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By M. Holuszko, I. Mikhalev

"Previous studies described by Galvin et al. (2017) have shown that for Australian bituminous coal fines, both in batch and in continuous process, the new improved oil agglomeration procedure based on the use of high-internal-phase (HIP) emulsions, as compared to the conventional “pure oil” agglomeration process, enables a significant reduction in the amount of oil while reaching a high yield of clean coal (approximately 90% of agglomerates greater than 355 µm in size) in a significantly shorter time. The HIP emulsion used in these experiments comprised up to 95% vol. aqueous solution of sodium chloride (3% wt. concentration) and for the rest, a mixture of kerosene (oil) and sorbitan monooleate (SMO emulsifier) in a 1:1 ratio as a binder. This study evaluates the applicability of the new HIP-oil agglomeration process to treat Canadian bituminous ultra-fine coal and Russian sub-bituminous coal fines and compares results from agglomeration to the flotation response of both coals. Oil agglomeration is known to be sensitive to surface properties of coal. Since surface properties of coals depend not only on the rank of coal but also on their origin (depositional environment) and mineralogical composition, both the applicability of this new improved agglomeration process to the non-Australian coals and its efficiency became the motivation for this study. To evaluate the applicability of the new process to both Canadian bituminous and Russian sub-bituminous coals, a series of bench-scale tests were carried out under conditions similar to those described by van Netten et al. (2016) for the Australian coals. Based on the results obtained in this research, new boundary conditions for the application of the HIP emulsion-based oil agglomeration process have been outlined and conclusions on the viability of the new process to treat ultra-fine coal from Western Canada and Russian sub-bituminous coal fines have been reached.INTRODUCTION In most cases, to meet the market requirements, the mined coal has to be processed to reduce the ash content by the removal of mineral matter and thus to increase the quality of the coal products (van Netten et al., 2016). Generally, flotation is used for processing fines from high rank coals; however, there are high losses of very fine coal due to the inefficiency of this process. Furthermore, difficulty in dewatering the fine coal results in excessive moisture levels causing coal handleability issues, which increases costs in the coal-cleaning industry (Capes & Darcovich, 1984). Much of the development that has occurred in fine coal cleaning has taken place with higher-value coal, often metallurgical (Klima et al., 2012). If the fine coal is deemed to be too difficult or expensive to process, it may be discarded as waste (van Netten et al, 2014). Such disposal not only creates an environmental liability but may also result in the loss of a valuable, high quality product that is better liberated than the coarser fractions of coal."

Jan 1, 2018

By Kauko T. Ingerttilä, Jouko O. Kallioinen, Jaakko O. Leppinen, Alexander V. Lashkul, Vladimir E. Nenno

The Separation in Froth (SIF) technique is based on the idea that the pulp is fed directly onto the froth layer prepared on the surface of liquid medium providing an effective method for separation of coarse particles up to a few millimeters size. Thus the SIF process can result in substantial savings in grinding energy and flotation chemicals. In this work flotation of apatite, calcite and silicate minerals from various industrial sources was investigated using laboratory and pilot plant-scale SIF machines. Flotation of diamonds was also investigated on laboratory scale. It was observed that all the minerals mentioned above can be successfully floated up to about 3 mm particle size. Beneficiation tests with the coarse fractions of classification circuits indicated that final grade calcite concentrate can be obtained with over 90% recovery in one SIF step in this grain size (typically 0,1 to 1,5 mm). Similarly, substantial upgrading of coarse apatite was achieved without grinding it to the fineness required by conventional flotation. SIF could also be applied to the recovery of coarse apatite from the tailings of a conventional flotation process. The capacity measured in the pilot plant test runs for a 1 m2 cell was typically 30 t/m2h. Presently, a full-scale process using the SIF technology is being installed for coarse apatite recovery.

Jan 1, 2003

By D. Hatfield, G. de Jager

"The rapid developments in computer vision and computational resources are creating new possibilities for the use of machine vision systems for industrial control. A number of commercial image analysis systems exist, and research into improved measurements of froth performance is ongoing. An integral part of the implementation of these systems is the validation of the relationship between image analysis measurements and flotation cell performance. This paper discusses the factors affecting concentrate flow and presents the results obtained from one such system with respect to its ability to estimate the flow of concentrate from a flotation cell.The relationship between froth flow speed and the rate of recovery of concentrate from a flotation cell was investigated on two industrial operations, both processing PGM (Platinum Group Metal) bearing ores. Results are presented that show a relationship between froth flow speed and concentrate yield."

Jan 1, 2003

By L. Bbosa

Positron Emission Particle Tracking (PEPT) and the Discrete Element Method (DEM) are used to investigate Power Draw in a laboratory scale tumbling mill. The mill is run dry in batch mode at different speeds using mono-size charge of glass beads, and is mounted along with a torque transducer to measure power. Particle tracking information from PEPT is used to reconstruct the motion of glass beads and infer the overall charge behavior, while DEM is employed to simulate particle motion and interaction, with collision mechanics calculated using the Hertz-Mindlin contact model. For PEPT and DEM data, the product of torque and average angular velocities in discrete cells are accumulated to obtain mill power. This method is found to be within statistical agreement with measured power for all tests. Spatial distributions plotted from this approach highlight the regions of the mill that draw the greatest power. A second technique to obtain Power Draw from DEM data which sums particle forces against the mill geometry is similarly found to accurately predict mill power with lower statistical error. Keywords: Power Draw, PEPT, DEM

Sep 1, 2012

By R. X. Li

The overall flow-sheet of producing chromium (III) sulfate is described in this paper. The suitable conditions of each process such as sintering, leaching, aluminum removal, reduction, and de-composition conditions were experimentally studied. The results show it is reasonable to produce chromium (III) sulfate with the flow-sheet pointed out in this research work. The final product is Cr2(SO4)3 solution contained 150~250g/L Cr.

Jan 1, 2014

By Z. K. Liu

Production of the amines collectors and cation surfactant gives out the liquid waste containing high COD (Chemical Oxygen Demand) and ammonium & nitrogen, which is difficult to be treated with conventional biological method to reach waste water discharge standard. In this paper an engineering practice of treatment on the liquid waste by the technology combined high effective microbe with A/O (Anaerobic& aerobic) process is presented. The quality of treated water comes up to class A national standard for discharging.

Jan 1, 2014

By L. J. Li, Q. Zhang, Z. H. Liu, Q. L. Chen

Phosphogypsum (PG) is an industrial waste from the production of phosphate fertilizer. The utilization of PG is restricted by its containing impurities, and the pretreatment is crucial to eliminating these impurities. The purpose of the research is to recycle pretreatment PG as raw material for preparation of a-calcium sulfate hemihydrate (a-HH) by salt solution method. The effect of pretreatment technologies of lime neutralization and washing on dehydration rate, phase composition and morphology evolution of a-HH were investigated by crystal water content analysis, XRD and SEM. Furthermore, the change of pH in the reaction process was also discussed in detail. The results show that the dehydration rate of conversion PG to a-HH increases and the corresponding induction period, crystal growth period and total time decrease with an increase in CaO dosage from 0.2% to 0.6%. In the presence of 0.4% CaO or 0.6% CaO, the a-HH presents a long hexagon-prism-shaped crystal with a purity of 94%, and the end face of a-HH presents polyhedron. The system pH sharply decreases with the reaction time under different CaO dosage, and the pH variation from the initial alkalinity to acidity. The main reason is that as the co-crystallized phosphorus dissolved and released HPO42-, and with the pH decreasing to 4-5, HPO42- transformed into H2PO4-. The dehydration rate of washing PG is lower than that of original PG. Compared with the original PG, a-HH with the larger width and smaller aspect ratio can be achieved from the pretreatment PG subjected to lime neutralization and washing, meanwhile the crystal surface is more smooth.

Jan 1, 2018

By M. Lundström, J. Aromaa, S. Seisko

"Gold dissolution was investigated in ferric chloride media, promoted as one of the most promising alternatives for cyanide-free gold leaching. The characteristics of gold open circuit potential (OCP) and its relation to gold dissolution rate was investigated. Furthermore, the reaction mechanism of gold dissolution in ferric chloride leaching was discussed. The effect of solution variables, [Fe3+] = 0.02–1.0 M, [Cl–] = 2–5 M, T = 25–95 °C and pH = 0–1.0, on OCP and dissolution rate were studied electrochemically using rotating disk electrode (RDE) and linear polarization resistance (LPR) method with ?cyc = 1000 RPM. The investigated gold OCPs in ferric chloride solutions were found to vary between 597 and 688 mV vs. saturated calomel electrode (SCE) and gold dissolution rates between 1.2·10–5–5.0·10–4 mol s–1 m–2. Increase in temperature (25–55 °C) and ferric concentration (0.02–1.0 M) changed OCP into more positive values, while increase in chloride concentration (2–5 M) decreased it. The logarithm of gold dissolution rate was shown to increase linearly with increasing OCP at the temperature range 25–95 °C, ferric concentration range 0.02–0.5 M and chloride concentration range 2–4 M. A notable increase in the gold dissolution reaction rate was evident at T > 55 °C. INTRODUCTION Currently cyanide leaching is the predominant method used in gold production from primary raw materials (Marsden and House, 2006). However, since the Baia Mare disaster in Romania in 2000, the use of cyanide has been the subject of international concern due to the toxic nature of the chemical posing a significant health threat if exposed to the ecological entities (Hilson and Monhenius, 2006; UNEP/OCHA, 2000). Therefore, several countries e.g., Costa Rica, Czech Republic, Germany, Hungary, Turkey, many states of the USA and provinces of Argentina, have started to ban or limit cyanidation via legislation (Laitos, 2012). Thus, alternative solutions, such as thiourea, thiosulphate, oil-coal agglomerates as well as halides have been investigated in order to replace cyanide as lixiviant (Adams, 2016; Aromaa et al., 2014; Aylmore, 2005; Hilson and Monhemius, 2006; Lampinen et al., 2015). Ferric and cupric chloride leaching have been reported to have advantage over cyanidation being capable to dissolve refractory gold minerals, without pre-treatment such as pressure oxidation or roasting (Angelidis et al., 1993; Lundström et al., 2014; Marsden and House, 2006; van Meersbergen et al., 1993). According to Aylmore (2005), 4% of publications for alternative lixiviants to cyanide in gold leaching were within category oxidative chloride processes including aqua regia and acid ferric chloride leaching. Further, some patents have been granted for ferric chloride leaching of gold (Abe and Hosaka, 2010; Lundström et al., 2016)"

Jan 1, 2018

By S. Kondratiev

Mechanism of the action of nonpolar physically adsorbed reactants in froth flotation is under discussion in the paper. It is shown that their basic influence on flotation includes removing of the kinetics restrictions of the flotation complex formation. Experimental data and practical evidence reported in the paper sustain the proposed mechanism. There are discussed potential dependence of the kinetics of dixanthogen formation on platinum and its influence on the induction time (IT).

Sep 1, 2012

It is well known that the crushing and grinding steps in the mineral processing of ores represent a substantial proportion of total energy, cost and carbon emission in mining. For instance a recent study calculated that 36% of the energy consumed by gold and copper producing mines in Australia was attributable to comminution (Ballantyne et al, 2012). Understanding this component of a business is essential in a world seeking to lower production costs, improve earnings and reduce its carbon footprint. The issue commands the attention and support of industry leaders in the mining sector, government, equipment manufacture, engineering design and research organizations. Furthermore, several researchers have often stated that globally, comminution processes consume between 3-4% of the world?s electrical energy production (Daniel and Lewis-Gray, 2011). In 2009-10, Australia?s Federal Government Energy Efficiency Opportunity (EEO) participants in the mining sector used 336.5 PJ, representing approximately 6 percent of Australia's total energy use. It is evident that the current practices of breaking rocks in tumbling mills are relatively inefficient (Fuerstenau and Abouzeid, 2002). Research and improved engineering design has established that a range of improved blasting, crushing and grinding techniques and flow sheets may lower project costs and carbon footprint. These include relatively simple process flow sheet strategies such as gangue rejection or pre-concentration prior to size reduction, a better combination of grinding technologies (both current and new systems), and selection of coarser grind sizes where ore and waste mineralogy allow. Yet, despite this systematic and detailed research, the industry remains somewhat reluctant to implement these strategies. CEEC (Coalition for Eco-Efficient Comminution) was established in 2011 to support knowledge sharing and change in an area of high-energy consumption for the global mineral industry. CEEC is a not-for-profit industry company, funded by grants from world wide industry companies, whose mission is to accelerate knowledge and technology transfer in the field of energy-efficient comminution. The key benefit to the mining sector arising from CEEC?s activities will be an increase in the rate at which more energy-efficient comminution data sets, processes, and technologies are developed, demonstrated, shared and applied. This will contribute directly to the industry?s target of reducing operating costs and carbon emissions. CEEC International Ltd and JKTech Pty Ltd teamed together to facilitate the inaugural CEEC Workshop, in June 2012. The purpose of the workshop was to produce a roadmap to provide guidelines for how (1) operations can achieve best EEC practice in the short to medium term, in collaboration with vendors, engineering companies and other service providers, and (2) what R&D is needed to achieve paradigm change in EEC in the medium to long term, e.g. 75% reduction in comminution energy in 10 years.

Sep 1, 2012

By K. W. Stöckelhuber, A. Wenger, H. J. Schulze

"An important elementary step of the flotation process is the forming, drainage and rupture of a thin intervening liquid film between bubble and mineral particle.After the encounter of the bubble with the solid surface a wetting film is formed. The initial thinning of this film is driven by the capillary pressure inside the bubble. When the film has reached a certain thickness rupture can take place.There are two possible mechanisms describing this process:-, Growing fluctuation waves (spinodal dewetting) on fluid interfaces under the influence of any kind of attractive forces (electrostatic, van der Waals). -, Nucleation inside the film.Metastable wetting films on negatively charged, hydrophobic glass surfaces (gaseous phase methylated), or on hydrophilic, positively charged glass surfaces (with Al3+ ions), have been analysed by means of the kinetics of film thinning according to the Reynolds law. These experiments demonstrate that both mechanisms can be responsible for the rupture of a thin wetting film. In the case of hydrophobic surfaces the nucleation mechanism is preferred; in the case of opposite charged silica surface the capillary waves mechanism due to an attractive electrostatic double layer force between silica and air bubble takes place.Hereby the existence of a long range hydrophobic force. on a hydrophobic surface can be excluded. The apparent interaction can be explained by the presence of gas nuclei formed on heterogeneous surface sites. The results provide deeper insight into the mechanisms of wetting film stability, adhesion process in flotation and droplet coalescence."

Jan 1, 2003

By Megha Patel

"The objective of this project was to investigate the application of Prompt Gamma Neutron Activation Analysis (PGNAA) technology to provide real-time on-belt elemental analysis of feed ore in base metal sulphide processing, in this case at the Mount Isa Mines Zinc-Lead Concentrator Heavy Medium Plant (HMP). After initial exploratory testwork proved successful, a Geoscan On-Belt Elemental Analyser was retrofitted onto the existing HMP feed conveyor. Dynamic calibration of the Geoscan was conducted based on laboratory XRF analysis results of the HMP feed conveyor hammer autosampler samples from May to November 2013. Comparison of the Geoscan results to the laboratory XRF analysis results during and after dynamic calibration indicated the technology had acceptable accuracy to be incorporated into HMP process control. The variation between the two sets of data includes all primary sampling, sample preparation and XRF analysis errors as well as the Geoscan errors themselves. The Geoscan instrument precision must be calculated separately through a duplicate sampling campaign and independent laboratory analysis before extending the scope of its range of application beyond HMP process control. The expected benefits of integrating the Geoscan real-time data into HMP process control are optimised HMP metal recovery, improved cost efficiency and improved stability of the downstream processes (milling and flotation). Utilisation of the Geoscan will also enable improved feedback to mines on grade control and dilution, and provide additional information on individual ore types when fed as campaigns to HMP."

Jan 1, 2014

By Genrich A. Denisov

Principles of ecologically friendly geo-technologies construction are formulated on the basis of the works of the leading scientists in the field of rational processing of mineral resources of the Russian Academy of Sciences. One of these concepts is a new direction in rotational disintegration of mineral and technogenic raw material with the purpose of effective subsequent enrichment. A large amount of practical experience has been accumulated in the industry on selective destruction by application of vibrational method on initial material with consideration of its physical-mechanical properties and mineral structure. This method is successfully realised in a conic inertial pulverisation devices constructed by Mekhanobr Institute (St. Petersburg). A new construction of conical-inertial pulverisation with a modification of disintegration force has been developed recently at Mekhanobr Institute. It allows, in some cases, to increase selectivity of subdivision and to avoid over-disintegration. Advantages of “wet” subdivision methods in conic inertial disintegration devices are proved. The efficiency of such subdivision can be increased due to rational use of the phenomenon of a dislocation-dynamic diffusion. Its advantage is proved by the effect on disintegrated material by frequency-modulated variable electrical fields of low power. It was shown in industrial conditions, that the productivity of the spherical mill can be increased by 10 %, and that it also prevents ecologically harmful surface active substances (SAS) in milling zone and it reduces the dust content in the air. The techniques of tentative estimation of efficiency of various proceedings technogenic materials and their classification are created. The scientific fundaments of rational, ecologically friendly technology of processing and regeneration of various kinds of technogenic raw material are developed. A number of effective technologies on processing of wastes is developed and inculcated in concentration factories and metallurgical factories.

Jan 1, 2003

By Brian Hart, Liuyin Xia, Staman Dimov

The recovery of rare earth elements (REE) is fast becoming of significant interest globally. Modern research and development programs (outside China) towards the optimization of REE mineral recovery by flotation have been lacking. Due to the mineralogical nature of many hosting deposits, the separation and recovery flotation flowsheets can be very complex. As part of a research project, a selected suite of hydroxamic acid collectors (Naphthoyl, Cyclohexyl, Benzoyl, Octyl, Terta-butyl benzoyl, Salicylic) were tested in order to examine their potential for recovery and selectivity. Micro flotation tests were conducted on a feed sample, recovery and grade of the products were used to evaluate their relative flotation efficiency and selectivity and these results (flotation with the hydroxamate collectors) were compared to a phosphoric acid/sulphonate collector mix(shorten as "mixed"). In the testing, the flotation response with the hydroxamate collectors was significantly better than the "mixed" collectors on freshly ground (no slimes removed) samples. Furthermore the tests revealed that for most of the hydroxamate reagents tested, their dosage requirements to achieve recoveries at the same levels was less than that for the "mixed" reagents. Product assays show that recovery of both La and Ce is significantly better for using the salicylic hydroxamate and that Nb, Y and Zr recovery are favored by using octyl hydroxamate. These results indicate mineral flotation selectivity could be achieved by using selective hydroxamtes. Spectral fingerprinting by TOF-SIMS surface analysis has allowed for the identification of reagent species. TOF-SIMS surface analyses of grains analysis confirmed that REE bearing grains reporting to the concentrates are doing so in response to collector attachment whereas grains reporting to the tails are doing so in response to a lack of collector. The TOF-SIMS surface data bas been used to examine the factors promoting flotation stream partitioning.

Jan 1, 2014

By Khoi Nguyen, Luke Keeney

"Hardness" is an important yet diverse material physical property and is a key parameter in the mining industry in fields such as comminution, geotechnical and blast modelling. Several laboratory and field based measurement techniques exist to measure hardness (e.g. Point Load Testing, Vickers, Brinell, A*b, BMWi, UCS), all are designed for specific applications. Current tests are generally destructive and require specific sample preparation procedures which results in high cost tests that are not conducted in adequate quantities to map hardness across an ore body. The EQUOtip rebound hardness tester is a device that has been developed for application in ore body hardness domaining within the AMIRA P843 GeMIII Research Project. The rebound hardness test is non-destructive and suitable for application on half and whole diamond drill core. Data acquisition protocols and a data processing software application (EQProcess) have been developed to facilitate routine collection of comparative hardness information. This paper outlines the data acquisition and processing methodology and provides application examples of defining relative hardness domains in different geological deposit styles.

Jan 1, 2014

By Carmina Quintanar, Mario Palominos

"The mining industry is currently facing significant challenges to identify and adopt sustainable collector chemistry that effectively recover value minerals in difficult-to-process low-grade resources. These are typically characterized by complex mineralogy and the presence of significant amounts of penalty gangue sulfide minerals, especially pyrit which is a challenge to separate from value minerals at many major mine operations. Three chemical strategies for dealing with gangue sulfides and penalty elements are: a) selective flotation of value minerals while rejecting penalty minerals in the whole circuit, b) rejecting penalty minerals in an appropriate part of the circuit using selective depressants, c) using a combination of selective collectors and depressants in appropriate parts of the circuit. This paper will evaluate different strategies for dealing with those penalty elements and propose the most efficient alternative. New products and application technologies have been developed in the past 25 years by Cytec for implementing these strategies as dictated by the particular needs of a given plant. However, in recognition of the growing interest in meeting the sustainability challenges, Cytec Research and Development have been focused in the development of greener products (collectors, modifiers and frothers) and processes using FLOTATION MATRIX 100TM approach used to develop the optimal collector system for each specific ore. An overview of these new developments is given in this paper using case studies of application of selective collectors and polymeric modifiers including the newer, greener chemistries."

Jan 1, 2014

By A. V. Kozub, D. O. Sharkovsky, R. I. Ismagilov

"Due to complex mineral composition and fine ingrained nature concentration of iron ores deposited in Mikhailovskoye mine field requires application of wet magnetic separation to produce 65–66% Fetotal and 8.2–8.6 %SiO2, concentrate with 90–94% of material being –0.044micron grain size. Higher specific consumption of ROM, increase of production costs with concurrent reduction of output - those are inevitable side effects of desired concentrate grade improvement. Large-scale complex analysis and surveys have been carried out aimed at concentrate grade improvement with concurrent output increase. Classification of feed in hydraulic cyclones (hereinafter referred to as hydrocyclones) has been the bottleneck for improvement of processing throughput and concentrate output. Hydrocyclone classification efficiency is 50-60% and further improvement is practically impossible. Actual circulating load may achieve as much as 500-600% while the optimal rate is 200-250%. Application of wet fine screening has been considered to improve iron ore concentrate grade. Objective of this work is to design processing flow diagram for unoxidized ferruginous quartzites with implementation of wet fine screening. Large-scale tests have been run in Crushing and Concentrating Plant with application of wet fine screening stage. These tests included application of wet fine screening in 2 and 3 stages of classification to separate desired grain sized material; replacement of hydrocyclone classification with fine screening; application of fine screening as additional stages to concentration process and screening of final concentrate. Testing Methods. EXPERIMENTS AS WELL AS THEORETICAL RESEARCH HAVE BEEN APPLIED FOR THE PURPOSES OF THIS WORK; INCLUDING MAGNETIC, GRAIN-SIZE AND CHEMICAL ANALYSIS OF CONCENTRATION PRODUCTS. MODERN ANALYTICAL DATABASE HAS BEEN APPLIED TO STUDY WET FINE SCREENING FEATURES, MINERAL AND PHYSICAL COMPOSITION OF CONCENTRATION PRODUCTS. Work Results: - analysis of wet fine screening application for iron ore concentration. - technological solutions enabling to improve slurry classification of fine ingrained low magnetic iron ore have been developed. - effective process flow diagram including fine screening has been designed based on the feasible and reasonable arrangement solutions."

Jan 1, 2018

By E. V. Koporulina, E. L. Chanturiya, M. V. Ryazantseva, E. S. Zhuravleva

"The morphology of the surface of sphalerite, galena and chalcopyrite and the adsorption of butyl xanthate under conditions of preliminary treatment of minerals by the products of water electrolysis were studied using atomic force microscopy (AFM) and Diffuse Reflection Infrared Fourier Transform Infrared Spectroscopy (FTIR). It was determined that practically all types of treatment by electrochemically modified water (a product of non-diaphragmatic treatment, anolyte and catholyte) lead to an increase of surface roughness of the studied minerals due to formation of small rounded shape particles. In contrast to that, after treatment of chalcopyrite by anolyte, its surface becomes smoother. Various effects of treatment by the water electrolysis products on the adsorption of chemical and physical forms of butyl xanthate on the studied sulfides were established. As a result, the efficiency of the complex of AFM and FTIR methods, as one of the ex-situ approaches for monitoring the surface state of sulfide minerals and direct investigation of BKx adsorption products was demonstrated.INTRODUCTION In mineral processing, copper-zinc sulfide ores are one of the most complex products in view of their mineral composition, fine dissemination, complex inter-growth and the proximity of the technological characteristics of copper, zinc and iron sulfides. For the most complete disintegration, fine grinding of ores to a size of 0.074-0.044 mm is necessary. Consequently, the main method for processing of such ores is flotation, which bases on the difference in physical and chemical properties of the mineral surfaces, in particular, degree of wettability. The separation of copper and zinc minerals and their separation from ferrous and other sulfides, sulfosalts and rock mineral is a very difficult task (Chanturiya, 2000). For the successful separation of copper and zinc minerals in the appropriate selective concentrates, it is necessary to find conditions for the most complete liberation of ore and rock-forming minerals and for increase the contrast in physical and chemical properties of their surfaces. Despite significant progress in the processing of copper-zinc sulfide ores, the problem of the selectivity of the separation of the main ore minerals has not yet been fully solved and requires innovative approaches (Chanturiya, 2015). To date, various methods of preliminary energy processing of complex ores are used: magnetic pulse treatment, impact by high-voltage nanosecond pulses, electrochemical effects (including products of water electrolysis (Chanturiya et al., 2014; Bunin et al., 2015; Chanturiya et al., 2014a; Chanturiya et al., 2016), processing with flotation reagents, etc. Electrochemical treatment of water in various modes allows to obtain products of electrolysis with different oxidation-reduction properties: acid anolyte with a high oxidation potential and dissolved oxygen content, an alkaline catholyte with high reducing properties and a product of non-diaphragmatic treatment with enhanced reduction properties."

Jan 1, 2018

In flotation, particulate materials are separated by controlling the hydrophobicity of the particles using appropriate collectors. In this regard, contact angle (?) is the most important process variable. However, the flotation models used in industry today do not include ? as a parameter. As result, flotation circuits are designed based on the first-order flotation rate constants (k) determined from laboratory experiments. A problem with this approach is that laboratory experiments usually give substantially higher k values than achievable in full-scale operations, which makes it difficult to use the model for plant design. In the present work, we have developed a model from first principles using both surface chemistry and hydrodynamic parameters, such as ?, ?-potentials, surface tension (?), particle size, energy dissipation rate, etc. The basic approach is similar to the one developed previously for bubble-particle interactions under laminar flow conditions (Yoon and Mao, J. Colloid and Interface Science, 181, 61, 1996) except that the model parameters have been modified by considering the turbulence in a flotation cell. In addition, the model describes the recovery processes in froth phase, including bubble-coarsening due to coalescence. Based on this model, we have developed a computer simulator (FlotSim) that can be used to design flotation circuits from the mineralogical (or liberation) data on the feed and the hydrodynamic characteristics of a flotation machine. Since the model is dynamic, it can also be used for process control. Further, the simulator has predictive capacity as it is based on a first-principles model. The model-based simulator has been validated in a carefully controlled bench-scale flotation experiments. Keywords: flotation kinetics, flotation model, contact angle,?-potential, size-by-size recovery, liberation, DLVO theory

Sep 1, 2012

By Chandra Sekhar Gahan

The present study aimed to investigate the depyritization of coal using iron oxidizing and sulphur oxidizing acidophilic chemolithotrophic microorganisms in an iron free 9K growth medium at varying pulp densities. Three different coal samples used in the shake flask study from three different countries such as domestic anthracite (Korean), Indonesian and Chinese lignite. Experiments were carried out in batch at a controlled temperature of 35 °C and varied pulp densities of 8%, 10% and 12% (w/v) with a working volume of 100 ml containing 10 ml of microbial inoculum and 90 ml of the iron free 9K growth medium. Coal samples were crushed and ground to fine size fractions <100 microns by attrition mill wet grinding. The progress in the experiments were followed by the regular measurements of pH, redox potential, viable planktonic cell count, residual Fe2+ ion concentration, amount of acid addition and amount of slaked lime addition. The pyritic sulfur removal percentage varied between 90-95% with highest sulfur removal with China coal (95%) followed by Korean Coal (93-94%) and slightly lower level for Indonesia coal (90%). However the pyrite oxidation was highest for Korean coal ranging between 78-80% followed by a similar level of pyrite oxidation of 50-61% for the Chinese and Indonesian coal. It was found that 10-12% pulp density would be fairly feasible for all the different coals tested leading to an economical process. Another benefit from this study is the iron free 9K growth medium, which will reduce the operation cost and overall it?s an environment friendly process.

Sep 1, 2012