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By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto

"The theoretical technique of computational modeling and the experimental determination of the enthalpy of adsorption of a ligand molecule onto a mineral surface deliver the same output parameters and, therefore, complement each other in investigating the affinity of different ligand types for mineral surfaces.This study ran parallel experimental tests and computational calculations to determine the enthalpy of adsorption of a series of increasing chain length xanthates onto a pyrite surface. The outcomes showed that, while the absolute energy values were different, the trends were similar. Both computational and experimental approaches showed that the extent of the interaction of the xanthate molecule increases with increasing carbon chain length. The computational values were larger than the experimental values, which could be explained, in part, by the addition of water to the computational system, which resulted in a decrease in the heat of adsorption on the (100) surface, compared to the adsorption of the collector in a vacuum. The computational method showed that, in the case of the pyrite (100) surface, the most exothermic reaction was obtained when the two xanthate sulfur atoms bridged two pyrite 5-coordinated iron atoms. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted for each of the C2, C3, C4 and C5 chain length xanthates.The experimentally determined exothermic increase in heat of adsorption for the addition of each CH2 group was found to be -8.17 kJ/mol. The contribution of the thiol head group was -34.9 kJ/mol. Previous studies on self-assembled monolayers have shown that these values are compatible with lateral interactions between CH2 groups and the exclusion of water. This study provides a rigorous experimental and computational approach which is intended to afford confidence in modelled data for the screening of new ligands for flotation processes.INTRODUCTIONComputational modelling is a fast and cost-effective method of screening collector molecules for the efficacy of their adsorption onto mineral surfaces. However, it is desirable to measure the computational outputs against experimental outputs to check for congruency. Computational modelling and experimental microcalorimetry both deliver the same output parameter: the energy of adsorption of the molecule onto the solid surface. These techniques are therefore ideally suited to complement one another in investigating the affinity of the interaction between collector molecules and mineral surfaces."

Jan 1, 2018

By C. S. Gundewar

About 90% of the barytes produced the world over is used for oil and gas drilling as weighting agent in drilling mud to control pressure, prevent blow out and provide lubrication. This is because of its unique properties like high specific gravity, water insolubility and intentness. India is one of the leading producers and exporters of barites. The Mangampeth Baryte deposit in Cuddapah district of Andhra Pradesh, India being the largest single deposit in the world having a reserves of about 80 million tonnes. Approximately 50% of the total reserves of grey barites of Mangampet deposit assays less than 92% BaSO4, the minimum stipulated grade for oil and gas drilling industries. To reach and recover the high grade barite, the overlying low grade has necessarily to be mined out and removed. At present this is being stacked separately at the mine site involving lot of labour and transport cost. Considerable barites is contained in the dumps adversely affecting the conservation and creating lot of environmental hazards. IBM being the premier organization in India in the field of conservation of minerals and environmental protection in mining has recognized the importance of adverse effect of these huge dumps at site. The Ore Dressing Division of IBM, Nagpur has characterized these dumps and developed the flotation process on a sample assaying 66% BaSO4 and 23.3% SiO2. The flotation concentrate obtained assayed 93.7% BaSO4, 2.38% SiO2 with BaSO4 recovery of 80% and meets the requirement of the oil industry. The flotation concentrate being non-wetable, can not be used as such as weighting agent, and hence the collector coating on the concentrate was removed either by acid treatment or heating to make it water wetable. The concentrate was 92% -325 mesh and having a specific gravity 4.3. The barites concentrates so produced meets the size, grade and specific gravity specifications required for use in oil drilling industry. Apart from the financial benefits the process augurs well for the commercial exploitation of these huge dumps in terms of (1) additional recovery of these valuable minerals and conservation, (2) reduction in dumps value, (3) improvement in environment and offering an excellent potential for export.

Jan 1, 2014

By K. Takahashi

Generally speaking, wastewater coming from the metallurgical process for recovering precious metal contains precious metals such as gold (Au), platinum (Pt), palladium (Pd), Silver (Ag), etc., which concentration is about 10 mg/L. In addition, there are other metals such as copper (Cu), iron (Fe), which concentration varies from several mg/L to more than 10,000 mg/L. It should be noted that the concentration of metals in wastewater is relatively high, considering the fact that these metals of similar concentration can be found in ores. However, most of these valuable metals are not treated, due to the high processing cost and technical problems. Within this frame, the authors put forward a new process that includes neutralization/reduction, precipitation and fusion. The idea is to recover and recycle Au, Ag, and Pd metals as well as protecting the environment by saving the resources. It was found that this new process was able to recover more than 90% of Au, Ag and Pd.

Jan 1, 2014

By S. J. Neethling

"Flotation is a complex process with many factors that influence the performance of a cell. This paper examines the impact of several key variables on the performance of flotation cells. The study makes use of a simulator for the froth phase of the flotation vessel, as the main purpose of this study is to separate the impact of different variables from one another.In experiments it is very difficult to separate the effect of variables from one another as a change in a singe input parameter, such as air rate, invariably also affects many of the other key variables, such as bubble size and bubble bursting rates. This interaction between variables makes it very hard to experimentally separate the impact of, for instance, the air rate from that of bubble size or bursting rate. In the simulator, though, it easy to make independent changes to these variables.In order to achieve this a base case simulation that is typical of many of the rougher cells found in sulphide flotation circuits was carried out. Four key variables, air rate, incoming bubble size, surface bubble size and the fraction of the bubbles flowing out of the cell unburst, were varied in order to obtain the system’s response.The most significant results were obtained when the bubble size was varied. An increase in the incoming bubble size has the effect of reducing the pulp zone recovery, but increases the froth zone recovery. If it were possible to vary the incoming bubble size without influencing the overflowing bubble size, the impact of the change would be unclear because of these two competing effects. The effect of a change in the overflowing bubble size has an opposite effect on the froth recovery, with larger bubbles resulting in lower froth recoveries."

Jan 1, 2003

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By F. H. Wang

The Yinmao Lead-Zinc Mine Co. Ltd. has got 50 years of mining history. In recent years, the manganese grade in the flotation tailings has been continuously increasing. In order to make fuller use of the existing resources, as well as to increase the company?s economic efficiency, our company adopted the technique ?magnetic separation? and ?iron removal? to effectively recycle the manganese concentrate resources.

Jan 1, 2014

By Harri J. Lehto, Marja I. Oja

"The purpose of grinding circuits is to produce a particle size distribution that has as much as possible the wanted particle size class. In practise, however, the production of the wanted size class is not at all as simple as it sounds. In the case of industrial minerals for example the end user may give very tight specifications for the particle size distribution and for the chemical composition of the product. This leads in many cases to a very demanding grinding process, if we want to reach and maintain these specifications. In other words, the required size distribution is not necessary the best possible for the chemical composition.Screen models aim to predict the size distribution and flow of the products when a feed size distribution, feed tonnage, and grade efficiency curve are known. The approach used in this study was to select the most suitable empirical model for classification. Suitability of the existing models has been evaluated and accuracy compared. The tests showed that best grade efficiency model was the Rosin-Rammler model.The performance of a screen was evaluated in order to minimize the amount of fine material in the screen overflow. The experiments were carried out using Derrick single-deck screen, first alone with recycling and then in the closed circuit with a rod mill using two different scales. The separate screen tests showed the expected behaviour of the grade efficiency curves. In the pilot tests the Leonard screen efficiencies stayed almost constant. This suggests that the screen works better in a milling circuit. However the loading of the screen turned the product of the mill coarser that helped screening. The grade efficiencies obtained from the pilot tests had the same general shape. The regression analysis of the pilot test runs did not give an acceptable correlation for the parameters. This suggests that pilot tests cannot be directly used to scale or to optimise industrial milling circuits. However they can be used to predict the trends of behaviour of an industrial circuit."

Jan 1, 2003

By Francesco Vegliò, Luigi Toro, Francesca Beolchini, Francesca Pagnanelli, Stefano Ubaldini

"Biosorption is an innovative technology used to remove heavy metals from aqueous solutions from mining waters and other industrial wastes. A wider application of this alternative process is strictly dependent on the understanding of the chemico-physical aspects involved, in order to optimize the operating conditions. Mechanistic models are the most useful tools used for understanding purposes, even if the empirical models are still widely applied for their simplicity.In this paper especially propagated biomasses of Sphaerotilus natans, calcium alginate and some waste materials were tested as adsorbents for single and binary solutions containing heavy metals at different pH. The equilibrium experimental results were fitted according to empirical and physical models with growing complexity outlining the inadequacy of the predictive models; in fact, the non-ideal interactions among metals require the insertion of additional correction parameters."

Jan 1, 2003

By A. Y. Senchenko, Y. V. Kulikov

"The most common technique for selection of grinding equipment is the Bond method implying determination of a ball mill work index (BWi). The method is perfect for greenfield projects where a ball mill must be sized to grind an ore to 80% passing 75-100 µm. Finer grinding will require application of specific correction factors to a standard equation since initially the method was not designated for sizing of fine (minus 75 µm) grinding mills. Significant issues are related to selection of grinding equipment for treatment of originally fine materials when the standard procedure is not applicable. In 1984, Levin published his special technique titled as “A proposed test for the determination of the grindability of fine materials”, where he offered to use the standard Bond ball mill for determination of a specific grinding energy. However, this method did not meet with wide recognition. In 2017, Institute TOMS under guidance of JKMRC’s specialists performed a testwork aimed at verification of a new universal technique for determination of grindability of initially fine materials. An object was to test three aged tailings samples for the subsequent modelling of comminution circuit and evaluation of potential throughput of the existing ball mills with final grind size of ?80 passing 53 µm. In parallel with development of the universal approach, TOMS’ specialists carried out tests according to the Levin method in order to compare the data resulted from two methods. The results from lab ball mill testing on three products following the alternative test methods are presented in this paper along with the testing methodology and results analysis. Specific energy was calculated for regrinding of the materials to the required size. Difference of the examined methods and assessment of their applicability for sizing of full-scale equipment are explored."

Jan 1, 2018

By Georges Delemontex, Nigel Grigg

"Pre-concentration of precious metal and base metal ore types is becoming more relevant with the discovery, development and operation of many lower grade deposits around the world. The fluctuations in metal prices and currencies expose many mines to risks especially dealing with low and variable ore grades. Pre-concentration, the process of concentrating the valuable metal into a smaller mass yield, effectively results in the introduction of higher feed grades to milling circuits. Gangue rejection, the removal of lower S.G. waste rock from the circuit, not only results in higher downstream grades but also potentially removes harder, non-valuable mineral, providing significant power savings within the circuit. The pre-concentration or ‘gangue rejection’ process offers a number of benefits when considering the treatment of marginal ore deposits, especially if it can be performed at a coarse crush size; these benefits include a reduction of the operating costs and the feed of more metal units to the mill. Gekko Systems has effectively utilized the Inline Pressure Jig (IPJ) to pre-concentrate the valuable metal, achieving high primary recoveries into a range of mass yields resulting in upgrade ratios between 2 and 10 times. This paper explores: the benefits of pre-concentrating ‘marginal’ ore deposits prior to the milling circuit; the selective rejection of ore types that may affect either the recovery or comminution process; and also looks into the potential to effectively reduce the ‘cut-off’ grade when considering the mine planning process. Case studies of projects using the IPJ to pre-concentrate and reject gangue are also included. Pre-concentration and gangue rejection provide the potential to develop marginal ore deposits, thus providing higher grades, less gangue and more metal at a lower operating cost to producers."

Jan 1, 2014

By Chris A. Fleming

"Interest in the recovery of cyanide from gold and silver plant tailings has heightened in recent years. This interest has been spurred by several factors:Increasingly stringent regulations throughout the gold producing world, governing discharge limits for free and total cyanide to tailings ponds and the environment.The increasing cost of active chemical treatment versus passive (natural degradation) treatment of tailing, to bring them in line with environmental regulations.The worldwide trend to processing of more complex gold ore bodies, which is usually accompanied by higher levels of cyanide consumptions and greater concentrations of cyanide (particularly the copper cyanide complex) in tailings.The growing negative perception of the general public for the gold mining industry, due to several highly publicized cyanide spills in recent years (breaches of tailings dams, accidents involving trucks carrying cyanide to gold plants, etc.).The ability to recover cyanide from gold plant tailings has been known almost as long as the cyanidation process has been practiced, but there has been little incentive to process tailings in this way in the past. With the development of technologies that make it possible to recover and recycle free or complexed cyanide directly from gold plant slurry tailings, which indicates, on paper at least, the potential for significant cost savings compared to cyanide destruction, coupled with the introduction of legislation to seriously limit the discharge of cyanide to the environment in most gold-producing regions of the world, many companies are evaluating the cyanide-recovery alternative."

Jan 1, 2003

By M. Ito

Cobalt-rich ferromanganese crust and nodule ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei. These ores require mineral processing to remove the sub-strate/nuclei rock before smelting. This paper reviews experimental results of previous investigations. Observations and analysis of 10 samples from different localities were carried out and it was found that the liberation ratio of crushed product was high even at coarse size fraction, 0.5mm to 4mm. Experimental and calculated results in the smelting stage confirmed that the separation product satisfies the standards of the subsequent smelting process if the substrate/nuclei rock is removed from the 0.5mm to 4mm fraction with high separation efficiency. There was a density difference between the substrate/nuclei rock and the ferromanganese component. Thus the coarse sized sample was treated with gravity separation; air table separation was used as a dry method and jig separation as a wet method and high grade values with high recoveries were obtained by both kinds of gravity separation.

Jan 1, 2014

By P. Khattri

At Tata Steel, Coal is washed in gravity and froth flotation circuit at 13-15 mm size and below. Being coal is high in ash (~35%) and difficult washability characteristics (having high (~40 %) NGM at desired ash levels) needs more and timely quality data of ROM for effective optimization and process control. Conventional approach of supplying quality data takes 4-5 hours time. This means during this period, it is assumed that coal is having similar characteristics as of previous set and it is not possible to fine tune during this time which resulted in yield loss. Hence producing clean coal on agreed ash value consistently is a challenging task because of high NGM and variation in input quality. To overcome the problem of collection of representative sample and timely result a new technology was adopted Prompt Gamma Neutron Activation Analysis (PGNAA) technology which is basically an online analyser using Gamma rays as the source to measure the ash content in coal running on a conveyor which gives real time ash analysis. The details of this technological intervention are discussed in details in this paper. Keywords: near gravity material, PGNAA

Sep 1, 2012

By Hui Zhang, Fei Yang, Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"For a copper-sulfur polymetallic mine in south China, the main valuable minerals were chalcopyrite, pyrite and pyrrhotite. The flotability of pyrrhotite was similar with chalcopyrite and pyrite and it was easy to be oxidized. As a result, the indexes of copper concentrate and sulfur concentrate were unsatisfactory. Furthermore, the recycling of tailings water ulteriorly deteriorated the technical indexes of copper-sulfur ore beneficiation. After a large amount of experimental studies, under the condition that the tailings water recycling rate was 100%, the copper concentrate with a grade of 22.25%Cu and a recovery of 82.46% on average was obtained for the raw ore containing 0.517%Cu, 15.94%S, 25.46%Fe on average, through using new technology “magnetic separation-flotation” and effective adjustment of parameters in the industrial test which was continuously conducted for 14 shifts in 5 days with a scale of about 75t/d. Comparing with the production indexes (the copper concentrate with a grade of 17.49%Cu, the recovery was 62.27%) during the corresponding period, the grade of copper concentrate increased 4.76%Cu, and the recovery increased 20 percentage points. Besides, the indexes of sulfur concentrate gained a considerable improvement. Currently, the new technology was adopted in the design of the new-built plant with a scale of 7000t/d of this mine. The new technology provided powerful support for the tailings water recycling and indexes improvement of copper-sulfur ore beneficiation.INTRODUCTION Chalcopyrite was usually associated with pyrite and pyrrhotite in copper-sulfur ore. Due to the similar flotability, it was difficult to obtain copper concentrate and sulfur concentrate with high grade. Furthermore, sulfide ore was easy to be oxidized and a large amount of ions formed in the pulp by the dissolution of minerals, which made the pulp become acidic. As a result, pyrite and pyrrhotite were easy to be activated in acidic solution and their flotabilities became stronger. Meanwhile, hydrophilic film formed on the surface of chalcopyrite in raw ore. The flotability of chalcopyrite became weaker and it made the separation of chalcopyrite from pyrite and pyrrhotite more difficult. So it was more difficult for copper and sulfur recovering with the recycling of tailings water containing high content of heavy metal ions and reagents."

Jan 1, 2018

By Yong Liu, Peng Qian, Shu-Feng Ye, Shao-Jun Chu, Pei-Wei Han

"Chromite with a low mass ratio of Cr to Fe (Cr/Fe ratio) was treated by the carbochlorination method using solid chlorinating agent (MgCl2 and CaCl2) and carbon in the present paper. The results showed that iron could be selective removed mainly in the form of FeCl2. The removal of iron was indirectly, which consisted of the decomposition of solid chlorinating agent to release Cl2/HCl and the carbochlorination of FeO•Cr2O3 by Cl2/HCl and C. The Cr/Fe ratio increased as increasing temperature from 700 ? to 900 ? in air atmosphere, while the tendency was opposite in N2 atmosphere. The removal efficiency of iron by CaCl2 was better than that by MgCl2. At last, a new pelletizing process was proposed to treat fine chromite with a low Cr/Fe ratio based on carbochlorination method, which could produce the high quality roasted chromite pellets with higher Cr/Fe ratio and compressive strength. INTRODUCTION Chromite is mainly used for the production of ferrochromium. A high Cr/Fe ratio (>2) of chromite is usually required to meet the technical specification of ferrochromium.(Gasik, 2013) Attentions have been attracted to the economic and efficient methods for the recovery of chromium from lower-grade ores as the higher-grade ores become depleted. However, the Cr/Fe ratio is difficult to improve through the conventional beneficiation methods (such as gravity concentration, flotation) due to the spinel composition, although beneficiation methods could increase the metal content of chromite ores by removing gangues.(Nafziger, 1982) The main industrial mineral of chromite is (Fe,Mg)O•(Cr,Al,Fe)2O3, which belongs to spinel magnetite.(Liu, 2013) Iron should be selectively removed through the structural dissociation of spinel to increase Cr/Fe ratio.(Nafziger, 1982)"

Jan 1, 2018

By D. J. Hallbom

The ?yield plastic? rheological model describes the flow behaviour of a variety of non-settling suspensions, including many types of mineral slurry. The current paper presents the laminar flow relationship (pressure gradient vs. flow rate) for a yield plastic fluid flowing through a pipe or cylinder. Simplified algebraic equations, suitable for engineering purposes, are presented for yield plastic fluids with values of the scaling factor in the range that includes most industrially important slurries. The laminar pipe flow relationship is one of the most important fluids engineering calculations. It may be used to determine the rheological parameters of a material in a capillary rheometer or flow loop. If the rheology is known, these relationships may be used to determine the laminar flow pressure gradient in pipelines of various sizes.

Jan 1, 2014

By Seungwoo Park, Gaurav Soni, Roe-Hoan Yoon, Hyunsun Do, Kaiwu Huang

In a flotation froth (and foam), air bubbles become larger due to coalescence, causing bubble size to increase, bubble surface area to decrease, and hence casing less hydrophobic particles to drop off to the pulp phase below. Thus, bubble coarsening provides an important mechanism by which product grades are increased. On the other hand, excessive bubble coarsening results in low recoveries. In the present work, a model describing the process of bubbles becoming coarser in a foam as they rise to the top by deriving a mathematical relation between the Plateau border area, which controls film drainage rate, and the lamella film thickness, which controls bubble-coalescence rate. The model has been derived by assuming that liquid drainage rate increases due to slip at the air/water interface, and that the critical rupture thickness is determined by the capillary waves created by thermal motion. The model developed in the present work can predict the bubble size ratio between the top and bottom of a foam as functions of aeration rate, foam height, and surface tension (frother dosage). The model predictions are in good agreement with the changes in bubble sizes measured using a high-speed camera.

Jan 1, 2014

By A. P. Chaves, D. Jose Neto, M. G. Bergerman, E. S. Mano

"More complex ore comminution and concentration operations have found increasing application in the mining industry due to lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. They allow removing a significant mass of material with little or no content of the relevant mineral before the ore is fed into the processing plant, with the consequent reduction in the mass to be processed in downstream operations. Significant benefits arise out of the use of pre-concentration, such as higher contained metal output without the need to increase the grinding or flotation capacity, and longer mine life. The grade of marginal ores could be enhanced to a level that would make their exploration economically feasible, which would result in increasing exploitable reserves. Nevertheless, few studies to date have assessed the resulting impacts on ore grinding energy consumption and wear after the gangue is removed through pre-concentration operations. This study evaluated the energy consumption and wear of grinding circuits in Brazilian mining operations in which the feed has gone through a pre-concentration stage. Such assessment was based on different samples of sulfide and oxide ores. Laboratory tests were carried out to investigate the power consumption and wear of grinding circuits with and without a pre-concentration stage. Laboratory test results were used to simulate industrial grinding circuits based on both alternatives and illustrate the environmental and economic benefits of each one.INTRODUCTION Increasingly complex ore concentration operations in several stages have found broadening application in recent years in view of lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. Different ore processing technologies can be used for that purpose, such as magnetic separation, density segregation, and separation methods based on high-tech sensors (ore sorting). Currently, the most common methods are gravimetric processes, in view of their low cost, particularly jigging and dense medium separation methods, such as the drum and cone separators manufactured by Western Machinery Company, Teska, Drewboy, Norwalt, Dynawhirlpool and Tri-flo, and dense medium cyclones (CAMPOS; LUZ; BRAGA, 2010). The use of dry ore sorters has also grown significantly in recent years (Jose Neto et al. 2017). The selection of the separator type depends essentially on the ore particle size, required flows, and operating density ranges. All these methods may even be used after preferential blasting in mining (Grigg & Delemontex, 2015)."

Jan 1, 2018

By O. Jerez, A. Novoselov, L. Gutiérrez, J. Morales, U. Kelm

"In Chile, the evaluation to reprocess tailings for elements other than the traditional Cu, Mo, Au, and Ag, as well as projects to implement long-term monitoring of mining residue sites are key elements of the government’s roadmap laid out for the mining industry for the next two decades. Characterization routines for tailings and mining residues in general have to be adapted from traditional ore and gangue mineral and micro-chemical studies. This contribution summarizes key aspects for the regional mining industry for a basic characterization of tailings with emphasis on small- to medium-size operations with limited in-house facilities and funds to carry out extensive characterization programs. The oldest tailings in Chile were deposited almost a century ago; this fact gives importance to the recovery of past ore /gangue feed information, process circuits and changes (e.g. acid to alkaline flotation), process water provenance and recovery, meteorological registers, and routines of filling a tailings impoundment. Basic characterization should include X-ray fluorescence spectrometry combined with laser diffraction (LD) granulometry followed by X-ray diffraction (XRD), optical microscopy (OM) and automated mineral analysis (AMA) on a reduced set of samples identified by hierarchical cluster analysis. For this detailed stage, only coarse tailings are recommended for direct a study by microscopy and automated mineralogy (P80 >100 µm); for fine tailings (P80 ~30 µm) a combination of XRD and deposit type adapted sequential extraction are more informative options. In particular, for XRD of clay phases, losses of crystallinity may result in deviation of spectra from standard reference phases due to prolonged storage. To monitor surface alteration, scanning electron microscopy can be complemented by Raman spectroscopy to detect residual reagents on mineral surfaces. For reactivity modeling BET measurements are essential."

Jan 1, 2018

By P. Somasundaran

Gangue minerals can often have severe adverse effects on selective value mineral separation. Such effects can be mediated through a variety of pathways or mechanisms. One popular mechanism is that of ?slime coating? or heterocoagulation, wherein the gangue mineral fines are believed to coat the value mineral surfaces and thereby reduce selectivity and floatability. Another pathway that has received relatively little attention is that mediated through the effect of gangue minerals on pulp rheology, and consequently selective separation. Our recent work in developing a scientific understanding of these effects has highlighted the prevalence and importance of this pathway. In this study, the impact of shape and morphology of serpentine gangue minerals on suspension rheology and selective Ni flotation from ultramafic ores was investigated. We found strong evidence for micro- and macro-network formation in the presence of acicular (needle-shaped) or fibrous minerals, which impacted pulp rheological properties. Results also supported the hypothesis that morphology has a greater role to play than mere shape. The size of the network ranged from 5 microns to 2 cm depending upon the amount and aspect ratio of fibrous minerals. These networks impede many flotation sub-processes, such as gas dispersion and bubble-particle interactions. Additionally, the small pore size of the networks prevents bubble penetration leading to a large transport of the gangue minerals to the concentrate via lifting of the entire network by bubble flux, which resulted in a significant grade dilution. Based on the scientific insights generated in this study various techniques have been developed to improve selective value mineral separation. Keywords: fibers, aspect ratio, microstructures, networks, pulp viscosity, gangue transport

Sep 1, 2012