equipment, the waste liquid and magnesium dioxide react effectively at ambient temperature and under atmosphere pressure. Via the press filter, a clear liquid predominately containing magnesium sulphate is obtained. It is further evaporated and crystallized by cooling, separated by centrifuge and dried. Consequently a high quality of industrial magnesium sulphate is achieved as the final product. In the course of process, as the majority of valuable component (SO42-) is recovered in the final product, most of impurities from waste acid is being removed into the by- product. With the simple operational process, it is possible for titanium dioxide plant to resolve the environmental problem completely and benefit from the industrial magnesium sulphate product as well. The filter cakes containing valuable elements such as Mg, S, Fe, Mn, V, Ti are by-product proposed to be used for manufacture of agriculture fertilizer particularly for peanut planting.

Jan 1, 2014

By Patricio Berrios, David Barriga, Peter Amelunxen, Gerson Sandoval, Roger Amelunxen

Laboratory test equipment and methods have undergone relatively little change since their introduction in the 1950’s. The Denver sub-A cell is still by far the most commonly used laboratory batch cell, but bottom-driven and instrumented cells are beginning to appear. Test procedures have also changed little over the past 60 years, and most engineers continue to rely on empirical models for predicted plant scale performance from laboratory scale tests. This approach is problematic, because changes in the froth phase characteristics in the lab hamper the reliability and reproducibility of the empirical extrapolation to plant scale. In a previous work, the authors reported on the impact of froth recovery at the laboratory cell, showing that variability in the froth recovery can lead to significant error in the modeled kinetic rate constant unless it is properly accounted for in the scale-up model. In this work, we review the role of hydraulic entrainment in the lab cell, and how variability in particle specific gravity, shape factor, and froth residence time can impact the entrainment recovery.

Jan 1, 2014