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By V. M. Bystritsky, M. G. Sapozhnikov, G. M. Nikitin, A. B. Sadovsky, Yu. N. Rogov

"At present kimberlite ore is processed in crushers or grinding rolls with subsequent grinding in wet mills down to a size of 0.2 mm. The basic disadvantage of the standard diamond processing technology is that crushing kimberlite ore can damage the most valuable large diamonds of few carats. Tagged neutron method offers a possible solution to this problem. It allows detecting diamond inside kimberlite ore without its disruption. The results of the tests of the neutron separator prototype carried out at the Lomonosov processing factory of PJSC Severalmaz are discussed. The possibility to detect the diamond in the rock whose size is 10 times larger than the size of the diamond is demonstrated.INTRODUCTION At present standard diamond processing technology implies disintegration of kimberlite ore in crushers or grinding rolls down to a size of 0.2 mm. It inevitably leads to high probability that large and most valuable diamonds could be damaged. The fraction of diamonds which lost integrity in the process of ore enrichment could be as large as 35-65% [1]. Tagged neutron method (TNM) [2] offers a possible solution to this problem. It allows detecting diamond inside kimberlite ore without its disruption. The main idea of the TNM is irradiation of an object by fast 14.1 MeV neutrons from binary nuclear reaction d + 3H ?4He + n (1) and detecting (tagging) the 4He (a-particle) that accompanies neutron. That gives possibility to determine direction of the neutron momentum. Those tagged neutrons irradiate kimberlite ore under investigation and produce gamma rays via inelastic scattering reactions with nuclei"

Jan 1, 2018

By Andrzej Luszczkiewicz, Aleksandra Potulska

"Flotation is a basic process of beneficiation of mineral raw materials which requires very fine grinding for liberation of valuable minerals. Probably flotation will also play this role in the future. In the case of flotation of difficult-to-upgrade non-ferrous ores, currently one of the most important trends in technology development is solution to fine grinding even down to a few micrometers in size and elaboration of effective flotation technology for such fine particles. Both industrial flotation data and many investigators suggest that the best results of flotation of ore minerals are observed for particle size range from 20 to 100 µm. Many base metal ores require grinding below 20, or even 10 µm, to liberate valuable ore components. However, industrial flotation of particles below 20 µm in size creates numerous challenges. Further complications may be caused by a complex nature of the ore, especially when the valuable metals are present in several different sulfide minerals. This problem occurs in the case of the Polish sedimentary copper ores. In the present study, flotation of the ore of different size distributions and degrees of grinding, having the size of particles below 25 µm, was investigated. The behavior of different sulfide minerals naturally present in the ore was analyzed. The best results of flotation tests were obtained for the ore ground down to 95% below 25 µm. Narrow size fractions -10; 10-15; 15-25; 25-40, and +40 µm were separated using special micro-sieves and mineralogical as well as chemical analyses of each size fraction were carried out for monitoring the behavior of the fine sulfide particles. Differences between flotation of chalcocite-digenite, bornite, chalcopyrite, covellite, galena and pyrite-marcasite naturally occurring in the ore were described. The role of different particle sizes in flotation performance of each mineral was also presented."

Jan 1, 2014

By D. W. Lui

Tangdan copper oxide deposit, the largest independent copper oxide deposit in China so far, is located in the northeast of Yunnan province, southwest of China. The ore from this deposit is characterized by: low grade, high oxidation ratio, and fine-grained disseminated, resulting in poor flotation recovery. The analysis of plant flotation data reveals that the loss of copper minerals into tailings is mainly with coarse size fraction due to insufficient liberation and fine size fractions, especially minus 10 microns fraction, which proved to be very difficult-to-float with conventional flotation. In order to improve the performances of plant flotation of this ore, laboratory flotation tests were conducted with the pure malachite, which was the principle copper oxide mineral in Tangdan copper ore deposit. The results obtained suggested that a finer grinding (up to -325 mesh or even -400 mesh) be needed to decrease the loss with coarse size fraction, and vacuum flotation is a promising way for the recovery of the fine malachite effectively.

Jan 1, 2014

By A. Luszczkiewicz

An innovative hybrid technology for beneficiation of difficult-to-process sedimentary copper ores comprising acidic leaching stage of the feed combined with subsequent flotation has been presented. Acidic leaching, preceding the flotation process, plays a beneficial role of efficient chemical grinding for liberation of copper sulphide minerals finely disseminated in the copper-bearing carbonate-shale rocks. The process was applied on a fully industrial scale. Flotation results were analysed for both chemically modified and unmodified flotation feeds. After several months of industrial scale operation, it was found that both metals recovery and concentrate grade remarkably increased as a result of application of chemical modification of the flotation feed. Beneficial effects of chemical pre-treatment of flotation middlings on selectivity at a comparable concentrate yield in industrial flotation scale, revealed a considerable increase of the total copper recovery by 3.5percent. Based on the industrial and laboratory investigations we consider a further development of the process and introduction of hydrometallurgy for better recovering of metals from low-grade copper concentrates

Sep 1, 2012

By Ye Junjian

The feed ore is the concentrate of low intensity magnetic separation of pyrite tailings, containing TFe47.47%, S19.41% and SiOpyrrhotite. The exploratory tests showed that using a process of flotation followed by magnetic separation could respectively obtain a sulphur concentrate of S 31.08% with a recovery of 82.89%, and an iron concentrate of TFe 59.97% and S 9.52%with a recovery of 30.93%. The reason of iron concentrates with high sulphur grade was that the sulphur grade of flotation tailings was 7.03%. So enhanced flotation for pyrrhotite was investigated in this research. Results show that when the natural pH of ore pulp varied from 5.5 to 6.0, a reagent combination of FS, LH, and BJ displayed the optimum flotation performance for pyrrhotite. After comparisons made on different flotation processing, the previous flotation flow of ?one roughing, one cleaning, one scavenging system and middling reprocessing?, was found, among others, to have the best flotation effect, as the grade and recovery of sulphur concentrate were 31.08% and 82.89%, respectively, and sulphur content of the flotation tailings was 7.03%. The above results indicated it was difficult to raise further the effect of flotation desulphurization. The authors therefore suggested that oxidizing roast should be adopted following the magnetic process for the purpose of further desulphurization. Besides, flue gas containing SO2 8.25%. And the valuable minerals are magnetite and 2 generated from roasting could be reused for sulphuric acid production. Keywords: pyrrhotite, enhanced flotation, desulphurization

Sep 1, 2012

By Lj. D. Andric

By the micronization-milling of the material, the size and the structure of its particles are changed and it comes to the increasing of the potential energy of the system as well as to the chem-ical activity of the material what is the result of an increased free surface and of the concentration of the grate defects, that is of the internal energy of the system. All these changes that are reached, show that new characteristics of treated materials are got by micronization process. Controlling the process of the micronization and by purpose directing of the new characteristics of the activated materials, we can have the positive effects and use them in more technologies. Talc is important nonmetallic mineral raw material that is widely used as either the basic raw material, or as filler. This has stimulated its technological investigation, as well as the investigation of its physical-chemical characteristics. In this paper are shown experimentally reached results of the physical-chemical characteristics of the talc during the process of the micronization in high energetic mill. In this paper, the optimum conditions of miconization of talc in high-energy-speed rotary mill and its influence micronization on a degree of Fe2O3recovery by hydrometallurgical methodes, are presented. The X-ray analysis of the obtained products showed that high quality talc with low content of can be obtained by these physical-chemical processes In this paper, the principles and application or fine and ultra-fine grinding high-energy attriton mill with small balls, enabling fast, efficient grinding, low energy consumption, short grinding time and easy handling will be described.

Jan 1, 2014

By M. Kalicinski, M. Lyssyy

"Access to information is a key component for making improvements to any process. This is particularly true for all aspects of the iron mining and steelmaking process. The ability to make rapid control decisions can significantly influence process outcomes, including ensuring product specification, mining quality, transportation limits, upgrade factors, waste bypass and direct shipping, among many others. While traditional laboratory methods provide feedback for such processes, having access to analysis results in real-time can lead to positive reactive and predictive control decisions to be made rapidly, leading to significant improvements throughout the process. Scantech has been designing, manufacturing and supplying technological products to the minerals industry since 2002 to enable the availability of such real-time information to a mine or plant, with the benefits being enjoyed by a wide range of operators. This paper provides a summary of the available technologies used in the iron ore and steel industries, as well as providing case studies of their use in African and Australian iron ore and European steel, as well as a description of the potential benefits of a range of analysis equipment.INTRODUCTION Access to information is critical for any process, and is a fundamental component for making process control decisions. In order to yield effective processing outcomes, it is important for that information to be readily available, preferably as quickly as possible, and to be as accurate as possible. While speed and accuracy are often traded off against each other, there are numerous technologies available in a processing environment that allow for both rapid flow of information and a high level of accuracy. The use of on-belt analysis equipment has a long trusted history of use in a number of mining and processing environments and industries, providing information such as elemental composition and grade of conveyed materials, moisture content, waste proportion and energy information. Australian company Scantech has been a provider of such equipment since 1981, and has become an industry leader in both the supply and development of on-belt analysers across a range of industries."

Jan 1, 2018

By Chen Zhiqiang, Luo Chuansheng, Chen Ziqiang, Liu Jianguo, Rao Jinshan

To comprehensively utilize the valuable resource in tailings, increase the economic benefit of mine, reduce the amount of tailings, prolong the service life of tailing dam, the comprehensive utilization of tailing resource is arousing the attention of more and more mines. Research of comprehensive recovery of feldspar and silica from Cu-Mo floatation tailings has been furthered. Technology of "De-sliming-Magnetic Separation-Reverse Flotation-Feldspar and Silica Separation" has been developed to utilize the resource. Slime is removed and reagents cost is reduced by de-sliming. The specific effective collector ZL is used in gangues reverse flotation, and GZ-818 is the collector in feldspar and silica separation. The grinding operation is vital to ensure the liberation degree of feldspar and to eliminate the reagents pollution on minerals surface. To a Cu-Mo flotation tailing assaying K2O 5.22%, Na2O 2.22%, Fe2O3 1.95%, Al2O3 12.05%, SiO270.66%, superfine K-feldspar and silica concentrates can be produced. The feldspar concentrate productivity is 29.67% assaying K2O 8.99%, Na2O 2.86%, Fe2O3 0.16%, Al2O3 16.99% and SiO2 68.92%. The silica concentrate productivity is 14.20% assaying 0.17% K2O, 0.04% Na2O, 0.01% Fe2O3, 0.55% Al2O3 and 98.17% SiO2. The technology provides technological reference model for the similar mines.

Jan 1, 2014

By Charlene Gokhale

Geopolymerisation has emerged during the last few years as an industrial and ecological approach to construction and waste management. By utilizing waste materials and their reactive properties, it is now possible to create geopolymers systems that not only mechanically durable enough to be used as construction materials but are also potential stable immobilisation systems for toxic waste. Previous studies by Van Jaarsveld et al. (1997) and Van Jaarsveld et al. (1998) have reported on the numerous applications of geopolymers in the immobilisation of toxic metals. Research into the possible utilisation of geopolymers as an encapsulation media for organic waste has however been rare. This paper therefore provides an insight into the possible utilisation of geopolymers as a binder for hazardous organic materials.

Jan 1, 2003

By S. A. Kubyshkin, A. A. Agafonov, A. L. Shakhnin, S. M. Sukharzhevsky, A. A. Komlev, N. V. Vorob’ev-Desyatovskii, A. Pichugina

Cyanidation of gold ore results in formation not only of Na[Au(CN)2], but also cyanometallate complexes of some transition metals. During subsequent gold extraction from such solutions and pulps, using activated carbons (??), a number of problems arise. An effective solution of the problem is not possible without detailed knowledge of the interaction mechanism of transition metals cyanide complexes with AC particles. The chemical properties of AC particles and graphene, saturated with [?u(CN)n](n-1)- (n=2, 3), were studied by XPS, ESR, SQUID, and DFT. The obtained results were compared with the data on AC adsorption of anionic form of Ag(I), Au(I), Cd(II), Hg(II), Cr(III), Fe(II), Fe(III), Co(III), Rh(III), Ni(II), Pd(II), Pt(II) and Pt(IV) cyanide complexes. The adsorption of [?u(CN)n](n-1)- (n=2, 3) on AC from aqueous solutions in air is accompanied with oxidation of ?u(I) atoms. Besides, Cu(II) and Cu(III) compounds were found on AC surface. Quantum-chemical calculations confirmed the possibility of formation of Cu(I) complex with carbene-like sites of AC. The reactions of [?u(CN)n](n-1)- (n=2, 3) complexes and aromatic carbenes and their cation-radical were theoretically studied at DFT PBE level to obtain the information on adsorption of cyanometallate complexes on AC. Carbenes with different fragments were regarded as a model of activated carbons, which have free edge sites with paired o and n electrons. It was shown that [Cu(CN)2]- bounds firmly with triplet carbene, if one Cu-CN bond breaks. The dissociation process occurs through a multi-step spin-crossing mechanism to reduce total spin multiplicity of the metal-carbene complex. The behavior of transition element complexes in contact with AC in aqueous solutions is determined by the following characteristics: geometrical structure of ionic complexes; nature of ligands bonded to the central atom; concentration of reactive oxygen species in solution and its pH; nature of binding sites of AC.

Jan 1, 2018

By D. W. Feng

Thiosulfate leaching has been considered as the most promising alternative to cyanidation for the recovery of gold from ores. The chemistry of the ammonia-thiosulfate-copper system is complicated due to the simultaneous presence of complexing ligands such as ammonia and thiosulfate, the Cu(II)-CU(I) redox couple and the stability of thiosulfate in solution. However, acceptable gold leaching rates can be achieved by maintaining suitable concentrations of thiosulfate, ammonia, cop-per and oxygen in the leach solution. The leaching of gold in thiosulfate solution is an electrochemical reaction involving the oxidation of gold to gold thiosulfate and the reduction of Cu(II) to Cu(I). Previous studies have shown that the reaction rate of gold was much higher in the presence of am-monia thiosulfate than corresponding sodium thiosulfate. This indicates that cations may affect the anodic oxidation of gold in thiosulfate solution. The present study utilises electrochemical tech-niques to study the anodic oxidation of gold in thiosulfate medium in the presence of the different alkali metal and alkaline earth metal ions. It has been shown that the presence of the heavier cations such as potassium, calcium, and caesium enhance the oxidation of gold in thiosulfate solution. Leaching tests also indicated the improved recovery of gold from a sulfide ore with the addition of heavier cations. XPS results demonstrated that the binding energy for gold shifted to lower values in the presence of the heavier cations, indicating the ready formation of ion-pair with gold thiosulfate at the gold surface during adsorption.

Jan 1, 2014

By S. Groudev

Acid drainage waters generated in the uranium deposit Curilo, Bulgaria, were treated by means of a pilot-scale passive system consisting of a permeable reactive multibarrier and a constructed wetland connected in a series. The multibarrier had a total volume of 23 m3 and consisted of an alkalizing limestone drain and an anoxic section for microbial dissimilatory sulphate reduction, bio-sorption and additional chemical neutralization. The waters had a pH in the range of about 2.5 ~ 4.0 and contained radionuclides (uranium, radium), heavy metals (copper, zinc, cadmium, lead, nickel, cobalt, iron, manganese), arsenic and sulphates in concentrations usually much higher than the relevant permissible levels for waters intended for use in agriculture and/or industry. The water flow rate through the multibarrier varied in the range of about 1 ~ 17 m3/24 h, reflecting water residence times of about 300 ~ 18 hours. An efficient removal of pollutants was achieved by the multibarrier during different climatic seasons, even during cold winter days at external air and water temperatures close to 0oC. The multibarrier effluents were enriched in dissolved organic compounds and in some cases still contained manganese and iron in concentrations higher than the relevant permissible levels. These pollutants were removed in the constructed wetland as a result of the activity of different heterotrophic microorganisms, including some bacteria able to oxidize the bivalent manganese and iron ions to Mn4+ and Fe3+, respectively.

Jan 1, 2014

By V. Dementiev

Pyrite cinders is a complex raw material, in which the valuable metals are: Au(2.04 g/t), Ag(35.0 g/t), Cu(0.38%), Zn(1.1%) and Fe(56.0%). In this case high costs for mining and ore processing are not required. The hydrometallurgical treatment of pyrite cinders using thiourea, sulfite and cyanide solutions are examined in this paper. It was found that thiourea leaching is ineffective due to high consumption of thiourea and sulfuric acid. The cyanidation on pyrite cinders was conducted. Various options of the preparation of the products for the subsequent cyanidation have been examined. The tests on cyanidation process optimization were conducted. The effectiveness of these cementation methods by metallic iron or extraction for copper recovery from water phase has been shown. Zinc precipitation can be found in the form of carbonate. In order to recover noble metals from cyanide solutions, the cementation onto zinc dust was tested. The developed technology provides for recovery at 49-56%Au, 20-25%Ag, 22.5%Cu and 50%Zn during NaCN (1.4 kg/t) and CaO (6 kg/t) consumption. The results of pilot plant testing are the basis for technical regulations in order to design a pyrite cinders treatment plant. The technology has been examined in pilot-plant conditions. In this case the recovery of 54.5%Au, 45.3%Ag, 30%Cu and 49.9%Zn was achieved to provide saleable products. Keywords: pyrite cinders, thiourea leaching

Sep 1, 2012

By I. A. Podkamennyi, O. E. Kovalchuk, G. P. Dvoychenkova

"Using the methods of electron microscopy and IR spectroscopy, mineral components in the run-of-mine kimberlites and on the surface of diamonds were identified. The mechanism and sequence of mineral formation on the surface of diamond crystals were established. Systematization and classification thereof were undertaken for the first time ever.INTRODUCTION The high content of diamonds sized -5 mm in the kimberlite ores of Western Yakutia determines their processing depth in the size class 0.5 mm and finer [1, 2]. These diamonds are recovered by grease and froth separation based on the natural hydrophobic properties of the crystals. When refractory altered kimberlite ores are fed into the industrial process, the performance of grease and froth separation of the diamond ore greatly deteriorates. [4, 10, 15, 17]. Altered kimberlites are known to contain up to 90% of secondary minerals. This reduces by up to 40% the recovery of diamonds by grease and froth separation. [6].Diamond crystals from the grease and froth separation tailings were investigated. On the surface of the examined diamonds, hydrophilic mineral formations were identified, responsible for reduced recovery by physicochemical separation methods [3, 12, 18]. The aim of this study was to identify and describe the relationship between the composition of kimberlite ores and mineral formations on the surface of diamond crystals in order to systematize, classify, and then develop methods of removal in grease and froth separation processes. MATERIALS Following materials were examined in this study: - kimberlites of various material composition, - resulting slimes, - diamond crystals from kimberlite ore processing products."

Jan 1, 2018

By Carlos Rabanal, Levi Guzmán

"The concern regarding grinding media consumption rates is as old as the invention of the tumbling mill. Over the years many materials and grinding media shapes have been tested. Through all this, steel grinding balls have proved to be the most effective media for comminution in tumbling mills. There have been several approaches to be able to the wear of the ball charge in any given mill, all of them based on limited empirical evidence. The mining industry still utilizes the Bond Abrasion test that was developed in the 1960´s. As shown later in this publication, this approach shows error greater than 60%. More recently, in 2007, Radziszewski from Mc Gill University has proposed a different total grinding media wear model; this model is based on decoupling the effects of the abrasion, corrosion and impact wear mechanisms. Also in 2007, Benavente, at the time with Moly-Cop Peru, presented an empirical model relating both ore properties and operational conditions that would affect the wear performance of the grinding media. For the database referred in this article, Benavente’s model shows an average error of ± 12% which represents a higher degree of improvement in comparison with previous approaches. The current paper presents recent research conducted by Moly-Cop Peru to further improve the capability of the empirical model originally developed by Benavente to estimate grinding media wear rates. The work performed included extensive determinations of the Bond Abrasion Index for different types of ores, collected at industrial grinding applications where the corresponding operational information was made available. The results of the research enabled us to build a more robust and confident model for estimating the grinding media wear rate. The average error of this new model is in the order of ± 9% which is a significant improvement over the models previously described."

Jan 1, 2014

By Kazutoshi Haga, Batnasan Altansukh, Shirchinnamjil Nyamdelger, Atsushi Shibayama, Narankhuu Ariunbolor, Gunchin Burmaa

In this study, the authors investigated the capability of an acidic thiourea solution and silicon-organic polymers (PSTM-3c, PSTM-3T) as ion-exchange resins to recover of gold from gold-bearing ore concentrates. Firstly, elemental gold present in flotation concentrates was dissolved by leaching with a solution of nitric acid and thiourea under the optimized conditions. The best result on gold thiourea leaching was obtained under a nitric acid concentration of 2 N, thiourea concentration of 2 %, and oxidant (Fe2(SO4)3) concentration of 3 %, solid:liquid ratio (S:L) of 1:20, leaching time of 6 hours at 20 °C with a gold recovery of 93.7 % for a gold flotation (unroasted) concentrate. For the roasted gold concentrate, the dissolution of gold was 94.8% under the optimized leaching condition as nitric acid concentration of 0.5 N, thiourea concentration of 2 %, and the oxidant concentration of 1 %, S:L ratio of 1:10, leaching time of 4 hours at 50 °C. Secondly, a series of sorption tests was carried out on a pregnant leach solution containing gold complex Au[S=C(NH2)2]2+ using silicon-organic polymers (PSTM-3c and PSTM-3T), respectively. The effects of solution pH, adsorption time and temperature in the sorption process are also studied. As the results, the PSTM-3c and PSTM-3T polymers were adsorbed about 94.4 % and 95.1 % gold from the pregnant leach solutions under the optimum sorption conditions, respectively. It was found that the both PSTM-3c and PSTM-3T polymers were effective for the recovery of gold from the pregnant leach solution of thiourea. Adsorption activity of the PSTM-3c and PSTM-3T polymers was confirmed by new peaks near 1700 cm-1 in the FT-IR spectrum of the gold-adsorbed polymers, respectively.

Jan 1, 2014

By Petrus van Staden, Dragan Milanovic, Francisco Sánchez, Eero Kolehmainen, Carlos Frias

"Currently there is no economical and viable process for on-site metal extraction from Low Grade, Complex or Poly-metallic deposits, and even more, there is not any industrial process or technology able to deal with polymetallic or bulk concentrates containing Cu+Zn+Pb base metals and also precious metals. Traditionally, metals recovery from polymetallic sulfide deposits is performed by mining, selective flotation to separate Cu, Pb and Zn concentrates, and finally, smelting/refining of those concentrates to obtain the refined metals. In many cases, selective flotation of that kind of complex ores produces low metals recovery and low concentrate quality containing impurities such as Hg, As, Bi, etc., which results in high penalties in treatment and refining charges, and consequently, worsening the economy of the mining business. Recovery of the valuable metals from Polymetallic, Complex or Low Grade ores could then be maximised by producing bulk concentrates or middling flotation products to feed novel hydrometallurgical processes, like the integral metallurgical system that is currently under development within the INTMET project. For example, producing bulk concentrates would increase more than 100% Cu+ Zn+Pb cumulative recovery versus conventional selective flotation. Founded by the Horizon-2020 EU Programme, the INTMET Project was started in February 2016 and will be running over three years. The INTMET consortium is led by Cobre Las Cruces (Spain) and integrates twelve partners from seven EU countries, and including Serbia and South Africa as well. The INTMET project represents a challenging opportunity to develop suitable technological solutions to deal efficiently with difficult, polymetallic and complex sulphide ores that are abundant in Europe and worldwide. Main activities carried out during the first 18 months of the INTMET project development includes: (i) An atmospheric leaching pilot plant having a capacity of 300 kg/h bulk concentrate which has been installed and operated continuously for nine months at the Las Cruces mine; (ii) Pressure leaching test work developed by Outotec; (iii) Bioleaching test work performed by Mintek in collaboration with MMI Bor. Prior test work was applied on bulk concentrate samples supplied from Spain, Portugal and Serbia. Some of the results of these technological developments have been very positive and are presented in this paper."

Jan 1, 2018

By Teemu Väyrynen, Matti Vilkko, Antti Jaatinen, Pekka Itävuo

"This paper shows that smooth and accurate feed-hopper level control is essential for consistent cone crusher operation. The objective of the paper is to define the best practices for tight control of cone crusher feed-hopper level. The paper discusses the challenges involved in a delay-dominant level control problem (specifically, dead-time-induced performance and stability issues, mass flow disturbances, process and actuator non-linearity) and proposes five corresponding control structures. The performance of the proposed control structure candidates is evaluated in a simulation study and, finally, a full-scale experiment is conducted for the best-performing candidate. The results of this study emphasize the importance of control structure selection. While the most obvious control structures failed to deliver the desired performance, the best result was achieved by using control structures that eliminate the conveyor transport delay (dead-time) from the control loop. In practice, the control loop dead-time can be eliminated by either using an actuator (variable-speed feed conveyor) that is connected directly to the feed-hopper, or by redefining the process boundaries closer to the used actuator (regulate the circuit mass balance instead of feed-hopper level). The presented control structures provide means to achieve a consistent cone crusher performance and size reduction. This facilitates efforts to improve the plant’s performance and increases the plant’s overall stability."

Jan 1, 2014

By M. A. Hampton

The surface oxidation of sulfide minerals in aqueous solutions is an important sub-process in sulfide flotation and hydrometallurgy, but a full understanding of the oxidation process and products is still lacking. Many oxidation pathways and products involving elemental sulfur, metal polysulfide, metal-deficient sulfide and sulfate have been proposed, confirmed and argued. In this paper we provide further insight into the surface electrochemical behaviour of galena in aqueous solutions. For this research we have developed a novel experimental system, that combines chronoamperometry and AC-mode AFM surface imaging, which allows for in-situ, synchronized electrochemical control and examination of oxidative surface morphology. At pH4, the morphology of elemental sulfur (detected by ex-situ Cryo-XPS) formed on the oxidizing galena surface depends on the electrochemical potential pathway. In multi-step chronoamperometry (i.e. four potential steps from 0 mV to + 350 mV) the sulfur forms as nanoscopic domains, whereas in single-step chronoamperometry (i.e. one potential step from 0 mV to + 350 mV) sulfur forms as a heterogeneous layer. In each case the oxidation is controlled so that the number of electrons (coulombs) passed per unit area is the same, therefore the amount of sulfur produced is also the same. The differences in morphology with electrochemical potential pathway are explained using a nucleation and growth model. The formation of sulfur on the surface increased both advancing and receding contact angle of galena, but the morphological changes induced by different electrochemical potential pathways did not significantly alter the hydrophobicity of the surface. Keywords: galena, lead sulfide, oxidation, Atomic Force Microscopy, electrochemistry, collectorless flotation, hydrophobic

Sep 1, 2012

By Peter Ay, Florian Logsch, Satyanarayana Narra

"The traditional lignin separation process from the precipitated suspension creates severe filtration problems by plugging of the filter medium due to the small particle size (20 to 60 µm) of the suspended lignins. The plugging causes further problems in the successive processing of the filter cake. A new lignin separation process has been developed at the Brandenburg University of Technology (BTU) Cottbus as a part of the Research and Development and Demonstration (R & D & D) project "LignoBioFuel". The new developed process separates lignin in the form of granules with diameters ranging from 100 µm to 300 µm. The restrainment of the granule’s size in their successive treatments is expected to result in higher filtration efficiencies and reduction in plugging of filter mediums. To evaluate the filtration efficiency, the filtration resistance of the produced granules as well as the conventional suspensions has been investigated. The results show that there is a 60 to 80 % filtration efficiency increase and around 60 % reduction in plugging of filter mediums with the lignin granules in comparison to the conventional suspensions. Furthermore the successive processing of lignin granules was easier due to their porous structures removing the impurities such as adherent acids and salts. The purity of the separated lignin was measured with their sulphur (reduced from 7 % to 2.7 %) and ash (reduced from 46 % to 0.5 %) contents. The newly developed process has displayed better results in comparison to that of the conventional process. The new process displays high potentials in optimizing and improving the present state of the art treatments and is promising several ecological, economical and environmental improvements."

Jan 1, 2014