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By Zhu Yangge, Zheng Guibing, Hu Xiaoxing

"Because of the similar crystal structure and surface properties, it is very difficult to realize the efficient separation of magnesite and dolomite by flotation, which is the main reason restricting the utilization of magnesite resources with dolomite symbiotic. To deal with a magnesite resources with high content of calcium impurity in northwest China, a novel decalcification technology by combining flotation with leaching is proposed in this paper. In flotation process, a novel flotation collector with good efficiency and low temperature resistance was developed, and the depression effect of sodium hexametaphosphate was investigated. In leaching process, the leaching rate difference of calcium and magnesium was observed. By industrial test, from the magnesite ore with MgO content of 43.96%,the grade and recovery of obtained concentrate ( calculated by MgO) are 47.28% and 67.68% respectively, at the same time, CaO content decreases from 3.91% to 0.30%, which means that more than 95% of CaO impurity is removed.INTRODUCTIONMagnesite is one of the main raw materials for the production of refractory materials, and it is widely used in metallurgy, chemicals, ceramic, construction and other industries. China is the most important supplier of highquality magnesite resources, accounting for about 60-70% of the world's identified supply of magnesite products is provide by China (Jewell, 2014). In recent years, high-quality magnesite ores can be directly used are going to run out in China, and the utilization of magnesite resources with high impurity content have drawn more attention.The main purpose of purification for magnesite is to remove SiO2 and CaO impurities which affects the strength of the refractory material. Flotation is the commonly used method to remove impurities in magnesite ore. Reverse flotation with cationic collector is usually adopted to remove silicon containing impurities, and a great deal of literature has been reported (Santana A. N. and Peres A. E. C., 2001; Wang and Sun, 2008; Zhu et al, 2014; Wu et al, 2015; Ivan B. et al, 2017). But when the major gangue component is dolomite, it is very difficult to realize the efficient separation due to the similar crystal structure and surface properties between magnesite and dolomite. To solve this problem, researches have studied the surface properties of magnesite and dolomite, such as wettability, electrical property, solubility and solution chemistry (Nermin and Nurgul, 2006; Nermin 2006; Ozbek and Abali, 1999; Lacin et al, 2005; Bayrak et al, 2006; Bakan et al, 2006; Chen G. and Tao D., 2004), but the commonly studied direct flotation using oleic acid as collector is still hard to receive an ideal effect."

Jan 1, 2018

By O. Martinsson

The Kiruna area is an important mining province in northern Sweden, which is dominated by Fe- and Cu-Au deposits. Economically most important for the region, are the apatite iron ores with an annual production of c. 43 M ton of crude Fe-ore and a total production of more than 2000 M ton of ore the last 100 years. The apatite iron ores in the Kiruna area are dominated by either Magnetite or Haematite and contain varying amounts of apatite giving them a content of Fe and P, which varies between 30-70 % and 0.05-5 %, respectively. A typical geochemical feature of the ores is the strong enrichment of REE that is caused by a high content of REE in apatite and the occurrence of Allanite and Monazite containing 22.4 and 69.8 wt% REO, respectively. At Kiirunavaara, the content of REE in apatite varies between 0.07 to 1.57 wt% REO with a dominance for the light rare earths. The variation in REE-content of apatite depending on textural and paragenetic aspects is not known but apatite grains may display a strong LREE-depletion due to hydrothermal alteration. Monazite occurs as rod-shaped or tabular inclusions in apatite and is suggested, to have formed in response to hydrothermal alteration of apatite after the emplacement of the ore. Inclusions are mainly found in the central part of apatite grains occurring in veins and schliren, while they are rare in apatite occurring disseminated in the ore. Monazite also occurs as larger grains outside apatite and together with Allanite is found in texturally and paragenetically different settings within the ore. These occurrences of REE-minerals may largely be a product of LREE mobilized by alteration of apatite after the emplacement of the ore. However, REE-minerals including Allanite and Monazite might also have formed directly from late magmatic fluids. Keywords: apatite, monazite, allanite, ree, kiirunavaara, iron ore of kiruna type, mineral chemistry

Sep 1, 2012

By D. Whittles, S. Kingman, S. Bradshaw, N. Miles

The influence of microwave energy at high electric field strength on ore strength has been investigated. Two ores of varying mineralogy were treated in both multimode and single mode microwave cavities. After treatment, any change in strength relative to untreated ore was established. It was shown that in the multimode cavity reduction in strength was related to the applied power level. Results of tests carried out in the single mode cavities showed that, for both ores, reductions in ore strength > 50% could be achieved in very short periods (<1 second). Thermal stress analysis showed that the mechanism of microwave induced failure was the development of tangential stresses at the grain boundaries. It was concluded that operation at 915 MHz with high power and short residence times gives feasible scale-up possibilities.

Jan 1, 2003

By ?. ?. Zimin, B. A. Kutlin, X. Baddamsuren

"The ore features of Mongolian fluorspar deposits are shown in the paper. The possibilities of the technological of ore processing on the Bor-Undur combine scheme improvement are analyzed there. Some recommendations are done for scheme development: spare output technologies, the usage large-sized ore separation, flotation by columnar flotation cells, leaching and concentrate agglomeration.New evaluation and usage of mineral sources approach was developed for Mongolian fluoride ores. The conception allows using maximally available mineral resources for getting of metallurgical and acid fluoride concentrates while mining and technological processes: mining (as well as quarrying) -storing, blending-crushing, grinding-combined processing methods-metallurgical using preparation It has been established mining and processing technological schemes should include:• spare blasting technologies providing minimum effect on fluorite crystals which follows ore selective excavation;• large-sized ore separation methods resulted in maximum recovery for these operations in respect to metallurgical fluorite concentrates;• grinding and flotation regimes providing high-quality flotation concentrates getting for their usein chemical industry;• fluorite concentrates agglomeration technologies for providing ability of their use in metallurgical and cement industriesThe results of industrial usage of jugging machines, columnar and pneumomechanical flotation machines for fluospar dressing.The technological approaches implementation in “Bor-Undur” plant maintenance within 1993-2002 years leaded to:• change plant status from just flotation one to gravitational-flotation characterized by technological process stages which are traditional for metallurgical industry and plant capacity increase from 400 to 600 thousand tones of treatment ore as well as concentrate production increase from 120 to 150-170 thousand tones including 120-140 thousand tones of acid grade concentrates with 97% CaF2 ."

Jan 1, 2003

By S. Narra, M. Nelles, I. Eickhoff, S. Teitge

"The aim of the research is to develop a holistic process flow for the recycling of glass fibres from glass reinforced plastics (GRP) and carbon fibres from carbon fibre reinforced plastics (CFRP), wherein the dissolution of the fibre epoxy resin matrix, separation of fibre fractions and their renewed material use is intended. In clear distinction to the previous research and development projects, the aim here is to recycle complex composite structures such as dismantled/disused wind turbine rotor blades and end-of-life composite wastes. In the course of the study, mechanical, hydrothermal and thermal processes and their combined procedures will be developed. As the fibre length is a decisive quality criterion in the recycling of composite materials, the further focus of the study will be the development of upstream and downstream material processing, in which the fibres are retained in their original form. The evaluation of the recycled fibres obtained is based on the elemental composition, measurement and morphological evaluation of individual filaments by scanning electron microscope (SEM), micro tensile tests on single fibres and their comparison to virgin fibres. The resulting process water is analysed by gas chromatography and mass spectroscopy (GC-MS) and a potential recirculation is determined. In cooperation with companies from the composite processing industry as well as recycling companies, a return of the recycled fibres to the known manufacturing process will be examined and an energetic and economic evaluation of the overall process will be carried out. Ambitious aim of the study is to achieve an actual recycling instead of the present downcycling or the energetic utilization. INTRODUCTION As global warming increases, so does the awareness of consumption and production of energy. To counteract the effects of global warming, renewable energy has been increasingly used during the last two decades, not only in Germany, but worldwide. Both, hydropower and wind energy, hereby play a fundamental role. After the end of their useful life of 20 to 30 years, the wind turbines (WTs) are being dismantled. Due to their foundations and tower segments, their recycling rate hereby exceeds 90% by mass. So far, the resulting rotor blade waste played a minor role accounting for only 2 - 3 weight-% of the total plant. Rotor blades of modern wind turbines are made of glass and carbon fibers, which are embedded in an epoxy or polyester resin matrix, balsa wood, PU or PET foams as fillers as well as various paints and coatings. These wastes currently end up in waste incineration or are sold to non-European countries."

Jan 1, 2018

By D. Whittles, S. Kingman, K. Jackson, S. Bradshaw, N. Miles

The influence of microwave energy at high electric field strength on ore strength has been investigated. Two ores of varying mineralogy were treated in both multimode and single mode microwave cavities. After treatment, any change in strength relative to untreated ore was established. It was shown that in the multimode cavity reduction in strength was related to the applied power level. Results of tests carried out in the single mode cavities showed that, for both ores, reductions in ore strength > 50% could be achieved in very short periods (<1 second). Thermal stress analysis showed that the mechanism of microwave induced failure was the development of tangential stresses at the grain boundaries. It was concluded that operation at 915 MHz with high power and short residence times gives feasible scale-up possibilities.

Jan 1, 2003

By S. I. Anufrieva, N. A. Permyakova, E. G. Likhnikeevich

"Russia’s rare metal reserves are composed of compositionally and structurally complex ores and are characterized by an increased content of natural radionuclides due to their geochemical similarity with rare metals. For instance, concentrates of Zashikhinsky daeposit are characterized by an increased content of uranium (0,06%) and thorium (0,59%); Beloziminsky deposit holds pyrochlore-apatite-magnetite-carbonate ores characterized by increased radioactivity (130 mkR/h) and containing 0,0016-0,0025% of uranium; Etykinsky deposit is characterized by columbite-pyrochlore-microlith mineralization with an average ore grade of 0,013% of uranium and 0,0020% of thorium; eudialyte concentrate of Lovozero deposit (Alluaiv area) belongs to Class II of mineral reserves. Industrial development of these mineral reserves involves the need to comply with environmental standards, public health requirements applicable to finished core and by-products, to take into account the amount and class of the generated radioactive waste, the possibility of disposal or recycling of the radioactive production waste. Concentration processes of radioactive rare metal feeds most often lead to a concentration of natural radionuclides and their accumulation in concentrates. Comprehensive hydrometallurgical processes are currently under development for such concentrates, aimed at producing salable products compliant with the radiation safety standards. The choice of the hydrometallurgical processing method for radioactive rare metal concentrates is based on the mineralogical component of the concentrate, textural and structural features, the distribution of valuable components and impurities, and the content of radionuclides. A systemic approach to the selection of processing methods, in particular integrating several methods, is an effective solution. Methods may not only be combined, but also inextricably linked with each other. Hydrometallurgical processing methods include leaching by acidic and alkaline agents; sulfatization for selectively decomposing the minerals and moving the bulk of U and Th into solution; fluorine extraction process. Methods of precipitation and co-precipitation, extraction (by liquid and solid extractants), sorption, and ion exchange are used to decontaminate the solutions by removing thorium, mezathorium, uranium, and their radioactive decay products. Agents used in hydrometallurgical processing of radioactive rare metal ores include sulfuric, nitric, hydrochloric, hydrofluoric acid, alkali (NaOH, KOH), sorbents (for example, AB-17) for sorption of uranium and extractants (mono- and bidentate organophosphorus compounds, diamides, etc.) for the extraction separation of rare, rare-earth, and radioactive elements."

Jan 1, 2018

Compressive crushing is applied in crushing plants used in mineral, mining, and aggregate in-dustry for fragmentation of rock materials. From a global perspective, the total volume of crushed rock is massive and corresponds to several billion tons. All societies have to fulfil a daily need of rock material products and its derivatives such as metals and minerals. The business for metals and minerals is global while the aggregates production is mainly a local industry. This paper presents a broader overview of optimisation with respect to product yield, use of natural resources and energy consumption. High level plant optimisation of compressive crushing plants is covered as well as real-time optimisation and optimisation of single production units. Each of three optimisation areas are presented and a discussion around how these three areas will be able to communicate with each other is given. Several models, e.g. process performance behav-iour with respect to wear, as well as fitness functions can be common for all three areas. Well-defined and representative fitness functions are of the utmost importance in order to assure that the optimisation results reflect the production targets. It is concluded that great benefits can be achieved by linking together different areas of optimisa-tion. The future for compressing crushing lies, without a doubt, in tailored processes both with re-spect to machines optimised for each customer, plant parameters and operation routines as well as an on-line adjustment, which takes into account current information and control possibilities.

Jan 1, 2014

By V. Dementiev

Pyrite cinders is a complex raw material, in which the valuable metals are: Au(2.04 g/t), Ag(35.0 g/t), Cu(0.38%), Zn(1.1%) and Fe(56.0%). In this case high costs for mining and ore processing are not required. The hydrometallurgical treatment of pyrite cinders using thiourea, sulfite and cyanide solutions are examined in this paper. It was found that thiourea leaching is ineffective due to high consumption of thiourea and sulfuric acid. The cyanidation on pyrite cinders was conducted. Various options of the preparation of the products for the subsequent cyanidation have been examined. The tests on cyanidation process optimization were conducted. The effectiveness of these cementation methods by metallic iron or extraction for copper recovery from water phase has been shown. Zinc precipitation can be found in the form of carbonate. In order to recover noble metals from cyanide solutions, the cementation onto zinc dust was tested. The developed technology provides for recovery at 49-56%Au, 20-25%Ag, 22.5%Cu and 50%Zn during NaCN (1.4 kg/t) and CaO (6 kg/t) consumption. The results of pilot plant testing are the basis for technical regulations in order to design a pyrite cinders treatment plant. The technology has been examined in pilot-plant conditions. In this case the recovery of 54.5%Au, 45.3%Ag, 30%Cu and 49.9%Zn was achieved to provide saleable products. Keywords: pyrite cinders, thiourea leaching

Sep 1, 2012

By D. J. Hallbom

The ?yield plastic? rheological model describes the flow behaviour of a variety of non-settling suspensions, including many types of mineral slurry. The current paper presents the laminar flow relationship (pressure gradient vs. flow rate) for a yield plastic fluid flowing through a pipe or cylinder. Simplified algebraic equations, suitable for engineering purposes, are presented for yield plastic fluids with values of the scaling factor in the range that includes most industrially important slurries. The laminar pipe flow relationship is one of the most important fluids engineering calculations. It may be used to determine the rheological parameters of a material in a capillary rheometer or flow loop. If the rheology is known, these relationships may be used to determine the laminar flow pressure gradient in pipelines of various sizes.

Jan 1, 2014

By Harri J. Lehto, Marja I. Oja

Empirical models used for predicting the performance of screens on the basis of capacity, cut size, water split and grade efficiency curves were evaluated. This paper reports experimental results obtained with single-deck Derrick screens. The performance of the screen was tested with limestone in a separate screen set-up, in a pilot plant and in industrial scale test runs. The results of pilot plant experiments showed that the measured water split was higher than the measured bypass. This is an indication to that water flow does not entrain the same proportion of all fine particles present in the feed which is advantageous for screening. The experimental design for the industrial test runs was made on the basis of the pilot plant tests. Suitability of the existing models has been checked and accuracy compared. The tests showed that best grade efficiency model was the Rosin-Rammler model. An empirical model for the evaluation of the model parameters as a function of pulp density of the feed and the load of the screen is suggested.

Jan 1, 2003

By J. Finch, F. Rosenblum, McGill University

The self-heating of sulphides can be a major hazard in mining operations and concentrate handling, particularly during transportation and associated storage. Self-heating results from the oxidation of sulphide minerals and can vary from being insignificant to potentially hazardous to life and infrastructure. It is essential that there be a reliable test methodology that can categorize a given sulphide material as to its self-heating potential. By their nature, sulphide ores and concentrates are complex and variable mineral combinations making it difficult to predict their self-heating behavior a-priori based on mineralogy or with a simple "snapshot" test. Furthermore, self-heating behavior will depend on the state of oxidation of the sulphides as well as time, temperature and humidity. A review of available testing apparatuses and protocols that can be used to assess self-heating potential is presented. Each of these methodologies was examined in relation to its ability to predict the latent self-heating hazard of a sulphide material. Several of the methods were compared to illustrate their strengths and weakness. The results indicated that a number of the test protocols may produce false negative indications of self-heating potential, constituting an obvious concern to the industry.

Jan 1, 2014

By Z. S. Abisheva

Results of the study targeted to development of universal acidic-extraction-precipitation technology for gallium recovery from the sublimates are presented in the paper. This will let to utilize a new non-traditional source for gallium production. Phase composition of gallium containing dust was studied. Forms of gallium in the sublimates were determined. The main form is Ga2O3, however, GaP form is also present in the cottrel dust and Na5Ga3F14 form is present in the dust of aluminum electrolysis. The possibility of gallium concentration was established via secondary pyro-selection of the dust. Kinetics of interaction of dust components with sulfuric acid was studied. The products of the interaction subsequently were leached with water. Optimum conditions for direct leaching with HCl and H2SO4 were determined providing gallium recovery from the cottrel dust and the ash carry outs up to 95 %. Gallium recovery from the primary dust and the secondary dust of aluminum electrolysis was at 52; 64 % and 63; 83 % respectively. Effect of Fe, P, K, Na and Al admixtures for gallium extraction from hydrochloric acid solutions was studied. It was shown that gallium chloride complex (GaCl4-) is extracted into the organic phase from the following acid mixtures: HCl + H2SO4, HCl + H3PO4, HCl + H2SO4 + H3PO4, HCl + HF. Kinetic regularities of gallium extraction in the system (tri butyl phosphate) TBP ? HCl - Ga were studied using diffusion cell method with agitation. Optimum conditions for gallium extraction from complex hydrochloric acid solutions with TBP were found providing 99.9 % recovery and separation coefficient for gallium and iron (III) of more than 25 in one stage. Sodium hydroxide and water were selected as reagents for re-extraction of gallium from the organic phase. Different options for disposal of by-products that are formed in the processing of cottrel dust, ash sublimates and dust of aluminum electrolysis were proposed and tested. Keywords: gallium, kinetic, sulfatization, leaching, extraction, technology

Sep 1, 2012

By Rainer M. Lotzien, Michael J. G. Battersby, Jan Kleefeld, Julian V. Brown, Rainer M. Imhof

A new flotation system has been developed to improve the generally slow separating differentials of fine bubbles and fine particle suspensions. The new technology is based on established pneumatic flotation designs called Imhoflot which use intensive in-line pre-aeration to aerate the flotation pulp prior to its introduction to the separating cell. In the new system (see figure 1) this separation is speeded up dramatically by the introduction of centrifugal motivation in the separating vessel, without the use of internal moving parts. The design focuses on providing increased differential forces on buoyant mineralised bubbles and hydrophilic fines. The commercial benefit to industry is much reduced residence time, less than 30 seconds, which offers considerable cost savings in equipment and infrastructure.

Jan 1, 2003

Datun Concentrator currently processes complex sulfide ores in Gejiu Municipality, Yunnan Province, China. The ore contains much higher arsenic than other ores. The run of mine ore is fed to the concentrator to recover copper and tin by bulk flotation and gravity concentration, and then the other sulphides, such as pyrite, arsenopyrite, etc. didn?t get utilized and are discarded as tailings due to the high arsenic content. In order to utilize the pyrites in the tailings, a series of tests have been conducted for finding the solution of arsenic removal from high arsenic-bearing pyrite concentrates through simple flotation process. By means of orthogonal experimental design, the optimized levels and main factors have been found out for the roughing stage. Through selection of the effective in-organic depressants for the arsenic-bearing minerals, the arsenic in the pyrite concentrate can be removed to meet the requirement of sulfuric acid plant (As%=0.5%) by the open flotation process, i.e., one-time roughing and two-time cleaning.

Jan 1, 2014

By M. Kinnunen

Handling of municipal solid waste (MSW) and control of its potential resources is becoming increasingly important in modern society. The OECD (Organization for Economic Co-operation and Development) average on municipal waste produced in 2003 was that of around 570 kg per inhabitant. In European Union countries around half amount is of MSW landfilled. In Finland still 88% of MSW was landfilled in 2004. Since incineration reduces MSW volume significantly while producing heat energy, it has become one of the most common waste handling techniques. The shortcoming of incineration is however, that incinerated MSW is often not pre-sorted and it produces slags and ashes as side streams from which recovery of metals is difficult. This paper looks into possibilities of scrap metal recovery for recycling from municipal solid waste incineration (MSWI) bottom ash. In order to do that, a flow sheet of physical separation methods was developed and tested with Finnish rotary furnace MSWI bottom ash. In addition, an empirical model for estimation of the recoveries of scrap metals with physical separation methods for treatment of MSWI bottom ash was developed. According to the results of this study, for 1 Mt of incinerated MSW with 30% mass reduction, a minimum resource potential of 100 kt for magnetic metal scrap of roughly 24 % grade and about 19 kt of non-magnetic metal scrap of roughly 65 % grade. In other words, 57 kg magnetic scrap and 12 kg non-magnetic scrap per inhabitant at the mentioned grades, respectively. Although wide variations of parameters affect the MSWI bottom ash quality, it can be said that a considerable amount of metals is drained into MSWI bottom ash. Results of this study show that from MSWI bottom ash significant material streams metal scrap can be reintroduced into the resource cycle which would otherwise be lost.

Jan 1, 2014

By E. T. Tuzcu

In this manuscript, a new approach for modeling the rate of grinding process is explained. A review about grinding rate definitions so far is given and the possible ultimate way for grinding modeling is given as modeling the rate based on energy spectra. The traditional/phenomenological approaches for modeling size distribution of grinding mills give their place to a new generation modeling technique. Developments in the computational methods and necessity to model product size distribution of large mills, larger than ball mill size, paved the way for this novel technique. The traditional grinding rate models are mostly based on the back calculated breakage parameters from the experimental data. However, direct modeling of breakage parameters and hence the prediction of size distribution of the grinding mills may become possible with this approach. The material breakage data and discrete element method (DEM) energy spectra are the main components of this approach. Albeit the focus in this study is on modeling of breakage rate under impact mode of breakage, the abrasion mode of breakage was also tested by carrying out abrasion tests. Impact mode of breakage was analyzed using ultra-fast load cell device (UFLC) and drop weight tester. Dry tumbling test was carried out for abrasion experiments. Obtained material breakage versus energy data are combined with the collision energy spectra to obtain the breakage rate function. In addition, the material breakage versus energy information from the tests is converted into breakage distribution function. The model was verified in a lab scale mill (90 cm diameter-15 cm length). 10 to 15 kg of limestone was ground using 50 mm steel ball at varying conditions, i.e., rpm, volume loading. It is shown that the proposed model predicts all (1, 2, 4 min.) grinding intervals for all experiments highly accurate.

Sep 1, 2012

By J. Yianatos

The regrinding stage is necessary to achieve the particle size (liberation) for the final upgrade in the cleaning flotation process. At present, vertical mills (Vertimill) are employed at industrial scale, using small steel balls as grinding media. The regrinding process characterization requires mixing regime knowledge along with the mean residence time of the liquid and solid phases. The residence time distribution (RTD) and the actual mean residence time estimations from theoretical relationships are complex due to the presence of three components (solid mineral, balls and water), mass transport characteristics and segregation affecting solid holdup. Therefore, the experimental RTD determination is suitable for industrial mills. In this work, RTD measurements were performed in two different industrial flotation plants. Both plants operate with Vertimills of 1000-1500 HP in the regrinding process with different circuit arrangements according to the plant treatment capacity. The RTD was measured using the radioactive tracer technique. This technique allows for non-invasive tracer detection where the procedure consists of selecting a liquid (Br82 in aqueous solution) or solid (irradiated solid) tracer for RTD data acquisition in real time. The RTD was modelled by the Large and Small Tanks in Series (LSTS) model, which allowed the characterization of the different mixing regimes for both liquid and solids in the regrinding mills. Effective mean residence times in the range 2-11 min were obtained with RTD shapes similar to those obtained in tumbling ball mills. It was found that residence times of liquid and fine particles were similar, which is consistent with results observed in other mixing systems, e.g. mechanical flotation cells. Also, the mean residence times estimated from the RTD allowed the mass balance adjustment to be validated from metallurgical sampling data. RTD estimations are useful for better understanding the Vertimill behaviour and to identify the actual breakage rates. Keywords: vertical mill, residence time distribution, particle size, modeling

Sep 1, 2012

Over the last four years, a major collaboration between CSIRO-MIS, UCT and JKMRC has produced two significant advances in the modelling of comminution. The Universal Comminution Model (UCM) uses parametric SPH/DEM studies of comminution and separation devices to calibrate mathematical models which are suitable for industrial use. The Virtual Comminution Machine (VCM) uses the same computationally intensive techniques based on discrete element modelling (DEM) and smoothed particle hydrodynamics (SPH) to directly model any comminution device by combining a CAD file describing the machine design, sophisticated ore characterisation methods and advanced particle scale flow and breakage simulation. The UCM should be useful for process analysis and optimisation of existing equipment and circuits while the VCM should make a major contribution to the evaluation and development of new machines. Progress to date is encouraging with several processes now well described using DEM. This paper also reports on progress towards combining DEM for particles with a realistic slurry model based on SPH for different types of comminution devices. In due course, this combination should allow accurate modelling of particle transport in wet mills to be combined with DEM models.

Jan 1, 2014

By R. Marandi

Biosorption of heavy metals can be an effective process for the removal of heavy metal ions from aqueous solutions. In this study, the adsorption properties of nonliving (boiling in NaOH) biomass of phanerochaete chrysosporium. For Pb (II) and Zn (II) were investigated by using batch adsorption techniques. The effects of initial metal ion concentration, initial pH, biosorbent concentration, stirring speed, effect of temperature and contact time on biosorption efficiency were studied. Experimental results indicated that the uptake capacity and adsorption yield of one metal ion were reduced by the presence of the other metal ion. In the experiments the optimum pH value was found out 6.0. The experimental adsorption data were fitted to the Langmuir and Frundlich adsorption models. The highest metals uptake was calculated for Zn (II) and Pb (II) were 57 and 87 respectively. desorption of heavy metal ions was performed by 50 mM HNO3 solution. The results indicated that the biomass of p.chrysosporium is a suitable biosorbent for removing heavy metals ion from aqueous solution.

Jan 1, 2014