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By Paul W. Cleary

"Particle scale simulation of industrial particle flows using DEM (Discrete Element Method) offers the opportunity for better understanding the flow dynamics leading to improvements in equipment design and operation that can potentially lead to large increases in efficiency, throughput or product quality. DEM has been used for modelling many industrial applications, particularly milling. This includes ball and rock motions and power consumption in ball mills, AG and SAG mills, vibrational segregation, flows in rotating drums, operation of dragline excavators and hopper flows. In mineral processing, DEM has been concentrated on mills because of their critical importance. However DEM also offers the opportunity to improve many other parts of mineral processing operations. These areas often do not receive the attention that the key comminution equipment commands, but can become critical when they fail or under-perform. Importantly their assessment/improvement using DEM is often much more feasible because of smaller problem sizes and the absence of poorly understood physics such as breakage. In this paper we describe DEM simulations of four important pieces of non-comminution equipment that are commonly found in or near mineral processing plants (these are shown in Figure 1):"

Jan 1, 2003

By Sergey Ulianov, Arkady Senchenko, Alexey Shvets, Arkady Bakotin

"This paper is devoted to ultrafine grinding of processing products. This process allows one to include into operation complex ores which earlier were considered as inefficient and economically inadvisable to treat. Fine dissemination of valuable component often does not allow its liberation via standard grinding in ball mills, and therefore requires modern methods of ultrafine grinding (UFG). An example of successful ultrafine grinding usage is its application for crude flotation concentrates regrinding before cleaner flotation stages. A problem often arises with a commercial copper concentrate production in the course of copper ore flotation. Crude flotation concentrate regrinding in a ball mill does not provide for good liberation of the material before cleaner stages. UFG application allows one to get commercial copper concentrate with copper grade of 20% and higher. Another example of ultrafine grinding application is its usage for highly refractory pyrite product received after gold-lead scavenger flotation of polymetallic ore. Earlier this product treatment was economically inefficient. At current application of ultrafine grinding down to 85% minus 20 µm and subsequent gravity processing it is possible to pass major part of gold (73.4%) into concentrate. The constraining factor for UFG application in processing may be the chemical activation of minerals. In the result of this, flotation selectivity may decrease. Therefore ultrafine grinding application extends the areas of efficient usage of metallurgical processes. New technologies allow increasing the level of valuable metals recovery."

Jan 1, 2014

By Luo Chuansheng, Rao Jinshan, He Xiaojuan, Qiu Xianyang

The dissemination grain size of chalcopyrite is really fine and refractory grains of -10µm take up 25%. Dissemination relationships among chalcopyrite with pyrrhotite, pyrite, marcasite and gangue minerals are complex. Content of Fe-bearing sulphides and Fe-bearing silicates associated with chalcopyrite reaches to about 60%. It’s hard to liberate and separate chalcopyrite from pyrrhotite. The above four are the main mineral processing difficulties of a copper ore in China. Because of the similar floatability and poor separation effect between chalcopyrite and pyrrhotite, enhanced depressing and collecting method was adopted in Cu-S separation before 2009. Due to the different magnetism among chalcopyrite, pyrrhotite and Fe-bearing silicates, magnetic separation is creatively induced in Cu floatation circuit based on the in-depth study of process mineralogy. High efficiency and new Cu-S separation technology of "Rough concentrate regrinding-pyrrhotite rejecting from middling by magnetic separation" and a highly selective copper minerals collector YL-1 had been developed to solve the difficult problems of refractory Cu-S separation, which are heavy load of middling recirculation,difficulty in upgrading Cu concentrate, unstable locked cycle and low separation indexes. And grade of Cu concentrate has been increased by 3.33%, recovery of Cu and Ag has been increased by 19.32% and 10% respectively.

Jan 1, 2014

By Fatemeh Saeidi, Malcolm S. Powell, Mohsen Yahyaei

In order to deal with the problems of existing comminution models a new approach towards the development of mechanistic models has been made so as to better understand the physics of milling processes and environments. Despite enormous improvement in this field a comprehensive study of rock breakage characterisation, appropriate for use in these types of models, is still scarce. This paper reviews the existing models of comminution according to ore characterisation techniques and parameters. The authors have looked into the existing testing methods and their applied mechanisms of breakage, using standard test results available at the JKMRC. The study includes classifying testing devices such as the drop weight tester, rotary breakage tester, slow compression, and piston and die based on the few major fundamental mechanisms of breakage that are experienced by rocks in the breakage process. The paper compares the range of particle size and energy utilisation, applied strain rates and loading mechanisms for the equipment. The product size distributions from the various equipment is compared for equivalent input energies, various loading rates but the same level of energy intensity, a broad range of energy including low energy utilisation and fines generation rate for equivalent specific energy input. The results clearly show that the outcomes and conclusions on competence and energy for breakage are a function of the test method that is applied. In ongoing work, it is proposed to investigate common tests that can be applied to characterising ores in a manner suited to modelling a range of comminution devices.

Jan 1, 2014

By Y. Y. Li, Q. Chen, Y. X. Cai, Q. Zhang, S. Mao

"Due to the influence of combustion conditions, the fly ash produced by some power plants has the problem of high-carbon content. The unburned carbon in fly ash can be removed by flotation, and the decarbon tailings should reach the national standard level I fly ash. The fineness of the requirement is one of the important indicators and is also an important factor affecting the tail ash activity. In this paper,adopting two methods investigate the effect of particle size on the flotation index: one is direct flotation of fly ash, and the other way is wet grinding + flotation of fly ash, comparing the two methods and selecting the appropriate process,which provides a way for the effective utilization of fly ash. INTRODUCTION Fly ash is a solid waste discharged from coal-fired power plants. The annual amount of emissions of fly ash are very large in China. The amount of fly ash were discharged from coal-fired power plants are increasing gradually, and the amount of fly ash stored has exceeded 2.5 billion tons, but the comprehensive utilization of fly ash is not high, which brings about a huge environmental problems( Lu et al.,2011). Carbon is a harmful component of fly ash in cement and concrete application (Zhang et al.,2008). Fly ash decarburization is an essential link to improve the utilization efficiency of fly ash and the reduce pollution ( Yang et al.,2012). Carbon is selected from fly ash to make full use of fly ash resources and improve utilization of fly ash (Li et al.,2008). In this paper, the flotation decarburization of high-carbon fly ash is studied, through comparing the grinding and not-grinding processes, optimizing the separation process of fly ash, which provides a way for the effective utilization of fly ash."

Jan 1, 2018

By Yuriy V. Gulyaev, Galina V. Sedelnikova, Valeriy D. Lunin, Valentin A. Chanturiya, Igor J. Bunin

"Probable mechanisms of disintegration of mineral particles in gold-containing sulphides and benefication products exposed to high-power electromagnetic pulses are discussed. Experimental data are presented to confirm the formation of breakdown channels and selective disintegration of mineral complexes as a result of pulse irradiation, which makes for efficient access of lixiviant solutions to precious metal grains and enhanced precious metal recovery into lixivia during leaching. Experiments with different gold-containing products revealed a synergetic effect of high-power electromagnetic pulses with widely varying parameters and moisture in mineral pores on breaking-up and gold extraction processes for various resistant goldcontaining mineral products.Several series of tests performed in IPKON RAS, IRE RAS and TsNIGRI yielded an absolute gain in precious metal recovery, up to 30-80 % for gold and 20-47 % for silver, with resultant gold recovery as high as 90 %. An essentially new, environmentally safe and energy-saving breaking-up technology has been developed for resistant gold-containing products. This new method would shorten the way from raw minerals to final products and help significantly reduce the cost of these products as it obviates the necessity for using the expensive procedures of energy-intensive and environmentally hazardous oxidative roasting and autoclave breaking-up for ore concentrates."

Jan 1, 2003

By Aziza A. Yousef, Suzan S. Ibrahim, Mahmoud A. Arafa, Mohamed A. Abdel Khalek

In view of the shortage of soft water all over the Middle East countries, seawater may be used to replace the fresh water in flotation beneficiation. The flotation process required about 7 m3 of fresh water/ ton ore. This article aimed to study the effect of seawater cations and anions on the flotation process of four important mineral commodities. The adsorption of collector, zeta-potential, zero point of charge and floatability of pure minerals were studied. The individual effects of different cations and anions that are predominant in seawater, within their more or less actual concentrations were studied on individual mineral and on groups of them. The troublesome Ca2+ and Mg2+ ions, in the anionic circuit could be controlled by soda ash addition to the pulp before the anionic collector. The addition of sodium silicate improved the floatation selectivity of mineral mixtures and natural ore. At the optimum conditions the calcareous phosphate ore yielded a concentrate recovery of 83% with a grade of 34% P2O5, with 0.61%MgO, which from an ore assaying (25.3% P2O5 and 9.4% MgO).

Jan 1, 2003

As the high-grade copper deposits in the world become depleted, there is an increasing focus on developing lower-grade ores which contain problematic impurities such as arsenic. Indeed, many high-arsenic ore bodies remain undeveloped because of their high arsenic levels. Separation of arsenic from copper at the beneficiation stage is difficult using the current processing techniques and invariably copper concentrates produced from these ores contain high arsenic levels, sometimes so high as to make them unacceptable to copper smelters. New, sustainable approaches are needed to allow development of high-arsenic copper ores while at the same time minimizing arsenic dispersion into the biosphere. The most promising route for separating arsenic from copper at the flotation stage centers on the use of pulp potential control. In recent years CSIRO has demonstrated at laboratory scale, for a number of high-arsenic copper ores, that crude flotation separation between arsenic-bearing minerals and copper-bearing minerals can be made. The differences in specific minerals responses to changes in pulp potential and pulp pH are exploited for this separation. Such separations nominally produce a low-arsenic high-copper concentrate and a low-copper high-arsenic concentrate. The former can be smelted without penalty, while the latter requires further treatment to capture and stabilize the arsenic and to recover the residual copper. Consideration has now been given to treatment options for the high-arsenic low-copper product. A pyrometallurgical option, involving a low temperature roast to selectively fume off the arsenic and leave a high-copper calcine, coupled with an arsenic stabilization step, has been demonstrated in the laboratory, and a preliminary techno-economic evaluation shows the process to be economically favorable. These results were recently published. CSIRO has now investigated an alternate hydrometallurgical option, involving atmospheric alkaline sulphide leaching of the high-arsenic product, where the arsenic is selectively dissolved leaving a copper-rich leach residue. The leaching testwork was carried at on the same high-arsenic low-copper material used in the roasting studies, enabling a techno-economic comparison of the alternate roasting and leaching treatment options to be made. The alkaline leaching work is briefly described and the results of the process option comparison presented and discussed. Keywords: arsenic, copper, economics, enargite, ore flotation, tennantite INTRODUCTION

Sep 1, 2012

By S. J. Neethling

"Liberation is a key driver in all mineral separation processes as it limits the maximum possible grade for a given recovery. In flotation, this is further complicated by the fact that it is surface exposure of the floatable minerals that determines the ultimate performance. Liberation, grade and surface exposure are commonly quantified using Scanning Electron Microscopy coupled to Energy Dispersive X-ray spectroscopy (SEM/EDX) analysis of polished sections. The intrinsically 2D nature of this technique can result in significant sampling errors and stereological effects that can affect the quantification of the ore’s textural characteristics. X-ray micro-Tomography (XMT) is an imaging method that can non-invasively and non-destructively delineate ore fragments in 3D, thus providing an alternative method that eliminates the need for stereological corrections and readily provides surface exposure. A methodology and automated algorithm were designed for extracting this information from images of closely packed particles, thus allowing samples containing a large number of particles to be assessed.The main drawback of XMT is that, unlike SEM/EDX, it cannot directly measure the mineralogy of the sample, instead producing a 3D X-ray attenuation map. We therefore also present an algorithm for calibrating the thresholding of the XMT images based on SEM/EDX images of sections through the same sample, thus allowing the liberation analysis to be carried out on a 3D mineral map in which the uncertainty in the mineral assignment is small and statistically quantified.The methodology was tested on low grade porphyry copper ore as this is both an industrially relevant and traditionally difficult system to quantify using XMT due to the similarity in the X-ray attenuation of the sulphide species, especially the pyrite and chalcopyrite. As each 3D volume imaged contain 100-1000s of grains, large data sets can be readily produced. By dividing these particles into classes based on both their surface exposure and grade, the extent to which there is preferential breakage of the particles can be assessed—an important consideration if sufficient surface liberation for good flotation performance is to be achieved at coarser particle sizes. It is also shown that erroneous conclusions can be drawn when basing the analysis on 2D sections through the particles."

Jan 1, 2018

By R. ?. Shishmarjov, Yu. ?. Davidenko, S. V. Bukhalov, ?. S. Baksheev, M. S. Shkirya, N. ?. Aikasheva, D. V. Bogdanovich, ?. Yu. Faustova

"The goal of prospecting operations in the Republic of Altay was to locate gold-sulfide-quartz mineralization. For this purpose we applied the technology of electromagnetic sounding and induced polarization (EMS-IP). These operations resulted in localizing promising sites with presence of sulfidization. The EMS-IP method proved to be highly efficient amongst other prospecting methods targeted at recognizing zones of sulfide mineralization making up 91%, considering that in more than half cases the ore intervals were the case. In the Yakutian diamondiferous province the EMS-IP technology was approbated during three field seasons to accomplish the assignments on searching for kimberlite bodies under conditions of various geological types. As a result, the reference objects were distinguished, and geoelectric parameters of kimberlite pipes of explosion were defined.INTRODUCTION In the time span 2015-2016 in Gorny Altay the EMS-IP technology was approbated in the Novokuznetsk area. The on-land areal geophysical survey was performed by EMS-IP method applied to identify, outline and locate promising sites with Au-Ag-bearing polymetallic mineralization within surveyed areas. Compared to the hosting rocks, the sulfides contained in polymetallic mineralization are typified by low specific electrical resistivity (SER) and high polarization. The areal survey conducted via EMS-IP method provided spatial characteristics of searched object. From July 2016 to August 2017 our expedition group carried out serial test works and laboratory investigations intending to define performance capabilities of EMS-IP technology in searching for kimberlite bodies under conditions of diverse geological types. The prerequisites for serial work were operations accomplished at the «Listvenichny» site lying 35 km away from Mirny town in the Sakha Republic (Yakutia), where the EMS-IP technology was probed for locating position and measuring geoelectric parameters of tuff pipe «Buardakhsky». After successful completion of operations it was decided to evaluate geoelectric parameters of kimberlite pipes of explosion."

Jan 1, 2018

By H. D. Mendoza, M. J. C. Zerna

This study aims to determine the stability of Philippine nickel laterite ore by investigating the behavior of fine minerals of silica (dave=1.514 µm), hematite (dave= 0 1.351 µm), and nickel oxide (dave=1.426 µm) and their mixed-components in dilute aqueous suspension as a function of pH and electrolyte concentration. The zeta- potentials of the minerals are measured and stabilities of different component systems in aqueous suspension are determined. Hamaker constants of the minerals in aqueous medium are derived by getting their respective critical coagulation concentrations (c.c.c.) at stable pH conditions and at various concentrations of KNO3. The iso-electric points (i.e.p) for silica, hematite, and nickel oxide particles are at pH 2, pH 7.5, and pH 8.5, respectively. The stability behaviors of component systems are as follows: a) Silica dispersion is stable at pH range 3-11and unstable at pH 2; b) Hematite dispersion is stable at pH 2-5 and pH 8-11, and unstable near pH 7; c) Nickel oxide dispersion is stable at pH range 10-11 and unstable at pH 3-9; d) Hematite-silica dispersion is stable at pH range 6-11 and unstable at pH range 3-5; e) Hematite-nickel oxide dispersion is slightly stable at pH range 3-4 and unstable at pH range 5-11; f) Silica-nickel oxide dispersion is stable at pH range 10-11 and unstable at pH range 3-9; and, g) Hematite-silica-nickel oxide dispersion is stable at pH range 10-11 and unstable at pH range 3-9. The stability of nickel laterite ore is similar to that of the three-component system in an aqueous environment. The stability tests are analyzed using the classical DLVO theory. The stability conditions in an aqueous environment are essential in developing the appropriate process flow for the separation/ recovery of nickel laterite mineral components and also in the treatment of nickel laterite -laden wastewaters.

Jan 1, 2018

By Paulo Castillo, Cesar Gomez, Jaime Alvarez

Operations using flotation to produce mineral concentrates require testing of frothers to characterize their ability to preserve bubble formation size and to build a stable froth. Many techniques have been proposed to measure parameters associated with these two roles. These techniques focus, in general, on only one of these roles and are based on special equipment operated at conditions quite different from those existing in industrial cells and columns. Both roles have been simultaneously characterized in a laboratory flotation column, but the requirements associated with the installation and operation of one of these units, are a serious limitation for its use on-site. A technique based on the use of a laboratory mechanical cell, a common piece of equipment in operations, will have wider application. Establishing the ability of a frother to control coalescence by preserving bubble formation size is done through bubble size measurements as a function of frother concentration. Froth build-up and stabilization is associated with the amount of water carried by bubbles into the froth layer, which has been demonstrated to correlate with the gas holdup in the collection zone. Procedures devised for determining the critical coalescence concentration (CCC) from measurements of bubble size as a function of frother concentration, and the gas holdup by collection of water displaced from the cell by the presence of bubbles at different frother concentrations, were tested. Three analytical-grade frothers were utilized: a straight-chain (1-heptanol) and a branched (MIBC) alcohol and a polyglycol (PPG425). The results obtained at a standard set of conditions, demonstrated consistent differences between these frothers, and the ranking from least to most effective for reducing bubble size or decreasing water drainage followed the same sequences found when more complex frother characterization techniques are used.

Jan 1, 2014

By Christopher M. Rule, Martyn P. Hay

"A methodology was developed in the mid-1980’s to predict plant performance from standard laboratory flotation tests. The methodology incorporates a flotation simulation program “SUPASIM” which translates flotation performance from bench-scale tests to full-scale plant. The technique is based on a simple, empirical kinetics model, and is tailored for use by the practical metallurgist. Kelsall’s unmodified equation incorporating two rate terms describing slow and fast floating components is used as the basis of the method. The flotation behaviour of an ore is described by a set of numbers, which can be compared in the evaluation of ore types, mineralogy and operating conditions. In so doing a precise relationship is developed between metallurgical performance in terms of grade and recovery and flotation kinetics.To date the performance of more than 20 flotation plants has been predicted, encompassing copper, lead, zinc, nickel, phosphate, pyrite, graphite, cassiterite, platinum and various slags. In three cases, plants have treated more than one type of ore. The method has successfully been used to predict and design four flotation plants using data generated from bench-scale laboratory flotation testwork. All have since been commissioned, and have performed as predicted. In the last year alone it has been used to drive flowsheet development for at least seven new plants in South Africa and the Americas. It is also being used to assist in the optimisation of existing operating plants."

Jan 1, 2003

By C. B. Yu

The ore comprise of chalcopyrite, valleriite, pyrite, pyrrhotite and so on. Serpentine and talc are chief gangues. Copper phase of the tail shows that mostly valleriite be losed in tail, 70% mineral of copper is valleriite in tail, so severity reduce the recovery of copper. The traditional flow-sheet in acidity mine pulp to flotat the valleriite, but copper-sulphur separated in high alkaline pulp, so the valleriite be losed else. Explores the characters of the valleriite?s surface, studys on the flow-sheet of flotat valleriite and copper-sulphur separated. In neutral mine pulp, adopt of cationic collector to flotat valleriite, adopt of hyposulphite to depressant pyrite in low alkaline pulp can advance the recovery of copper to 5.06%.

Jan 1, 2014

By I. I. Maximov

The paper describes the results of studies performed with a view to develop an improved technology for processing high-grade massive and cupriferous ores of the Talnakh deposit, the main valuable components being nickel, copper and PGM. The studies? main task was production of nickel concentrate with nickel content of approx. 15%, nickel recovery being as high as possible. The studies were performed on two ore samples. One sample was a mix containing high-grade massive (78%) and cupriferous (22%) ores with nickel content of 1.93% and copper content of 3.6%; the other sample was a mix of high-grade ores with nickel content of 2.25% and copper content of 3.72%. Main ore minerals were copper sulfides ? chalcopyrite and cubanite, their total content being 10.5% ~ 11%, pentlandite (5.2% ~ 6.1%) and pyrrhotite (36.7% ~ 42.9%). Influence of grinding media on pentlandite and pyrrhotite separation results, achieved through combined use of triethylenetetramine (TETA) and sodium sulfite (SS), was also investigated. It is shown, that combined application of TETA/SS in the ratio of 1:2, permits to grind products in metal mill (mild steel) with metal balls (mild steel), achieving results that are similar to those achieved by means of grinding in inert grinding media with TETA/SS ratio of 1:1. Application of the developed technology provided for production of high-grade nickel concentrate with nickel content of 14.7% ~ 15.6%, nickel recovery being 76 % ~ 77%. Earlier experiments performed on the above mentioned ore mix permitted to produce nickel concentrate with nickel content of 10%, nickel recovery being 75.9%. Consequently, nickel content was increased by 4.7% ~ 5.6%, and a higher nickel recovery was achieved. The paper also describes metallurgical results related to nickel, copper and PGM with regard to all processing products.

Jan 1, 2014

By Valentin V. Shatalov, Irina V. Pastukhova, Alexander V. Kurkov

"We have developed a technology to improve the quality of low-grade concentrates containing minerals of tantalum, niobium and tin on the basis of given conception by the way of improving selectivity and using certain reagents composition. The basic collector presents a traditional or complex-forming collector used together with organic diphilic reagents – the secondary reagents regarding the basic flotation regiment, capable of forming associates with the main collector on the surface of the mineral, thus altering the interaction energy. In the given process the main collector is the fraction of hydroxamic acids C7-C9, the reagent of the secondary action – sulphosuccinamate, which added in moderate concentrations range provides for a synergistic effect.We have determined the parameters of the process stability and necessary modifying reagents for a selective recovery of tantalum, niobium and tin minerals from refractory products. Variants have been studied where the main collector and the secondary action reagent were substituted with some more efficient flotation reagents. A possibility of a more flexible reagent compounding for the process has been shown. The flotation process is highly stable regards the saline composition of the liquid phase in the pulp. It can operate under conditions of the complete water recycling with the total salt content up to 12 kg/m3, iron up to 1.2 kg/m3.The given results consider the efficiency testing of the suggested technology for the gravitation products, which were obtained from ores of various genesis and contain large quantity of the most refractory minerals, such as topaz (80%), gamet (55%), tourmaline (30%). High selectivity of the process has been registered with the metal recovery about 92-98%, which appears to be similar to hydrometallurgical operations under certain conditions."

Jan 1, 2003

By Chuanyao Sun, Zhenguo Song, Aijun Ren

"Lead-Zinc sulfide ore containing carbon is one of typical refractory resource. Because organic carbon has natural floatability, it has a great negative influence on flotation of lead-zinc sulfide ores. It is difficult to obtain qualified lead concentrate by flotation using conventional reagent system. In order to reduce the influence of organic carbon on lead and zinc flotation, two alternatives, i.e., removal carbon by pre-flotation or adding carbon depressant in lead and zinc flotation, can be adopted. If the flowsheet of removal carbon by pre-flotation is adopted, the lead and zinc recovery which are lost in the carbon tailings is often higher. If conventional carbon depressants are used in lead and zinc flotation, it has a certain depression effect on lead minerals. In the paper, the ore grading 1.49% Pb, 5.73% Zn, and organic carbon 3.14% has been carried out by flotation tests. In the bulk flotation of carbon and lead minerals, Pb concentrate is only about grading 21.00% Pb. In the pre-flotation of organic carbon, it’s hard to remove most of carbon, and the loss of Pb and Zinc recovery is too much in carbon tailings. New carbon depressant BK547 and three conventional carbon depressants including sodium lignosulphonate, Fe-Cr-lignosulfonate, and dextrin, are used in comparative tests of Pb flotation, and results show that BK547 have a good depression on organic carbon, and have almost no effect on Pb flotation. Using BK547 as carbon depressant, cycle test in flowsheet of two-stage Pb and Zn selective flotation and coarse concentrate regrinding have been carried out, and results show that concentrates grading 62.51% Pb and 41.33% Zn are obtained at recoveries of 70.24% Zn and 83.58% Zn.INTRODUCTION Lead and zinc mineral resources are still the main source of lead and zinc metal. For lead-zinc sulphide ore, lead concentrate and zinc concentrate are obtained by flotation. Minerals separation by flotation is a complex process and is dependent, along with other factors, on the relative distribution of hydrophobic (e.g. collector, polysulfide, elemental sulfide) and hydrophilic (e.g. metal hydroxide) species between different particles of the same mineral phase and between mineral phases (Piantadosi & Smart, 2002; Boulton, Fornasiero & Ralston, 2003). Organic carbon has natural floatability and is often associated with lead-zinc sulphide ores. If the content of organic carbon in the ore is more, the flotation index will become worse. The main problem is that the concentrates has too low grade to be qualified grade products for sale. At the same time, the consumption of reagents is more than ordinary ores without organic carbon. In order to solve the influence of organic carbon on the flotation of lead and zinc and other sulphide ores, a lot of research works have been carried out."

Jan 1, 2018

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By de Vaux. D.

Synthetic water with a calcium concentration of 80 ppm and 500 ppm was prepared and the flotation results obtained compared to a simple electrolyte in order to determine the effect water quality has on pentlandite and pyroxene surface alteration and, ultimately, floatability. During the study, the possible effect of interactions between the minerals investigated and Ca2+ ions in the presence of sodium isobutyl xanthate was studied at pH 6 and pH 9 by means of zeta potential determinations, microflotation tests and ToF-SIMS analysis. The results obtained have demonstrated that water quality does play a significant role in flotation recovery at the experimental conditions used.

Jan 1, 2003

By Z. Y. Ma, M. D. Liu, Z. Z. Liu, J. K. Zhou

"An optimization method of microwave assisted leaching of copper anode slime was proposed based on Taguchi method. The results showed that the solid-liquid ratio was the most important factor affecting SNR(signal noise ratio) of the copper, tellurium and selenium leaching efficiencies, and its contributions to the copper, tellurium and selenium leaching efficiencies were 58.34%, 55.54% and 60.74%, respectively. Solid-liquid ratio was a significant factor to SNR(copper, tellurium and selenium). Reaction period was a less significant factor to SNR(copper and tellurium) and concentration of sulphuric acid was a less significant factor to SNR(selenium) while microwave power was an non-significant factor, its contributions to the copper, tellurium and selenium efficiencies were 3.22%, 11.73% and 12.73%, respectively. The optimized parameters of the microwave assisted leaching of copper were as follow: microwave power of 500 W, reaction period of 10 min, solid-liquid ratio of 0.10 g·mL-1 and H2SO4 concentration of 1.0 mol·L-1. The optimized parameters of the microwave assisted leaching of tellurium and selenium were as follow: microwave power of 800 W, reaction period of 15 min, solid-liquid ratio of 0.10 g·mL-1 and H2SO4 concentration of 1.0 mol·L-1. The validation experiments under the optimized conditions has been carried out, the copper, tellurium and selenium leaching efficiencies were 98.66%, 84.32% and 64.54%, respectively. INTRODUCTION As important valuable by-products, copper anode slimes are collected from the bottom of the electrolytic bath in the electrolytic copper refining process(Kilic, 2013). The value of the anode slime is determined by the content of rare metals and precious metals(Liu, 2014). Generally, pretreatment of copper anode slime is the first stage of the whole process. The aim of the pretreatment process is to remove Cu, Te and Se etc and enrich the valuable metals. The methods of pretreatment process can be differentiated into: pyrometallurgical processing and hydrometallurgical processing(Amer, 2003). The hydrometallurgical processes are more promising compared to pyrometallurgical processes in terms of cost effectiveness, low energy consumption and environmental concerns(Ranjbar, 2014). However, the disadvantages of the hydrometallurgy process are evident, such as lengthy processing times and low efficiency. Therefore, it is necessary to develop a highly efficient and environmentally friendly pretreatment method."

Jan 1, 2018