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By Andrzej Wieniewski, Cezary Regula, Bozena Skorupska, Krystian Cichy

"In this paper, experiences from Polish non-ferrous metals ores enrichment plants in the copper and blende concentrates quality improvement are discussed. The blende concentrate being produced in ZGH Boleslaw S.A., with Zn content of about 54,5% is characterized by the relatively high magnesium content reaching a level of 1% resulting from the dolomite presence, while for the zinc production by electrowinning a concentrate in which magnesium content should not exceed 0,3% is required. The implemented new technology for the quality improvement of blende concentrate is based on the leaching of zinc concentrate with sulfuric acid aimed at dissolving of the contained dolomite, and then flotation of the leached concentrate. It allows to obtain a concentrate with magnesium content below 0,1% at the simultaneously increased zinc content to about 57,5%. In the paper, laboratory tests results on the development of optimal flotation flowsheet for the gypsum removal and the industrial tests results concerning the process optimization of this flotation are discussed. In turn, the copper concentrate being produced in Polish copper ore enrichment plants KGHM PM S.A., is characterized by the increased organic carbon content - above 8%. It creates problems with the smelting of this concentrate because of difficulties with the heat removal derived from the combustion of organic carbon in the flash smelting process. The implementation of segregating flotation to the industrial practice allows the effective production of two concentrates with the differentiated chemical compositions - a concentrate with increased copper content and reduced organic carbon content for the flash smelting process, and a concentrate with lower copper content and increased organic carbon content for the shaft smelting process. In the paper, conditions of the segregating flotation and the achieved results are described."

Jan 1, 2014

By Wei Sun, Ruolin Wang, Jianjun Wang, Xiaodong Li, Honghu Tang, Yuehua Hu, Anh V. Nguyen, Haisheng Han, Kefeng Chen, Zhao Wei

It is difficult to separate scheelite especially from fluorite with fatty acid collectors because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface. A simplified flotation process using Pb-BHA complexes was developed to replace the energy-inefficient Petrov’s process of using a fatty acid, increasing the recovery of scheelite and reducing the cost. The relationship between surface chemical properties (crystal chemistry, solubility, and Zeta potential) of minerals and flotation by using a fatty acid or Pb-BHA complexes was studied in detail to provide new insights into the selective separation mechanism. The results indicate that the scheelite surface exposes more O atoms than Ca and that they are negatively charged due to the anisometric dissolution of Ca and WO4, which provides the possibility for separation using selective interfacial reaction. The FTIR and Zeta potential results indicate that both chemical and electrostatic adsorption play an important role in the adsorption of Pb-BHA complexes on the scheelite surface. The XPS results of the atomic composition and binding energies confirmed the presence of the adsorbed Pb-BHA complexes and that O and Ca may be the active adsorption sites. Therefore, scheelite was able to be collected by forming either a Ca-O-Pbcollector or W-O-Pb-collector (BHA). However, fluorite was only able to be collected by a fatty acid collector and colloidal [H2SiO3]n -, and a high temperature was needed improve the selective desorption of the adsorbed fatty acid collector by forming Ca-[H2SiO3]n - on the fluorite surface, resulting in serious problems in industry. However, the Pb-BHA complexes significantly contribute to improving the recovery of scheelite minerals, simplifying the flotation process, and circulation of the residual reagents and water. The new process has been applied in Shizhuyuan Mine, and improved the recovery by almost 10%.

Jan 1, 2018

By John O. Marsden

"Technology development and innovation has played a crucial role in the copper industry throughout history. The effective development and implementation of new technologies allows mankind to produce copper at progressively lower cost of production at a given feed grade and mineral type. This progress serves to counteract cost inflation/escalation over time and, depending on the magnitude of the cost benefit, allows ore cut off grades to be reduced thereby improving the availability, accessibility and utilization of resources. Two broad categories of technology development and innovation play a key role in this process: (i) incremental improvements and optimization of existing technology provide benefits in the near- to medium-term, and (ii) step change technologies provide value over the longer term. A key issue for potential developers and implementers of new step change technology is how to justify resource allocation and expenditures for such initiatives. This paper examines this issue with reference to specific case studies in the copper industry. INTRODUCTION AND BACKGROUND Technology development and innovation has played a crucial role in the commodity minerals industry throughout history, and none more important than the copper industry. As new, cost-efficient technologies are commercialized, the cost of production in real terms at a given ore feed grade and mineral type decreases. This progress enables ore cut off grades to be reduced allowing lower grade material to be processed economically, which in turn increases the availability and supply of the metal or mineral of interest. Cost inflation/escalation works in the opposite direction, squeezing margins for operations utilizing incumbent technology to process material from a given ore deposit. A prior review by the author considered the issue of technology development and sustainable competitive advantage. This review concluded that first movers and fast followers can achieve competitive advantage for periods of 10-15 years through effective deployment of new technologies (Marsden, 2004). A new, more comprehensive study and evaluation was completed in 2014. This paper presents a portion of the results from the 2014 study."

Jan 1, 2018

By Christian O’Keefe, Alex Van der Spek

"Evaluation of inequalities of the partial sums defining cumulative grade and recovery prove that cumulative grade has an upper bound not dependent on the bank number and cumulative recovery possesses an upper bound proportional to the bank number. This explains one observed characteristic of cumulative grade versus cumulative recovery curves. The existence of such maxima combined with the observed shape of cumulative grade-recovery curves leads us to postulate that these curves can be well described by rectangular hyperbolae. Rectangular hyperbolae are characterized by asymptotes at right angles to each other. It is proven that this property can be used to derive an equation for the cumulative mass flow of the concentrate in terms of the asymptotic values of cumulative grade and cumulative recovery. Fitting hyperbolae to experimental cumulative grade cumulative recovery plant data then results in estimates of the maximum grade, the maximum recovery and a constant which may be taken as a performance coefficient of a row. Normalization of the cumulative grade and the cumulative recovery by their respective maxima gives rise to a graphical representation that can be used to evaluate the operating performance of a row of floatation bank cells. The normalization procedure removes the bias that is introduced by inevitable variation in mass flow of the feed and variation in feed mineralogy or feed particle size distribution. Reduction of the normalized data collapses all cumulative grade-recovery data onto one and the same curve. This removes the differences caused by the variation in row performance. The reduced cumulative grade-recovery data scatters around a common hyperbola. This can be used to gauge the validity of the assumptions made. Normalized cumulative mass pull is determined from the fitted values of the maximum recovery and maximum grade. This may serve as an alternative performance indicator of the floatation row."

Jan 1, 2014

By F Battaglia-Brunet, D. H. Morin, Foucher S. ’

In the mineral-processing field, bioleaching of metal sulphide concentrates is currently operated in very large mechanically agitated tanks. Such bioreactors have considerable requirements in terms of power consumption for mixing, aeration and heat transfer. The use of slurry bubble column, where the particles are suspended by gas motion as well as by liquid upward flow, could be an alternative to achieve bioleaching in more economical conditions. In order to compare these two techniques, a unit of stirred reactors in cascade and a bubble column were comparatively operated at laboratory scale in the bioleaching of a pyrite concentrate. For both pieces of equipment, experiments were performed not only in batch mode but also in continuous conditions.

Jan 1, 2003

By P. Gao, J. W. Yu

"Pre-concentration is a necessary step for upgrading low-grade iron ores, and its aim is to remove gangue minerals for improving efficiency of downstream separation process. The most important pre-concentration technique for iron ores, including hematite, siderite and limonite, is magnetic separation based on the appreciable differences between the desired iron minerals and gangue minerals in magnetic susceptibility. In this paper, the separation efficiency of one-stage low-intensity magnetic roughing combined with two-stage high-gradient magnetic scavenging for the pre-concentration of a low-grade hematite from Donganshan was investigated. It is a BIF type of ore containing hematite, magnetite and a bit of siderite, and an average content of Fe is about 34.6%. The effects of grinding fineness and magnetic field intensity for scavenging I and II were studied and optimized. The results showed that a magnetic preconcentrate assaying 42.7% with a recovery of 95.4% was obtained under the conditions of ore grinding fineness of -74 µm 70%, magnetic field intensity of 300 mT and 800 mT for scavenging I and II, respectively. Over 20% of the feed was rejected as the final tailings assaying 6.4% Fe. Meanwhile, the XRD, iron chemical phase and SEM analyses of different stage products revealed that hematite, magnetite and siderite could be recovered successfully by magnetic separation. However, some ultra-fine hematite particles (-10 µm) were difficult to be captured by magnet, and lost in the final tailing, resulting in lower iron recovery.INTRODUCTION Donganshan iron ore belongs to sedimentary-metamorphic iron formation called banded iron formation (BIF), which is formed in the Precambrian with a layered structure composed of ore bodies (Shen, 2012). Such type of iron deposit contains various iron-bearing minerals like hematite, magnetite, and siderite, suggesting it may be amenable to pre-concentration with magnetic separation. The pre-concentration process is effectively applied in recovering hematite, magnetite and siderite from iron ore, due to its benefits of further upgrading iron ore and improving separation efficiency. The most important pre-concentration technique for iron ore is magnetic separation, including low-intensity magnetic separation and high-gradient magnetic separation, based on the fact that there are appreciable differences between the desired hematite, magnetite or siderite and the gangue minerals in magnetic susceptibility."

Jan 1, 2018

By Alok Tripathy

A simulation code called SIMJIG and the user interfaces have been developed using discrete element method (DEM) and the .NET platform respectively for the jigging process. DEM platform is used for tracking of particles in the jigging operation. DEM uses the net force balance on the particles to track the trajectory of the particle. Simulation results are compared with experimental results obtained by jigging of low grade iron ore lumps. Two different iron ore samples one from Chatishgarh and one from Odisha were used for the experimental studies. The Alljig? stratification test rig meant for batch laboratory experimental studies has been used in the present work. The behavior of different sizes of material on jigging has been examined. Later, the particle size behavior during jigging at different layers of the jig bed has been studied. Further stratification profile across the jig bed has also been studied. It was observed that simulation results are matching quite nicely with the experimental results. The SIMJIG simulator developed in the present study could be used for predicting the performance of the jigging operation effectively. Keywords: DEM, gravity concentration, jigging, iron ore, simulation

Sep 1, 2012

By X. L. Song

A large amount of tailings in concentrators bring a series of problems to the environment and society. It is significant to reclaim the huge tailings and reuse them in industries in order to utilize mineral resources adequately. Primarily Lead-Zinc tailings with a certain quality of clay and feldspar were used to produce ceramic tiles by sintering method under specific technical conditions. By testing the properties of the ceramic tiles, it was shown that the amount of Lead-Zinc tailing used in the tiles was 60%~70%, and the mechanics properties were good. The optimum proportion parameters were Lead-Zinc tailing 60%, clay 35%, feldspar 5%, and the maximum flexural strength of tiles was up to 38.2MPa when it was sintered at 1090? for 30min. Its flexural strength, water absorption and thermal shock resistance reached the State Standard of GB/T4100.4. The product is suitable to be used in pavements and paths of parks.

Jan 1, 2014

By Ayumu Tokumaru, Shuji Owada, Gangfeng Liu

"Several million spent catalytic converters are disposed annually worldwideandeach containing about 0.5-1g ofplatinum and 1-2g of all the platinum group metals (PGMs), then,it is fairly significant to recover PGMs from the spent automobile catalyst. The PGMs’ recovery is a proven technology, including pyro-and hydrometallurgicalmethods, and the highestrecovery can achieve approx. 98 wt.% by acid-leaching method, but theserecyclingtechnology seems to be too highlyenergy-consuming. SincePGMs aredistributed only in coat layer in spent catalyst, it is of great significance to enrich the coat layerwith some physical methods as a pretreatment.In this paper, according to the double-deck structureof the catalyst andthe different properties of the two main compositions, alumina-ceria phase of coat layer and cordieritephase of substrate, the concentration of the coat layer was investigated by combiningthree kinds of physical separation technologies, heating-quenching, crushing and surface grinding. In the first stage, thermal stresscouldgeneratebetween the two phasesby thermal expansion difference,to producefracturesin the thinnest part of coat layerand micro-cracksin coat layerand at the interface of coat layerand cordierite substrate. The second stage of crushing, by jaw and roll crushers, could break dominantly the coat layer and the third stage of surface grinding, carried out by attritor, promoted further separation and concentration of coat layer fromthe substrate.We also improved the attritor grinding by adding a new lift-arm to the cell for achieving better mobility of sample particles in the selective surface grinding."

Jan 1, 2014

By Garren Edwards, van der Westhuizen. Andre

"Due to the depletion of easily treated coarser ores, more mineralogically complex ores with smaller valuable mineral grain sizes are treated, the means to liberate these minerals lies in grinding finer (Partyka & Yan, 2007). Grinding to these fine sizes is energy intensive, and using standard ball mills are energy inefficient at these sizes (P80 < 75µm). Therefore, stirred mills are becoming increasingly prevalent in the mineral processing industry. In order to optimize these mills, the effects and mechanisms of the significant variables need to be understood. This paper investigates a laboratory scale vertical stirred mill (Deswik mill) in an ultra fine grinding application of a South African platinum ore. The operating variables that are considered are stirrer speed, media size, media filling, and slurry density. The resulting grinding efficiencies are considered in two ways. Firstly, a statistical model is fitted to identify the effect of the significant variables on grinding efficiency, and secondly, the grinding efficiencies are also considered in terms of a stress energy model to determine whether this can partly explain the grinding mechanism in this mill. A factorial design of experiments was used on three levels for each variable, such that only linear interactions, second order interactions and two variable interactions are included in the statistical model. The results show that tip speed, media size, percent solids and mill filling are all significant to the grind, at differing energy inputs in the grinding process. The interaction effects of these variables are also dependent on the energy inputs. The results also found that the Kwade stress energy model is applicable to this mill and can be very useful to find the most efficient operating conditions for this system. The most energy efficient operating conditions in terms of mill speed and media size were typically somewhat below the standard operating conditions and it is expected that this is most probably done in order to increase the grinding rate, but at the expense of sacrificing some grinding efficiency."

Jan 1, 2014

By A. Wieniewski

The observed progress in technology of non-ferrous ores enrichment and condition of machines and equipment in the ores concentrators on the one hand have brought a possibility and on the other resulted in necessity for introduction of modernization actions. Positive results of investigations into influence of chemical modification of selected products of enrichment process on copper ores enrichment results gave possibility for implementation of chemical-flotation technologies of ores enrichment. The substantial development in flotation machines structure has contributed to modernization of flotation process resulting in increase of enrichment efficiency. The paper presents the idea and results of chemical modification of difficult in enrichment semi-products in the technology of copper ores enrichment and the results obtained after application of the modernised technology. The structure of large-volume flotation machines used in various stages of flotation and current situation in modernization of flotation process in copper ores concentrators are also described. The paper presents industrial-scale results of flotation after application of modified flotation reagents of collector group. Introduction of modifiers into the widely used xanthates resulted in increase of copper recovery in concentrate.

Jan 1, 2014

By Junwei Han, Wenhua Li, Wenqing Qin, Fen Jiao, Wei Liu, Jiaqi Xu

"A novel technology was developed to study the process of recycling copper from waste printed circuit boards (WPCBs), which are the main source of metal production in the next decades. The chemical compositions of the WPCBs were investigated. The results indicated that the PCB powder was mainly composed of copper (38.5 wt.%), iron, aluminum, and non-metallic materials. Copper is mainly in the form of Cu and is the most valuable metal for the recycle of WPCBs. The concentrated WPCBs powder, obtained by the mechanical process, were pressed as the anode, which was directly electrolyzed to produce copper. The effects of H2SO4 concentration, Cu2+ concentration, current density, pole pitch, and liquid-to-solid ratio on the voltage, current efficiency, and copper extraction were investigated. The results indicated that the optimum conditions were liquid-to-solid ratio of 30 mL/g, current density of 571 A/m2, sulfuric acid concentration of 180 g/L, 50 g/L of copper ion, polar distance of 3 cm. Under the conditions, a desired current efficiency could be achieved. Meanwhile, about 95.62% Cu was recovered from the WPCBs. The experimental studies also revealed that the purity of copper obtained at the highest current efficiency was higher to 99.98%. Produced copper sheet were characterized by X-ray diffraction (XRD). XRD analysis indicated that the copper was the main phase. INTRODUCTION With the rapid development of electronic industry, more and more waste electronic and electrical equipments (WEEE) are generated every year (Fogarasi et al., 2012; Liang et al., 2013). The production of printed circuit boards (PCBs) is the base of electronic industry, because it is the essential part of all electrical and electronic equipments (Schlummer et al., 2007). As a result, a considerable amount of waste PCBs containing plenty of heavy metals have to be treated. In general, PCBs contain about 28% metals that are abundant non-ferrous metals such as Cu, Pb, and Sn. Printed circuit boards can be considered as a secondary resource for recycling rather than wasting. The contents of gold and silver respectively reach 80 g/t and 3300 g/t, which are much higher than that of primary ores. Copper is the main metal of PCB and its content is as high as 26.8% ( Zhang et al., 2009)."

Jan 1, 2018

By Milind Chikhale, Ranjeev Kumar, Keshav Tyagi

Ore characterisation including mineralogy and beneficiation testwork of an ore is very important for determination of possible products and their quality. The results of such study help in ascertaining the beneficiation process route for the ore. The present study deals with ore characterisation study and beneficiation testwork on the samples of hematite iron ore with goethite impurity. The characterisation study reveals that the hematite is under alteration stage to goethite which has become an integral part of hematite. High goethite/limonite content is enhancing the loss of ignition content of the ore and reducing its Fe content. The findings indicate that in case of hematite iron ore associated with goethite and limonite, it is difficult to achieve high grade of concentrate above 65% Fe. It depends on the amount of goethite and limonite minerals and their association with hematite. These minerals contain aluminous impurities and hence, their rejection becomes essential. Separation of limonite and of goethite to limited extent is possible. In case of goethite, effective liberation is not achieved where it occurs as surface alteration product of hematite grains. The gangue mineral reported are clay and gibbsite, and are closely associated with iron minerals. The test work results indicate the grade and recovery of Fe along with alumina and silica content in lumps, sinter fines and pellet feed fines that can be achieved for the different ore types vis-a-vis the percent of available hematite in the ore. The recovery of iron is dependent on the hematite available and the loss of iron values in tailings is more because of rejection of limonite and goethite.

Jan 1, 2014

By Sanjeeva Latchireddi

The effective utilization of the energy in comminution devices depend on how efficiently the broken particles leave the breakage field as soon as they reach product size. In crushers the transport of broken particles smaller than CSS is done by gravity (vertical) thus allowing the energy to be applied to new particles. However, in AG/SAG mills, gravity becomes the energy field and the transport of particles is horizontal which needs a suitable discharge mechanism and has been found to have significant effect on grinding efficiency. The material transport in AG/SAG mills depend on how efficiently the discharge system (grate and pulp lifters) operates. Material transport plays a significant role on efficiency of horizontal grinding mills ? AG/SAG/Ball mills. The magnitude of benefits that can be achieved with efficient material transport in AG/SAG mills has been demonstrated in a Greenfield milling operation at Mirabela Mineração?s SantaRita Nickel operation located in northeastern part of Bahia in Brazil. This grinding circuit was commissioned in October 2009, which was designed as a typical SABC circuit to grind 4.6 mtpa (575tph) to produce a P80 of 125um with 10-12% ball charge in SAG mill. However, it has been operating as ABC circuit without any grinding media in SAG mill. The nameplate design capacity has been achieved in few days and has gradually increased to an average of +800 tph and still it is operating in ABC mode. The milling circuit commissioning resulted in small and relatively simple measures to rectify, which was reflected in the rapid commissioning of the milling circuit and it achieved the nameplate capacity within days. The Santa Rita grinding circuit consists of one 30?x 15.4? 8.5MW SAG Mill fitted with Outotec patented Turbo Pulp Lifters (TPL TM ) in close circuit with HP400 short head pebble crusher and one 20? x 28.4? 5.5MW Ball Mill in closed circuit with Warman cyclone cluster fitted with 10 x 26? CAVEX cyclones. This paper examines the comminution design process, operating philosophies, experiences, post commissioning optimization, and future development works. Evaluation of the milling circuit performance relative to the design criteria is also discussed. Keywords: Autogenous Grate (AG), Semi-Autogenous Grate (SAG, Turbo Pulp Lifter (TPL)

Sep 1, 2012

By Lang Shiping

The criteria for designing a crushing chamber are presented and a program for designing the shape of the chamber is proposed. During the chamber shape design, major design parameters are analyzed first, optimized parameters are determined next and the basic shape of chamber is figured out finally. In the basic chamber design program, the influence of abrasion of basic chamber shape and material characteristic are not accounted for usually. Here, based on the minimum abrasion of chamber shape and uniform particle size theory, the equation for chamber surface curve and the transcending function were formulated and a low-abrasion chamber was designed. Since the chamber shape designed based on experience and experiments is not necessarily the best, optimal design of the crushing chamber shape was carried out. Cubic spline function was used to represent the chamber shape curve and a mathematical model was formulated. The optimal shape solution was obtained using a complex method. Finally, the optimal chamber shape was determined by matching the moving cone stroke S, moving cone speed N and the moving cone bottom angle Thus, superior technical performance of the cone chamber was achieved.

Sep 1, 2012

By A. Lane

Africa is ripe with opportunity for the mining industry. The continent has large, and relatively unexplored mineral deposits, and recent high economic growth rates have meaningfully improved the political, economic, and infrastructural environments. However, these opportunities are accompanied by significant risks, including resource nationalism, uncertain regulation, corruption, and continuing political instability (up to and including war). Forward-looking companies actively manage these risks by creating a sense of shared purpose with the countries and communities that own the resources, using tools such as stakeholder analysis, local narratives, scenario planning, and constituency engagement. They also measure socio-economic impact to insure the creation and demonstration of shared value.

Sep 1, 2012

By Jan J. Cilliers, Nicolas Barbian, Esther Ventura-Medina

"Froth structure and stability are known to play an important role in determining flotation recovery and selectivity. An industrial sampling campaign was performed to develop a clearer understanding of the effect of flotation variables on froth stability and the role played by the resulting stability on flotation performance.Froth stability was estimated as the fraction of bubbles bursting on the surface of the froth through image analysis and the solids loading on the bubbles at the top surface. It was generally found that high air flowrates resulted in a drop of froth stability showed by a drop in the fraction of air overflowing and a decrease in the solids loading and simultaneously produced low copper recoveries and low concentrate grades. Deep froths only allowed a small fraction of air to overflow and consequently produced low recoveries. An increase from a standard to high frother dosage did not result in a larger fraction of air overflowing, hence producing low recoveries. Likewise, low frother addition only allows low recoveries because the resulting unstable froth cannot support itself. Low aeration was found to be preferential as it allowed high particle loading, therefore high bubble stabilisation, and low gangue entrainment, resulting in the highest flotation performance.Additional laboratory tests were performed to introduce a new stability parameter and to give a clearer understanding of the effect of flotation variables on froth stability. The results confirmed some of the observations made on the plant."

Jan 1, 2003

With rapid development of Chinese iron & steel industry, it is of significance to intensify the utilization of domestic complex iron ore resources. The tin, zinc-bearing complex iron ores are typical polymetallic and intractable ones because of the complicated intergrowth relations among the multi-elements, and they have not been efficiently utilized, presently. Based on the thermodynamic analysis of iron, tin and zinc oxides reduction by CO, the technological conditions of tin and zinc recovery and pellets preparation from tin, zinc-containing iron concentrates by selective reduction roasting are studied and a new comprehensive utilization process is developed in this investigation. Under the optimum conditions, the tin and zinc volatilization is respectively in excess of 80% and 70%, and the compression strength of roasted pellet is more than 2500 N/P. Moreover, the residual tin and zinc in the finished pellets is below 0.06%. The finished pellets can be used as high quality iron-making burdens for large-scale blast furnace.

Jan 1, 2014

By F. Karakas

Water based paint formulations consist of some industrial minerals with quantities varying from 20 to 50 %. Quality of paint is directly related to these minerals used as pigment or filler in the production. Titanium dioxide is the most important and expensive pigment in paint formulations. Other minerals such as calcite and calcined kaolin are used as filler and mainly as a substitute for TiO2. Consequently, particle-particle interactions including adsorption, coating and size distribution of pigment mixture directly affects the paint quality. In the present paper, a new type of pigment mixture for possible use in architectural water based paints was developed through grinding. The effect of different types of grinding methods on physical properties of TiO2 and calcite mixture and the quality of paint produced by these mixtures have been revealed. Three different types of mills; conventional ball mill, vibratory ball mill and high-speed attritor were used for grinding of TiO2 and calcite. Viscosity, zeta potential and particle size distributions were used to characterize the pigment mixtures obtained upon grinding. The quality of paint was evaluated by standards based on both wet and dry paints such as viscosity, density, opacity and gloss. The paint produced with the pigment mixtures prepared in vibratory ball mill and high speed attritor showed improvement in physical properties particularly in the distribution and dispersion of mineral particles. Keywords: grinding, pigment, paint, TiO2, calcite

Sep 1, 2012

By P. Gao, J. W. Yu

"Magnetizing roasting-magnetic separation is an important route for the beneficiation of refractory iron ores. In this investigation, a pilot-scale fluidized magnetizing roasting reactor was introduced and used to study the effects of roasting temperature and the flow rates of reducing gas CO and fluidizing gas N2, on the magnetizing roasting performance of an Anshan-type carbonate-bearing fine iron ore. The results showed that the hematite was almost reduced to magnetite by a gas mixture of 4 m3/h CO and 1 m3/h N2 at a roasting temperature of 540 °C. Under the optimized conditions, a high-grade magnetic concentrate assaying 66.1 wt.% Fe with a recovery rate of 91.2% was achieved from an Anshan-type carbonate-bearing fine iron ore assaying 42.0 wt.% Fe. The XRD, VSM, and optical microscopy analyses revealed that the siderite was successfully converted to magnetite by roasting. Some coarse hematite particles were difficult to reduce to magnetite completely; however, these generated magnetite particles with a fine hematite core could also be effectively recovered by magnetic separation after liberation from gangue minerals due to their strong magnetism. INTRODUCTION Magnetizing roasting followed by low-intensity magnetic separation has been considered as an effective solution, both technologically and economically, when upgrading refractory iron ores (Zhang et al., 2012; Peng et al., 2012; Li and Zhu, 2012). According to the type of roasting reactor, the magnetization roasting can be divided into shaft furnace roasting, rotary kiln roasting, and fluidized bed roasting (Zhu and Li, 2014).Shaft furnace magnetization roasting system is mainly composed of heating and reduction processes. The hematite ore is first heated to 700~800 °C in the heating zone, then falls into reduction zone where the weakly magnetic hematite is reduced to magnetite by coke oven gas at 550~600 °C (Yan et al., 2012). However, several years of engineering practices indicate that the shaft furnace can only process the hematite ores with a granularity of 15 ~75 mm, and the shaft furnace roasting is also characterized by heterogeneity of roasted product. Hence, the shaft furnace magnetization roasting technology is gradually replaced by high-gradient magnetic separation with the development of high-gradient magnetic separator. The rotary kiln generally handles the hematite ores with a grain size of less than 30 mm (Zhu and Li, 2014), however the formation of clinker ring in the rotary kiln will affect the yield of iron resource. In the fluidized bed furnace, the hematite ore is shaken up by an upward current of gas which maintains the individual particles in suspension (Yu et al., 2018). The precise adjustment of the gas velocity to the particle size and the specific weight of the hematite ore, make it possible to generate a floating mixture of gas and solids which behaves almost like a liquid (Yu et al., 2017a). The process is reported to have the following advantages over the other roasting techniques: ease of control due to absence of moving parts within the reactor, homogeneity of roasted products, ability to handle fine particles, and high efficiency of heat transfer and mass transfer (Li et al., 2015; Yu et al., 2017b). However, the simultaneous heating and reductive magnetization of hematite ore occur at the same place in the conventional fluidized bed reactor. Therefore, the reductive atmosphere, as well as the safety and stability of anti-explosion are hard to be controlled. Besides, the roasting temperature for conventional fluidized bed furnace is usually up to 950~1150 °C (Liu et al., 2017). Thus, the formation of clinker ring caused by high temperature will affect the operating efficiency."

Jan 1, 2018