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By Xianjun Lu

This paper presents gold occurrence investigations on the altered rock gold deposit from Jiaodong area of China, and comparisons of gold occurrence in the ore samples from different mining levels. According to the results, the chemical and mineral compositions of raw materials from different mining levels are quite similar. However, the relative content and grain size of gold minerals are quite different between the two mining levels of -130m~-340m and -550m~-650m. In the ore of upper mining levels of -130m~-340m, electrum is the dominant gold mineral and accounts for about 80% of the total gold minerals, while native gold is minor and accounts for about 20%. As for the ore of deep mining levels of -550m~-650m, the major gold mineral shifts to native gold which accounts for 67%, while the ratio of electrum drops to about 33%. Coarser gold grain size was observed in the upper mining level ore with a mean size of 33.05µm while the gold grain size was much finer in the ore of deep mining levels with a mean size of 22.85µm. Furthermore, the gold mineral associations also show different patterns between the upper mining level samples and the deep mining level samples. Of the three observed gold association types such as inclusion gold, fissure gold and interparticle gold, more inclusion gold was found in the ore of deep mining levels. The inclusion gold accounts for 62% in the ore of deep mining levels, while that in the ore of upper mining levels accounts for about 56%. Further study revealed that the dominant gold associated minerals are pyrite and sulphides and only a small amount of gold is associated with quartz and silicates. It was shown that the altered rock gold ore from Jiaodong area can be regarded as a free milling gold ore, but the processing parameters should be optimized for the ores in different mining levels according to the different gold occurrence. In addition, it was predicted that enhanced gold liberation is necessary for the ore in deep mining levels.

Sep 1, 2012

By John A. Rumball, Martin R. Houchin

Data from autogenous and semi-autogenous tests in a 1.67m diameter mill have been analysed in terms of a new model for rock abrasion. This model defines specific rate as the rate of production of fines (material less than 13mm) per unit mass of rock, where the term “rock” is applied to all ore pieces of ore coarser than the grate size. In most cases, an allowance for preliminary rounding and cleavage was made. A method has been developed to analyse steady-state data, using piecewise fitting to the cumulative size distributions. The model was compared to the well-established models, which are based on the population balance method. The specific rate increased for all rock sizes as the volume of 100mm balls in the mill was increased. Tests using a coarser feed and smaller balls provided further evidence that once rocks are rounded, abrasion is due to localised surface damage, caused by impacts, rather than rotational shear. An allowance for rapid rounding of jagged rocks, followed by less rapid abrasion of rounded pebbles was also tested, but the analysis was not conclusive. The average specific rate is a useful measure of the capacity of a primary mill. The effect of power intensity (kW/t of ore) was also investigated as a means of extrapolating the pilot-plant data to large production mills.

Sep 29, 2003

By D. Saramak

The proposal of the nip zone angle determination in HPGR crushing process is presented in the paper. Knowledge of the nip zone angle value, in turn, makes it possible to determine the real maximum pressing force in the high-pressure comminution. Two methods of determination of this maximum pressure were proposed and verified. The first method is based on the roll?s geometry, and the change of the HPGR chamber?s volume together with the roll rotation, while the second one considers the outlet gap width impact. Results of the nip zone angle calculations according to both methods are similar and show convergence with the real operating conditions. The verification was carried out in a piston-die press, and experimental results show that methodology of the nip zone angle determination presented in the paper has its practical confirmation. A proper determination of the nip zone border makes it possible to calculate the comminution probability of given type of material and is a basis for the HPGR crushing process modeling and optimization. Keywords: HPGR, comminution, nip zone, ore processing

Sep 1, 2012

By D. Pienaar, B. McFadzean, T. Jordaan

"Dithiophosphate (DTP) collectors have the lowest affinity for sulfide mineral surfaces compared to other common sulfide mineral collectors, such as xanthates and dithiocarbamates. In some cases it has been found that DTP does not adsorb onto the mineral surface at all and yet increases in recoveries and grades are noticed with the addition of DTP. Many studies have investigated the interactive effects of collector mixtures. However, there have been relatively few studies on the interactive effects between frother molecules and collectors. This study investigates the interactions between different types of frothers and sodium diethyl dithiophosphate.The study found that there were large increases in pyrite and galena microflotation recoveries at both pH4 and pH9 when DTP was mixed with small amounts of frother at a constant bubble size, showing that these increases were neither mineral-specific nor pH-specific. The same effect was not present when xanthate was used as a collector. The increases in recovery when using the DTP-frother mixture were similar irrespective of the type of alcohol or polypropylene glycol frother that was used. In an attempt to distinguish the mechanism of enhanced flotation recovery, various supplementary experiments were performed. It was found through adsorption experiments that no DTP was adsorbing on to the mineral surface. Therefore, interactions at the air-water interface were performed. Surface tension and critical coalescence concentration tests showed that, while DTP is a weak surfactant at the air-water interface, it does not have a synergistic effect in the presence of frother. DTP-frother mixtures do, however, show interactions in the froth phase, indicating an interaction in the thin films. It is proposed that there is a DTP-frother interaction on the bubble surface that enhances the rate of film thinning at the 3-phase bubble-particle contact."

Jan 1, 2018

By Jihoe Kwon, Daeyang Lee, Mario Fujimura-Kashiwagui, Heechan Cho

"Calcium carbonate is one of the most widely used mineral in today's industries such as plastic, paper and pigment. There are many essential physicochemical properties required by each industry field but the most common requisite is size. One way to achieve appropriate size is grinding. Grinding is typically an energy intensive process, consuming about 40% of total energy cost in mineral process. Due to that reason, optimization of grinding process is a critical element to achieve price competitiveness. Two different type of grinding apparatus were hired to find out optimum condition in terms of energy efficiency. Utilizing samples containing 10, 20, 30 and 40% solids concentrations, a 1l batch type attrition mill was operated as the first grinding step at various operating speed with 1? to 5? grinding media in order to study the optimum operating conditions to reach submicron particles. Next, a 0.15l vertical beads mill was tested as next step with 100? to 500? grinding media to study the optimum conditions in the submicron range. Net energy and the specific energy input was measured to reach stated size ranges. Also, using a back-calculation based on the population balance model further operating conditions were studied. There were several competitive combinations which showed significant energy efficiency improvement when compared with the single step grinding."

Jan 1, 2014

By V. G. Prikhodko, G. I. Sukhinin, I. V. Yarygin, A. V. Fedoseev, S. A. Novopashin

"The first experiments on the vacuum drying of spherical clay sample are presented and the theoretical model of the process is considered. The model is based on the solution of the heat and the moisture transfer equations with the effective thermal conductivity and water diffusion coefficients for wet porous clay-like medium. The time and radial dependence of the temperature and the moisture were calculated for different initial conditions. The results obtained for the time dependence of the moisture content are in good agreement with the experimental results obtained in the initial period, when all the moisture in the sample did not freeze to form an ice crust. INTRODUCTION Capillary-porous materials very often occur in nature and in industry. A porous medium is a solid matrix with voids, or pores, which are continuously connected. These pores are usually filled with fluids or moisture, water vapor and air that can pass through the medium because the voids are interconnected. The void fraction in the solid matrix is referred to as the porosity. Porosity or void fraction is a measure of the void (i.e. ""empty"") spaces in a material, and is a fraction of the volume of voids over the total volume. The moisture content in porous media determines the properties of the porous body, its mechanical and thermo-physical properties, such as density, plasticity, viscoelasticity, swelling, cracking, and so on. Complex processes of heat and mass transfer occur in porous bodies when they are heated or cooled, during drying or freezing (Luikov,1966). The course of these processes depends essentially on the physical-chemical composition of the solid matrix of the porous body, on its fractal dimension, porosity and morphology. The clay and clay minerals are the most important porous materials in the history of the mankind (Mukherjee, 2013). Clay is a very fine grained, unconsolidated rock matter, which is plastic when wet, but becomes hard and stony when heated. It has its origin in natural processes, mostly complex weathering, transported and deposited by sedimentation within geological periods. Clay is composed of silica {SiO2), Alumina (Al2O3) and water (H2O) plus appreciable concentrations of oxides of iron, alkali and alkaline earth, and contains groups of crystalline substances such as quartz, feldspar, and mica. Building materials, bricks, and tiles, pottery, porcelain and faience are made from clay. Clay is used in the food and medical industry, and, not least, in the mining industry as a carrier containing aluminum, silicon and other valuable elements, as well as metals (copper, gold) as constituents, contained in the pores in the form of micro- and nano-particles or grains."

Jan 1, 2018

By Ashok M. Raichur, S. P. Vijayalakshmi

"Recent advances in technology and the growing environmental concern have laid emphasis on the usage of fine clean coal. Coal fines are also generated in large amounts during various coal processing operations and are difficult to be treated, handled and disposed. Since most of the operations use water as the carrying medium, the fines so generated contain lot of moisture. Conventional technique for processing coal fines includes flocculation by a polymeric reagent followed by moisture removal using a rotary drum or a pressure plate filter, which produce a product with more than 30% moisture. Polymeric flocculants though required in small amounts, need high shear mixing for good performance and operate only in a narrow pH range. Moreover they increase the viscosity of the solution by many folds. Hence it becomes imperative to emulate newer methods for efficient fine coal processing. One such method is the novel use of microorganisms in coal processing.The present investigation deals with the utilization of two gram-positive microorganisms, Mycobacterium phlei and Bacillus subtilis, as bio flocculants and dewatering aids in fine coal processing. Preliminary characterization done on J-coal and M.phlei showed that they are negatively charged over most of the pH range. B.subtilis was found to possess positive charge below pH 4.7. The adhesion studies proved the high potential of microorganisms for adsorption to surfaces. Adhesion tests were conducted at various experimental conditions by varying parameters like pH and ionic strength of the suspension. Results obtained showed that adhesion is always higher in the presence of an electrolyte like KNO3 and most of the adhesion takes place in 15 minutes. With change in pH the amount of B.subtilis adhering on to J-coal remained almost constant and for M.phlei it decreased at higher pH values. Increase in ionic strength did not increase the adhesion of bacteria. Flocculation experiments confirmed the ability of the bacteria to act as bio flocculants. It was seen that about 98% of the coal settled in about 2 minutes on the addition of bacteria along with the addition of the electrolyte. The electrolyte was found to be indispensable for efficient flocculation of the coal suspension and for the attainment of a clear supernatant after flocculation. Also the optical micrographs revealed the formation of large, tight flocs when the electrolyte is present along with the bacteria. Further, flocculation tests were done in the pH range of 2-10 and the flocculation efficiency was found to be independent of pH."

Jan 1, 2003

By Ashok Kumar, Subhadra Sen Dr. Rashmi Kumari, D. P. Chakraborty, Ajay kumar Gupta

The blast furnace coke quality depends on the characteristics of coal blend, pre-carbonization techniques adopted such as stamping, vibro-compaction etc., and coking conditions. Of the above, coal blend plays a significant role in the production of quality coke. Furthermore, the quality of the blend depends on the quality of individual coals and their interaction making up the blend. During transportation and stockpiling, coal is in contact with air for periods of time that sometimes may exceed several months. During this time, reaction with oxygen in the presence of water, sunlight and possibly elevated temperatures may take place. The resulting weathered coal suffers some alteration in its technological properties, which in turn affects coke quality for Blast Furnace operation adversely. In this work, two coals belong two prime hard coking and hard coking categories, namely Illawarra & Tahmoor, were selected and kept in a separate stock pile for a period of 120 days. These coals were characterized in terms of proximate, rheological & petrography properties at a regular frequency. This report summarizes the impact of weathering on the coking behaviour of these two coals in terms of properties as mentioned above. However, the rate of loss depends on coal rank and storage conditions. This has been seen through this study that the loss depends on coal rank and storage conditions. Deterioration of rheological and petrographic properties were seen higher for low-rank coals, like in this study Tahmoor, which is a low rank coal, compared to Illawarra showed higher degree of coking property degradation within the same time period under identical environmental conditions. Low-rank coal deteriorates at a faster rate because low-rank coal is dominated by free radicals that easily react with oxygen, resulting in the creation of various carbonyl groups and weathered vitrinite. Based on the results obtained in this study, size of stock piles for different qualities of coals to be maintained, at a specific time, can be determined and recommended, so that target coke quality is always achieved.

Jan 1, 2018

By Xinyang Xu, Chen Zhang, Lixia Li, Zhitao Yuan

"Density functional theory was employed to clarify the mechanisms of the activation of a quartz surface and its collection by the flotation method at the molecular level. The calculation results indicated that hydrogen bonds on the quartz surface (1 0 1) existed in pairs while in contact with water. The simulation was carried out to investigate the different effects of Ca2+ and Ca(OH)+ on a quartz surface with hydrogen bonds, and the results suggested that Ca(OH)+ most likely adsorbed onto and activated the quartz surface. Mulliken population analysis of the external oxygen atom of the quartz surface, calcium atom of Ca(OH)+, and the oxygen atom of oleate showed that there were electron transfer and the formation of a chemical bond between Ca1-O1 and Ca1-O3, which were indicative of strong interactions between the three atoms. In addition, the –OH of the Ca(OH)+ contributed to the activation, which suggested that the Ca(OH)+ group acted as a bridge between the surfaces of oleate and quartz.INTRODUCTIONFlotation is an effective separation method in mineral processing that takes advantage of the physicochemical differences between minerals and gangue, and the properties of the mineral surfaces play a key role in this process (Liu et al. 2016, Qin et al. 2017). In the reverse flotation process of iron ore, gangues are captured by cationic or anionic collectors and floated with air-bubbles as tailings, and the pre-depressed iron oxide minerals are left at the bottom as concentrates (Lima et al. 2013, Yianatos et al. 2015, Zhu et al. 2015). Quartz (SiO2) is one of the major gangues of hematite ores and cannot be easily removed. It is a naturally hydrophilic mineral, in which silicon is the cation in its crystal structure and has very limited solubility. Therefore, quartz must be activated, usually by metal ions, for its effective rejection as a float-product by reverse flotation (AIME. et al. 1976)."

Jan 1, 2018

By C. L. Xiao

With reference to the test report carried out by Guangzhou Nonferrous Metal Research Institute in 1983, the mineral process flow sheet of Yichun Tantalum-niobium mine is determined based on the characters of ores and successful experiences in light of the problems in the existing flowsheet: The ore is desilted before crushing; the primary slime is separately treated; the staged grinding process used while the fine slime is collectedly treated with tantalum and niobium as the main recoveries and lepidolite and feldspar powder as the secondary. The flowsheet is featured by comprehensive recovery, low investment and low energy cost.

Jan 1, 2014

By ?. S. Yusupov, V. P. Isupov, N. Z. Lyakhov, A. G. Vladimirov, S. A. Kondratiev

"Considering the shortage of lithium reserves, the desirability has been shown of studying the possibility of processing into spodumene concentrates the concentration tailings and low-grade ore reserves at Transbaikalian Mining and Processing Project (ZabGOK). The mineral and chemical composition and the particle size distribution of the mineral feed, separability and recoverability of spodumene have been studied, forming the basis for the development of a concentration process and flowsheet for the studied mineral resource. Prospects have been established for impact ore grinding in a disintegrator, the efficiency of mechanochemical processes has been shown in the separation of quartz and feldspar and the recovery of lithium from concentrates.INTRODUCTION Lithium is widely used in various industries - nuclear power engineering, defense technology, power generation, ceramics, special-purpose glass and other technologies. The increasing demand for lithium and its compounds (lithium carbonate and hydroxide) for use in the manufacture of high-tech products (lithium-based materials for chemical sources of electric power and electrochemical energy) explains the need for establishing a sustainable raw material base (Mohr et al. 2012; Moores, 2007). The main sources of lithium are spodumene pegmatites (Vladimirov et al. 2012; Garret, 2004), brines (salars), and hydromineral materials (Garret, 2004; Zeng and Liu, 2009; Kotsupalo and Ryabtsev, 2008). However, in view of the absence in Russia of extractable hydromineral resources of lithium, the practical significance of spodumene ores remains decisive. Russia controls some of the world’s largest reserves of rare-metal pegmatites holding over 8 million tons of Li2O: approximately 7 million tons on the Kola peninsula and 1 million tons in the Sayan mountains. The main lithium mineral in pegmatites is spodumene LiAlSi2O6 containing 8.1% Li2O. It can be efficiently recovered by gravitational concentration and flotation. However, most of the deposits are located in remote areas and none is currently developed. In this connection, special research is focused on technogenic raw materials, which are increasingly seen as a solution to the resource base problem (Chanturia, 2008, Kurkov and Kotova, 2007)."

Jan 1, 2018

By M. D. Amirova

Cyanide-free technology of complex copper-lead ores flotation may be improved through enlarged range of pH values, enhanced copper recovery into copper concentrates due to additional recovery of secondary copper sulfides, as well as through enhanced efficiency of lead sulfides depression in process of new flotation modifiers-based selective separation. Study of the effects of flotation modifier (of metal nature) on minerals surface conditions proved that the xanthate is practically not adsorbed on the galenite surfaces due to minerals hydrophilization. Joint effects of sodium sulfite and modifier enhance process conditions for intensive galenite depression and at the same time for effective chalcopyrite and chalcosine flotation within a large pH values range (from pH=8 to pH=10). Identified mechanisms carry inference that proposed chemical reagent treating method is very promising for selective copper-lead concentrates separation. Potential use of carbon-containing materials as zinc flotation modifier to enhancing zinc recovery in processes of lead-zinc ores treatment has been studied. In our flotation tests we used Shalkiya (South Kazakhstan) lead-zinc ores containing such impurities as carbon shales, which presence impedes the process of saleable concentrates production and gives rise to excessive consumption of flotation agents due to the xanthate adsorption on the carbon. Lead and zinc concentrates were produced by process stages as follows: ores milled to 95% Cl. -0.074 +0; lead and zinc roughing flotation and further recleaner and testing operations. Test flotation in open process cycle resulted in enhancing zinc recovery into zinc concentrates by 21.1% and increasing zinc content in zinc concentrates by 3.96% that evidences promising potentialities for use of carbon-containing products as additional zinc flotation modifier. Works were carried out under National Program 2003~2005 of fundamental researches ?Physical and Chemical Mechanisms of Interactions in Multicomponent Solid and Liquid Systems Specific for Integrated Processing of Complex Metal-Containing Minerals and Technogenic Raw Materials? and contractual Agreement 2005 Optimization of Production and Technology of Shalkiya Lead-Zinc Ores Processing at Kentau Dressing Works.

Jan 1, 2014

By D. Z. Wang

A red copper plate, discovered in the ruins of Dachengshan in Hebei province, was recognized as a forged one rather than a cast one, which means it was probably made from natural copper during the Longshan Culture period (2200~2208 BC) in the Chinese history. The copperware, found in the Niangniang Tai relics in Wuwei city, Gansu province, contains 99.6% copper and 0.4% Sn, Pb, Sb and Ni, which was guessed to be made during the Qijia Culture about 2000~ 1900 BC in the Chinese history in the late Neolithic before Shang dynasty. This shows that Chinese ancestors were able to distinguish, sort and use some native metals and minerals more than 4000 years ago.

Jan 1, 2014

By Leopoldo Gutierrez

Eight oil sand ores with the bitumen content ranging between 3.6 and 15 wt.% and the fines content (-44 micrometers size fraction) between 9 and 69 vol.% were subjected to the standard alkali extraction test used to measure the degree of oxidation of metallurgical coals. The results showed that there is a strong correlation between the absorbance of extracted solutions at a wavelength of 520 nm and the ratio of the fines content to the bitumen content. The latter factor is directly relevant to assessing the extractability of bitumen from oil sand ores. Bitumen extraction tests showed that the bitumen recovery decreased from 90 % to 30 % when the absorbance at 520 nm increased from 0.23 to 0.64. A comparison of the UV/visible spectra of solutions obtained from the alkali extraction tests with solutions of Aldrich Humic Acids suggest that low bitumen/high fines oil sand ores release substantial amounts of organic matter very similar, if not identical, to humic acids. In contrast, high-bitumen and low-fines ores do not release as much of the organic matter, and UV spectra of these leached substances are quite different from those of humic acids. Overall, the results show that chemical composition of bitumen in the tested ores varies greatly with ore type and oxidation, and that the alkali extraction test is a promising technique to quickly assess the extractability of bitumen from a given ore type.

Sep 1, 2012

By T. S. Reddy

Research and Development Centre for Iron and Steel (RDCIS) a unit of Steel Authority of India Limited (SAIL) is continuously engaged in reduction of energy consumption at SAIL plants by implementing innovative and new concepts. In this regard, continuous efforts are being made to recover waste heat in Sinter Plants. This paper discusses existing waste heat recovery measures taken and proposed measures planned in Sinter Plants. One such effort is on waste heat recovery from sinter coolers. Hot sinter is discharged to the crusher at the end of the sinter machine at a temperature of 500 to 800°C. Temperature of hot sinter is brought down to nearly 100°C in the sinter cooler with air-cooling. The air after cooling the sinter is generally discharged to the atmosphere at about 225 to 300°C. It is planned to recover heat from the hot air that is being released to atmosphere and heat the process water, which is being added at ambient temperature in mixing drum at Bhilai Steel Plant. The temperature of raw sinter mix will be raised by addition of this hot water, which will help in improving the productivity of sinter machine. It is estimated that Waste heat recovery to the tune of 1.5 to 2.0 Gcal/h is possible with reduction in CO2 emissions in the range of 4000 to 5000 ton/year. The novel approach that is being adopted is addition of hot water in mixing drum for higher sinter productivity for the first time in India. Keywords: waste heat recovery, sinter plant, hot water generation, emission reduction, CDM

Sep 1, 2012

By Jussi Liipo, Pertti Lamberg

Image analysis of process samples gives precise data on particles and their composition. The results presented as liberation tables and maximum grade-recovery curves are informative and good for comparing different feed materials, but basing on them it is impossible to predict the results of the mineral separation process (flotation, magnetic separation, gravity separation) in details. The exact and extensive particle data has remained large unused, because there has not been a model nor a modeling program to include particle information in mineral separation processes. This study introduces a method, which incorporates the particle data in the kinetic model of flotation. Similar approach can be used in modeling other separation processes, too.

Jan 1, 2003

By Thomas Mütze, Michael Klichowicz, Mathis Reichert, Holger Lieberwirth

"Self-similarity is proofed to be a common feature when brittle material is comminuted, either in particle bed or single particle mode. Appropriate test work is well documented for particle sizes less than 7 mm in several publications. In contrast, almost no research has been done for coarser particles. The aim of this paper is to show that the fracture pattern of coarser material also tends to be self-similar. Hence, single particles of quartzite, granodiorite and dolomite were comminuted under compressive load. The focus was set on three different size fractions -3.15 +2.5 mm, -31.5 +25 mm and lumps -300 mm. According to the wide range of particle sizes, three different piston-die presses were used with a maximum compressive force ranging from 5 kN to 4000 kN. The force-displacement curves were recorded in order to calculate the specific comminution energy. Additionally, the -31.5 +25 mm size fraction was crushed in a laboratory scale jaw crusher and a roll crusher. Some authors report that the energy-size-reduction relationship of self-similar materials can be approximated by a linear function, which is independent of the comminution equipment. In their charts the slope can be seen as a product-size-independent grindability measure. Our tests show a self-similar breakage behavior when particles in a range of -300 +3 mm are comminuted in single particle mode. Furthermore, the products of the piston-die-presses and the roll crusher are similar to each other in a self-similar representation of the particle size distribution. The jaw crusher product, however, is not self-similar compared to the piston-die-press products. Finally, the linear energy-size-reduction relationships are confirmed for each fraction, but show size dependent slopes."

Jan 1, 2014

By A. Y. Senchenko, Y. V. Kulikov

"The most common technique for selection of grinding equipment is the Bond method implying determination of a ball mill work index (BWi). The method is perfect for greenfield projects where a ball mill must be sized to grind an ore to 80% passing 75-100 µm. Finer grinding will require application of specific correction factors to a standard equation since initially the method was not designated for sizing of fine (minus 75 µm) grinding mills. Significant issues are related to selection of grinding equipment for treatment of originally fine materials when the standard procedure is not applicable. In 1984, Levin published his special technique titled as “A proposed test for the determination of the grindability of fine materials”, where he offered to use the standard Bond ball mill for determination of a specific grinding energy. However, this method did not meet with wide recognition. In 2017, Institute TOMS under guidance of JKMRC’s specialists performed a testwork aimed at verification of a new universal technique for determination of grindability of initially fine materials. An object was to test three aged tailings samples for the subsequent modelling of comminution circuit and evaluation of potential throughput of the existing ball mills with final grind size of ?80 passing 53 µm. In parallel with development of the universal approach, TOMS’ specialists carried out tests according to the Levin method in order to compare the data resulted from two methods. The results from lab ball mill testing on three products following the alternative test methods are presented in this paper along with the testing methodology and results analysis. Specific energy was calculated for regrinding of the materials to the required size. Difference of the examined methods and assessment of their applicability for sizing of full-scale equipment are explored."

Jan 1, 2018

By N. Nikolaeva, A. Romashev, T. Aleksandrova

Energetic characteristics identify energy consumption for destruction of prills and kinetic characteristics rate formation of finished size grade in the course of destruction and identify crushing and grinding equipment capacity. And if screen sizing or classification processes are applied in the cycle of ore preparation, then the use of characteristics of separation to size – separating characteristics – is required for theoretical description. Separating characteristics have a lower profile for ore preparation but, nevertheless, they have to be taken into account especially for balance and design calculations of crushing and grinding circuits. In most cases there are impregnations of minerals which vary widely in energy consumption and destruction kinetics and thus polyminerality must be considered as one of priority factor. Raw materials which passed through crushing and grinding processes can be assessed numerically by functions of fractional composition of two types: differential distribution function y ( €) and assay function B( c ) . A set of experiments on grinding of crushed raw materials at different time (up to various sizes) was conducted to analyze effect of grinding size of carbonaceous overburden on function y € and B ( c) as well as to justify the possibility of preconcentration of raw materials at the stage of ore preparation. Analysis of metals distribution per size grades showed that metals are concentrated in size grades of less than 0.315 mm (which is equivalent of cut point for this type of raw material), however, there is no overgrinding and oversludging of material, and enriched product for its further processing can be excluded with the help of classification. The stage of size segregation was tested as a method of preconcentration of raw materials for optimization of ore preparation and further separation.

Jan 1, 2018

By E. V. Leont'eva, V. R. Vafin, A. G. Kladova, N. L. Medyanik, A. P. Ponomarev

"The thermochemical technology for recovery gold, silver from mature flotation tailings of pyrite ores by two-stage sintering with chlorine-ammonium reagents and leaching of bakes with water is developed. The economic effect of the technology implementation is calculated. KEYWORDS Gold and silver recovery, mature flotation tailings, pyrite ores, chlorine-ammonium reagents, leaching INTRODUCTION The relevance of processing the technogenic reserves of ore mining and concentration wastes accumulated over the long operation periods of mineral deposits is beyond doubt. Hundreds of tons of precious and non-ferrous metals that were not recovered during the primary processing are concentrated in the accumulated wastes. For example, tailing storage facilities (TSF) at the mineral processing plants in the Southern Urals region of Russia hold more than one hundred tons of gold and thousands of tons of silver in the mature flotation tailings (MFT) of copper pyrite ores. Secondary processing of technogenic materials is facilitated by the fact that they are preprocessed — ground and compactly deposited on the surface, but complicated by the low (compared to ores) grade, uneven distribution of the valuable minerals, altered and unstable material composition of the mineral feed. This leads to low recovery rates of valuable metals by conventional physicochemical processing methods. It is necessary to develop innovative methods of deep integrated processing of industrial wastes, based on the study of the material composition of specific technogenic mineral resources and based on ensuring the environmental safety of the resulting secondary waste. MATERIALS AND METHODS The object of this study are the MFT of Uchaly Concentrator in the Republic of Bashkortostan, Russia, which processes copper pyrite and copper-zinc ores. According to the data of particle size, chemical, X-ray phase, and optical microscopic analyzes, samples of the MFT are characterized by considerable particle fineness (the fraction of the size class -41 µm is 89-90%), low grade of gold (1.7-2.0 g/t) and silver (18.0-19.5 g/t), comparable grades of iron (23.0-26.8%) and sulfur (28.1-28.7), but different grades of copper (0.12 - 0.73%) and zinc (0.34-1.26%). The most common mineral in the samples is pyrite (50 - 56%), found in intergrowth with grains of other sulfides (0.1-4%) - sphalerite, tennantite, chalcopyrite, covellite. Quartz and aluminosilicates are the dominant rock minerals (21-36%). Based on the results of the phase analysis, it was established that approximately 70% of the gold in the samples is found in a form that is resistant to cyanidation — it is locked in sulfides (52-56%) and quartz and coated by films. Along with sulfides and rock minerals, common gold and silver minerals (chalcogenides, intermetallides, native gold) in the form of submicro- and nano-sized precipitates are also associated with intergrowth of a complex structure. These features of the material composition allow classifying the MFT of the pyrite ores as a mature feed material and emphasize the need for chemical non-cyanide methods to recover gold and silver from the mature minerals and associations they are found in."

Jan 1, 2018