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By I. I. Beloglazov, G. A. Iusupov, A. Ju. Feoktistov

"The aim of this paper is to study the numerical modeling of the crushing process in a jaw crusher with complex motion jaws using Discrete Element Method (DEM). The main goals are to ensure the conformity of numerical simulation results to the experimental data, optimize the operating modes and the crusher design and develop automated verification and calibration methodology. It is offered to use automated selection of mathematical model parameters using large- or laboratory-scale experiments instead of deriving parameters from conventional intensive material tests (e.g. drop-weight test). Experimental data were obtained from a large-scale crusher designed and manufactured by the company “Mekhanobr-Tekhnika”. Both jaws have their drive shafts located asymmetrically; one jaw is driven in the upper part, the second at the base. The crushing process involves fragmentation of single smoothed rectangular granite particles of the same weight. During the experiment, the required parameters such as particle size distribution were obtained for further computer simulations. Based on the obtained experimental data, the Rocky DEM model was built. Simulation breakage parameters were calibrated using automated parameter selection methodology based on multiple set of parameter-controlled simulations. A good correlation of the experimental data and numerical simulation data was obtained. The methodology in combination with well-known capabilities of simulation modeling will help reduce the research time in the development of new mineral processing equipment.INTRODUCTION Preparation of rock mass for enrichment includes the power-consuming processes of crushing and grinding. Initial rock mass crushing is performed by means of drilling and blasting operations. To reduce the average size of a rock piece, primary crushers, mostly jaw crushers, are further applied. The advantages of the jaw crusher are simple design, easy maintenance and repair. One of the drawbacks is large oscillating masses and, thus, high power consumption during operation (55 - 200 kW). Jaw crushing simulation will help optimize the crushing process and improve further rock transportation and processing performance."

Jan 1, 2018

By John A. Herbst

The Mineral Processing Industry needs accurate Production Simulators for the design of future plants and expansions. To achieve this, these simulators should not only provide an accurate portrayal of the dynamics of individual pieces of equipment they should include the impact of discrete stochastic events such as scheduled and unscheduled maintenance so the relationships between availability, equipment sizes, and plant capacity are understood. To provide such a tool accurate dynamic Population Balance Models need to be combined with solid discrete event modeling. The current paper provides a description of how these two disparate modeling techniques were combined and the associated benefits from this combination. Keywords: dynamic plant simulation, population balance models, discrete event models, prefeasibility and feasibility studies, plant design and expansion

Sep 1, 2012

By F. M. Isik

Due to not to being our own sources, some energy sources such as oil and natural gas which are used frequently, are not reliable energy sources for our country. Coal is an important energy source that Turkey also has a certain reserve as many countries have. To be able to use for many years the reserves of this source that comes from fossils, there is a great need to make more investigation and development activities on it. On behalf of using more productively the current sources, briquetting facility is represented that commenced production in The Aegean Lignite Establishment in 2005 which is in Manisa, Soma. This facility is a part of General Directorate of Turkish Coal. This facility is run by Soma Coal Establishment that works in return for royalty in a licensed field that belongs to TKI. As the demand of market for 0.5 mm dust coal diminishes, we had to accumulate and stock unmerchantable dust coal. Besides, we have intermixed 0.5- 1 mm powder coal and 0.1 ? 0.5 mm fine powder coal obtained as a result of washing in coal washer with thermic coal with low price as we could not find a client in the market. In this study, the production stages of briquette coal with high quality produced as a result of pressing by mixing 0.5- 1 mm powder coal and 0.1 ? 0.5 mm fine powder coal with molasse and lime, quality control, and data?s obtained about calories and solidity of products were presented. By briquetting of 0.5- 1 mm powder coal and 0.1 ? 0.5 mm fine powder coal washed in coal washer, it became possible to sell these coals on a high unit price and by providing the demand of coal of the market, we contributed to productivity of our firm. Keywords: briquette coal, briquetting, producing stage

Sep 1, 2012

By Dominic Howarth, Diana Drinkwater, Don McKee

"The pressures on mining and minerals education at the tertiary level are well known. Within Australia, for example, the number of undergraduate mining engineering courses with 30 or more students in each year has reduced to three (University of Queensland, University of New South Wales and Curtin University). Similar declines in both student numbers and participating institutions are evident in many other parts of the world, and notably in USA and most countries in Europe.An in depth study of the Australian sector was conducted in 1997/1998, resulting in the Back from the Brink report (Carter 1998). The Australian situation was summarised as follows.Australia’s minerals education system, in its current form, is fragile and is in no position to seize the opportunity (i.e. world leadership in minerals education) and is more likely to succumb to the threat.Current trends include:- an acute shortage of talented academic staff, as a result of University remuneration packages having become hopelessly uncompetitive with those in the minerals industry;- small student populations and high relative costs, making mineral specific courses vulnerable to closures, when Universities are under extreme cost pressures; this situation will be exacerbated if enrolments drop in response to, say, a cyclical down turn in the industry; and- under-resourcing of minerals departments because of their comparatively small size, making these departments incapable of delivering top class teaching in all aspects of their courses, despite being excellent in some areas.Most of the Australian issues identified above have direct parallels in other countries.The most common response of institutions to the threats is to seek strength, and in some cases survival, through various forms of linkages and networks. A number of these associations, which are frequently defensive in nature, are outlined in the paper."

Jan 1, 2003

By P. Matias

The study involved two projects that will produce copper concentrate and may have their operations integrated. Transport by trucks, conveyor belt, and the equipment called RopeCon were evaluated as options for the ore transport between the sites. A rainforest stretch, that Vale S.A. demands to preserve, is situated between the projects. It was suggested to further review RopeCon because it presents minimal interactions with the environment. To design the preliminary system layout, a research was done on the rainforest cover height data, but the information found was scarce and imprecise. For preserving the local forest, the use of this data would conduct to the oversizing of RopeCon towers and, consequently, overestimation of its costs. For the acquisition of reliable information, a method was developed using local data acquired through airborne laser survey. The volume between the digital surface and terrain models was calculated to generate a surface representing the forest cover height. It was revealed, by plotting the points obtained from this surface, that 85% of the vegetation is below 25 m. This height is suggested to review the preliminary project with a more accurate design of the equipment towers, thus reducing its costs estimates. The method permits the precise location of the large trees, making easier to find a pathway, for linear-shaped facilities, that would minimize the creation of vegetation-free zones as a measure to protect equipments against falling trees and forest fires. Keywords: forest cover, mining projects facilities, digital models, airborne laser survey

Sep 1, 2012

By Janne Kytökari

Controlling a wide range of minerals processes with single control system is an ordinary way to operate in mines all over the world these days. However the potential of these systems is not yet fully recognized nor utilized. The key issue is to manage the information in a way that enables automating the day-to-day tasks, quality control and safety functions. At the same time it provides means for optimization and constant improvement of processes creating a working environment where the system helps employees to do their key tasks instead of searching, modifying, and transmitting the huge number of information arising every day. The distribution of control system nodes enables the other processes to run heedless of a problem occurring in one of the sub-processes. Also the control room can be in remote location such as in large city removing the need to travel substantially long distances to plant sites every day. When all essential information is brought to the same place there is less risk for a mishap to happen due to information breaks that are often the cause of them. One of the biggest single reasons that result in production losses are break downs of machinery usually caused by normal wear, misuse, incorrect utilization rate etc. For this reason it is important to measure the condition of machines using vibration measurement and diagnostics. By moving from failure or time-based maintenance towards predictive or performance maintenance generates eventually a steady and predictable process but also results in significant long term savings. The mineral process at Talvivaara mine is based on bioheapleaching, whereby metals are leached from ore as a result of bacterial action. Bioleaching is a fairly new technology used in metals recovery. Therefore it is important for the mine to collect and analyze data from different stages of the minerals process. Talvivaara mine?s Metso DNA system has integrated machine condition monitoring and information management. These are not only necessary but also crucial in environmental conditions where the outside temperature can drop below -35°C, where ice and snow dominate the landscape and impact the equipment for four months a year and where distances between equipment can be up to 7.5 kilometers. Keywords: DCS, analyzer, machine condition monitoring, automation, remote communications, optimization, mining, metso DNA, Talvivaara

Sep 1, 2012

By P. Raghavan1

Reverse froth flotation experiments were carried out in the laboratory using two different types of kaolins for the separation and removal of coloring titanoferrous impurities from cryo-filtered clay after subjecting to high shear pre-treatment. This high shear pre-treatment consists of high shear agitation of a high solids clay slurry with the dispersant (high shear dispersion, HSD) followed by high shear agitation with the collector (high shear conditioning, HSC). After this pretreatment, the slurry is diluted and reverse flotation is carried out. One sample is from, Gujarat, India (Mamuara clay, ?MC?) while the 2nd sample is from Amberg, Germany (AKW clay, ?AC?). While MC consisted of 89% particles below 2µm and analyzed 1.06% of TiO2 and 0.29% Fe2O3 and measured a brightness of 83.4 %ISO, the corresponding values for AC are 67% below 2µm, 0.3% of TiO2? 0.49% Fe2O3 and 83.4 %ISO. The flotation performance is found to be greatly influenced by the conditions of high shear treatment. Important variables are HSD intensity (rpm), HSD time, HSC intensity (rpm), HSC time, HSD/HSC time ratio, ?HSD+HSC? total time etc. Higher shear intensities favor both the impurity liberation and collection. For both clays, it could be shown that impurity removal increases as total pretreatment time (?HSD +HSC? total time) increases up to a certain limit. For MC, the HSD time was only half or less than that of HSC time, while for AC, HSD time is at least twice (or more) than HSC time which is just an opposite manifestation. This is believed to be due to the striking differences between these two clays. Most importantly, the shear frequency is found more influential than the shear rate for the overall flotation performance for both clays. Interestingly, at high shear frequencies, i.e., when a stirrer with more number of teeth on the rotor is used, the ?HSD+HSC? total time is greatly reduced. Again, increased shear frequency helps to reduce flotation time and significantly improves flotation performance. At optimum conditions, product titania reduced to 0.35% for MC whereas the same reduced to 0.13% for AC. The product of flotation of MC measured 85%ISO brightness while that of AC measured84.6%ISO thus enhancing the value of the final product. It could also be established that the high shear pre-treatment shows better flotation performance than that due to collector dosage. Keywords: high shear dispersion, high shear conditioning, titanoferrous impurities, shear rate, shear frequency, brightness, clay recovery, Mamuara clay, AKW clay

Sep 1, 2012

By Fengnian Shi

In the current energy-sensitive world, sustainable development in the mineral industry will require new, better and more efficient processes. Novel comminution methods, which offer the prospect of achieving the required outcomes of size reduction and mineral liberation at lower energy consumption, are continually being sought. In the past five years, extensive research using high voltage pulse electrical comminution technology has been carried out at the Julius Kruttschnitt Mineral Research Centre (JKMRC), in collaboration with selFrag AG. The major outcome of this research is the development of the concept of pre-weakening ore particles by electrical comminution procedures to reduce the energy consumption in the downstream grinding circuit. The research has also verified the preferential liberation of valuable minerals by electrical comminution. Given the advantages, several potential applications of electrical comminution in the mineral industry are proposed, including AG/SAG mill feed pre-weakening, pebble treatment, ball mill feed pre-weakening, early recovery of the liberated valuable minerals, crack/micro crack generation for improved leaching, and smelter slag treatment. For the mineral industry to utilize electrical comminution, two emerging issues identified from the research need to be address. They are the energy consumption by electrical comminution in the locked cycle treatment and the facilities scale up necessary to move this technology from the laboratory to the plant. Keywords: high voltage pulses, electrical comminution, energy efficiency, mineral liberation

Sep 1, 2012

By Z. G. Li

The large-scale vibrating screen has been applied widely in coal industry and other industrial areas as a kind of important device. As vibration mechanical device, it works very hardly and works in very bad environment so that the structure of screen is damaged easily. Therefore, it is very important that how to detect the fault of structure as early as possible to make the repair schedule reasonably and economically and to avoid the body hurt and device damage. As a kind of important structure of vibrating screen, the lower crossbeam is the main carrying structure and it is easily damaged, so it is regarded as a researched object in this thesis and it is tested under the load in the laboratory. Based on the test, acoustic emission wave signals can be got-ten by modern acoustic emission testing technique. Then, the ?wavelet packet - energy? from the characteristics of acquiring signals is used as neural network input vector. In the BP network structure design, the design of a hidden layer with variable number of BP network is established. Based on the error by contrast, the best nerve number can be identified in the hidden layer. Through integrated analysis, using Levenberg-Marquard BP study algorithm, network-training errors are relatively small, the acoustic emission signal is used in BP neural network as a pattern of recognition. In Matlab6.5, neural network model identification is created and taking advantage of nonlinearity and the ability of learning and memory of Neural Network, this model is fixed by training structure of network with training samples. The work presented shows that acoustical emission signal processing and research on early fatigue fault diagnosis based on the wavelet and the neural network is viable.

Jan 1, 2014

By G. Weingrill, H. Flachberger, J. Neubacher

The so called Bublon®-process is an innovative process for the controlled expansion of volcanic glasses such as Perlite and for thermal treatment of other minerals. In this manner, functional light fillers with astonishingly altered physical properties can be manufactured. In contrast to conventional Perlite expanding processes no fossil fuels are burned in order to achieve the expansion. Instead, the feed material is heated electrically mainly by radiation based on heat transfer from heating elements. The main advantage is the better controllability of the production process. Therefore, the heating elements are segmented along the flow of the particles, hence in direction of the ongoing expansion. Overheating of the particles, which ultimately leads to the destruction of the particle surfaces and consequently decreasing the quality of the expansion product, can be reduced significantly. Due to flow characteristics and settling behaviors of fines the lower particle size limit of the feed in this process is restricted to not less than 100 µm. Otherwise process instabilities are to be expected. Manufacturing industry demands light and fine hollow microspheres. Therefore, a proven cooperation between Montanuniversität Leoben and Bublon GmbH was formed to develop a new process called ‘Bublite’. This issue was addressed by changing the conveying principle into a pneumatically conveying system transporting particles from the bottom to the top of the kiln by the means of a drag flow. This approach makes it possible to handle the difficult flow patterns in the kiln and to control the retention time of the particles in the heat transfer zone. As a result, it is now possible to expand very fine Perlite particles into a high quality functional lightweight filler with a glazed-closed surface. The dependence of the polymer industry on importing this kind of fillers from overseas can be reduced by producing it close to sites of demand. Also the Perlite mining and processing companies benefit from this technology because the mine lifespan and the output of the processing plant can be increased.

Jan 1, 2018

By A. Boehm

Mineral selective flash roasting (Steiner process) in oxidizing atmosphere was tested successfully for the efficient low intensity magnetic separation of siderite from ankerite and other gangue minerals within the ore of the Steirische Erzberg, Austria. The calcium, magnesium and manganese containing siderite turns selectively into a ferromagnetic oxide phase while ankerite remains paramagnetic. The expulsion of CO2 increases the volume specific surface depending on the selected temperature. Unlike pure iron oxides absorbing SO2 below 530°C, the calcined siderite (enriched in the magnetic product of the Steiner process) acts as a sorbent for SO2 between 500 and 820°C. The effect was studied by thermogravimetric analysis and particle bed tests complemented with neutron thermo diffractometry (D20/ ILL). The energy input was simulated with the help of a tube furnace. The composition of the artificial combustion gas permeating the bed was close to that measured in pilot scale tests (6 % CO2, 12 % O2, 700 vpm SO2). The evaluation of data relating the SO2 variation in the off gas monitored by electrochemical cells to the actual phase composition revealed an intermediate ferrite phase as absorber. During the rapid decomposition in oxidizing atmosphere starting at 500°C the occurring siderite alters to a (CaO, MgO, MnO)Fe2O3 ferrite as an intermediate phase accompanied with sudden SO2 absorption. SO2 disintegrates the ferrite structure forming MgSO4 and MnSO4, taking Fe2O3 as a catalyst. Ankerite (enriched in the non magnetics of the Steiner process) starts to absorb at temperatures above 1000°C forming gypsum. The findings support the SO2 controlled operation of the Steiner process by ?autodesulfurisation?. It explains aspects of the SO2 implementation reactions within off gas recycling in Austrian sinterstrands. Keywords: magnetising flash roasting, neutron thermo diffractometry, SO2 absorption, siderite, ankerite

Sep 1, 2012

By J. A. Sweet

The issues facing graduate training in the mineral processing industry are not too different today from those that prompted the initiation of the Anglo American Platinum Graduate Development Programme (AGDP) in 2002. Graduate metallurgists in South Africa enter the industry from different undergraduate programmes at various tertiary institutions, and so the knowledge and skills of the young graduates varies. Further, the geographical expansion of the industry combined with the downsizing of business units means that there are fewer opportunities for young graduates to be mentored through their first few years on site. Anglo American Platinum chose to address these issues by implementing an intensive, structured graduate training programme for all their new metallurgical graduates, known as the AGDP. The first two years of experience of the AGDP, from the viewpoints of both graduates and lecturers, were presented to the mineral processing community at the IMPC in Turkey in 2006 (Sweet et al, 2006). From the beginning, the programme was structured in a modular fashion to include a basic technical ?toolbox? including statistics, the scientific method and sampling protocols, while the mineral processing content comprised advanced learning in comminution, classification and flotation (later extended to include hydrometallurgy). Technical communication ? both written and verbal ? was included from the start. The programme was focussed very strongly on site work (?learning by doing?), with a major integrated site campaign conducted and analysed by each cohort. In 2012 the AGDP will accept its ninth cohort into the programme. This paper describes how Anglo American Platinum and the University of Cape Town have developed and adapted the programme over the last few years, in response to the challenges of the global recession, skills retention, and the changing operational needs of the company. The programme, which was drawn up to accommodate around 15 concentrator-only graduates, now accommodates 35-40 concentrator, smelter and refinery graduates annually. The programme has also been modified to facilitate new graduates spending most of their first year on the operations. The benefits of the programme for Anglo American Platinum have been tangible, and will be discussed in the paper. Keywords: graduate training, technology transfer

Sep 1, 2012

By C. Gomez, J. Finch, R. Dalhke, J. Torrealba-Vargas

The velocity of gas passing through a flotation cell can be estimated by collecting bubbles by natural buoyancy in a closed tube and measuring the rate of pressure increase. The governing equation is derived and verified. Single- and two-tube gas velocity sensors are described. The latter design permits a correction for bulk density and level change during signal collection.

Jan 1, 2003

By Chris A. Fleming

"The ability to recover cyanide from gold plant tailings has been known almost as long as the cyanidation process has been practiced, but there has been little incentive to process tailings in this way in the past. With the development of technologies that make it possible to recover and recycle free or complexed cyanide directly from gold plant slurry tailings, which indicates, on paper at least, significant cost savings compared to cyanide destruction, coupled with the introduction of legislation to seriously limit the discharge of cyanide to the environment in most gold-producing regions of the world, many companies are evaluating the cyanide-recovery alternative.There is arguably an even more compelling reason for mining companies to consider cyanide recycling. With the growing storm of negative public opinion that the use of cyanide in the mining industry is attracting - following several highly publicized spills over the last couple of years - the time has come for the gold industry to demonstrate environmental diligence and stewardship in the use of this commodity that is so vital for their industry. There is no doubt that the widespread implementation of cyanide recycling will reduce the impact of the cyanidation process on the environment, both by reducing the risk of spills (with less cyanide being transported from manufacturing plants to gold mines), and by reducing the loading of toxic and nontoxic metals and ions in the tailings.This paper briefly discusses the pros and cons of the different processes that are available for the treatment of gold plant tailings to regenerate and recovery cyanide for recycling, and presents a techno-economic argument for the incorporation of this technology into many gold plant flowsheets today."

Jan 1, 2003

By Venkataramana Runkana, Pradip Gautham, Beena Rai, Sreedhar Reddy

"IT enabled platforms are the key to provide an integrated view of the business activity or an enterprise as a whole. Attempts to integrate all functions in an enterprise such as mine-to-market initiatives, wherever and to whatever extent implemented, have provided significant benefits to the industry. The transformative potential of IT enabled integration platforms is illustrated in this communication from our own work in this field. TCS PREMAP (Platform for the Realization of Materials and Products) is a knowledge-driven engineering design and development platform which leverages modeling and simulation and artificial intelligence into the engineering design process. We illustrate the customization of this generic platform for the design and optimization of mineral processing plants in an integrated manner. TCS PEACOCK (Process and Equipment Analytics for Optimization and Control) has been developed to enable automation of data analytics in the operating plants. We illustrate its utility and power in improving the plant performance with the help of case studies from our work on pelletization of iron ores and optimization of flotation plants. INTRODUCTION We are living in an exciting digital era. With the advent of cloud computing and social media on the one hand and rapid advances being made in several research areas of interest to us in the minerals and metals industry such as artificial intelligence (AI) & machine learning, robotics, unmanned vehicles including drones, big data analytics, 3D printing, sensor technologies, renewable energies and internet of things (IoT), many disruptive transformations in our industry are on the horizon. Recent advances in information technology (IT) and knowledge engineering, in combination with appropriate domain expertise, that is, our enhanced understanding of the underlying science of mining and mineral processing operations and the availability of a variety of powerful modeling-simulation tools make it possible to address the challenging problems facing the mining and mineral processing industry, in an integrated manner."

Jan 1, 2018

By R. Lestari

Newmont Batu Hijau operates with an accelerated mining rate to optimize life of mine (LOM) project economics. This results in a portion of ore mined being stockpiled for reclaim and processing throughout, and at the end of mine life. LOM economics can be further enhanced by preserving stockpiled ore value by mitigating oxidation effects. A detailed stockpile ore oxidation study was conducted to: ?? Develop a practical understanding of how oxidation affects ore value; ?? Determine how oxidation rate can be controlled, and; ?? Determine how oxidation effects can be mitigated to preserve ore value. The result of the study is a stockpile management strategy that significantly reduces oxidation related losses and, implementation of that strategy within practical constraints. Implementation includes installation of Controlled Potential Sulfidisation (CPS) flotation to facilitate oxidised sulfide copper recovery and, recovery of dissolved copper from stockpile drainage solution into saleable product. This paper describes the study results including managing and predicting stockpile oxidation with time, monitoring performance of implemented CPS flotation and recovery of dissolved copper from stockpile drainage. These are essential elements of successful long term mine operation in Batu Hijau.

Jan 1, 2014

By S. Castro

The aim of the present paper is to review the current technologies for arsenic removal in the copper metallurgical industry, and to show the progress made with some promising emerging strategies, involving the pre-treatment of copper-arsenic concentrates by selective flotation or by alkaline leaching with Na2S-NaOH solutions. The advantages of alkaline leaching are the selective dissolution of arsenic and antimony, the high extraction yield, and the practically nil loss of copper, which remains in the clean copper concentrate as a CuS residue. Alkaline ?cured? ? a procedure similar to ?acid-cured? in conventional leaching ? improves arsenic extraction and reagent consumption, making this an interesting technology for the treatment of high As-Sb concentrates. In light of recent advances on the selective flotation of enargite and tennantite, the importance of redox conditions to control the flotation/depression of enargite-tennantite from copper sulfides has been well established. However, problems of selectivity must still be solved. Additionally, the limitation imposed in some cases by the need to recover the molybdenum by-product must be considered. The application of selective flotation to obtain a high-arsenic or ?dirty? concentrate and its sub-sequent treatment by the alkaline leaching process is suggested.

Jan 1, 2014

By E. Scheepers

The process under investigation is the large-scale production of phosphorus. Gravity delivers the feed, consisting of pelletised apatite, coke and silica (in the form of gravel), to a submerged arc furnace through ten, evenly distributed feed chutes ensuring constant packed bed volume. Within this packed bed, solid-gas reactions are dominant in generating the gaseous product. These reactions, as well as the packed bed itself, were the main focus in the development of a fully three-dimensional CFD model in which fluid flow and energy distribution are represented as functions of chemical reactions, heating and melting of material and heat losses. The associated complex process interactions necessitated the creation of two process-specific, user-developed models that integrates accurate, thermodynamical data with computational fluid dynamics calculations, as well as reaction kinetics. The boundary conditions are provided by industrial measurements, and the key model parameters of reaction kinetics were obtained by laboratory experiments for different feed mixtures. Thirteen temperature probes installed inside the refractory lining of the furnace especially for this project allowed parameter fitting and validation to be guided within the constraints of real measurements. Simulation results reveal a thin, dome-shaped, reductive zone where conditions are optimum for maximum phosphorus recovery, as well as evidence of a thermal reserve zone similar to an ironmaking blast furnace located above this reduction zone. When compared to actual operating data, the CFD model can successfully predict the specific power consumption, the phosphorus in the slag and gaseous product flowrate under given operating conditions. This CFD model forms part of a larger project that aims to create a Dynamic-CFD hybrid control model.

Jan 1, 2014

By H. Kasaini

Batch wise adsorption tests for platinum (Pt) on the surface of activated carbon pellets (Norit RO 0.8 BET surface area 1100 mg/g) were carried out in mixed chloride solution. The purpose of this study was to assess and compare the adsorption performance of amine-treated activated carbons (AACs) and native activated carbons (NACs) in terms of adsorption capacity and selectivity. The effect of pH and temperature on adsorption capacity and selectivity was established. The amine- treated ACs were prepared by anchoring the amino groups (butyl amines) on the surface of AC pellets in aqueous media and the UV-Vis was used to determine the amount of amine sequestered from solution by ACs. The dosage of butyl amine on the surface of ACs averaged 0.15 g/g, carbon. The adsorption mechanism was described by the ionization and complexation model whereby interaction between the protonated AAC surface and the anionic chlorocomplex ions (PtCl5 [H2O]-, PtCl62-) proceeded by either electrostatic attraction or/and by covalent bonding [(NH3)2PtCl6 or (CH2COO)2PtCl6]. By comparison, the adsorption capacities of Pt on amine-treated ACs and native ACs were 53.8 mg/g and 33.03 mg/g, respectively which highlight the benefits of anchoring functional molecules on ACs. The selectivity of AACs was influenced by solution pH. Pt adsorbed selectively on the surface of amine-treated ACs at pH<1.5. The highest separation factor that was recoded pertained to Pt and Fe species (ßPt/Fe = 90) then followed by Pt and Ni species (ßPt/Ni = 30) or Pt and Cu species (ßPt/Cu = 15). The lowest separation factor was recorded for Pt and Cr ions (ßPt/N= 5). Adsorption kinetics of Pt on amine-treated AC surfaces, according to the first and second order reactions, were investigated and results showed that rates were in the order 10= 5). -4 min-1 and 102 g?min/mg, respectively. The pseudo 1st order kinetics predicted the adsorption capacity of 51.81 mg/g which was almost similar to the experimental value (53.8 mg/g) while the second order rate equation predicted Pt adsorption capacity of 40.1 mg/g. Both The Langmuir and Toth isotherm fitted the Pt adsorption at pH < 1.0. The Freundlich isotherm tended to underestimate the adsorption capacity of AACs.

Jan 1, 2014

By L. Muhr, Y. -T. Tang, M. -O. Simonnot, B. Laubie, R. -L. Qui, Z. Chour

"Agromining aims at recovering metals from different secondary resources with hyperaccumulating plants. These natural plants can selectively concentrate metals at very high level and can be transformed to produce commercial compounds. The classical strategy to recover metals from hyperaccumulator plants is based on hydrometallurgy. It consists of: i) burning the plant to obtain ash, which is a very rich bio-ore without organic matter, ii) transferring the target element(s) into aqueous solution by acid leaching and iii) purifying the leach liquor to obtain the target element(s) in the desired form. This method has enabled us to obtain nickel salts, nickel oxide, zinc and cadmium from different plants. However, it is not possible to apply this approach to recover rare earth elements (REEs) from the fern D. dichotoma, growing on mine tailings in South China. Actually, this plant is very rich in silicon: plant burning gives an amorphous ash, very stable despite severe leaching conditions. Therefore, the strategy has been changed and processes are currently developed to extract REEs by direct leaching of the biomass, without burning the plant. Several conditions (i.e. leaching solutions) have been investigated, showing that a good extraction yield was obtained with HNO3 0.5 N (around 84%). This yield was increased to 99% by adding a complexing resin into the leaching solution. After two-steps of elution, results have shown that is possible to recover 75% of the REEs at 81% purity.INTRODUCTION The demand of rare earth elements (REEs) (including 15 lanthanides, yttrium and scandium) has been growing sharply over the past years, because of their industrial applications. REEs are essential elements for emerging technologies, and are used for example in permanent magnets, lamp phosphors or rechargeable batteries. China is the main producer, and the market supply became tense in 2010 when this country decided to limit exports of these elements. Exploitable mineral resources, as well as REE separation capacity are concentrated in a few countries (e.g. USA, Australia, Malaysia, France), which increases the supply risk. Therefore, these elements are considered as critical raw materials (CRM) for many countries and especially for EU (Fortier and Gambogi, 2017)."

Jan 1, 2018