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By M. Pischtschan, S. Belz, M. Perrucci

In High Pressure Grinding Rolls (HPGR), the material grinding takes place between the fixed and floating rollers. In this regard, the rollers start to wear over a period of time, which is impacted by for e.g.: ore characteristics, operating pressure, feed material size and non-uniform feed presentation across the roller width. HPGR operational experiences have shown that the rollers do not wear at the same rate. This differential wear rate over time leads to differences in the tangential speeds of the rollers, causing an uneven gap between the fixed and floating rollers in relation to the material. This unwanted but extremely common situation results in a less effective grinding process due to the fact that the slip between rollers is not optimal. As the rollers wear profile increases, the roller with smaller diameter starts to wear further, deteriorating the comminution efficiency up to a point where operators have to stop the HPGR to replace the rollers. Since the wear rate of the rollers is not equal, the replacement of the same cannot be properly planned so that their life-time are fully utilized. In this paper, a dynamic load share control with the use of ABB’s variable speed drive system is proposed, which provides the possibility to the HPGR operator to impact the roller wear in such a way that it equalizes the wear rate to a certain extent and extends the roller life time. Called RollXtend™, this solution includes a load share factor which can be parameterized based on the wear measurement performed manually during maintenance procedure. Additionally, this paper describes an automated load sharing concept based on a non-invasive wear measurement method. The partial results of the technology trial in a copper/gold mine are presented, which aimed at detecting stud damage and estimating the real rollers profile throughout their life time. The final objective of the pilot project was reduce the amount of planned and unplanned downtimes of the HPGR by increasing the rollers life time and avoiding catastrophic stud damages.

Jan 1, 2018

By J. Yvon, Inna V. Filippova

"The aim of this work is to seek the inhibitors of the meteoric and bacterial dissolution of sulphides and gangue minerals to stop the undesirable chemical reactions during conservation of the flotation wastes. The approach of passivation of surfaces by chemical treatment of the solid phase is applied for this objective.The samples taken from different depths of an old French waste dump revealed the capacity of the flotation tailings to produce acid waters (pH 1.8-2.4) and to release heavy metals. Mineralogical studies show not only the product of sulphide oxidation, i.e. sulphates, but also the complex transformations of aluminosilicates in acidic liquid phase. The detection by XRD of aluminium hydroxides (gibbsite, boehmite) allows supposing the recrystallisation phenomena during tailings conservation.Comparative tests of the passivation of the surface of sulphide minerals and waste of flotation with using of conventional reagents (CaO, NaOH, phosphates) and original reagents for this purpose (alkyl dithiocarbamates) allow to identify the optimal treatment conditions and the efficient chemicals.Leach tests were carried out in percolation columns during 68 weeks. The normalised leaching tests according to French legislation were run to confirm the selected treatment conditions. The results obtained show that a single treatment with carbamate inhibits the oxidation of the pyrite and the other sulphides, and totally prevents the formation of acid waters (the stabilised pH was 5.3-5.8). Treatment of in situ drainage water allows to obtaining a total precipitation of heavy metals: the residual concentrations of Fe, Cu and Zn are lower than 0,1 mg/l.The passivation of sulphides is the result of the formation with carbamate (studied by IR spectroscopy and XPS) of organometallic compounds, which are stable in acid medium. The presence of thiuramdisulphide (product of alkylcarbamate oxidation) at the mineral surface stabilises the mixed adsorption layer and leads to a considerable reduction in the hydratation rate of surface by avoiding the corrosion of the pyrite. No aluminium was detected in leach solution with this treatment."

Jan 1, 2003

By Liu Jin

"In order to reduce the dosage costs and increase the economic benefits of a full floating process in a low grade complex multi-metals W-Mo ore, based on the study of the magnetic characteristics of the main gangue minerals, a joint process by magnetic separation and floatation technology is adopted. The first step of the flowsheet is to recover magnetite by magnetic separation, then remove the magnetic gangues by high gradient magnetic separation (HGMS) and finally recycle the W-Mo from the magnetically separated tailings by flotation. Results of the lab experiment show that in comparison with the full flotation process, the floatation feed tonnage of the combined flowsheet are only 46%. The grade and the recovery of Mo in the rough Mo-Bi concentrate is similar with the original one while the WO3 in the tungsten rough concentrate is increased from 3.85% to 6.64%. The dosage costs are reduced by 53%. The new process can significantly improve the plant economically. INTRODUCTION With the continuous exploitation of scheelite resources, the easily obtained resource is gradually depleting. The ""lean, fine and complex"" scheelite resource has become the main research object of tungsten beneficiation (Lou et al., 2010) (Xiao et al., 2013). The passive situation of tungsten beneficiation can be reversed by enhancing technological innovation and investment in science and technology, changing the business philosophy and mode of production, optimizing the process structure and process conditions, improving various technical indexes and reducing production costs of reagents, which will maximize economic benefits (Jiang et al., 2012 ) (Zhu et al., 2016). A polymetallic deposit of tungsten molybdenum bismuth original process adopts a full flotation process. With the expansion of stope mining, the content of valuable metals in the ore continues to decrease, resulting in a high cost per ton of concentrate produced and a low output value (Li et al., 2015)."

Jan 1, 2018

By Valery V. Kostjuk, Victor. N. Bredikhin, Alexander I. Shevelev, Evgeny A. Kazban

"The investigations to improve the process data have been done in order to stabilize the functioning of drying units. The scheme of turnings preparation with centrifuging and subsequent thermal degreasing (tandem) is proposed. To improve the efficiency of the process the scheme of reclamation of the centrifuge fugate is developed with production of oil and service circulating water. Empirical dependences of the turnings temperature influence on the lubricant-coolants content in centrifuging are gained. When the turnings temperature is increased to 80 C the residual content of LC is decreased by 1.5%. The investigations aimed to improve the preparation of non-ferrous turnings have allowed to decrease the melting loss by 15-20%; to stabilize the process of thermal drying of turnings; to decrease sharply (by 60- 70%) the volume of LC combustion products; to reclaim the centrifuge fugate and produce oil and servicecirculating water.Non-ferrous turning and primarily aluminum and copper alloys turning is a stable source of secondary raw materials for metallurgical works.Direct by lubricant-coolants (LC) of various types: synthetic, semi synthetic, oily and emulsions.On the base of investigations concerning various methods of the non-ferrous turning processing the favorable one has been selected taking in to consideration the economy, ecology and quality of the finished product (alloy). Two-stage process is developed. The main idea of the process is the elimination of the lubricant-coolants (LC) to the limit specified in advance. The applied method is centrifuging with subsequent final elimination of LC by thermal method.Constant value of LC content at the inlet of the thermal unit excludes practically the oxidation of metal and as a consequence increases the output by 10 –15 % in metallurgical processing."

Jan 1, 2003

By Valentin V. Shatalov, Irina V. Pastukhova, Alexander V. Kurkov

"We have developed a technology to improve the quality of low-grade concentrates containing minerals of tantalum, niobium and tin on the basis of given conception by the way of improving selectivity and using certain reagents composition. The basic collector presents a traditional or complex-forming collector used together with organic diphilic reagents – the secondary reagents regarding the basic flotation regiment, capable of forming associates with the main collector on the surface of the mineral, thus altering the interaction energy. In the given process the main collector is the fraction of hydroxamic acids C7-C9, the reagent of the secondary action – sulphosuccinamate, which added in moderate concentrations range provides for a synergistic effect.We have determined the parameters of the process stability and necessary modifying reagents for a selective recovery of tantalum, niobium and tin minerals from refractory products. Variants have been studied where the main collector and the secondary action reagent were substituted with some more efficient flotation reagents. A possibility of a more flexible reagent compounding for the process has been shown. The flotation process is highly stable regards the saline composition of the liquid phase in the pulp. It can operate under conditions of the complete water recycling with the total salt content up to 12 kg/m3, iron up to 1.2 kg/m3.The given results consider the efficiency testing of the suggested technology for the gravitation products, which were obtained from ores of various genesis and contain large quantity of the most refractory minerals, such as topaz (80%), gamet (55%), tourmaline (30%). High selectivity of the process has been registered with the metal recovery about 92-98%, which appears to be similar to hydrometallurgical operations under certain conditions."

Jan 1, 2003

By A. E. Sobolev

The kinetics of hydrochemical oxidation of antimonite in solutions of nitric acid was studied using the rotating disk method and the factor experiment design. The dependences of the antimonite?s oxidation rate on concentration of nitric acid solutions, temperature, disk rotation frequency, and duration of interaction were determined. The adequate kinetic models allowing calculating the specific oxidation rate at any combination of the values of the influencing factors were obtained. The oxidation process is found to proceed in a mixed mode, close to chemically controlled. Gradually, as the sediments of elemental sulphur and Sb2O5 accumulate on the disk surface, the process becomes controlled by internal diffusion. The observed high (more than second) order of the oxidation rate with respect to the concentration of nitric acid was explained by the autocatalytic action of the acid reduction products. The apparent activation energy depends on the stage of interaction. At the initial stage (in a mixed mode of the process proceeding), it depends on nitric acid concentration and varies from 31.5 kJ?mol?1 (in 2 M HNO3) to 36.1 kJ?mol?1 (in 10 M HNO3). This trend indicates the weakening of diffusion limitations with a nitric acid concentration increase. When the process is controlled by internal diffusion, the apparent activation energy was found to be 14.5 kJ?mol?1. The obtained kinetic characteristics enlarge the database on hydrochemical oxidation kinetics of sulphides and can be used for the elaboration of the recommendations for the effective comprehensive exploitation of antimony-bearing ores and concentrates.

Jan 1, 2014

By Wayne I. van Drunick

"Energy balance modeling has recently been shown to be a competent tool in the estimation of SAG mill discharge rheology. Work performed by van Drunick and Moys (2001) validated the ability of an energybalance filter to estimate the slurry density from an operating SAG mill. The importance of rheological data is highlighted by several authors who show the effects on load behaviour and thus mill performance. Energy balance models were developed to account for the dynamic energies in the mill discharge sump. The models then made it possible to infer the mill discharge density. A sampling campaign was performed and the errors from the sump energy balance were within tolerable limits.Since the initial results were published, it has been decided to further develop the modeling techniques in order to focus on balancing the energies around the entire mill. The critical measurements for the energy balance will be the temperatures of all the streams entering and leaving the mill, including energy losses to the environment. Metso’s OCS© (Optimising Control System) currently controls the 3 SAG mills at Anglogold’s Mponeng Gold Plant (South Africa). The OCS has built-in Kalman filtering tools to effectively handle variances and noise in the models and the mill circuit data respectively. The new models are therefore constructed in the OCS platform, and will be run in parallel with Metso’s current modeling and filtering systems. The work is a collaborative effort between Anglogold, the University of the Witwatersrand and Metso. The benefits of energy modeling, compared to mass modeling, are that energy data are more accurately measurable than mass data. The inferred mill parameters can therefore be improved provided that a competent set of models is produced to process the (accurate) thermal measurements."

Jan 1, 2003

By Venkata S. Buddhiraju

Pelletization of iron ores involves balling on a rotating disc to produce wet pellets and induration of wet pellets on a moving grate to produce fired pellets. The quality of pellets produced and the productivity of the pelletization process depend strongly on the characteristics of the feed to the pelletization disc, especially the particle size distribution and the moisture content. The upstream processes involved in the preparation of pelletization feed include grinding, thickening and filtration of the iron ore slurry. The focus of the present work is the closed circuit wet grinding of iron ores. The circuit consists of a primary ball mill, a regrind mill and a hydrocyclone. A population balance model was developed to predict the grinding kinetics and an empirical model was fitted for the separation of fine particles from the coarse particles in the hydrocyclone. Batch grinding kinetics experiments were performed on a laboratory scale ball mill to obtain the ore breakage parameters which were subsequently used for the simulation of the industrial mills. The models were customized for the industrial operations and the effects of different process variables like feed flow rate, water flow rate, etc., on the size distribution of product from the grinding circuit were studied. Additionally, different circuit configurations were simulated to determine operating conditions that could result in the desirable product particle size distribution. The results of simulation were in close agreement with plant observations and the new circuits explored through simulation have helped in identifying potential opportunities for process optimization and control

Sep 1, 2012

By Swati Mohanty

Spiral concentrator, which works on the principle of gravity separation, is widely used in the mineral industries for separation of solid particles based on the size and density. In the present study, CFD simulation of the flow profile on a laboratory scale spiral concentrator of height 2.29 m, pitch 0.435 m and width 0.17m was carried out. A single computational domain covering the entire spiral was considered. Volume-of-Fluid algorithm was used to track the interface and predict the flow profile. In the present study the Donor-Acceptor method was used for the calculation of volume fraction in the cell. Simulation results show that the velocity increases as the water flows down due to the convective force and gravitational force, but the viscous force acting in the opposite direction retards the flow. Thus the maximum velocity is attained at turn three at which the viscous force overpowers the other forces and further down the velocity decreases. Measured water depths along the radius of the spiral at various heights were compared with simulated depths, which were in good agreement. The simulated liquid phase velocity profile was used to carry out preliminary studies on the flow profile of solid particles of size 500 micron and densities 2600kg/m3 and 5100kg/m3, based on the Lagrangian model taking into consideration fluid-particle interaction.

Sep 1, 2012

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

By T. X. Hu

Pyrite ore is one of the main raw materials in the production of sulfuric acid. For a long time, the raw material containing the pyrite, which is used to produce sulfuric acid, generally contains S only 32%~45%. A plenty of residue from the sulfuric acid production contains 40%~50% Fe and 1%~2% S. Some of the residue also contains Cu, Pb, Zn and other harmful elements like As, thus it pollutes environment seriously and is solid waste. The research on comprehensive utilization of the residue has been made by many scholars. Through the study, the residue can only be used to pro-duce iron concentrate and the iron oxide red pigment. But because of the complex techniques, the low recovery, the low grade of iron concentrate , high sulfur in iron concentrate, causing second waste residue and the environmental pollution, the residue is mainly used as an accessory material in the production of cement, and is of a low value. Therefore, the iron resource in pyrite has not been used efficiently until now. In the paper, the flotation condition test, the flotation open circuit test and the flotation closed circuit test to produce high-purity pyrite concentrate with the low-grade pyrite ore in oceanic ore deposit have been carried on. Flotation reagent scheme of sulfuric acid used as activator and butyl xanthate as collector is determined. After four times depth cleaning, high-purity pyrite concentrate containing 52.82% S, 44.29% Fe, and only 2.89% impurities has been obtained. The S recovery is 99.13%, and the Fe recovery is 96.00% in the high-purity pyrite concentrate. The oxidizing roasting depth desulfurization experiment of the high-purity pyrite concentrate has been conducted. The results show that the Fe grade in the residue obtained is 68.58%, the content of S is 0.25%, the content of P is 0.0084%, the content of As is 0.0065%. The residue is a kind of high-quality iron-smelting raw material. Based on the above experiments, the industrial experiments on producing high-purity pyrite concentrate with the low-grade pyrite ore, and producing sulfuric acid and iron concentrate with high-purity pyrite concentrate have been done. The results indicate that the high-purity pyrite concentrate with the S grade of 51.24%, the Fe grade of 44.15% has been obtained. The iron concentrate obtained with 65.73% Fe and 0.23% S is a sort of high-quality iron-smelting raw material applied to the production of steel and iron smelting. Through the experimental study, the sulfur and iron resources in the pyrite ore have been recovered and utilized efficiently.

Jan 1, 2014

By V. A. Chanturiya

The results study the minerals oxidation were obtained by us during the methods of microscopic, FT-IR spectroscopic, XRD and chemical analyses of sulphides in tailings of copper-nickel wastes in Kola peninsula. Sulphide minerals begin to oxidize already at the stage of stockpiling and initial stages of storing. The proportion of non-ferrous metals and magnesium oxide increases with time, calcium partially precipitating in the form of gypsum. Comparison of heavy metal contents in pore solutions in cur-rent and stale copper-nickel ore concentration tailings has revealed a significant difference in practically all the parameters. The lower metal contents in current tailing pore solutions (by 5~30 times) are probably due to the presence of float reagent residues blocking oxidation. Much lower concentrations of magnesium and calcium can be accounted for by the difference in kinetics: the rate of sulphide oxidation at this stage is much higher than that of solution interaction with non-metallic minerals as the result of which the solid phase ? solution equilibrium is not achieved. It is generally believed worldwide that it the mining wastes with acidic pore solutions that pose the greatest hazard for the environment. Our findings suggest that although the solution pH in all the samples is higher than 7.8, the contain heavy metal concentrations by far exceeding permissible values. The direct determination of the total and silicate Ni contents in the tailings from current production and in storage tailings has shown that both sulphide and silicate Ni forms occur in tailings. However, the role of silicate Ni is much larger in the storage tailings. The average silicate Ni content accounts for 10% of the bulk Ni content in the current tailings and it increases to 40% in the storage tailings. Thus, the storage tailings are marked not only by sulphide oxidation and the removal of water-soluble sulfates, but also by the interaction of sulfates with the silicate matrix. Although complete equilibrium is not achieved even within 30 yr under polar-region conditions, the major part of the Ni in fine-grained fractions passes into silicate form. The probability of Ni transition to the silicate form directly correlates with the dispersion of the material and the amount of chemically reactive serpentine and hydrochlorite. The migration of Ni as sulfates and its precipitation by chemically active silicates distorts the distribution of this component in the coarse- and fine-grained fractions that are typical of tailings from the current production of copper-nickel ores. On the one hand, the variation of the mode of Ni occurrence in storage tailings lowers the value of technogenic raw materials as a source of this metal.

Jan 1, 2014

By Yuqing Feng, Ping Fang, Dezhou Wei, Zichuan Guan, Shuling Gao, Baoyu Cui

"Air core, as an inevitable phenomenon of rotational flow field inside hydrocyclone, has a major impact on hydrocyclone’s separation characteristics. The air core formation process, its structural features and its influencing factors were investigated systematically in this paper. Numerical study on the air core of a f50 mm hydrocyclone was carried out using a commercial computational fluid dynamics (CFD) modelling software package ANSYS/Fluent with the selection of Reynolds Stress Model (RSM) for the turbulence model and Volume of Fluid (VOF) for capturing the air-liquid interface. Physical experiments were conducted under the same geometry and operation conditions and the particle image velocimetry (PIV) technology was used to measure the liquid flow. The CFD results are compared with the experimental measurement with good agreement demonstrated. The air core was formed generally at around 0.7 s, air outsides of the air core was eliminated completely after 1.7 s. The centreline axial velocities and the water blocking hydrocyclone simulations showed that air of the air core entered the hydrocyclone from the underflow area and exhausted from the overflow area, but there was also some air flowing into the air core from the overflow area. The largest swing of the air core occurred on the top of the underflow pipe, and a protuberance similar to the shape of Adam’s apple appeared when the air entered the vortex finder. CFD simulation results also showed that the air core diameter was decided by axial position and parameters of hydrocyclone. The structural parameters have more effects on the air core diameter than the operational parameters."

Jan 1, 2014

By Barda K. Mishra, Surya P. Mehrotra

"INTRODUCTIONIn a jig, which is primarily a coarse mineral concentration device, the bed of mineral particles is pulsated with a stream of water resulting in the particles of different specific gravities. It operates in a cyclic manner – the jig cycle consists of four stages, namely, inlet, expansion, exhaust and compression. In the inlet stage the bed lifts up en masse. Near the end of the lift stroke the particles at the bottom of the bed start falling resulting in the loosing of the bed which, in turn, causes its expansion or dilation. During the third and fourth stages the particle resettle through the fluid, and the bed collapses back to its original volume. The pulsation and suction are repeated to bring about stratification with respect to specific gravity across the bed height. Various parameters affecting the stratification process include amplitude and frequency of pulsation, bed thickness, rate of hutch water flow, and feed characteristics. This paper first presents a review of various jigging theories and then describes a new approach to mathematical modeling of jigging employing the discrete element method.JIG MODEL BASED ON DISCRETE ELEMENT METHOD (DEM) APPROACHThe jig models based on DEM essentially involve tracking the position of each particle incrementally, applying Newton’s law of motion and a force displacement law at the contact. The model presented here is based on a three dimensional mathematical description of solid-solid and fluid-solid interactions. In this model, the force balance on a particle is extended to account for the effect of continuously varying fluid on the particle. The total force on each particle is made up of a known external body force, fluid particle interaction force and particle-particle and/or particle-wall interaction force. The fluid-particle interactive force is primarily made of drag and buoyancy. Di Felice’s correlation is used to evaluate the drag force. Solid-solid interaction is described by treating particles as discrete elements that are indestructible but interact with each other and any other elements present, such as walls, when they make physical contacts. A pair of spring and dashpot represents a contact The contact forces are computed from the amount and the rate of overlap of the particles at the contact. The motion of the particle is due to movement of the fluid, which transmits its energy through the particle-particle contacts. A computer program incorporating both the contact and the fluid model has been developed. It takes the operating parameters such as amplitude and frequency of the pulsating fluid, pertinent data concerning particle properties and the geometry of the jig bed as inputs."

Jan 1, 2003

By Peng Qian, Xiao Li, Guoyan Fu, Peiwei Han, Yongliang Wang, Shufeng Ye

"Arsenic removal from high arsenic gold concentrate is conducive to increase the mineral value and realize the mineral comprehensive utilization. This study investigated the alkaline pressure oxidation leaching (APOL) of an arsenical gold concentrate in lower temperature to separate the arsenic into filtrate. The effects of temperature, NaOH concentration, solid-liquid ratio, reaction pressure and stirring speed on the leaching efficiency were investigated, and the characteristics of the gold concentrate and leaching residues were evaluated using XRD and SEM analysis methods. The obtained results showed that by using lower temperature (<60?) it is possible to avoid the production of elemental sulfur during the leaching process, which is benefit for the oxidation of arsenopyrite; When the reaction was carried out under appropriate conditions, more than 98% of the arsenic will be extracted into the filtrate as the form of arsenate or thioarsenate. INTRODUCTION In recent years, there has been considerable interest in the recovery of gold from refractory arsenical gold ore. The arsenic in this kind of ore usually exists as the form of arsenopyrite, and the gold surrounded by arsenopyrite exists as the form of fine particles, which will give many difficulties to metallurgical work. When the content of arsenic in the gold ore is more than 0.5%, it will seriously penalize the smelting efficiency (Ruiz et al., 2014). So pretreatment of the refractory gold ore is necessary to obtain the largest economic value and environmental benefits (Balaz et al., 2000). The oxidation pretreatment processes mainly include roasting oxidation, pressure oxidation, chemical treatment and biological treatment (Ann et al., 1992; Kou and Chen, 2012; Tongamp et al., 2010; Fernandez et al., 1995; Lin and Zheng, 1996). Among them, the roasting oxidation and pressure oxidation are the more ordinary processes in industry. The roasting oxidation process is the mature and adaptable technology, but the production of waste gas containing sulfur and arsenic will pollute the environment. The pressure oxidation method possesses certain metallurgical and environmental advantages, and can efficiently decompose the mineral. According to the different solution media, the pretreatment can be divided into alkaline and acidic pressure leaching pretreatments (Papangelakis and Demopoulos, 1990; Hiskey and Sanchez, 1995). The acidic pressure oxidation method has been used in most smelting plants for high arsenic gold ore pretreatment, while the alkaline pressure oxidation is still not widely applied. Compared with the acidic pressure oxidation, the alkaline pressure oxidation can be realized under lower temperatures."

Jan 1, 2018

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto

"The theoretical technique of computational modeling and the experimental determination of the enthalpy of adsorption of a ligand molecule onto a mineral surface deliver the same output parameters and, therefore, complement each other in investigating the affinity of different ligand types for mineral surfaces.This study ran parallel experimental tests and computational calculations to determine the enthalpy of adsorption of a series of increasing chain length xanthates onto a pyrite surface. The outcomes showed that, while the absolute energy values were different, the trends were similar. Both computational and experimental approaches showed that the extent of the interaction of the xanthate molecule increases with increasing carbon chain length. The computational values were larger than the experimental values, which could be explained, in part, by the addition of water to the computational system, which resulted in a decrease in the heat of adsorption on the (100) surface, compared to the adsorption of the collector in a vacuum. The computational method showed that, in the case of the pyrite (100) surface, the most exothermic reaction was obtained when the two xanthate sulfur atoms bridged two pyrite 5-coordinated iron atoms. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted for each of the C2, C3, C4 and C5 chain length xanthates.The experimentally determined exothermic increase in heat of adsorption for the addition of each CH2 group was found to be -8.17 kJ/mol. The contribution of the thiol head group was -34.9 kJ/mol. Previous studies on self-assembled monolayers have shown that these values are compatible with lateral interactions between CH2 groups and the exclusion of water. This study provides a rigorous experimental and computational approach which is intended to afford confidence in modelled data for the screening of new ligands for flotation processes.INTRODUCTIONComputational modelling is a fast and cost-effective method of screening collector molecules for the efficacy of their adsorption onto mineral surfaces. However, it is desirable to measure the computational outputs against experimental outputs to check for congruency. Computational modelling and experimental microcalorimetry both deliver the same output parameter: the energy of adsorption of the molecule onto the solid surface. These techniques are therefore ideally suited to complement one another in investigating the affinity of the interaction between collector molecules and mineral surfaces."

Jan 1, 2018

By V. A. Masloboev, A. V. Svetlov, D. V. Makarov

"The methods of heap leaching are considered to be the most promising for the low-grade copper-nickel raw materials. The article presents intensification capabilities of the process. Objects of research: the low-grade copper-nickel ores of Moncheplutone deposits (Moroshkovoye Lake, Nyud Terrasa, Nittis-Kumuzh’ya-Travyanaya (NKT), as well as the copper-nickel ore dressing tailings of the “Kola MMC” JSC. The following directions for the intensification of the low-grade copper-nickel raw materials heap leaching have been considered: preliminary electric pulse destruction (EPD) of ore; ore crushing and further sulfuric acid agglomeration. The impact of sulfuric acid concentration (1-3%) on the extraction of non-ferrous metals kinetics from the copper-nickel ore dressing tailings under various conditions of the percolation leaching has been studied. INTRODUCTION The low-grade grade sulfide ores at the abandoned and producing deposits, overburden rocks, mill tailings and non-ferrous slag are thought to be one of the large-scale sources for non-ferrous metals, on the one hand. On the other hand, they are known to be the subjects of emergency environmental danger. For this reason, the use of mine dumps and tailings, as well as the remained ores left in the ground as raw products, and at the same time decreasing the load on environment, are considered to be the pressing ecological and economic issue (Chanturia et al., 2012). Methods of heap hydrometallurgical and bacterial leaching are sure to be potentially productive for processing such low-grade and technogenic raw materials (Petersen, 2016). The early studies of hydrometallurgical method possibility to process copper-nickel ores of the Murmansk region deposits were launched in the seventies of the previous century (Golovko et al., 1978). For referencing purposes, the main types of impregnated ores from the deposits Zhdanovskoye, Kaula, Sopchinsky Plast and Lovnoozerskoye were selected. The metal content varied, as %: 0.46-1.49 of nickel, 0.01-0.62 of copper. In the first experiments, the solution containing 150g/l of H2SO4 and 135g/l of NaCl, was used in the capacity of leaching reagent. The possibility of underground metals leaching from the ores of the Lovnoozerskoye deposit was justified due to the performed laboratory and further large-sized tests."

Jan 1, 2018

By P. Oliveira, A. Peres, A. Silva

"The decrease in iron content and increase in contaminants grade, associated with greater participation of compact and semi-compact materials, has impacted the recovery of a mechanical cells flotation circuit in the Iron Quadrangle, Brazil. The recovery decrease in the flotation stage motivated the current conventional flotation circuit reevaluation seeking alternatives to restore the recovery, without affecting the final concentrate quality parameters, with low investment. Sampling, chemical characterization of samples, bench scale flotation experiments, and mass balances were conducted. Analysis of the results showed opportunities to improve the circuit performance. The stages prior to the flotation circuit changes were: rougher, cleaner, recleaner and scavenger. In the previous configuration, recleaner was operated as cleaner scavenger and the iron grade in the scavenger concentrate was 23%, representing 38% of the new feed. After the circuit change, the circulating load was reduced from 38% to 15% and the iron content was upgraded to 42%, resulting in increased residence time. The iron content in the global tailings of the concentrator was decreased from 10.9% (year of 2013 average) to 10.2%, representing gains in both mass and metallurgical recoveries.INTRODUCTIONRegarding plant practice, the year 1972 represents a landmark for the concentration of iron ores in Brazil. VALE started up 28 units of WHIMS (wet high intensity magnetic separators) at the Cauê plant in Itabira, each one producing 1x106 t/year of concentrate. Later 17 WHIMS machines were commissioned at Conceição. During the 80’s decade of last century, changes in the ROM required the addition of a cleaner flotation stage to decrease the silica content in the pellet feed.The first company to use reverse cationic flotation as the only concentration operation of iron ore was SAMARCO (start up in 1977). Since 2015 flotation has been utilized at VALE in Itabira as major concentration process, magnetic separation acting as scavenger stage.The Jones matrix type WHIMS were manufactured for decades under patent by KHD Humboldt Wedag. After the expiration of the Jones patent, Eriez Magnetics took the world leadership regarding WHIMS manufacturing. The Brazilian branch of Eriez is Inbras. Based on plant practice experience at the Fabrica concentrator, the Brazilian company Gaustec was established (RIBEIRO and RIBEIRO, 2010) and is now present in different countries. The mega sized WHIMS GHX-1400 (18.000 Gauss, gaps smaller than 1.5 mm) were developed to face the challenge of huge throughput required by iron ore processing (Ribeiro et al, 2017)."

Jan 1, 2018

By Chao Li, Kym Runge, Saeed Farrokhpay, Dee Bradshaw

"It is well known that froth phase has a controlling influence on the overall flotation performance. Froth recovery is expected to be affected by froth transportation behaviour. The latter has been represented by different volume balance and energy balance based models. In froth transportation models based on a volume balance, the froth phase is divided into different zones. The total froth residence time is the sum of the time spent in each zone and is dependent on the cell geometry, bubble burst rate and the position that bubbles enter into the froth phase. Alternatively, the froth transportation model based on an energy balance treats the froth phase as a block. In this model, froth height above the concentrate lip is being predicted by minimising the energy of the system which is dependent on the froth geometry, froth stability and froth rheology. The froth height can be used to calculate the froth efficiency of delivering mineralized bubbles from the pulp to the concentrate lip. This paper critically analyses the current models of froth transportation in flotation, and examines the limitations of these models. The importance of froth rheology, which is the resistance to the froth flow towards the discharging weir, in determining froth transportation, is also highlighted."

Jan 1, 2014

The air recovery from a flotation cell is the fraction of inlet air which overflows the weir as un-broken bubbles. The air recovery is an important factor in froth phase phenomena; such as gangue entrainment and froth recovery. Increasing the air recovery, results in a higher recovery of attached mineral particles. Air recovery can be measured experimentally on plant using image processing of the top surface of an overflowing froth. The air recovery is directly linked to froth stability and the bursting rate of the bubbles at the froth surface, making it very difficult to predict. Experimental results show a very strong correlation between the superficial velocity of the inlet air and the superficial velocity of the air leaving the cell through the froth surface due to bursting, calculated from the experimentally measured air recovery. This correlation holds over multiple banks from different plants. Development of a power law equation around the inlet air velocity and the bubble solids loading on the froth surface allows the superficial air velocity through the top surface of the froth to be predicted, and from this the air recovery. This model is valid for use when operating beyond the peak in air recovery.

Jan 1, 2014