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By A. D. Shuloyakov, G. A. Finkelstein, V. I. Kurets, A. K. Vedin

"In disintegrating solid ores with mineral values disseminated in them, one of the principal tasks is to selectively separate valuable mineral particles from the matrix in which they reside, striving at the same time to keep their natural shape and size as intact as possible.The conventional mechanical disintegration methods do not meet this most important requirement in full. The other major objective here is to reduce electric power consumption during the fragmentation stage, since up to 65 per cent of the total power consumption at concentrators processing ores of non-ferrous, ferrous, rare, and precious metals is spent on disintegration steps.Numerous experiments conducted on dozens of ore types (tin, tungsten, and many others, as well as on rock containing diamonds, rubies, emeralds, etc.) have invariably demonstrated by far superior integrity of mineral values as compared with that obtained by mechanical as well as other types of disintegration.However, the process remains as power-intensive as ever which is due to the imperfect nature of the electro-technical devices that convert the network electric current into high-voltage electric impulses responsible for the disintegration process.The maximum capacity attained in disintegrating the hardest materials from 40 mm to 2 mm size in a single operating chamber with four high-voltage electrodes does not exceed 1.0-1.5 t/h. Attempts at increasing the number of electrodes and the capacity of the operating chamber have failed so far because of high overall dimensions and mass of the electrical part of the installation supplying the chamber with pulsating current, as well as of the commutation requirements. At the same time, a number of overseas operations have reported a significant breakthrough in their attempts to reduce dozens of times the overall dimensions and mass of the discharge impulse generating installation (EIS), which enables us to contemplate to increase the capacity of the EIS at least ten times in the nearest future. Yet, even with the currently achieved capacity of the EIS, these installations have found wide use in geological surveying, precious and semi-precious stones production, in grinding super hard materials, etc., since they provide spectacular selectivity of disintegration and thus the integrity of valuable mineral crystals."

Jan 1, 2003

By Ramon V. V de Araújo, Roberto B. E Trindade, Pablo R. Fica-Piras

"Lead has been reported to affect blood vessels and kidneys. It also produces adverse effects in the mental and physical development of children and nervous system of adults. It is also considered as a possible cause of cancer. Because of all these threats to the human life, the reduction of its environmental occurrence, by means of recycling, is an important additional advantage to the usual ones derived of the procedures of the secondary metallurgy: lead can be recycled several times maintaining its characteristics equivalent to the primary one.Furthermore, this way of producing the metal avoids the environmental impacts of primary lead melting. Also, as an additional advantage, it triggers the metallurgical process with a raw material in what we observe higher lead content than in the natural ores. Some of the potential sources for these purposes are: ashes, slags, electrode residues, anodic muds, spent electrolytes, solid and liquid wastes, industrial or automotive catalysts, worn-out or obsolete equipment components and/or final consumption products.About 40% of world’s lead production comes from automotive batteries, mainly composed of four parts: plastic box, electrolyte (diluted sulphuric acid), contacts and connectors of Pd-Sb and plates (PbSO4, PbO2 and PbO). The plates represent 75% of the total mass. Metallic parts can be melted at moderate temperatures and then refined. The remaining fraction, constituted by the non-metallic portions, can be recovered by hydro and electro-metallurgical routes. These routes are preferred instead of pyrometallurgical ones due to the ultimate emissions of lead particulates and sulphur dioxide.The principal constituent of the residual paste of batteries is the lead sulphate. In this process, the paste is treated in two stages: in the first, lixiviating with Na2CO3 (desulphurization of the paste), obtaining PbCO3 and Na2SO4; in the second, the lead carbonate is lixiviated with HNO3, producing Pb(NO3)2, soluble, that can be converted to metallic lead by electrolysis. The reaction of PbSO4 with Na2CO3 in aqueous solutions is fast: the global rate is limited by the diffusion of the carbonate ions inside the reaction medium."

Jan 1, 2003

By Xiaoming Wang

This paper presents an arcuate magnetic separator to remove the grinding ball fragment directly from the mill discharge, which will cause wear to downstream processing equipment such as pump, hydro cyclones and pebble crusher. Furth more this type separator was applied in Wushan mine under China National Group Corporation in China. After months of operation, the equipment has been a success. It removes majority of ball fragments from mill discharge. Keywords: magnetic separator, sag mill, pebble crusher, grinding ball fragments

Sep 1, 2012

By Briony C. Ruse, David V. Boger, Fiona Sofra1

"The sustainability of the mining industry must be addressed through improving tailings management. The use of thickened tailings and pastes stems from a paradigm shift towards designing tailings disposal sites to suit their surrounding environment, rather than manipulating the environment to accommodate the tailings. Thickened tailings and pastes usually exhibit non-Newtonian behaviour, so a thorough understanding of the rheological characteristics of the material is required in order to determine the disposal plant operating conditions.As environmental factors translate into economic issues, minimising waste production using dry disposal methods is gaining popularity. The use of rheological information is of high importance in evaluating the spreading characteristics, the transportation and the dewatering of thickened mineral tailings. The principles outlined may be applied to many industries encompassing a wide range of waste materials. The main obstacle to the widespread implementation of dry disposal methods has been the high initial capital cost of the methods due to the dewatering step, and the high cost of pumping thick suspensions across any great distance. Proper and thorough costing of tailings disposal activities combined with an accounting approach that shows closure and post-closure care costs on a per tonne basis of tailings disposed throughout the life of the tailings facility will show that dry disposal methods are more favourable than they might seem on initial appraisal."

Jan 1, 2003

By A. N. Zagorodnyaya, T. N. Bukurov, Z. S. Abisheva, A. S. Sharipova

"This work presents the results of the development of a flowchart for the processing of copper production dusts resulting in the production of of lead sulphate, tribasic lead sulfate (TBLS), ammonium perrhenate, zinc, copper-cadmium cake.Dust having the following composition (wt. %): Pb 39.3, Zn 6.5, Cu 5.5, Stotal 10.8, As 1.05, SiO2 0.6, Cd 0.8, Bi 0.04, Ag 0.02, Re 0.03 was used in the work. Chemical and X-ray analyses indicated that lead, zinc and copper are generally present in dusts in the form of sulfates, various amounts of oxides, sulfides, silicates; sulfur (according to chemical analysis data) is present in the form of sulfates (~ 90%) and in the form of sulfides (~ 10%).Studies have been made on two-stage stripping of copper production dusts containing lead, zinc, copper, cadmium, rhenium in the form of various compounds, at first with soda solution, then with nitric acid solution. It has been indicated that the combination of the operations allows the recovery of 98% rhenium, 82% lead, 92% copper, and 96% zinc and cadmium each in the solution. Furthermore, at the stage of dust leaching with soda, 80% of rhenium and 0.01% of nonferrous metals each are recovered in the solution. Remaining quantities of all metals are recovered in nitric acid solution up to maximum values. Such behaviour of metals is caused by metal phase content in dusts and properties being formed during leaching of compounds. At the stage of dust leaching with soda solutions, carbonates with various compositions are formed due to the exchange reaction between nonferrous metal sulfates and sodium carbonate. The conversion of PbSO4 into PbCO3 is apparently occurs in the solid phase and the conversion of readily watersoluble zinc, copper, and cadmium sulfates into that of carbonate salts occurs in the liquid phase. Rhenium passes into solution due to the presence of rhenium greater quantity in dust in the form of readily soluble perrhenate. Some portion of the perrhenate is, probable, blocked by lead sulfate and liberated in the conversion of PbSO4 into PbCO3."

Jan 1, 2003

By Francesco Montanari, Gianni Schena

"Recent improvements in X-ray computed tomography allow investigation of objects several tens of millimetres in dimension with spatial resolutions in the order of a few microns. These improvements are made possible by coupling the micro-focus technology adopted by some of the latest cone-beam X-ray sources with an increase in the efficiency of the detectors. The micro-focus technology allows the production of clearer images at high magnification by reducing the penumbra (fuzziness) associated with larger focal spot size.Even higher resolutions can be expected in the next few years with the commercialisation of nano-focus X-ray tubes. In practice one can inspect a system of fine composite particles and analyze the different mineralogical phases in each individual particle. Computed tomography allows accurate liberation studies, e.g. providing liberation spectra or washability data in tens of minutes. However, on-line application of micro-focus computed tomography is unlikely in the foreseeable future, despite rapid development.Dual-energy (DE) radiography is another X-ray technique, which allows retrieval of the volumetric content of valuable components in two-phase particles in a fraction of a second. A digital radiograph of a single two-phase particle produces a grey level image, where the luminosity of the pixels is determined by the sum of the attenuation levels of all the structures. Thus morphological and compositional effects concur to produce the radiographic image, which does not allow retrieval of the composition of the particle, as the 3D-structure of the particle is compressed into a 2D-image, with an obvious loss of information. Thus, in principle it is not possible to discriminate between thick, comparatively penetrable, and thin, comparatively impenetrable mineralogical components."

Jan 1, 2003

By Jian Zhang, Yongfu Yu, Fuguang Zhang, Liping Che

There is one large-scaled iron ore deposit in Inner Mongolia of China, but it is very complex which includes about 170 types of minerals and 71 elements. The hematite, magnetite are mainly iron ores. It is difficult that the iron mineral can be separated efficiently by common dressing methods due to the complexity, and the iron concentrates in the mineral processing factory contains many foreign substance such as K, Na and Si so that the process in iron mill is influenced because of the foreign substance, so it is vital reducing the foreign substance.

Jan 1, 2003

By Wang Xiaotie, Yu Yongfu, Che Liping, Zhang Fuguang

The flotation process of native Rare Earth minerals such as bastnasite, monazite, mixed minerals of bastnasite and monazite, using the new effective collector Dh was studied in this paper, respectively, and the flotation properties are described. The good qualities of the new collector Dh were revealed through comparing with other collector of Rare Earth minerals. The test results of different ore samples show that at moderate pulp pH (8.5-9.5), Rare earth minerals can be effectively separated from barium, calcium and silicon bearing intergrowth minerals (barite, calcite and silicate minerals) and high quality Rare Earth concentrates can be obtained successfully by the new collector Dh, acid silica gel, turpentine and reagents fitting together rationally. In order to determine optimum technical conditions, the effect of pulp pH, pulp temperature, pulp density and the effect of dosage of reagents (Dh and acid silica gel) on the flotation were investigated in the test.

Jan 1, 2003

By Liping Yu Che, Xiaotie Wang, Mingli Cao, Jizu Yongfu Yuan

"It is difficult separating fluorite from Ca, Ba, Si intergrowth minerals than simple from Si, using common reagents such as combination of oleic acid or paraffin soap and water glass, but the finest quality fluorite concentrate whose grade is over 96%F must be required in chemical plant.This paper studies the flotation process of native fluorite from calcite, barite and silicate minerals whose flotation properties is similar to fluorite, using new effective collector H602 and new depressor S602 that is cheaper in cost, and describes the flotation properties. In order to determine optimum flotation separation condition, the effect of pulp pH, pulp temperature, pulp density and the effect of dosage of reagents on flotation were investigated and the flotation result was provided by oleic acid collector and the results of collector H602 were compared with those of collector oleic acid in the test. The test result of ore samples shows that at moderate pulp pH values (10.5-11.5) and other moderate technical conditions, the fluorite mineral can be obtained by new reagents and the rational reagents combination. The conclusion is 98%F of fluorite concentrate can be obtained, using the combination of H602 and S602 and only 5 steps in techniques. The paper discusses the mechanism of the flotation separation of fluorite mineral from intergrowth minerals."

Jan 1, 2003

"The Merensky Reef is a platinum group minerals (PGM) bearing reef in the Bushveld Igneous Complex in South Africa. The reef has been treated by bulk PGM and sulphide flotation with the aim of maximisingthe valuable minerals recovery and gangue minerals rejection.Synthetic water with a calcium concentration of 80 ppm and 500 ppm was prepared and the flotation results obtained were compared to a simple electrolyte in order to determine the effect water quality has on pentlandite and pyroxene surface alteration and, ultimately, floatability. During the study, the possible effect of interactions between the minerals investigated and Ca2+ ions in the presence of sodium isobutyl xanthate was studied at pH 6 and pH 9 by means of zeta potential determinations, microflotation tests and ToF-SIMS analysis.The results obtained on 1:1 pentlandite-pyroxene mixtures showed that the quality of process water plays an important role in flotation. The flotation recoveries of pentlandite and pyroxene were lower in synthetic process water compared to those obtained in a simple electrolyte solution."

Jan 1, 2003

By Daniela Venter, Stephen Chryssoulis, Ken Stowe

"A sampling campaign was conducted at Kemess in order to identify and assess the chemical and physical factors, which control free gold flotation kinetics in the rougher and cleaner circuits. The rationale behind this approach was that accurate knowledge of the parameters affecting free gold flotation kinetics, can be used to determine how to accelerate free gold flotation. Collected samples were composites of 5-6 cuts over a four-hour period, at steady plant conditions.In the rougher circuit, coarser equidimensional gold particles floated ahead of the finer grained and the flaky gold. Sulphur followed by molybdenum and to a lesser extent silver enhanced gold flotation kinetics, while hydroxyl followed by carbonate ions induced depression."

Jan 1, 2003

By G. Demi, G. Belardi, N. Shehu, S. Cico

The physico-chemical interaction between minerals such as olivine, chromite and serpentine and the ions most commonly present in solution, like Ca and Mg and flotation reagents such as EDTA and oleic acid was investigated. The study was conducted via release tests, electrophoretic measurements and microflotation of selected minerals coming from the Kukes deposit (Albania).

Jan 1, 2003

By C. Y. Sun

Flotation of chalcopyrite and unactivated malachite with xanthates (ethylxanthate, butylxanthate, octylxanthate and dodecylxanthate) is studied in this paper. Minerals interacted with xanthates are detected by FTIR, and simulated by molecular mechanics. It shows that chalcopyrite can be floated with 4 kinds of xanthates, and unactivated malachite can?t be floated with ethylxanthate but can be floated directly with later 3 kinds of xanthates while characteristic absorption peaks of those four kinds of xanthates are all detected by FTIR on chalcopyrite and malachite surface. After simulating the interaction between xanthate and mineral, it shows that H2O and OH-can interact with chalcopyrite and malachite, and their interaction energy may be so called energy bulwark which must be overcome by collector when collector interacts on minerals; the two sulfur atoms in xanthate group interact with copper and neighbor iron atoms on chalcopyrite. It also shows that molecular mechanics results with logP of collectors can interpret the mechanism of xanthate-mineral on atom scale.

Jan 1, 2014

By André Mans, Frans B. Waanders

"Ferrosilicon (Fe-Si) is an important commercial material and it forms the basis of the powder used in dense medium separation (DMS) of various minerals in a minerals beneficiation process. Current losses of Ferrosilicon (Fe-Si), which is used in the dense medium separation (DMS) of iron ore at Kumba Resources, Sishen, South Africa occur due to adhesion to the separation products and also by being present in the effluent stream, due to abrasion. The losses contribute greatly to the running cost of the plant and the purpose of this project was to determine the characteristics of the unused Fe-Si and then to characterise the changes that occur during storage and the use thereof.A Scanning Electron Microscope (SEM) and Mössbauer Spectroscopy (MS) were used to investigate the characteristics of the fresh and used Fe-Si. The SEM analyses of the Fe-Si yielded a composition of 15 wt.% Si and 85 wt.% Fe with minor impurities of Mn and Cr (<1 wt. %), resulting in an ordered phase with a calculated composition of Fe2Si. The average density of the Fe-Si was found to be 7.177 g.cm-3 whilst the size distribution was determined with the d50 of the particles being approximately 30 µm. A slurry, containing 10% solids was prepared, which had a density of about 1.1 g.cm-3 and this slurry was used to conduct the various experiments under laboratory conditions at the university. Samples were taken at regular intervals from a storage container containing a lime solution as well as from a closed circulation circuit system, kept at a constant temperature of about 60°C. Mössbauer Spectroscopy yielded, for the new fresh Fe-Si-samples, a two-sextet spectrum with hyperfine magnetic field strengths of 19.9T and 30.7T respectively, and the yellow-brown froth was found to be akaganeite or ß-FeOOH.It was found that the biggest loss of Fe-Si was due to the abrasion of the particles during the DMS process. A possible change in magnetic properties was also observed, leading to further losses that could occur during prolonged use of the medium. No clear changes to the Fe-Si occurred during correct storage methods, as was initially thought."

Jan 1, 2003

By Barda K. Mishra, Surya P. Mehrotra

"INTRODUCTIONIn a jig, which is primarily a coarse mineral concentration device, the bed of mineral particles is pulsated with a stream of water resulting in the particles of different specific gravities. It operates in a cyclic manner – the jig cycle consists of four stages, namely, inlet, expansion, exhaust and compression. In the inlet stage the bed lifts up en masse. Near the end of the lift stroke the particles at the bottom of the bed start falling resulting in the loosing of the bed which, in turn, causes its expansion or dilation. During the third and fourth stages the particle resettle through the fluid, and the bed collapses back to its original volume. The pulsation and suction are repeated to bring about stratification with respect to specific gravity across the bed height. Various parameters affecting the stratification process include amplitude and frequency of pulsation, bed thickness, rate of hutch water flow, and feed characteristics. This paper first presents a review of various jigging theories and then describes a new approach to mathematical modeling of jigging employing the discrete element method.JIG MODEL BASED ON DISCRETE ELEMENT METHOD (DEM) APPROACHThe jig models based on DEM essentially involve tracking the position of each particle incrementally, applying Newton’s law of motion and a force displacement law at the contact. The model presented here is based on a three dimensional mathematical description of solid-solid and fluid-solid interactions. In this model, the force balance on a particle is extended to account for the effect of continuously varying fluid on the particle. The total force on each particle is made up of a known external body force, fluid particle interaction force and particle-particle and/or particle-wall interaction force. The fluid-particle interactive force is primarily made of drag and buoyancy. Di Felice’s correlation is used to evaluate the drag force. Solid-solid interaction is described by treating particles as discrete elements that are indestructible but interact with each other and any other elements present, such as walls, when they make physical contacts. A pair of spring and dashpot represents a contact The contact forces are computed from the amount and the rate of overlap of the particles at the contact. The motion of the particle is due to movement of the fluid, which transmits its energy through the particle-particle contacts. A computer program incorporating both the contact and the fluid model has been developed. It takes the operating parameters such as amplitude and frequency of the pulsating fluid, pertinent data concerning particle properties and the geometry of the jig bed as inputs."

Jan 1, 2003

By Máximo Pérez, Julio C. Videla, Rosa Dzioba

"This paper reports the hydrometallurgical treatment of gravity concentrates of gold samples and outcrops associated with graphite ores obtained from:• flotation tailings of crystalline graphite minerals• outcrop samples of graphitic rock associated with auriferous minerals and free gold located in the Villa Union district and surrounding areas - La Rioja Province - Argentina.Previous studies of the flotation potential of crystalline graphite minerals failed to consider the presence of noble metals.The samples represent a mineralized zone of crystalline graphite which is distributed in different formations with a NE - SW trend in Maz, Punta Colorada and Las Ramaditas hills, covering an area of about 300 square kilometers."

Jan 1, 2003

By Buks Kruger

"After the milling and flotation of the platinum bearing ore, the flotation concentrate is electrically smelted in 6-in-line electric arc furnaces and the resulting furnace matte treated in Peirce Smith converters to remove the iron sulphide. The iron free (less than 1% Fe) converter matte is then granulated and sent to the Base Metals- and Precious Metals Refineries for further processing.During the smelting and converting processes two distinct gas streams are produced.The Peirce Smith converter off gas contains 4% - 9% SO2 which is treated in a conventional Sulphuric Acid Plant to produce sulphuric acid (H2SO4).The electric furnace off gas contains 0.9% SO2 and was (until September 2002) vented through a 91 meter high stack to atmosphere.Off gasses which contain less than 3% SO2 is difficult to handle and quite a few processes had been developed over the years to cope with this gas. A broad spectrum of process suppliers and technology approaches is available and the different technologies can be divided into a few main approaches i.e.Scrubbing of the off gas with an alkaline solution to produce an environmentally friendly and stable waste product which can be discharged onto a tailings dam or permanent landfill site.Physical absorption of the SO2 into a chemical solution to produce high quality chemically pure process chemicals.Catalytic reaction of SO2 with O2 to produce SO3 which is absorbed in water to produce sulphuric acid of less than 90% strength.In October 2002 Impala Platinum commissioned a Sulfacid Plant at its Smelter in Rustenburg which recovers the SO2 from the electric furnace off gasses into a weak sulphuric acid solution.The Sulfacid Plant technology is widely used in the paint pigment industry. This is, however, the first application of the technology on electric furnace off gas.The furnace off gasses contains flue dust which is removed in electrostatic precipitators. The gas exiting the precipitators normally still contains between 40 mg/Nm3 and 60 mg/Nm3 dust and passes through a quench-scrubber before entering the reactors. The quench-scrubber cools the electric furnace offgas down from ± 200 °C to 60 °C and act as a final dust removal stage."

Jan 1, 2003

By Scott C. Brown, Ivan U. Vakarelski

The particles commonly encountered in mineral benefication schemes have irregularites that are expressed at many different length scales. In part, this originates from preceding processes (e.g. makedown, comminution, handling and storage), which are known to chemically and physically modify the bulk particle and its surface. Interparticle tribology, dissolution and reprecipitation events along with large-scale mechanical stresses are just a handful of the interactions encountered during processing of particles prior to separation. It is feasible to imagine that each one of these events may impose a fingerprint of characteristic nanoscale, microscale, and macroscale morphological changes that can modify the overall interaction of these particles within a system. Suprisingly there are just a few works on how these resulting features can alter the performance of benefication schemes, and especially flotation.

Jan 1, 2003

By Elena L. Chanturiya, Vladimir A. Bocharov, Roman A. Amosov

"In many volcanogenic base metal deposits of Russia the gold is closely associated with copper sulphides and pyrite. The recovery of gold associated with pyrite is especially difficult problem.Investigations of gold chemical state and mineral forms in copper-zinc sulphide ores of Gay and Barsuchiy Log deposits in the Urals have been made using EPMA, optic image-analysis, XRA, SEM, thermo-electrical force measurements and selective gold leaching experiments.Two gold varieties are determined: 1) free native gold particles (from 5 µm up to 0,25-1,0 mm), which can be liberated after grinding of ore up to 0,074 µm and named “free gold”; 2)”invisible” gold, including finely disseminated native gold and chemically bound gold. The second variety can’t be disclosed during grinding. Free gold can be recovered by gravitation and flotation while the processing behaviour of “invisible” gold is determined by properties of gold-bearing sulphides: pyrite and chalcopyrite. According to results of diagnostic leaching experiments in ores of deposits mentioned above the part by weight of free gold reaches 70%, the part by weight of the ”invisible” gold is up to 20%. About 10% of gold is enclosed in quartz and acid-soluble minerals.Theoretically (taking into account gold distribution data) it’s may anticipate gold recovery by gravitation up to 60%. However after grinding up to 50-60% of class –0,074 mm only about 40% of gold passes into oversize product including 30% of free gold and 8% of ”invisible” one. It can be recovered by gravitation. Remaining free gold and ”invisible” gold can be extracted by flotation – 25% in total. Inevitable gold losses in tailings may reach 8-10%."

Jan 1, 2003

By Georg Unland, Thomas Wegner

"Impact crushers are widely used in different industries to crush materials which can vary from soft to hard and from ductile to brittle. However, the sizing of impact crushers is still based rather on empirical than on scientific approaches. Therefore, a test rotor was developed in order to investigate the principles of comminution by impact. Rocks of diabase with different diameters were used to gain the crushing properties with the following results:RESISTANCE AGAINST CRUSHINGLikelihood of BreakageThe likelihood of breakage is a function of the impact velocity and the particle diameter. The likelihood increases with higher velocities and larger diameters. Maximum Crushing ForceThe crushing force is related to the area of projection of the rock. The smaller the particles and the higher the velocities the larger are the maximum related contact forces.Contact TimeThe contact time increases with the rock diameter whereas the influence of the impact velocity is neglectable.Mass Specific Crushing WorkThe mass specific crushing work decreases with the particle diameter and increases with the impact velocity."

Jan 1, 2003