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By E. Guerrini, M. Maccagni, J. Nielsen

"The solution for the treatment of the EAFD has not yet been fully achieved. Some of this dust has still not found an appropriate final destination. Large consortium treatment plants are quite expensive both in terms of investment and operating cost. Meanwhile, the tolling expenses for steel production companies are becoming very important, causing them to look for alternatives. Some steel plants are looking to close their production loop by internal treatment of their dust. Some years ago, Engitec began studying the coupling of the EZINEX® Process, an ammonium chloride electrolysis to recover the zinc contained in the EAFD, with the INDUTEC® Process, a pyro process based on an induction furnace that can convert EAFD into a C.Z.O. similar to the Waelz oxide. The combination of these two processes provides an alternative to the existing treatment options and is particularly interesting for relatively small capacities. In this paper, we would like to give the latest update about these two processes and their possible integration INTRODUCTION Zinc is contained in numerous wastes and secondary raw materials that can be thought of as high zinc concentrate mines. This is a very interesting source of Zn that is typically easily exploitable. Unfortunately, only a portion of these materials are currently processed to recover the metal value, while stabilized or unstabilized landfilling is often the final destination. Pyrometallurgical processes are mainly used to convert the zinc into crude zinc oxide (CZO). The various processes are very similar and characterized by the fact that the zinc bearing materials are usually submitted to a thermal treatment [1] in which the zinc is reduced, vaporized and re-oxidized producing CZO. This material not only contains zinc oxide, but also relatively high concentrations of heavy metals. Many potential CZO sources, such as electric arc furnace dust (EAF), galvanizing ashes, brass foundry and converters fumes also contain chlorides, fluorides and alkali metals that will transfer to the CZO. The classic example is the Waelz oxide [2]. This CZO is an intermediate product that must be transformed into zinc salts or zinc metal. Until now, the conversion to zinc metal is done through two main processes: the sulphate leaching and electrowinning system and the Imperial Smelting Process (ISP). ISP is facing a crisis for technical and economic reasons that has led to the closing of most of the existing plants. In any case, before being fed to one of these two processes, the CZO must be treated to eliminate or reduce some of the contained impurities. In particular, the halides are most harmful to these processes."

Jan 1, 2018

By E. Guerrini, M. Maccagni, J. Nielsen

"The solution for the treatment of the EAFD has not yet been fully achieved. Some of this dust has still not found an appropriate final destination. Large consortium treatment plants are quite expensive both in terms of investment and operating cost. Meanwhile, the tolling expenses for steel production companies are becoming very important, causing them to look for alternatives. Some steel plants are looking to close their production loop by internal treatment of their dust. Some years ago, Engitec began studying the coupling of the EZINEX® Process, an ammonium chloride electrolysis to recover the zinc contained in the EAFD, with the INDUTEC® Process, a pyro process based on an induction furnace that can convert EAFD into a C.Z.O. similar to the Waelz oxide. The combination of these two processes provides an alternative to the existing treatment options and is particularly interesting for relatively small capacities. In this paper, we would like to give the latest update about these two processes and their possible integration INTRODUCTION Zinc is contained in numerous wastes and secondary raw materials that can be thought of as high zinc concentrate mines. This is a very interesting source of Zn that is typically easily exploitable. Unfortunately, only a portion of these materials are currently processed to recover the metal value, while stabilized or unstabilized landfilling is often the final destination. Pyrometallurgical processes are mainly used to convert the zinc into crude zinc oxide (CZO). The various processes are very similar and characterized by the fact that the zinc bearing materials are usually submitted to a thermal treatment [1] in which the zinc is reduced, vaporized and re-oxidized producing CZO. This material not only contains zinc oxide, but also relatively high concentrations of heavy metals. Many potential CZO sources, such as electric arc furnace dust (EAF), galvanizing ashes, brass foundry and converters fumes also contain chlorides, fluorides and alkali metals that will transfer to the CZO. The classic example is the Waelz oxide [2]. This CZO is an intermediate product that must be transformed into zinc salts or zinc metal. Until now, the conversion to zinc metal is done through two main processes: the sulphate leaching and electrowinning system and the Imperial Smelting Process (ISP). ISP is facing a crisis for technical and economic reasons that has led to the closing of most of the existing plants. In any case, before being fed to one of these two processes, the CZO must be treated to eliminate or reduce some of the contained impurities. In particular, the halides are most harmful to these processes."

Jan 1, 2018

By Luis Bergh, Francisco Díaz, Isabel Panire, Juan Yianatos, Luis Vinnett

"In this paper, industrial data of residence time distribution (RTD) in mechanical flotation cells is presented, which were measured in several plants using the radioactive tracer technique. Results include mechanical flotation cells of 100 - 300 m3, which were operated with effective residence times from 2 to 7 min. Tests were developed in forced air and self-aerated cells for liquid and solids (non-floatable) per size classes. Different RTD model structures including perfect mixer, Large and Small Tanks in Series (LSTS) and by-pass flow plus perfect mixer were evaluated and compared for single cells. The actual mixing regime was related to the effective residence times and cell designs based on the model fitting. By-pass flow percentages were typically lower than 10%, therefore the perfect mixer model plus a dead time was a suitable model structure in most cases. On the other hand, the arrangement of cells in series was effective in reducing the bypass flow observed in single cells (by-pass flow percentage greater than 5%). In addition, the N perfectly mixed reactor in series model was used to represent the mixing regime along flotation banks, which were operated with mean residence times in the range of 18 - 53 min. Results showed that N tanks in series plus dead time were closer to the actual values in most cases."

Jan 1, 2014

By Thi Hien Tran, Huy Hoan Nguyen, Thi Thu Hien-Dinh, Hong Son Nguyen, Duy Anh Dao

"Lithium discovered in La Vi deposit, Quang Ngai province in the Central of Vietnam was estimated with a reserve of approximately 1.5 million tones of lithium ore, which was characterized by mainly lepidolite with muscovite, albite, and quartz. This study investigated reasonable flowsheet and optimal conditions of enrichment technology for lepidolite from the mined ore by flotation process, and producing Li2CO3 and LiCl from lepidolite concentrate by hydrometallurgical process. The significant conditions for froth flotation of lithium ore including particle size, pH of ore slurry, pulp density, chemical spending (collectors, activators, depressants, and frothers), stirring and flotation time were investigated. The identified reasonable flowsheet and optimal conditions for froth flotation the La Vi lithium ore processed lepidolite concentrate containing up to 4 wt.% Li2O with a recovery of 87.61 wt.%. The processes of sulfation roasting lepidolite concentrate using FeSO4.7H2O, then leaching in H2SO4 solution, and removing impurities were carried out to prepare a pure lithium-bearing solution for producing Li2CO3 and LiCl. The products containing 99.05 wt.% of Li2CO3 and 99.02 wt.% of LiCl were obtained with recoveries of 82.97 wt.% and 85.77 wt.%, respectively. The obtained results indicated that lithium ore in La Vi deposit can be processed to produce commercial lithium products and lead the study to develop technology for a new industry of lithium processing in Vietnam.INTRODUCTION Lithium is the lightest metal, which has many superior properties in both metal and compound (such as Li2CO3, LiCl...) states since its discovery in 1817 by Swedish chemist Johan August Arfwedson. Lithium is a favourable material for many high technology fields such as aerospace industry and chemical industry. Some industrial fields which present the main consumptions of lithium include ceramic, glass, aluminum alloy, lubricants, rechargeable Li-ion batteries, synthetic rubber, and pharmaceuticals. The worldwide production of lithium in 2014 was 31,700 tones, continually increased in 2015 of 5% presented 32,500 tones (USGS, 2016). The demand for lithium tends to increase because of the raising in consumption of lithium batteries. Lithium is mined from salar brines, mainly in Chile and Bolivia, but also from granites and pegmatites, which contain minerals with high lithium content such as spodumene - LiAlSi2O6 (Heinrich et al., 1978; Linnen et al., 2012); petalite - LiAlSi4O10 (Sitando & Crouse, 2012); zinnwaldite - KLiFe2+Al(AlSi3O10)(F,OH)2 (Paukov et al., 2010; Kondás J. & Jandová J., 2006); lepidolite - K(Li,Al)3(Si,Al)4O10(F,OH)2 (Luong et al., 2013); and amblygonite - LiAlPO4F (Garrett, 2004)."

Jan 1, 2018

By A. Wieniewski

The observed progress in technology of non-ferrous ores enrichment and condition of machines and equipment in the ores concentrators on the one hand have brought a possibility and on the other resulted in necessity for introduction of modernization actions. Positive results of investigations into influence of chemical modification of selected products of enrichment process on copper ores enrichment results gave possibility for implementation of chemical-flotation technologies of ores enrichment. The substantial development in flotation machines structure has contributed to modernization of flotation process resulting in increase of enrichment efficiency. The paper presents the idea and results of chemical modification of difficult in enrichment semi-products in the technology of copper ores enrichment and the results obtained after application of the modernised technology. The structure of large-volume flotation machines used in various stages of flotation and current situation in modernization of flotation process in copper ores concentrators are also described. The paper presents industrial-scale results of flotation after application of modified flotation reagents of collector group. Introduction of modifiers into the widely used xanthates resulted in increase of copper recovery in concentrate.

Jan 1, 2014

By J. Yianatos

The regrinding stage is necessary to achieve the particle size (liberation) for the final upgrade in the cleaning flotation process. At present, vertical mills (Vertimill) are employed at industrial scale, using small steel balls as grinding media. The regrinding process characterization requires mixing regime knowledge along with the mean residence time of the liquid and solid phases. The residence time distribution (RTD) and the actual mean residence time estimations from theoretical relationships are complex due to the presence of three components (solid mineral, balls and water), mass transport characteristics and segregation affecting solid holdup. Therefore, the experimental RTD determination is suitable for industrial mills. In this work, RTD measurements were performed in two different industrial flotation plants. Both plants operate with Vertimills of 1000-1500 HP in the regrinding process with different circuit arrangements according to the plant treatment capacity. The RTD was measured using the radioactive tracer technique. This technique allows for non-invasive tracer detection where the procedure consists of selecting a liquid (Br82 in aqueous solution) or solid (irradiated solid) tracer for RTD data acquisition in real time. The RTD was modelled by the Large and Small Tanks in Series (LSTS) model, which allowed the characterization of the different mixing regimes for both liquid and solids in the regrinding mills. Effective mean residence times in the range 2-11 min were obtained with RTD shapes similar to those obtained in tumbling ball mills. It was found that residence times of liquid and fine particles were similar, which is consistent with results observed in other mixing systems, e.g. mechanical flotation cells. Also, the mean residence times estimated from the RTD allowed the mass balance adjustment to be validated from metallurgical sampling data. RTD estimations are useful for better understanding the Vertimill behaviour and to identify the actual breakage rates. Keywords: vertical mill, residence time distribution, particle size, modeling

Sep 1, 2012

By D. J. Borrow, K. van Netten

"A fine coal tailings feed was selectively agglomerated using a concentrated water in oil emulsion binder consisting of 95% aqueous phase and 5% organic phase. The purpose of the study was to investigate a continuous system in plug flow, providing a rapid beneficiation technique with high selectivity and recovery. The development of the novel binder was undertaken in previous work in a batch system consisting of a high-speed blender. In this previous work, it was found that agglomeration could be achieved in 3 s, providing the binder was pre-dispersed. Furthermore, it was found that, depending on the feed, only ~1 wt% of oil was required to achieve agglomeration, some 10 times less than required in traditional oil agglomeration. In a more recent study, the technique was adapted into a continuous process. Due to the rapid speed of the process using the emulsion binder it was found that a simple flow constriction within a 1 inch pipe was sufficient to achieve the selective agglomeration observed in the batch system. In this previous study, a coal feed consisting of a flotation product was agglomerated at a superficial slurry velocity of 1.3 m/s using a partially closed ball valve as the flow constriction. In the current study, a feed consisting of fine coal tailings with an ash content of 50.1% was used to establish the influence of superficial slurry velocity on the agglomeration process. The superficial slurry velocity was varied between 1.3- 4.2 m/s, while maintaining a constant pressure drop of 100 kPa across the flow constriction. The flow constriction consisted of a partially closed ball valve. It was found that increasing the superficial slurry velocity across the flow constriction reduced the amount of organic liquid required to achieve agglomeration. Under the optimum conditions, a combustible recovery of 80.4% was achieved at a product ash content of 9.6%. This work demonstrates a valuable product can be rapidly produced from tailings material using the novel emulsion binder. INTRODUCTION A significant opportunity exists to recover fine coal from material that is currently classified as waste. This waste material, also called tailings, is currently considered not economic to process due to its high ash content, low solids concentration, and the fine size of the particles. Thus, for this opportunity to be realised, a process is required that is highly selective and has the ability to economically recover fine particles at high throughputs. The technique of oil agglomeration has previously been considered as a candidate for the recovery of fine coal, as it is highly selective and has no lower limit on the size of particle that can be recovered (Capes and Jonasson, 1989). However, the cost of the oil required as the binding agent in the process has proven to be a significant barrier to any long-term applications (Swanson, Nicol, and Bensley, 1977). Recently, however, Yoon and co-workers have developed an ultrafine coal separation process that utilizes an oil phase for the recovery of the hydrophobic coal particles and have implemented an oil recycle to greatly reduce the consumption and thus cost of the oil (Yoon et al., 2016)."

Jan 1, 2018

By N. Naude, W. P. Roux

"Traditionally minerals processing equipment, such as jigs, are studied by characterising the feed and products from these processes. With this approach important details on the mechanisms of a process can be overlooked since assumptions have to be made on the internal operations of the equipment. Positron Emission Particle Tracking (PEPT) is a non-invasive technique that can be used to track a particle’s movement inside a closed vessel. PEPT makes it possible to observe the inner workings of a process, providing new information that was unattainable only a few years ago. Jigging has long been considered as one of the most difficult mineral processing techniques to model, due to the complexity of the mechanisms contributing to the separation of minerals during the jigging process. In this investigation PEPT was used to study the particle flow inside a laboratory batch jig. The aim was to determine if the particle trajectories could provide new insight into the jigging and its mechanisms. Three dimensional particle trajectories were observed with spatial and temporal resolution high enough to see details of the individual pulses during jigging. It was found that the pulse height is very dependent on the position in the jig bed. The vertical component from the trajectories showed the rate at which particles move through the jig bed (stratification rate) and it was seen that the density of a particle affects the stratification rate more that the particle’s size and that the shape in the range that was tested had little to no influence. Other phenomena such as a circular flow pattern was observed inside the jig and it was found that smaller lower density particles are affected by this circular flow pattern which tend to disperse these particles throughout the jig bed. Visualising the flow inside a jig by means of PEPT has shown to be instrumental in the deeper understanding of the process."

Jan 1, 2018

By B. Das

The processing of banded iron ore by direct anionic and reverse cationic flotation to produce pellet grade concentrate is investigated. This low-grade iron ore, known as banded hematite quartzite (BHQ) contains 41.8% Fe, 41.5% SiO2, 1.2% Al2O3, and 0.5% LOI. The flotation behavior of BHQ is studied by varying the effect of concentration of collector, frother, dispersant and pH. Oleic acid and dodecylamine are used as the anionic and cationic collectors respectively. The parameters that gave the best results in cell flotation are utilized in 100 mm diameter flotation column. All the results are compared with regard to the iron grade and recovery in concentrate. It is observed that, anionic collector with dispersant dosage of 220 g/ton, at pH ~8.5 is selective and yielded a high-grade iron concentrate with low silica as impurity. Also, it is possible to achieve an iron concentrate with 64% Fe at 30-37% weight recovery. The characterization studies of the BHQ ore using X-ray diffraction (XRD) technique and liberation analysis with QEMSCAN® are carried out. The sample contains 58.8% hematite and 37.7% quartz and the liberation of hematite particles are found to be 90.3% in -25 µm size. An alternative statistical modeling approach called response surface methodology was also undertaken to optimize the operating parameters in order to maximize the iron grade and recovery. The predicted results by the model are in agreement with the experimental values.

Sep 1, 2012

By B. Das

The separation of iron values from a typical Indian iron ore slimes containing 57.2% Fe, 5.81% SiO2 and 7.05% Al2O3 by wet magnetic separation and selective magnetic coating is investigated. The iron phases, which are mostly paramagnetic in nature, have been coated with magnetite or colloidal magnetite in presence of surfactant by manipulating the surface properties of the minerals. The studies have indicated that an iron concentrate containing 62.32% Fe with 66.5% iron recovery can be obtained at medium magnetic intensity of 7.8 kG which is much less compared to normal magnetic intensity of 13 kG to14 kG required for hematite-goethite separation. The performance of this technique with respect to both grade and recovery is superior to conventional magnetic separation or flotation of iron ore slimes.

Jan 1, 2014

By J. D. Miller, C. L. Lin

In general, x-ray computed tomographic (CT) techniques are able to provide 3D images of the internal structure of opaque materials in a nondestructive manner. The unique cone beam geometry allows acquisition of all 2D projections with only one rotation of the sample thus providing for fast data acquisition and better x-ray utilization, as a complete 2-D detector array receives the cone-shaped flux of rays. Thus, an isotropic 3D volume can be reconstructed without the mechanical translation and the stacking of sequential slices as is the case for more conventional CT scanners. In this regard, a state-of-the-art, custom designed xray microtomography facility to provide very detailed 3D spatial analysis of multiphase particles has been installed and is in operation at the University of Utah. The reconstructed 3D tomographic volume allows for an adjustable spatial resolution from 5 to 20 microns for sample dimensions from 10 to 40 mm in diameter, respectively. Utilization of this custom designed cone-beam x-ray microtomography system is discussed. Applications described include: coal washability analysis for the design and operation of coal preparation plants, liberation analysis for evaluation of grinding practice and separation efficiency, mineral exposure analysis for prediction of the ultimate recovery from heap leaching operations, and analysis of the pore structure network of packed particle beds for simulation of flow through such porous structures as encountered in filtration and heap leaching.

Jan 1, 2003

By Alexsandro Berger

Many thickener operations continue to be constrained by their ability to process consolidated underflows with high yield stress and associated rheological characteristics. To maximise separation efficiencies within a thickener operation the use of both engineering and reagents are always considered. BASF is developing a Novel Flocculant Technology (NFT), which combines both of these aspects to enhance the performance of the thickener operation, improving the areas of pumping efficiency, underflow density and throughput. The development progression through stages of laboratory scale batch test work to pilot scale dynamic testing has demonstrated the ability of BASF NFT to maintain effective flocculation performance whilst increasing the rate of underflow consolidation, and significantly reducing the associated underflow yield stress of the treated material. This paper will present application data through full scale dynamic testing conducted on a granite washing circuit to demonstrate the performance benefits that NFT offers to a thickener operation. Compared to the conventional flocculant treatment, within the operation parameters and conditions employed during the full scale trials, the NFT produced a reduction in underflow rheology (yield stress) of around 45 % relative to a given solids and improved the underflow consolidation by providing at least 20% relative higher underflow solids loading than the upper limit of the given typical thickener operation. Keywords: flocculation, thickener operation, rheology, yield stress, underflow density, throughput, slump test

Sep 1, 2012

By Grant C. Lukey, Jannie S. J. van Deventer

"The environmental effects of the mining and mineral industry include destruction of natural habitats, changes in river regimes and water tables, and other serious ecological impacts. In this century, it is likely that water will become a critical resource, and in most countries the mining industry competes for a share of this resource. The Kyoto Protocol may at first seem only relevant to the coal mining and power industry, however, it should not be forgotten that the mining and mineral industry is a significant consumer of power. Therefore the ratification of the Kyoto Protocol by most developed countries and the introduction of a carbon credit trading scheme will impact on the industry by potentially increased costs in utilities and waste discharges. It is clear therefore that the mining industry faces many challenges in the coming years. The mining industry?s commitment to sustainable development needs to continue to evolve, in order to meet these challenges effectively. With the advent of globalisation of the industry, it is now an opportune time for the industry to gain international agreement on how they want the industry to achieve sustainability in future years; such a progressive approach is necessary, otherwise government will force the industry to change, which may not necessarily be the best outcome for the industry.INTRODUCTIONThe Earth Summit in Rio de Janeiro in 1992 was an opportunity for world leaders to assemble and discuss strategies and initiatives that provide for further industrial growth without adverse effects on the environment. The World Summit on Sustainable Development held last year in Johannesburg, South Africa, was an opportunity to evaluate those initiatives implemented over the past 10 years, and to set a new and sustainable direction for the future. It is clear that industrial and technology development will continue at a rapid pace in order to serve the needs of a growing world population, but it is essential that the course of this development is well planned, well executed, and that it is sustainable. In reality, while government officials and politicians continue to debate policy and international protocols, the environment continues to suffer and the effects of climate change and global-warming become more real each day."

Jan 1, 2003

By D. Johann, E. Zanetti, I. A. S. Brum, P. M. Zancan, A. F. Castro

"This study was done from a sample of coal mined at the Vale-Mozambique mine, located in Moatize district, Tete Province. The aim of this work is to analyze the reagent system in the flotation of coal fines belonging to the Upper Chipanga layer (UC). Among coal processing methods, flotation stands out as one of the most important for the concentration of this material, in particular in the treatment of fine particles. The total feed of the Vale-Mozambique processing plant is 8,000 tph of coal, where 10% of this feed corresponds to the fine fraction that feeds the flotation circuit. The material used in this study had a particle size of 96% smaller than 0.25 mm. The reagents used in the flotation tests were betacol and diesel oil as hydrophobizing agents and MIBC as frother. The range of betacol concentrations in the first test phase was 200 g/t to 500 g/t, and in the second phase 200g /t to 500g /t while diesel oil and MIBC were kept constant at 300 g/t. The immediate analysis followed the Brazilian standards NBR 8289, NBR 8293, NBR 8290; and NBR 8299. The results showed that it is possible, from a feed with ash content around 22.84%, to obtain products with levels below of 10% ash, with a mass recovery around 50%. The recovery of carbonaceous matter was also evaluated and presented positive results. Complementing this study, the effect of H2O recovery was evaluated and it was observed that for the concentrations of betacol the recoveries ranged from 6 to 9%, and for diesel oil plus MIBC were 4 to 7%.INTRODUCTION Considering the increase in population and energy consumption as humanity has been living along the last decades and the consequent demand for non-renewable natural resources, it is clear the challenge of the mineral industry in the search for new technologies and improvement of the existing ones. This challenge is justified by the need for better industrial results and to meet the market specifications, taking into account the reduction of deposits with higher contents and the need for beneficiation of more complex ores, lower levels and lower release granulometry. Usually in these situations, processes already well-established as the gravimetric (Sampaio and Tavares, 2005) have not good results."

Jan 1, 2018

By Erico Tabosa

The turbulence characteristics and measurement techniques for agitated tanks are well established for liquid and liquid-gas systems. However, the literature shows that the overall energy dissipation rate (related to turbulence) is affected not only by air addition, but also by the concentration of solids. Unfortunately, there are no reliable measurement techniques for characterizing turbulence in a three phase (liquid-solids-gas) environmental system, which is the case in a flotation cell. Therefore, the effect of turbulence on flotation kinetics is very much one of conjecture. The aim of this work was to develop a sensor to characterize the degree of velocity fluctuation, which is related to turbulence, in a flotation cell operating with slurry and air. This sensor comprises a piezoelectric film transducer that converts mechanical to electrical energy. Hence, when the sensor deflects backwards and forwards an AC voltage is created. Flotation studies carried out using this sensor in a 3m3 Metso RCS cell processing a copper sulphide ore showed a highly turbulent impeller zone with transition to a significantly less turbulent zone in the upper portion of the cell. The transition region moves as the cell operating variables are changed, for instance the impeller speed, impeller size, air rate and feed solids concentration. Keywords: mechanical flotation cell hydrodynamics, turbulence characterization

Sep 1, 2012

By A. Oleynik

The paper presents the modeling and simulation experience in field of research into the mineral row material separation. Features of the subject domain generate a need of different approaches using for modeling and simulation. The general scheme of separation modeling process and some examples of developed simulators are presented. Due to different features and standards of knowledge, different formal models should be used to describe and analyze separation processes in the frame of general scheme. The main types of simulators are modeling tools based on statistical, analytical or expert (logical) methods. Advantages and disadvantages of each method above are mentioned in the paper. Based on the studies in the field considered, an aggregated mathematical model of a separation process has been generated. The aggregated model is presented by two combined equations. The actual apparatus model is formed by substitution of the particular functional expressions of the forces acting in the apparatus into the aggregated model. The developed simulation tools are based on integration of limited experimental data and on ex-pert knowledge available on separation processes. Simulation does not allow producing an optimal, in terms of mathematics, solution. But it gives an opportunity to produce and compare quite adequate solution variants in real time. The results obtained are the theoretical and methodological base for integrated information technologies to support studies in the field of mineral processing.

Jan 1, 2014

By T. Bhambhani, O. Yavuzkan, D. R. Nagaraj

"The recovery of oxide Cu minerals by flotation is a longstanding challenge in the minerals industry, especially for high acid-consuming ores which would not be economical for direct acid leaching. Sulfidization (often using controlled potential sulfidization or CPS) using NaSH (or Na2S) followed by flotation using traditional sulfide collectors is the widely used technique. CPS has certain limitations: a) inability to recover certain oxide Cu minerals because they are refractory to sulfidization, b) high consumption of NaSH (or Na2S), and c) potential health and safety hazards associated with NaSH (and Na2S). Flotation of oxide copper minerals using alkyl hydroxamate (AHX) collector has been studied extensively. Investigations using single minerals and laboratory ore flotation have been conducted in the past to demonstrate the efficacy of alkyl hydroxamates. The technology has been used intermittently in plants. One of the main challenges in plant use has been quantifying the true potential for alkyl hydroxamates for recovery of various oxide Cu species in complex and variable ore systems and identifying the most suitable conditions for optimal use. Quantitative mineralogical analysis using QEMSCAN was used in this study to characterize flotation products lab flotation samples. Analysis of concentrates and tails from hydroxamate flotation and CPS flotation stages demonstrated that certain oxide Cu minerals respond exclusively to alkyl hydroxamates and not to CPS. The hierarchy of interaction of AHX with the various oxide Cu minerals could be inferred from these studies. Finally, these studies also allowed quantification of a group of minerals species, which (erroneously) report as part of the Acid-Soluble Cu [ASCu] but cannot be recovered by flotation, thereby facilitating an estimation of the true recovery potential for alkyl hydroxamate.INTRODUCTIONCopper that is economically recoverable occurs in three major types of ores, which are defined by the modal mineralogy of Cu. For sulfide ores, Cu occurs as sulfide minerals and is satisfactorily recovered by flotation using sulfide collectors. Non-sulfide ores, which contain Cu in the form of oxides, phosphates, carbonates and silicates, described in the industry as “oxide” ores (or ores containing “acid-soluble” Cu or ASCu), are currently treated using hydrometallurgy, which involves leaching with dilute sulfuric acid followed by solvent extraction and electrowinning, unless the ores contain acid consuming gangue minerals such as dolomite. For mixed sulfide-oxide ores (i.e. containing both sulfide and oxide Cu minerals) that do not contain acid consuming gangue minerals, Cu values are easily recovered by flotation of sulfide Cu minerals followed by leaching of oxides (only when a leach plant is available). However, when the ore contains acid consuming gangue minerals flotation is required to recover both sulfide and oxide Cu minerals."

Jan 1, 2018

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, J. Taguta

The adsorption of heterocyclic collectors such 2-mercaptobenzothiazole (MBT), 2-mercaptobenzoxazole (MBO), 2-mercaptobenzimidazole (MBI) and their derivatives on pyrite form a basis in understanding the flotation reactivity that may be applicable in a wide range of sulphide minerals. This study uses a computational and experimental approach to determine the heat of adsorption of MBT, MBO, MBI and modified MBT collectors onto pyrite surfaces. Computational calculations found that the adsorption energies were in the order: MBO > MBI > MBT. The heterocyclic collectors were adsorbed in their thiolate form on the surface. In the case of the pyrite (100) surface, the MBT adsorbed through the exocyclic sulphur atom, while MBO and MBI adsorbed through the exocyclic sulphur and N atoms onto the 5-coordinated Fe atom. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted, where the MBT exocyclic sulphur atom bridged on the 5- coordinated Fe and surface 2-coordinated sulphur atoms, while the N atom adsorbed on the 5-coordinated Fe atom. In the case of MBO and MBI, dissociation of the exocyclic sulphur atom from the collector occurred with subsequent interaction with the surface 5-cordinated Fe and 2-coordinated S atoms. This resulted in the collector carbon atom adsorbing on the surface 2-coordinated S atom, while the N atom adsorbed on the 5-coordinated Fe atom. The adsorption of the modified MBT was found to be more exothermic than the MBT, which showed that introduction of a –CS2 group on the exocyclic sulphur atom improved the affinity of MBT on the surface, and was thus a better flotation collector. The computational results were supported by experimental enthalpy of adsorption measurements and microflotation tests. The chemistry of the heterocyclic thioamides is complicated by the fact that they can exist in a number of tautomeric and ionic forms at different pH’s. This is discussed in relation to the flotation and calorimetric data.

Jan 1, 2018

By Z. D. Tan

The continuous digestion technological conditions of phosphate tailings with high magnesium content in sulfuric and phosphoric mixed acid is studied in this paper. The influences of excess coefficient of sulfuric acid, weight liquid to solid, reaction temperature and time on conversion of P2O5 and MgO are discussed. The influence of infiltration capacity of phosphogypsum by the concentration of liquid-phase SO3 is discussed too. Under the optimal technological conditions, the conversion of P2O5 is 95.56% and MgO 98.63%, the filtration rate of phosphogypsum increases with the increasing of liquid-phase concentration of SO3, the optimal apparent concentration of SO3 is 0.135~0.14g? mL-1 in liquid-phase. The filtration rate of phosphogypsum is 1473kg? m-2? h-1. N-P-Mg compound fertilizer was produced by adding magnesia powder and inflating ammonia in filtering medium.

Jan 1, 2014

By D. Govender

Theoretical flotation models suggest that there is a positive relationship between bubble-particle collision rates and turbulent kinetic energy dissipation. Fine particle flotation performance is generally enhanced by increased collision frequency and hence higher energy dissipation. Contrarily, increased turbulence in the rotor-stator region is related to higher detachment frequency of the coarser size range. Therefore, the optimal modes of recovery for the ?fine? and ?coarse? size classes are diametrically opposed. Industrial applications have previously confirmed that applying greater power to flotation slurries yields significant improvements in fine particle recovery. However, recovery of the coarser size class favors a different flotation environment. An improvement in the kinetics of the fine and coarse size classes, provided there is no adverse metallurgical influence on the intermediate size ranges, is obviously beneficial to the overall recovery response. Managing the local turbulent kinetic energy dissipation, and hence the power imparted to the slurry, offers the benefit of targeting the particle size ranges exhibiting slower kinetics. FLSmidth recently introduced the practical implementation of this concept. In principle, it decouples flotation regimes where fine and coarse particles exhibit preferential recovery. In the case of naturally aspirated machines (Wemco®), it is referred to as Hybrid Energy Flotation? and incorporates at least three phases: ? Standard flotation machines (standard energy input, rpm, rotor size/type) at the beginning of the row, where flotation is typically froth phase limited and operational, and set-up parameters have a limited influence on the recovery. ? Higher-powered flotation machines (high rpm, high power rotor size/type) at the end of the row to improve fine particle recovery. ? Lower-powered flotation machines (low rpm, low power rotor size/type) to enhance coarse particle recovery. In evaluating the effect of turbulent kinetic energy on flotation performance, the spatial distribution and its effect on size denominated recovery needs to be evaluated. The mean energy dissipation rate is a measure of the bulk energy input, but CFD-based models offer a more introspective view of flotation sub-processes. A CFD-based flotation model is used to highlight the effect of turbulent dissipation energy on attachment and detachment rates. Preferential collection zones for ?fine? and ?coarse? particles are predicted for both forced air and naturally aspirated machines. Keywords: CFD-based model, attachment, detachment, energy dissipation, hybrid energy flotation?, forced air, naturally aspirated

Sep 1, 2012