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By D. R. Nagaraj, Raymond Farinato

Water constitutes one of the most valuable resources employed in mineral recovery and processing. Identifying potential problems encountered in mineral processing in waters unusable for drinking or agriculture (including seawater and even hypersaline waters), understanding chemical factor interactions, and optimization of flotation reagents will greatly expand our ability to create more sustainable beneficiation technologies. The current paucity of our knowledgebase regarding high salinity effects on flotation clearly signals a need for a significant research effort. We report here results of a study designed to probe effects of pulp chemistry on metallurgical performance in the flotation of Cu and Cu-Mo ores in saline waters. The results clearly demonstrate that pH (more correctly dosage of pH modifier to target a pH set point) has the most significant effect on Mo recovery when using seawater. This is linked to the formation/precipitation of Mg(OH)2 when pH = 10.3 (in seawater). The type of pH modifier used, NaOH or Ca(OH)2, had no impact on Cu or Mo recovery, indicating that Ca2+ ions were not involved in any reduction in Mo recovery in the pH range of 9-11. Our results in tap water spiked with either Ca2+ or Mg2+ ions in the same pH range (controlled by NaOH), confirmed that Ca2+ ions had no effect on Cu or Mo recovery, but that addition of Mg2+ ions had a severe adverse effect on Mo recovery at pH = 9.5, and to a lesser extent on Cu recovery. The onset of Mg(OH)2 precipitation occurred at a higher pH, and the adverse impact of Mg(OH)2 on Cu recovery (and perhaps Mo recovery as well) was less, in sea water than in tap water spiked with Mg2+. These effects are attributed to the mitigating role of the high electrolyte concentration, notably NaCl.

Jan 1, 2014

By Priyanka Dhar, Kurt Aasly, Hanumantha Rao Kota, Hassan Bouzahzah, Maria Thornhill

The interest in investigating the processing characteristics of mineral deposits in Norway has seen an upsurge in the last decade. One of the major areas of interest is a huge copper deposit, operated by NUSSIR ASA located in the Repparfjord Tectonic Window in the caledonides of west Finnmark. This study reports analysis of ore from the deposit for development and modifications in the flotation flowsheet for the NUSSIR ASA copper ore. The mineralogical characterization for the ore sample was achived by optical microscopy and Zeiss automated mineralogy while grinding characteristics were tested using Bond Index tests. The results confirmed the presence of Cu minerals in the form of chalcocite, chalcopyrite and bornite in the samples, which are mainly liberated in the – 105 µm size range. The majority of non-liberated copper sulphides associated with silica and the carbonates varies from 3 to 28 percent in the –250 µm samples . It is also observed that the copper minerals are uniformly distributed in all size ranges. Selective flotation of NUSSIR copper ore was performed in different size fractions with a motive to identify the correct liberation size and thus to obtain a copper concentrate meeting the quality requirements. The flotation experiments are essentially performed in two stages: the rougher and the cleaner stage. Mass balance calculations were performed showing that approximately 88 percent of copper can be obtained at the end of the process. Ultimately, overall circuit copper recoveries ranged between 83.5 to 88.1 % with a concentrate grade of 35 to 48 % Cu.

Jan 1, 2018

By O. A. Bascur

"In recent years, metal producing companies have increased their investment in automation and technological innovation, embracing new opportunities to enable transformational change. Internet of Things (IoT) is one of many transformational initiatives, which can fundamentally revolutionize how industrial complexes operate. Whatever the issue, the answer is in the abundant and growing quantity of real time data and events collected in the grinding and flotation circuits in a mineral processing plant. Based on earlier work, today a grade recovery model permits identifying the best operating conditions in real time. We will review the strategy for increasing the value of the abundance instrumentation in current plants. An optimal Gaudin size distribution model provides augmented information from traditional sensors to find the optimal grind cut to reduce metal losses in the flotation circuits. The large amount of sensors in a flotation circuits permits to estimate the recovery and to find the optimal froth depth and aeration using an air holdup flotation model. The paper will describe the strategy of classifying data for on line generation of insights to using operational intelligence tools. We will discuss the implementation Recovery/Grind strategy with industrial examples in non-ferrous mineral processing and iron beneficiation.INTRODUCTIONThe declining supplies of high grade ores and increasing consumption of mineral and metal products have demanded higher operational efficiencies with minimum capital investments. The objective of copper flotation objectives are based on maximizing the dollars return on the concentrate produced. The economic efficiency is maximized by manipulating the circuit along the grade/recovery curve relationship. To achieve such objective improved stabilization of the grinding and flotation circuits are required (Oosthuizen, Craig, and Jamsa-Jounela, 2017)."

Jan 1, 2018

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and. crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study. Examination of the elemental composition of the minerals, ion-molecular components of the liquid phase in suspensions, surface properties of sulfides and different flotation reagents sorption forms was performed using the methods of X-ray phase and spectral analysis, potentiometry, UV and IR spectrometry, computer image analysis, and computer simulation techniques. The role of isomorphous impurities in the formation of hydrophobic sulfhydric collector layers on mineral surfaces in complex ore processing has been elucidated. The parameters characterizing the variability of the Fe:S ratio in pyrite of different origin have been determined based on non-stoichiometry characteristics of natural gold-bearing sulfide crystals. An ingenious method of formatting and linear approximation of experimental data was used to find out the quantitative relationships between the impurity content, electrophysical characteristics, non-stoichiometry and floatability of pyrite from a number of different deposits. The effect of the impurity species present in sulfides on the characteristic pH value marking the floatability peaks as such and their trend of shift towards higher alkalinity has been revealed. A theoretical substantiation has been given to prognostic assessment criteria for processing characteristics of gold-bearing sulfide minerals with varying composition. New flotation reagents and advanced reagent systems which help to increase the contrast of processing characteristics for different gold-bearing sulfides, resulting in improved selectivity, have been developed. The mechanism of selective flotation of precious metal-bearing Fe and As sulfides achieved by using short-chain dithiocarbamates and a mixture of cyclic trithiocarbonate with oxyalkylsulfides has been analyzed.

Jan 1, 2003

By S. Narra

The importance of bio-products production is enhanced with the abundance and renewability of ligno- cellulosic biomass in comparison to the depleting fossil fuels especially in producing environment friendly energy. Lignin is obtained as a sludge residue from the pulp and paper industries as well as from the bio- ethanol /bio-gas production plants. Lignin is a renewable fuel with a high heating value equivalent to anthracite coal, low ash content and hydrophobic properties. The extracted lignin in paper and pulp mills is usually burnt at the mill directly to cover the energy production costs of the mill. The efficient utilization of lignin can reduce the percentage of lignin sludge used for energy production in comparison to the present situation. Presently the lignin is burnt /incinerated as sludge with minimum of 30 to 50 % moisture content. This high moisture content reduces the energy efficiency and simultaneously utilizes more amount of lignin sludge in producing the required energy. This paper explains a possibility of integrating sludge-pelleting techniques in paper and pulp mills. The integrated sludge-pelleting techniques would lead to an optimal utilization of lignin for energy and would simultaneously save the lignin resource for material utilization. The sludge pelleting process solves also the problem of handling, storage and explosion risks of lignin when compared to the present situation.

Sep 1, 2012

By Yimin Zhu, Dezhou Wei, Haijun Liang, Zhifu Zhou

It has been fairly well established by many experiments that Thiobacillus ferrooxidans (T. ferrooxidans), also named Acidithiobacillus ferrooxidans(Kelly and Wood, 2000),can depress the floatability of pyrite. However, the mechanisms governing the process have not been known completely. In the present investigation, wettability and electrokinetic studies were carried out to examine the surface chemical changes on pyrite before and after interaction with T. ferrooxidans or its secretions. Attachment of T. ferrooxidans to pyrite was observed using a scanning electron microscope. The results of experiments showed that, under certain conditions, T. ferrooxidans and its secretions would obviously change the surface electricity of pyrite and result in the iso-electric point of pyrite shifting notably. However, the surface wettability of pyrite hardly changed and its hydrophobicity increased little after interaction with T. ferrooxidans and its secretions. Based on the results of the present investigation it can be reasoned that the depression of floatability of pyrite is due to the reduction of surface free energy, rather than the increase of surface hydrophilicity of pyrite. The decrease of surface free energy weakens the attachment of collector to pyrite; during the process bacterial protein plays the most important role and the bacterial chemotaxis strengthens the effect.

Jan 1, 2003

By I. Silin, H. Wotruba, J. Huben, A. Ognyanova

"With increasing shortage of raw materials, the beneficiation of ultra-fine ores will play a larger role in the near future. Many established process technologies do not yield satisfactory separation results for ultra-fine materials. Without selectivity, high-grade concentrates cannot be produced. The material at hand is a taconite which had to be ground to d(90) = 25 µm to guarantee liberation of the iron oxides. The comminution was done by High Pressure Grinding Roll (HPGR) and resulted in smooth surfaces and clear grain boundaries. This is an indication of selective grinding and mineral liberation. Further processing steps included selective desliming, magnetic separation as well as reverse flotation. INTRODUCTION During the last centuries, the processing of iron ores became increasingly important. The coarse-grained, so-called lump ores that are ready for direct usage in blast furnaces without further processing are becoming gradually less abundant. The processing of ultra-fine-grained ores, which in addition require a complex ore beneficiation due to the composition of the material, will progressively gain relevance with increasing resource shortages in the future (Arvidson, 2013). The term “ultra-fine” does not hold a precise definition in mineral processing. In this paper, “ultra-fine-grained” ores are defined by the required grind size for full liberation smaller than 20 µm. Many established mineral processing technologies do not yield satisfactory separation results for ultra-fine materials. Thus, they are limited in their application to produce high-grade concentrates suitable for sintering and pelletizing for direct reduction processes. The production of a high-grade iron concentrate (over 68% Fe) with low silica content (under 2.5% SiO2) is possible from both magnetite and hematite containing ore. In addition to the mineral processing technologies (magnetic and gravity separation, flotation), technologies for the liberation of fine-grained iron ores need to be developed and improved. In contrast to the conventional wet grinding circuit by means of tumbling mills, several future trends in dry and wet grinding and regrinding are already in use. These include technologies such as vibration mills (Palla®Mill), stirred media mills (Vertimill®), vertical roller mills (Loesche) and high-pressure grinding rolls (HPGR) (Jankovic, 2015). This study preliminary investigated the mineral processing of a low-grade, ultra-fine-grained, complex iron ore in a laboratory scale after dry grinding by HPGR to 90% < 25 µm without consideration of the grinding, milling, energy and classification cost."

Jan 1, 2018

By A. Makavetskas

"The purpose of the research is to study the mineralogical features of the structure of the wall accretion formed during melting on the working surface of the walls of metallurgical aggregates and adversely affect the stability of the lining of blast furnaces (BF). We presented the results of studies of the material composition of lining and wall accretion of the furnaces of blast furnaces of the metallurgical plant specializing in the smelting of ferromanganese, nodular and pig iron. It is established that the garnissage is an aggregate of layered texture, formed as a result of the crystallization of slag and metallic melts. Refractory calcium and magnesium silicates and aluminosilicates (minerals of the melilite group, leicite, olivine group minerals) and amorphous glassy oxide solid solutions of variable composition crystallize from the slag melts in the upper part of the hearth. In the slag matrix, inclusions of carbon (amorphous and graphite) and products of crystallization of metallic melts of alpha-iron, iron carbides and / or manganese are observed. Evidence of carbon evolution (in the form of graphite) is precisely in the crystallization of metal melts, there are significant differences in the structure of carbon in coke and in the garnissage. The conducted studies confirm that it is impossible to obtain reliable information on the material composition of new formations in the blast-furnace process without using a complex of modern methods of technological mineralogy.INTRODUCTION The formation of the wall accretion (garnissage) - a solid protective layer as a result of smelting products crystallization on the inner (working) surface of the liner. This is due to the design of blast furnaces with a high-efficiency heat sink using copper coolers and the use of carbon blocks with high thermal conductivity in the lining. The objective of the study was research of the material composition of the lining and wall accretion of the blast furnace hearth of one metallurgical plant that specialized in smelting ferromanganese, nodular and pig iron, to assess the effect of new formations for stability of the lining of blast furnaces (BF)."

Jan 1, 2018

By Vitaly Kretov, Valery Golikov, Vladimir Ryaboy, Elena Shepeta

"The aim of the study was to develop and implement more efficient dialkyldithiophosphate collectors. A hypothesis has been formulated on the action of dialkyldithiophosphates in the flotation of sulphide ores based on the assessment of their complexing properties and surface activity at the liquid-gas border. Dialkyldithiophosphates form weaker complexes with cations of heavy metals compared to xanthates, and are characterized by a large difference in the strength of their complexes with heavy metal cations. It provides higher selectivity of dialkyldithiophosphates in the separation of non-ferrous metal sulphides and iron sulphides from them. To make a quality assessment of the impact of surface activity of the synthesized collectors on their selectivity of action and collecting power, an assessment of the surface tension of their aqueous solutions has been performed using the stalagmometer method. It is well known that a stronger collector is characterized by a greater surface activity, in contrast to a more selective collector which is characterized by a lower surface activity. Based on studies, new dialkyldithiophosphate collectors BTF 163 and BTF 1552 are suggested for use in the flotation of sulphides to increase the recovery of copper, gold and silver. The collector BTF 163 was introduced at a gold processing plant in Kazakhstan and has been undergoing industrial testing in the sulphide cycle of scheelite-skarn-sulphide ores in a factory in the far east of Russia. The collector BTF 1552, which increases the recovery of silver and gold by 3%, was approved for industrial testing in another far-eastern factory. A modification of the reagent BTF 1552, the new reagent BTF 1522, was introduced in the flotation of copper-zinc ore at a factory in Kazakhstan."

Jan 1, 2014

By T. S. Reddy

Research and Development Centre for Iron and Steel (RDCIS) a unit of Steel Authority of India Limited (SAIL) is continuously engaged in reduction of energy consumption at SAIL plants by implementing innovative and new concepts. In this regard, continuous efforts are being made to recover waste heat in Sinter Plants. This paper discusses existing waste heat recovery measures taken and proposed measures planned in Sinter Plants. One such effort is on waste heat recovery from sinter coolers. Hot sinter is discharged to the crusher at the end of the sinter machine at a temperature of 500 to 800°C. Temperature of hot sinter is brought down to nearly 100°C in the sinter cooler with air-cooling. The air after cooling the sinter is generally discharged to the atmosphere at about 225 to 300°C. It is planned to recover heat from the hot air that is being released to atmosphere and heat the process water, which is being added at ambient temperature in mixing drum at Bhilai Steel Plant. The temperature of raw sinter mix will be raised by addition of this hot water, which will help in improving the productivity of sinter machine. It is estimated that Waste heat recovery to the tune of 1.5 to 2.0 Gcal/h is possible with reduction in CO2 emissions in the range of 4000 to 5000 ton/year. The novel approach that is being adopted is addition of hot water in mixing drum for higher sinter productivity for the first time in India. Keywords: waste heat recovery, sinter plant, hot water generation, emission reduction, CDM

Sep 1, 2012

By P. Braga, A. Chaves, S. França, A. Luz

"In Brazil, there are no official reserves of molybdenum, and the unofficial reserves are modest. Therefore, the molybdenum ore (molybdenite) produced as a co-product or by-product of emerald mining in the region of Campo Formoso, BA, has arisen as the only economic option. The flotation process is commonly used in Brazil for the recovery of molybdenite from emerald mining tailings, but it produces low-content molybdenite concentrates, thereby resulting in a product with low economic value. The molybdenite concentrate produced in Campo Formoso contains 83.5% MoS2 (50% Mo), which is less than the international standard product that contains > 90% MoS2 (54% Mo).This low value is due to the presence of talc, which is a naturally hydrophobic mineral that is also floated with the molybdenite during the flotation process. Separability studies were done in a Partridge-Smith cell using dextrin and quebracho as a molybdenite depressor in solution at different concentrations and pH values to produce a technical-grade concentrate (i.e., 90% MoS2). These basic studies were accompanied by measurements of the zeta potential and contact angle, which was determined by the capillary rise method. The results of these floatability studies were used in bench flotation tests, which were performed in a Denver laboratory flotation cell. A molybdenite concentrate of 93.4% MoS2 was obtained when dextrin was used at a concentration of 100 g/t."

Jan 1, 2014

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014

By V. Panayotov, M. Panayotova

"The combined use of semiconductor properties and specific flotation characteristics of minerals under different conditions with external influences ensures a possibility for process control and management. This work presents the relations between the volumetric and surface characteristics of minerals and the minerals' flotation ability (flotability), as well as the possibility for the flotability purposeful change. Results from proprietary laboratory and industrial research are presented showing how controlled impacts on minerals and flotation pulp improve flotation technology. Such an approach reveals prospects for the creation of new technologies for the minerals' beneficiation.INTRODUCTIONThe decrease of the useful components content in the ores, the increasingly complex nature of the raw materials, the increasing energy consumption per the unit of production, and the need to solve the problems related to the environment pollution require solutions different than the existing classical ones. One of the ways to find such solutions is the detailed consideration of the fundamental properties of minerals and, in particular, of minerals having semiconductor properties. The studies of Plaksin et al. (1968), Chanturia and Shafeev (1977), Chanturia and Vigdergauz (2008), Carta et al. (1973), Hoberg and Shneider (1975), Rao et al. (1992) have given an idea of the energy state of the minerals, their flotation ability, and the ways in which this ability can be changed in one or the other direction. The main line in these works is the study and use of the relationship between bulk and flotation properties of minerals. To improve the efficiency of the process, it is also necessary to consider the relationship between the surface properties of the minerals, especially minerals-semiconductors, and their flotation ability.THEORETICAL BACKGROUND IN BRIEFA quantitative estimation of energy changes in a solid phase in the process of flotation may be made by taking in account the changes in the Fermi level. Its position in the forbidden band is an indicator about the direction and the intensity of electron exchange between solid and liquid phases. The Fermi level energy EF enables the estimation of flotability, intensity of needed external impact before flotation, as well as efficiency of the process going on. Quantitative estimation of these processes can be made by means of the flotability coefficient Kf."

Jan 1, 2018

By Alexey P. Tatarinov

Under modern economic conditions in Russia, gold heap leaching is the most effective way of investing into gold-mining industry. Gold is recoverable from small-size deposits, low-grade ores from oxidation zone, cut-off grades, and overburden rocks using heap leaching. This technology is cost-effective and allows a saleable metal to be obtained within the first year of operation. The investments for heap leaching are lower than those of for a traditional plant technology. Production cost per one gram of Au is 5-7 times lower than that of during a plant flow sheet. A seasonal development of mines can be possible. With reference to this, heap leaching resembles the technology of placer deposits development. One of the major advantages of heap leaching is the form of the product. Gold can be obtained as dissolved in a clarified PLS, which allows the further quick treatment. The amenability of ores to heap leaching depends on their mineralogical composition. Oxidized porous ores with a good access of a lixiviant to valuable particles can be treated without pre-crushing. Clayish minerals are often found in oxidized ores with free gold. In order to build ground for heap, several major methods combined with various pad materials are used. These methods have been used at many plants and are reliable. The development of heap leaching technology for gold ores for the deposits from Yakutia, Zabaikalsky region, Primorye region, Uzbekistan, Tadjikistan, and Kazakhstan began in the 70s. However, it has been commercially used only since 1990. The first heap leach plants were built and commissioned in the USSR in 1991 at Vassilkovsloye deposit (Kazakhstan) and at Maiskoye deposit in Russia in 1994. Pilot plant testing was conducted in 1996 using ores from Kuranakh ore field, deposits Phiskulturnaya-Kholodnaya and Lopukhovskoye from the Aldan region. After the first successful commissioning of heap leaching plant in Russia, this technology has been commercially applied for deposits. Every year 1-2 heap-leaching plants were commissioned. More than 30 heap-leaching plants have been commissioned both in Russia and in the former Soviet Union using technologies developed by IRGIREDMET. Keywords: cyanide leaching, heap leaching, ore, percolation, solutions, lime technology

Sep 1, 2012

By Yury V. Kulikov, Rakan Rahbani, Arkady Y. Senchenko

"The relevancy of complex minerals treatment is constantly increasing taking into account mineral resources depletion. Different refractory ores and concentrates, oxidized and polymetallic ores, as well as metallurgical products (slags) can be assigned to such mineral type. The treatment of such products via conventional flowsheets requires considerable capital and operational costs and does not always provide high recovery level of valuable components into a saleable product. Therefore, considerable amount of ores and metallurgical products are not treated, or treated inefficiently. One of the most promising approaches that allows economic treatment of refractory products is their ultrafine grinding down to 5-20 µm with subsequent processing or hydrometallurgy. Horizontal bead mills - the IsaMillTM, developed by Xstrata Technology, received their wide application in mining industry. Standard testing is performed under laboratory conditions in an M4 IsaMillTM (volume - 4 liters) to define the parameters of fine grinding. This mill completely simulates the operation of full scale industrial mills up to 50 m3 in volume (up to 8000 kW motor). The paper describes fine grinding technology performed in bead mills, and the importance of testing according to a certified method for industrial equipment selection. The paper contains description of promising directions of fine grinding technology application for several projects in Russia and Kazakhstan."

Jan 1, 2014

By L. Stamenov, H. Bouzahzah, S. Gaydardzhiev, D. Naumov

"The Chelopech epithermal arsenic bearing high-sulphidation, copper-gold deposit located in Bulgaria is often referred as the richest European gold deposit currently under exploitation. Key points from the flotation circuit of the processing plant have been sampled and selected physicochemical parameters measured. Plant survey has followed with selected samples being submitted to chemical and mineral liberation analysis (MLA). Quantitative analysis has enabled to link the flotation response of the main copper bearing minerals with the physiochemical parameters (Eh, DO, EDTA extractable Cu and Fe) being measured. Data from mineral liberation analysis have highlighted an important process-relevant information explaining the variable floatability in the various granulometric classes.The low chalcopyrite recovery could be linked to the non-sufficient amount of dissolved oxygen measured in the copper selective flotation circuit. Given the finely-disseminated copper bearing minerals, the observed copper losses inside the flotation could be also explained by the insufficient degree of liberation of the mineral grains. Suggestions for improvement in metallurgical recovery are therefore proposed.INTRODUCTIONThe Chelopech deposit is a high sulphidation (HS) volcanic-hosted epithermal gold-copper one (Bonev et al., 2002; Kouzmanov et al, 2009; Strashimirov, et al. 2002). It is considered as one of the largest and economically most important ore deposits in Bulgaria, and often is referred to Europe’s largest currently mined gold resource. It is located in the Srednogorie zone which falls within the central sector of the extensive Tethyan–Eurasian copper belt formed during Mesozoic–Cenozoic time along the southern margin of Eurasia. The Srednogorie zone has the features of a subduction-related, Late Cretaceous island arc, with development of a calk-alkaline to sub-alkaline volcano-plutonic magmatism and associated hydrothermal ore deposits (Bonev et al., 2002).Ore mineralisation occurs as veins, mineralised breccia, and massive sulphide replacements and disseminations. Three mineralisation stages have been identified at Chelopech deposit. An early pyrite–marcasite mineralisation (stage I), characterised by disseminated to massive pyrite followed and partly brecciated by enargite– luzonite and tennantite–chalcopyrite–bornite (stage II) mineralisation. The gold is met in ores belonging to the stage II. Sphalerite and galena veins characterise stage III, best developed below and adjacent to the pyrite–enargite– chalcopyrite ore bodies. Advanced argillic altered volcanoclastic rocks commonly host this mineralisation (Chambefort and R. Moritz, 2014)."

Jan 1, 2018

By Andrei Yevdokimov, Ivan Sidorov, Olga Lanchakova, Olga Khmelnitskaya, Tatiana Chikina

"The paper focuses on the results of the research on development of hydrometallurgical process of gold recovery from refractory sulfide flotation concentrates based on fine and ultrafine grinding. Refractory concentrates (the degree of refractoriness is 16.9%-82.6%) were chosen for testing. The efficiency of the process based on fine and ultrafine grinding to treat flotation concentrates with gold intergrown with sulfides and rock-forming minerals was shown. Based on the test work conducted, the process option was chosen. In included grinding of flotation concentrate to the size of 98% minus 20µm in a bead mill, lime treatment with air blow, CIL, filtration and detoxification of liquid phase of the slurry. This process (compared to the basic option) provides the recovery of gold from 82.6%, up to 94.0% and decreases the residual grade in the tailings from 3.3g/t to 1.1g/t at the consumption of 12.6NaCNkg/t. Based on the results of the test work and pilot plant testing, project design criteria of flotation circuit at a Russian plant was developed."

Jan 1, 2014

By H. H. Li

Reverse flotation is usually used for hematite/silica or bauxite/clay flotation separation in which the silica or clay is floated and rejected. Some properties of these silicate minerals such as particle size and surface characteristics have significant effect on their flotation behaviours. Firstly, the silicate mineral particles (especially clay minerals) generally have fine particle size (< 5 microns) in their natural states or due to overgrinding and they display poor flotation kinetics, consequently having low flotation recovery. Secondly, the wettability difference on different particle basal planes influences the affinity for adsorptions of different types of chemicals such as collectors or macro-molecule. Common polyacrylamide (PAM) flocculants can be used to minimize the exposure of the most hydrophilic planes of clay particles via hydrogen bonding but they can not efficiently enhance the overall particle surface floatability due to the hydrophilic properties of this type of macromolecules. A novel method to improve both flotation kinetics and surface wettability of silicate minerals has been developed and studied. That is to use a temperature-sensitive polymer, poly (N-isopropyl acrylamide) (PNIPAM), as a process aid in the flotation of silicate minerals. Unlike PAM polymers, PNIPAM can induce a hydrophilic/hydrophobic transition on the particle surface when the temperature is changed to be lower or higher than its critical solution temperature (CST). At a lower temperature, the PNIPAM adsorbs on the particle surface via hydrogen bond similar to PAM. It induces strong hydrophobic aggregation when the temperature is increased above the CST. Thus, both floc size and mineral floatability are greatly increased. The flotation results show very good flotation performance and the addition of conventional flotation collector was no more required because the increased particle surface hydrophobicity induced by PNIPAM. Contact angle measurements explained the role of PNIPAM in manipulating particle surface hydrophilic/hydrophobic transition.

Jan 1, 2014

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"Silver is currently lost as jarosite during the pressure oxidation of sulphides and cyanidation of the residues yields 5-10% of silver. Efforts to recover silver from complex sulphides, which contain economic fractions of silver require an understanding of the behaviour of acanthite during pressure oxidation. However, previous studies of acanthite (Ag2S) reaction have been complicated by the formation of argento-jarosite and uncertainties arise on the interpretation of the results.In this work, the acid pressure oxidation of high-grade natural silver sulphide mineral (acanthite) was carried out at 110-150°C and under the conditions similar to that of pressure oxidation of complex sulphide. The predominant product of reaction is elemental sulphur. The rate of reaction increases with increasing temperature and with the presence of ferric ions. The kinetics is controlled by chemical reaction with activation energy of 72.6 kJ/mol. The rate of reaction decreases with the presence of silver sulphate in the initial slurry. The proposed overall reaction is close to: []"

Jan 1, 2003

By Carlos Rabanal, Levi Guzmán

"The concern regarding grinding media consumption rates is as old as the invention of the tumbling mill. Over the years many materials and grinding media shapes have been tested. Through all this, steel grinding balls have proved to be the most effective media for comminution in tumbling mills. There have been several approaches to be able to the wear of the ball charge in any given mill, all of them based on limited empirical evidence. The mining industry still utilizes the Bond Abrasion test that was developed in the 1960´s. As shown later in this publication, this approach shows error greater than 60%. More recently, in 2007, Radziszewski from Mc Gill University has proposed a different total grinding media wear model; this model is based on decoupling the effects of the abrasion, corrosion and impact wear mechanisms. Also in 2007, Benavente, at the time with Moly-Cop Peru, presented an empirical model relating both ore properties and operational conditions that would affect the wear performance of the grinding media. For the database referred in this article, Benavente’s model shows an average error of ± 12% which represents a higher degree of improvement in comparison with previous approaches. The current paper presents recent research conducted by Moly-Cop Peru to further improve the capability of the empirical model originally developed by Benavente to estimate grinding media wear rates. The work performed included extensive determinations of the Bond Abrasion Index for different types of ores, collected at industrial grinding applications where the corresponding operational information was made available. The results of the research enabled us to build a more robust and confident model for estimating the grinding media wear rate. The average error of this new model is in the order of ± 9% which is a significant improvement over the models previously described."

Jan 1, 2014