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By M. T. Spyridopolous, S. J. Neethling

"There has been a significant research interest in the stability of single thin films, including prediction of their failure based on disjoining pressure and film thickness experiments and DLVO theory. It is, however, notoriously difficult to correlate information on the failure of a single thin film with measurements of foam stability. This is particularly true for the prediction of dynamic foam stability indicators, such as equilibrium froth height and surface bubble size.An alternative experimental approach to studying single thin film failure for predicting foam stability is to measure directly the coalescence probability between two approaching bubbles in a surfactant solution. These experiments can be performed under different chemical and physical conditions by using a micromanipulator that allows variation of bubble size, surfactant concentration, approach velocity and stationary position. The interface radius of curvature, the time to coalescence and the film area between the bubbles can be measured directly using image analysis.In a foam, the force exerted on the thin film separating two bubbles depends on the local radius of curvature of the Plateau borders and vertices, which depends in turn on the local liquid content. Results from different bubble sizes in the micromanipulator therefore translate into regions of different liquid content in the foam. Small bubbles, having a high radius of curvature correspond to the low-liquid content (Polyhederschaum) region higher in the foam, and large bubbles to the wetter (Kugelschaum) region closer to the liquid-foam interface. Experiments with different holding distances between the bubbles correspond to differences in bubble size in the foam, as the size of the film between the bubbles varies."

Jan 1, 2003

By D. Govender

Theoretical flotation models suggest that there is a positive relationship between bubble-particle collision rates and turbulent kinetic energy dissipation. Fine particle flotation performance is generally enhanced by increased collision frequency and hence higher energy dissipation. Contrarily, increased turbulence in the rotor-stator region is related to higher detachment frequency of the coarser size range. Therefore, the optimal modes of recovery for the ?fine? and ?coarse? size classes are diametrically opposed. Industrial applications have previously confirmed that applying greater power to flotation slurries yields significant improvements in fine particle recovery. However, recovery of the coarser size class favors a different flotation environment. An improvement in the kinetics of the fine and coarse size classes, provided there is no adverse metallurgical influence on the intermediate size ranges, is obviously beneficial to the overall recovery response. Managing the local turbulent kinetic energy dissipation, and hence the power imparted to the slurry, offers the benefit of targeting the particle size ranges exhibiting slower kinetics. FLSmidth recently introduced the practical implementation of this concept. In principle, it decouples flotation regimes where fine and coarse particles exhibit preferential recovery. In the case of naturally aspirated machines (Wemco®), it is referred to as Hybrid Energy Flotation? and incorporates at least three phases: ? Standard flotation machines (standard energy input, rpm, rotor size/type) at the beginning of the row, where flotation is typically froth phase limited and operational, and set-up parameters have a limited influence on the recovery. ? Higher-powered flotation machines (high rpm, high power rotor size/type) at the end of the row to improve fine particle recovery. ? Lower-powered flotation machines (low rpm, low power rotor size/type) to enhance coarse particle recovery. In evaluating the effect of turbulent kinetic energy on flotation performance, the spatial distribution and its effect on size denominated recovery needs to be evaluated. The mean energy dissipation rate is a measure of the bulk energy input, but CFD-based models offer a more introspective view of flotation sub-processes. A CFD-based flotation model is used to highlight the effect of turbulent dissipation energy on attachment and detachment rates. Preferential collection zones for ?fine? and ?coarse? particles are predicted for both forced air and naturally aspirated machines. Keywords: CFD-based model, attachment, detachment, energy dissipation, hybrid energy flotation?, forced air, naturally aspirated

Sep 1, 2012

By C. Gomez, J. Finch, R. Dalhke, J. Torrealba-Vargas

The velocity of gas passing through a flotation cell can be estimated by collecting bubbles by natural buoyancy in a closed tube and measuring the rate of pressure increase. The governing equation is derived and verified. Single- and two-tube gas velocity sensors are described. The latter design permits a correction for bulk density and level change during signal collection.

Jan 1, 2003

By M. Bhartia

India is the 5th largest producer of steel in the world and is slated to produce more than 180 Mt by 2020. Expectedly about 50 % of this would be through the Blast furnace route and the rest through Sponge iron / DRI route. Considering that there will not be any major change in iron making technology by that time, the Blast operation would require lump ore (10-40mm) with around 64% Fe grade and sinter fines (<10mm) with 60% Fe (min) as its feed. DRI process would need calibrated ore of size 5-18 mm as the most suitable size of feed. It is also expected that of the total requirement of ore for the DRI route a significant part would be DRI pellets. In India, there is considerable debate going on regarding the technology to be adopted for the processing of iron ore and there is a lack of clear consensus. The above scenario indicates that the processing requirement of iron ore in the country would involve both washing technology as well as beneficiation technology. CDE Asia Ltd is in the forefront of iron ore processing in the country and the experience gained by the company over the last few years of functioning has led the company to believe that route to be adopted depends on the end product requirement and the starting grade of the feed. Keeping in mind the nature of the feed required for the Blast furnace & DRI operation; it is obvious that good washing technology would be highly beneficial to the iron ore industry. Depending on the grade of ore available the limits of washing will be decided and equipment for lump ore beneficiation such as jigs could be incorporated into the washing circuit. Scrubbing of ore either before washing or selectively scrubbing the lumps could be necessary. Very low grade ore and jig rejects would be required to be totally ground and beneficiated for the production of pellet feed in order to utilize the iron ore resources entirely. Another source of ore for pelletisation would be slimes generated from the washing process as well as the huge quantities already available in the tailings dams in the operating mines. Deslimimg and magnetic route of beneficiation could release at 30-40% of the Fe locked up in these tailings ponds/dams. The paper describes the concept with examples from operating plants and proposes how the adoption could be engineered through test work and proper plan of integration. Keywords: washing, beneficiation, iron ore, lumps, sinter fines, pellets, jigs, screens, evowash, nanowash, thickeners, log washers, drum scrubbers

Sep 1, 2012

By A. De1

Because of the extremely low utilization of strain energy in the breakage of solid particles, the energy efficiency prevalent in comminution technology is extremely poor. Schoenert considered that single-particle comminution under slow compression is the most energy-efficient mode of comminution and that energy efficiency should be compared to that. The usual method for grinding minerals and cement has been the ball mill, in which the hit-and-miss aspect of loose-bed comminution severely reduces energy efficiency. The fine grinding of minerals is a particularly energy-intensive process. Schoenert showed that the energy consumed in the comminution of particles in confined beds is second only to that of single-particle comminution under slow compression and developed the method of conducting particle-bed comminution continuously in a high-pressure roll mill. Since its first industrial installation in 1985, the high-pressure roll mill has established itself as the comminution device of choice for significantly improving the productivity and energy efficiency of size reduction from coarse size feeds down to products finer than 20 microns. The first of several hundred installations were in cement plants. The preliminary design and optimization of the industrial operation of high-pressure grinding roll (HPGR) systems, owing to the continuous nature of the device, cannot be efficiently done through laboratory experiments and needs to be achieved through proper system modeling. While the energetics of size reduction in high-pressure grinding rolls has been modeled very well, no model exists for the macroscopic variables in HPGR comminution. In high-pressure roll mill grinding, size reduction results from confined particle-bed comminution under compressive stresses such that the daughter particles produced are highly fractured, stressed, or otherwise weakened. This paper attempts to relate the comminution / compaction behavior for confined particle-bed under compression in a piston-die press with the macroscopic variables in HPGR comminution. A model describing the pressure-densification relationship is presented and used to accurately simulate the macroscopic variables in high-pressure grinding rolls, utilizing experimental data for particle-bed comminution with the piston-die press. The accuracy of the predictive simulations strongly suggests that, starting with a few batch-mode laboratory-scale experiments, it should be possible not only to identify the optimal operating conditions for existing operations but also to successfully design new industrial high- pressure grinding roll systems.

Sep 1, 2012

By P. K. Rozakeas

It has been experimentally demonstrated that the application of electrokinetic techniques in the continuous flow of coal-water suspensions within a helical anode-cathode pipe geometry effectively causes a significant reduction in the wall shear stress. This reduction in the frictional force at the cathodic pipe wall surface is attributed to a decrease in the concentration of coal particles in this flow region caused by the migration of negatively charged coal particles towards the anodic surface(s). The disadvantage of flow-intrusive geometries is the reduction in effective flow area as well as an increase in frictional surface area caused by the placement of the anode(s) within the flow region. Experimental data is presented for a non-intrusive helical anode-cathode geometry embedded in the pipe wall which shows that a reduction in pumping energy of approximately an order of magnitude is possible. A sample of sub-bituminous black coal fines having a mean particle size of approximately 17 microns was used to prepare coal-water suspensions with a solids concentration of 50%(w/w). The practical and economic implications of this work relate to an enhanced method of long distance transportation of slurries in pipes as well as an alternative technique for continuously separating solid-liquid suspensions.

Jan 1, 2014

By John Nell, Paul den Hoed

Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and high-titania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes. Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites. A reaction mechanism is presented; where possible, its validity is demonstrated by the support of empirical observations.

Jan 1, 2003

By A. Gueciouer, A. Akkouche, K. Chalah, A. Benmounah

"Drilling solid waste is a typical industrial solid waste, and it is a major pollutant source to ecological environment. Generally, waste management dewatering systems separate solids and fine particles from the liquid phase of drilling fluid, thereby leaving a clarified aqueous solution and allow the cleaning of waste fluids. Typically, dewatering waste management systems clean drilling fluid through coagulation, flocculation and/or mechanical separation. Chemicals used in dewatering are based on the coagulation-flocculation process, which it facilitate the removal of suspended solids and colloidal particles. The factors which can promote the coagulation-flocculation are velocity gradient, contact time, and PH. The objective of this work is to optimize a formulation adequate for dewatering based on the coagulation-flocculation process used coagulant (Aluminum sulphate), anionic flocculants (Partially Hydrolyzed Polyacrylamide) and anionic polyelectrolytes (in solid form with linear chain with very high molecular weight). The results obtained show the good efficiency of the coagulant and flocculants. INTRODUCTION Rig site dewatering of drilling fluids with recycling of processed water can help an operator to comply with environmental rules by reducing volumes of waste and reducing long term liabilities. It can also reduce disposal costs and provide a cleaner drill site overall. Most of the environmental concerns during the 1980s involved hazardous materials and toxic wastes. Drilling fluids, many of which are chemically benign, have escaped many of the difficult-to-comply-with rules and regulations. During the 1990s, however, operators may be required to submit a written plan for liquid waste reduction for even nonhazardous materials. Many states and local agencies may institute total bans on oil field wastes. Drilling rigs typically produce about 1 bbl of liquid waste for every 1 ft of hole drilled. Thus, a typical drilling operation can produce a large quantity of waste [1]. To improve the dewaterability of sludge, different pretreatment processes have been widely studied and developed including thermal, chemical, magnetic, mechanical, acoustic, electric, electro-acoustic and their hybrid treatment processes [2]. Rig site dewatering (figure 1) is the process of injecting coagulants or flocculating chemicals into the mud entering a large clarifying centrifuge. Coagulation occurs when the solid and allowing it to be attracted to other solids by van der waals forces. Flocculation is the binding of individual solid particles into aggregates of multiple particles. It is physical, rather than electrical, and occurs when one segment of a flocculating polymer chain absorbs simultaneously onto more than one particle [3]."

Jan 1, 2018

By Ghislain Bournival, Seher Ata, Yesenia Saavedra Moreno

"In froth flotation, frothers are commonly added to the pulp to modify the interfacial properties of bubbles. These properties may be modelled using commercial software packages. The volume of fluid (VOF) method was used to track the interface motion during the post-rupture oscillation of the newly formed bubble. The aim of this research was to provide an insight into the modelling of viscoelastic phenomena through the coalescence dynamics of two bubbles in solutions of various surface tensions using a three-dimensional computational study. Different surface tensions were used to simulate changes in methyl isobutyl carbinol (MIBC) concentration. The computational results were evaluated by comparing the oscillatory motion of the newly formed bubble for the different MIBC concentrations. For known MIBC concentrations, the deviations of the computational damping constants from the experiments were quantified, revealing possible deviations in the VOF surface tension model. In addition, the analysis provided insight into the flow patterns of the fluids and the effect of frother concentration on the velocity magnitude in the liquid and air phases. This analysis provided a further understanding of coalescence dynamic and post-rupture oscillation in froth flotation. Such a process is believed to affect the stability of particles at the interface due to the release of surface energy when the bubble surface is reduced.INTRODUCTIONIn froth flotation, bubble coalescence is an important phenomenon that is highly dependent on the interfacial properties of the liquid film between bubbles. It is known that the frother adsorption at the liquid-air interface changes the interfacial properties, resulting in an increase of surface elasticity and reduction of surface energy (Pugh, 2016). However, in a two-phase system, it is the frother type, concentration, frother molecule conformation at the interface and viscoelasticity properties that dictate film stability (Pugh, 2016). The viscoelasticity phenomena can be explained in terms of surface viscosity, which quantifies the energy dissipation at the interface and surface elasticity that represents the energy absorbed at the interface as result of bubble oscillation (Pugh, 2016). In the case of systems stabilized by nonionic frothers, it has been shown that surface forces alone do not account for film stability, but the viscoelasticity represents the ability to damp external disturbances in the thin film separating the bubbles and prevent coalescence (Santini et al., 2007)."

Jan 1, 2018

By F. M. Zafar Kaifi

Magnesite producing companies rely on high grade purity MgO. The mineralogy of magnesite has a significant impact on the manufacturing of magnesite bricks. The manufacturing process of bricks companies utilizes 90% magnesite from 85%~90% MgO. The main objective of the magnesite bricks was to utilizes the indigenous raw material available in bulk quantity. With better under-standing of chemistry of the mineral species and strict control of bricks manufacturing/processing conditions can be better produce efficiently, a low cost high quality bricks with minimum detrimental environmental impact.

Jan 1, 2014

By Takashi Furuyama, Sukeyuki Mori, Abel Bissombolo

"In flotation practice, a good recovery of minerals largely depends on the degree to which the valuable minerals have been liberated from the associated gangue during the grinding process. Therefore, a regular measurement of the degree of liberation can provide data for the assessment of the quality of separation and predicts the effect of changes in the grinding-classifying circuit on flotation process. Generally, the standard procedure for measuring the degree of liberation requires the preparation of polished sections - a time consuming operation that also has the disadvantage of providing an overestimated number of free particles because of the stereological nature of produced samples.The present work is an alternative approach to avoid these miscalculations and establish a system of control for fluorite flotation plants. The system deals no only with the state of liberation but also the dynamic behavior of individuals particles and mineral components within the grinding-classifying and flotation circuits. It involves methods such as sieving, x-ray diffraction analysis, study of polished sections and microscopic counting of preliminarily sieved minerals particles from a fluorite processing plant, randomly dispersed on a glass slide, but not embedded in a resin mounting medium. If a complete information on the textural properties of minerals in the ore (including its mineral components distribution) can be obtained through x-ray diffraction analysis and study of polished sections, the microscopic counting is used to determinate with enough accuracy the mineral liberation, estimate the grade of fluorite ore and products, determinate the deportment and approximate recovery of individuals particles and mineral components within the investigated circuit. For a count of 100-1000 particles in each n-size range, the counting method was found to be a particularly reliable and less time consuming operation that could substitute the chemical analysis of fluorite ore for an estimate of the grade:"

Jan 1, 2003

By Chi Zhang, Junyi Wu

"With the increasing popularity of lithium cobalt oxide in lithium ion battery industry, which is driven by new energy vehicle and mobile device applications, the demand of cobalt is also growing rapidly in recent years. There is a significant trend of increasing investment on cobalt capacity in China, and the automation renovation is considered as an option of improving production efficiency. This study aimed at evaluating the practicability of stainless permanent cathode blank and automatic stripping process in cobalt electrowinning process. The purpose is to replace the old starter sheet process in cobalt electrowinning, which so far was used by most of cobalt refineries in China, but very labor intensive and exposed operators to serious aerosols that contained both cobalt and acid. In the old starter sheet process, the initial cobalt starter sheet is produced onto a plate made of titanium, while the titanium cathode blank and hanger bar fit the critical corrosive environment but is lack of mechanical strength for automatic production which has been mature in copper electrowinning process. To evaluate the proper materials instead of titanium, the coupon corrosion tests with different raw materials including 316L and other stainless steel grades were held for several months in production environment at a cobalt tank house in China. Following the comparison between titanium and other tested materials, a pilot production test in a cobalt tank house is also on-going.INTRODUCTION Cobalt has been known in early China and used in pottery glazes, and the ancient Greeks and Romans used its compounds to make colored glass since long time ago. The blue on the colored porcelain from the Tang Dynasty in China was also due to the presence of cobalt compounds. The word cobalt is known being derived from the German kobalt, from kobold meaning ""goblin"", because the cobalt-bearing blue ore, CoAsS, was called kobaltin in Europe in the Middle Ages, it may have been thought to be harmful to the health of the miners because of arsenic in the ores."

Jan 1, 2018

By Gurubasayya Swamy

This paper presents the performance study of sag mill in the processing of gold ore. Deterioting ore grade and high demand of metals has tremendously influenced the SAG mills. Today?s high capacity Semi-autogenous grinding (SAG) mills expand vast amounts of energy and in doing so consume tons of shell liners and steel balls, while processing ore. Semi-autogenous (SAG) mill performance is influenced by ball charge, feed properties, shell, grate, and pulp lifter design. In the performance study of SAG mill, based on the results obtained it can be observed that SAG mill performed better at feed size +4 inch and grinding media consumption 0.90kg/mt. In the present study the effect of crusher bypass on SAG mill performance, an immediate drop of throughput ranging from 10-20tph is observed. Keywords: sag mill, pulp lifters, grinding media, energy, consumption, throughput

Sep 1, 2012

By Chao Li, Kym Runge, Saeed Farrokhpay, Dee Bradshaw

"It is well known that froth phase has a controlling influence on the overall flotation performance. Froth recovery is expected to be affected by froth transportation behaviour. The latter has been represented by different volume balance and energy balance based models. In froth transportation models based on a volume balance, the froth phase is divided into different zones. The total froth residence time is the sum of the time spent in each zone and is dependent on the cell geometry, bubble burst rate and the position that bubbles enter into the froth phase. Alternatively, the froth transportation model based on an energy balance treats the froth phase as a block. In this model, froth height above the concentrate lip is being predicted by minimising the energy of the system which is dependent on the froth geometry, froth stability and froth rheology. The froth height can be used to calculate the froth efficiency of delivering mineralized bubbles from the pulp to the concentrate lip. This paper critically analyses the current models of froth transportation in flotation, and examines the limitations of these models. The importance of froth rheology, which is the resistance to the froth flow towards the discharging weir, in determining froth transportation, is also highlighted."

Jan 1, 2014

By Alban Lynch, Benigno Aquino, Hakan Dündar, Alexander Kalugin, Marco Delgado, Alberto Palomino, Ali Türkistanli

Dynamic separators are efficient dry classifiers because new designs during the last 50 years have reduced the by-pass and improved the partition curve. By contrast cyclones have been used as classifiers in wet grinding circuits for 50 years but without serious change and the early problems which were caused by high and variable by-pass, and different mineral specific gravities, still exist. High frequency screens are now used for wet separation and the operating characteristics of closed grinding circuits using cyclones or screens are discussed. Data come from circuits at the Condestable, Cerro Lindo, El Brocal and Catalina Huanca mines in Peru, the Eczacibasi mine in Turkey, and the Apatit mine in central Kola Peninsula in Russia. All classifier data are described by their partition curves and all mill data by their breakage rates. With cyclones the by-pass, d50, and sharpness of the partition curve change as operating conditions change but with high frequency screens the values vary little because the by-pass is low, the sharpness is high, and d50 depends on the aperture size. Data from all plants indicate that lower by-pass and sharper separation improve breakage rates and throughputs. An initial model of the screen is proposed.

Jan 1, 2014

By A. F. Raschenko, Y. A. Golodcov, V. V. Elshin

"The autoclave noble metal desorption in apparatuses with a dense stationary sorbent layer is perspective for the technology of sorption gold and silver extraction from solutions and pulps by carbon sorbents. The study of the mechanism and optimization of the autoclave desorption process involve some difficulties. To overcome them it is necessary to use mathematical and quantum-chemical modelling. The given paper deals with a mathematical model for the dynamics of gold and silver desorption from active carbons by alkali solutions based on the physical-chemical notions of the process. The kinetics and the mechanism of the process were investigated using the mathematical model for gold and silver desorption.The calculation of the efficient mass-transfer coefficient (ße) for various initial and intermediate noble metal concentrations in carbon (Cy) made it possible to find that the dependence of ße on Cy in case of gold desoprtion shows a clear extreme character. The value of the initial metal concentration in carbon therewith does not influence the character of the curve the inflection point of which is changed essentially at elevated process temperatures only. The revealed characteristic property, in the author's opinion can only be indicative of the change in the mechanism of gold desorption under autoclave desorption conditions. The assumed [Au(CN)(OH)]- type intermediate that has a higher diffusion coefficient in comparison with the adsorbed complex [Au(CN)2]- can be considered as an intermediate compound in the process of gold desorption."

Jan 1, 2003

By Luis Bergh, Juan Yianatos, Luis Vinnett

"Process automation as an engineering discipline is more than control systems since it includes industrial instrumentation, such as sensors, transmitters and actuators, as well as control and supervision systems, collection and transmission of data and real-time software applications to supervise and control the operation of plants or industrial processes. In the last several decades, accelerated technological development has provided a variety of software and hardware tools to aid development, maintenance and continuous improvement of automated systems. These developments however seldom reach their full potential in real plants. There are many factors to be considered, among them human capital specific training and the organization model. In this paper, a methodology for training engineers in advanced control and supervision of flotation plants is presented based on study of the application of these technologies in hybrid pilot plants. Since experimentation in real plants may present undesirable risks and costs, and simulation studies are usually limited to some unrealistic conditions, a laboratory where on-line measurements of the hydrodynamic behaviour of a pilot plant is mixed with phenomenological models has been created. In this form, an environment as close as possible to a real plant can be recreated. A flotation column and a circuit of three pneumatic cells are fully instrumented and connected to a PLC and PC network. In the control room, students learn applications of classical PID control in a DCS environment, advanced predictive control, on-line process operation diagnosis, fault analysis, virtual sensors and expert-fuzzy systems. Several undergraduate and graduate courses and theses are supported by this Process Control Laboratory infrastructure. Examples of these applications are discussed."

Jan 1, 2014

By P. Harris

"Comparison of the two most commonly used classes of depressant in the South African platinum industry is complicated by the fact that these polymers induce different effects on the surfaces onto which they adsorb. The use of carboxymethyl cellulose (CMC), which is ionically charged in solution, can lead to increased particle dispersion in addition to the effect of reduced surface hydrophobicity (depression). Guar is typically only slightly charged in solution. Comparison of these two depressants is complicated since it is uncertain whether differences in their action is a result of either depression of dispersion effects.This work investigates the role of dispersion independently to that of depression in the batch flotation of a platinum bearing ore. An inorganic dispersant, sodium hexametaphosphate (NaHMP) was added in parallel to the uncharged guar depressant to simulate the action of depressants with varying degrees of dispersion. By distinguishing between the material recovered by entrainment and the floatable gangue and by including the effects of froth stability it was possible to decouple the effects of dispersion and depression.The results show that both dispersion and depression led to increased grade of the sulphide minerals. Depression leads to a decreased recovery of floatable gangue minerals. Dispersion leads to an increased recovery rate of these minerals and an accompanying decrease in froth stability."

Jan 1, 2003

As a leading global company in the mining sector, we are committed to sustainable development. To this end, we invest in the responsible, integrated management of economic, environmental and social issues. Vale?s objective is for our businesses to produce local, regional and global prosperity, enabling the construction of a positive legacy throughout the lifecycle of our activities. This covers everything from talking with stakeholders and preventing failures to complying with legislation, paying constant attention to environmental issues and respecting ethics in business. Keywords: sustainable development

Sep 1, 2012

By Peter N. Holtham, Mary M. Ng

"Resistivity measurements of minerals in the laboratory are commonly made with a low DC voltage source. Common test voltages specified in the ASTM Standard D257 are 100, 250, 500, 1000, 2500, 5000, 10000 and 15000 V, however 100 and 500 V are the most frequently used. Resistivity results obtained in the laboratory have been used to infer the electrical behaviour of minerals undergoing electrostatic separation. However because the voltages employed in electrostatic separation in the plant are of the order of thousands of volts, typically greater than 15000 V, whether the laboratory results are applicable as a predictor of plant performance is a critical question. It is unclear whether resistivity values taken at a low voltage are characteristic of those seen in electrostatic separation, in which the minerals are exposed to a much higher voltage. No definitive answer could be found in the literature.In this work, the resistivities of zircon, rutile and ilmenite were measured in a corona field for the first time. The measurement principle was based on a technique developed to measure fly ash resistivity in electrostatic precipitators, however the test apparatus and findings are novel.Resistivities of rutile and zircon were found to be easy to measure. The values measured in a corona field were several orders of magnitude less than those obtained with a dc voltage of 100 V. Evidence of back corona was observed with zircon. When the voltage drop was greater than the sample layer could withstand a localised electrical stress developed, resulting in a voltage breakdown, at which point a sudden surge of corona current (back corona) was detected in the sample layer. Rutile, on the other hand, exposed to the same conditions as that of zircon (i.e. same temperature and applied voltage) did not exhibit any sign of back corona. Its resistivity across the range of test voltages (14 to 33 kV) remained fairly constant."

Jan 1, 2003