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By B. W. Zhao

Quantitative analysis of minerals composing in ore is primary in process mineralogy, a veracious quantification and analysis is very crucial to optimize or design a beneficiation process, especially for a low grade and complicated ore. This paper will discuss a SEM-EDS based quantitative analysis developed in JKtech Australia through an example from Jinchuan lean ore. For a low grade, com-plex intergrowths and texture lean ore, chemical phase analysis of value minerals and identification by optical microscope are very essential, unite the SEM-EDS based quantitative analysis, we can understand exactly the lean ore, explain and quantify the process performance.

Jan 1, 2014

By A. Üçyildiz

Magnesium borates of varying compositions and properties are synthesized using different reagents and methods for the possible potential uses as termoluminescent material, anti-wear and anti-friction additive, fire retardant, catalyst for the conversion of hydrocarbons, whisker material and ferroelastic material. In the current work, the conditions for synthesizing MgB4O7 compound by high-temperature solid-state reactions were investigated using boric acid and magnesium oxide as the starting materials. The MgO:B2O3 mole ratios applied in the experiments were 1:1, 1:2, 1:3 and the thermal behaviours of each mixture were studied between 25~1200°C by TG/DTA analyses under static air atmosphere to find out the probable formation temperature of MgB4O7 phase. Considering TG/DTA results, freshly prepared boric acid and magnesium oxide solid mixtures were heated at predeter-mined temperatures and the phases were identified by XRD analyses. Accordingly, MgO:B2O3 mole ratio of 1:2, heating temperature of 950°C and a reaction time of 2 hours were selected as the optimum conditions for the formation of maximum amounts of MgB4O7. After obtaining solids prepared at the pre-determined optimum conditions, their chemical composition, IR spectrum, TG/DTA pattern, B.E.T. surface area value, particle size distribution and SEM images were deter-mined to point out the possible use areas. Experimental results showed that it was not possible to obtain pure product at the optimum conditions due to formation of minor amounts of t-Mg2B2O5 and the presence of some unreacted B2O3. The product synthesized has the potential for use as a corrosion inhibitor on some metal surfaces.

Jan 1, 2014

By Ye Junjian

The feed ore is the concentrate of low intensity magnetic separation of pyrite tailings, containing TFe47.47%, S19.41% and SiOpyrrhotite. The exploratory tests showed that using a process of flotation followed by magnetic separation could respectively obtain a sulphur concentrate of S 31.08% with a recovery of 82.89%, and an iron concentrate of TFe 59.97% and S 9.52%with a recovery of 30.93%. The reason of iron concentrates with high sulphur grade was that the sulphur grade of flotation tailings was 7.03%. So enhanced flotation for pyrrhotite was investigated in this research. Results show that when the natural pH of ore pulp varied from 5.5 to 6.0, a reagent combination of FS, LH, and BJ displayed the optimum flotation performance for pyrrhotite. After comparisons made on different flotation processing, the previous flotation flow of ?one roughing, one cleaning, one scavenging system and middling reprocessing?, was found, among others, to have the best flotation effect, as the grade and recovery of sulphur concentrate were 31.08% and 82.89%, respectively, and sulphur content of the flotation tailings was 7.03%. The above results indicated it was difficult to raise further the effect of flotation desulphurization. The authors therefore suggested that oxidizing roast should be adopted following the magnetic process for the purpose of further desulphurization. Besides, flue gas containing SO2 8.25%. And the valuable minerals are magnetite and 2 generated from roasting could be reused for sulphuric acid production. Keywords: pyrrhotite, enhanced flotation, desulphurization

Sep 1, 2012

By P. Yu, L. X. Liu

"A mechanistic model for tumbling mills was developed during PhD studies at the JKMRC. The concept was presented at the IMPC of 2014, followed by progress in a sub-process of the model presented at the IMPC of 2016. Additionally, a number of papers on the sub-models and breakage function have been published. This paper provides a consolidated summary of the outcomes and status of the model. The overall model structure is presented along with the sub-models such as appearance functions, breakage rate functions, energy distribution, transport, and multicomponent grinding interaction model. The strengths and capabilities of the model structure as achieved to date are presented. The gaps in knowledge and sub-processes are also presented, providing a guide to the areas that require further research and development. It is proposed that the approach developed in this paper provides a structure that can accommodate future mechanistic, dynamic mill model evolution that can incorporate the latest research outcomes and provide a platform to test modelling improvements. This can assist in substantially improving the predictive mill modelling capability in the industry, the importance of which should not be underestimated for this workhorse of mineral processing.INTRODUCTION Grinding is almost the largest single energy-consuming process in the mineral processing industry, which was estimated that about 0.2% of global, and 1.3% of Australia’s electricity is consumed by comminution of gold and copper ores (Ballantyne and Powell, 2014). Although there are some relatively new grinding mills, such as stirred mills, vibrating mills and HPGRs (High-Pressure Grinding Rolls), etc., tumbling mills, as the traditional grinding facilities, are more extensively used."

Jan 1, 2018

By I. I. Beloglazov, G. A. Iusupov, A. Ju. Feoktistov

"The aim of this paper is to study the numerical modeling of the crushing process in a jaw crusher with complex motion jaws using Discrete Element Method (DEM). The main goals are to ensure the conformity of numerical simulation results to the experimental data, optimize the operating modes and the crusher design and develop automated verification and calibration methodology. It is offered to use automated selection of mathematical model parameters using large- or laboratory-scale experiments instead of deriving parameters from conventional intensive material tests (e.g. drop-weight test). Experimental data were obtained from a large-scale crusher designed and manufactured by the company “Mekhanobr-Tekhnika”. Both jaws have their drive shafts located asymmetrically; one jaw is driven in the upper part, the second at the base. The crushing process involves fragmentation of single smoothed rectangular granite particles of the same weight. During the experiment, the required parameters such as particle size distribution were obtained for further computer simulations. Based on the obtained experimental data, the Rocky DEM model was built. Simulation breakage parameters were calibrated using automated parameter selection methodology based on multiple set of parameter-controlled simulations. A good correlation of the experimental data and numerical simulation data was obtained. The methodology in combination with well-known capabilities of simulation modeling will help reduce the research time in the development of new mineral processing equipment.INTRODUCTION Preparation of rock mass for enrichment includes the power-consuming processes of crushing and grinding. Initial rock mass crushing is performed by means of drilling and blasting operations. To reduce the average size of a rock piece, primary crushers, mostly jaw crushers, are further applied. The advantages of the jaw crusher are simple design, easy maintenance and repair. One of the drawbacks is large oscillating masses and, thus, high power consumption during operation (55 - 200 kW). Jaw crushing simulation will help optimize the crushing process and improve further rock transportation and processing performance."

Jan 1, 2018

By James Y. Oldshue

"Very seldom is it possible when contacting a gas with a slurry to measure the dissolved gas concentration in the slurry, and even were it possible, seldom are equilibrium data available with a suitable Henry’s law constant.In general, by assuming a reasonable value for the dissolved gas concentration in the slurry and a corresponding equilibrium gas partial pressure P*, Kga values can be calculated for the pilot plant and scaled up. Then, with the same P* value at various reaction conditions, a mixer can be designed which is quite satisfactory, having a reasonable design factor for full-scale performance.We will take as an example a slurry of a known solids composition and use a continuous 4 tank system. By assuming a percentage saturation of the dissolved gas in the first tank, the dissolved gas concentration can be obtained in the other three tanks. It usually is possible to measure the off-gas composition in each of the 4 tanks. If the top of the tanks is connected in the form of a multi-compartmented horizontal autoclave, then a modified top off-gas composition in each compartment must be used."

Jan 1, 2003

By Choi Sang-Ken, Chung Hun-Saeng, Kim Byoung-Gon, Park Chong-Lyuck

Fine grinding of crystalline graphite was conducted using a dry attrition mill with a vacuum system to investigate the characteristics of size reduction. Low pressure and high temperature conditions in the grinding mill were found to greatly improve the efficiency of the size reduction of graphite. Natural flaky graphite of .100 mesh was ground into sub-micron sizes, then over 90% of the product were able to be reduced below 1?without disrupting their crystallinity in a short period of time. Reducing the atmospheric pressure in the grinding environment promotes the removal of chemical species such as oxygen and water molecules adsorbed on the graphite particle, resulting in effective size reduction while maintaining the crystallinity of graphite.

Jan 1, 2003

By V. V. Morozov, I. S. Barmin, A. V. Tugolukov, V. V. Polivanskaya

"It was presents the results of research on improving reagent regime and scheme of enrichment of slime classes of Apatite-Staffelite ores and tailings stockpile of Kovdorsky enrichment plant. It was investigated the regularities of flocculation in the processes of thickening and selective flotation apatite-bearing ores. It was established character of the influence of flotation reagents on the flocculation process. It was shown that the sodium silicate and soda ash have a stabilizing effect by thickening of sludges. Neonol and oleic acid have a coagulating or flocculating effect. It was tested the new regime flotation, involving an initial conditioning with using of reagent - dispersants before feeding the pulp into the flotation and subsequent conditioning with reagents having a coagulating effect. The flowsheet and reagent regime for enrichment of fine-grained tailings stockpiled was developed, which providing production of standard apatite concentrate and increasing the recovery of valuable components. There are presented results of the research of activities of strong organic surfactant on solubility of colloidal form fatty acid collector and aggregate stability of fine minerals in the process of thickening and flotation. Surfactants such as Neonol have been investigated for increasing the activity of the collectors. When using the process of thickening sludge fraction with flocculant Praestol 2540 and stadial conditioning of sludge were obtained concentrates containing up to 38.1% P2O5 at recovery. INTRODUCTION A feature of the Apatite-Staffelite ores of the Kovdorsky deposit is the presence of a large number of fine mineral particles and a reduced hardness of phosphate minerals (Beloborodov et al., 2010, Tugolukov et al., 2012). Formed in the ore-preparation process, sludges are lost with a discharge in the thickening operation. Sludge is characterized by an increased content of phosphorus pentoxide (P2O5). Losses of P2O5 at enrichment of the stale tailings of Kovdorsky GOK reach 14.0%. The high losses of P2O5 caused a profound study of the behavior of thin apatite classes under conditions of thickening and flotation."

Jan 1, 2018

By Danilo Zim, Matheus Paschoalino, Denis Guimarães, Jasbir Gill

The shortage of water supply in some regions of the globe is particularly problematic and forces mining companies to adopt alternatives like pumping sea water from the ocean up to the mining sites. Although deaeration of sea water or the use of lined pipelines are known options to prevent corrosion during pumping, a recent development of a new corrosion inhibitor allowed the use of simple mild steel pipelines for this purpose. The objective of this study is to demonstrate the recent advances of this technology in protecting against not only general corrosion but localized corrosion, main cause of corrosion-related pipeline failures. Corrosion studies were carried out using electrochemical techniques, weight loss balance as well microscopy surface analysis in order to measure and therefore evaluate the treatment efficiency. The right dosage of corrosion inhibitors may vary depending on water composition and characteristics of each system. Differences were observed depending on the sea water source. Pretreatment of metallic surface impacts the observed corrosion rate which can be as low as 3.6 mpy. The absence of pitting or localized corrosion was achieved in aerated seawater.

Jan 1, 2014

By B. Vasanthakumar

In this study, the effect of adaptation of B.subtilis to sphalerite and galena with respect to the selective flotation of sphalerite from the sphalerite-galena synthetic mixture has been examined. The changes in the surface charge of the mineral and the bacterium, cell wall components and the profiles of secreted proteins are discussed. The flotation recovery of galena increases with the increase in the adaptation cycle of B.subtilis to sphalerite and galena, while the flotation recovery of sphalerite is independent of the adaptation cycle with either mineral. From the gel electrophoresis analysis, the protein profile for the unadapted and adapted cells is found to differ distinctly and this may be attributed to varying molecular weight fractions arising from different growth conditions. Electrokinetic measurements showed shifts in the iso-electric points of not only B.subtilis but also of the chosen minerals after adaptation. Additionally, the zeta potential of B.subtilis is found to become less negative after bacterial adaptation to the chosen sulfide minerals, while it showed an increase in the magnitude of surface negative charge after various enzymatic treatments. The change in the surface morphology and cell wall components such as phosphate, uronic acid and acetylated sugars of the bacterial species during adaptation to sphalerite and galena has been assessed. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite can be preferentially floated from galena in the presence of the insoluble fraction of lysed B.subtilis cells initially adapted to sphalerite, with a high selectivity index. Keywords: bioflotation, b.subtilis, mineral adaptation, sphalerite, galena

Sep 1, 2012

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By A. Oleynik

The paper presents the modeling and simulation experience in field of research into the mineral row material separation. Features of the subject domain generate a need of different approaches using for modeling and simulation. The general scheme of separation modeling process and some examples of developed simulators are presented. Due to different features and standards of knowledge, different formal models should be used to describe and analyze separation processes in the frame of general scheme. The main types of simulators are modeling tools based on statistical, analytical or expert (logical) methods. Advantages and disadvantages of each method above are mentioned in the paper. Based on the studies in the field considered, an aggregated mathematical model of a separation process has been generated. The aggregated model is presented by two combined equations. The actual apparatus model is formed by substitution of the particular functional expressions of the forces acting in the apparatus into the aggregated model. The developed simulation tools are based on integration of limited experimental data and on ex-pert knowledge available on separation processes. Simulation does not allow producing an optimal, in terms of mathematics, solution. But it gives an opportunity to produce and compare quite adequate solution variants in real time. The results obtained are the theoretical and methodological base for integrated information technologies to support studies in the field of mineral processing.

Jan 1, 2014

By W. S. Eu

Thermal treatment of mineral ores can initiate thermal phase transformations which can affect either their activation or deactivation, subsequently influencing their ability to dissolve in a leaching reagent. The formation of rutile and hematite from ilmenite minerals, for example, has been suggested to occur through a series of reduction and segregation reactions. This process has been used in beneficiating low-grade weathered ilmenite ores to higher grade rutile. Despite decades of re-search, the mechanism of this process is not well understood, because dissolved intermediates are poorly crystalline and are difficult to quantify, with the exception of the final rutile products. Previous studies have shown that disrupted intermediate phases, by thermal treatment, are most susceptible to reagent attack and can often demonstrate ?activation? effects. In this study, synchrotron based X-ray diffraction method was used to investigate in-situ and in real-time the transformation of ilmenite minerals to rutile and hematite during calcination. The rate of formation and disappearance of specific Bragg peaks during the reaction and thermal decomposition of the mineral were used to derive an understanding of the solid-state reactions. The effects of the mineral transformation were validated by laboratory based batch calcination and leaching in sulphuric acid. The results suggest that transformation of major mineral phases occurs within of specific window of operation and thermal treatment appears to influence the extent of activation and leachability of ilmenite minerals.

Jan 1, 2014

By G. Mucsi

This paper deals with the laboratory investigation of cathode ray tube (CRT) glass based glass foam, a relatively new product so called ?Geofil bubbles?. The main process engineering material properties of raw materials, such as particle size distribution, moisture content, density and specific surface area are shown. Then the preparation of raw cathode ray tube glass waste is presented including the following steps: crushing in impact crusher, grinding in laboratory scale ball mill, mixing, pelleting and sintering. We found that it was possible to produce foam glass (with proper mechanical stability and particle density) from the investigated waste CRT glass. The material characteristics of the final product strongly depend on the sintering conditions. Optimum conditions were determined particle size fraction was found to be 4-6 mm, temperature 800 0C, residence time 7.5 min. Keywords: waste CRT glass, grinding, pelleting, sintering, glass foam

Sep 1, 2012

By Felipe Sepulveda, Edelmira Gálvez, Luis Cisternas

"In mineral processing, the recovery and/or concentration of the value components cannot occur in one operational stage, therefore requiring the use of separation circuits based on several flotation stages. The components to be separated are typically distributed at different concentrations and different particle sizes, resulting in different levels of recovery. Typically, more than one value component must be selectively removed by exploiting the differences in the components’ floatability at different pH values, pulp potential and particle size. Several methods for the design of these circuits are available in the literature, but comparatively few studies present circuit analysis tools or address the design of a multiple-product flotation circuit. In this study, global sensitivity analysis was used to analyze a flotation circuit with several products, such as copper, lead and zinc. This analysis was based on the Eureka mine concentrator plant. The analysis was performed for each of the sections of the circuit as an overall evaluation of the circuit. The Sobol’ method and the correlation method were used to evaluate the Eureka mine concentrator plant using the SimLab 2.2 software."

Jan 1, 2014

By Walter W. Focke, Zola Kwela, Willem van der Merwe, Arao Manhique

"The advantages of the de Wet zirconium process for the manufacture of AZST from zircon sand include: Fewer processing steps; removal of radioactivity by leaching rather than by precipitation; alkali reagent recovery in the form of a sodium silicate solution that is essentially free of radioactivity; fewer waste streams and less waste to discard.Here we report on our efforts at maximizing the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since they do not hydrolyse in water they limit the recovery of alkali. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed. Optimum process conditions, with respect to NaOH recovery, correspond to a 2:1 stoichiometry and fusing for 2-hour at 850°C. At these conditions the alkali recovery is ca. 78% and the zirconia yield is ca. 57%."

Jan 1, 2003

By Carmina Quintanar, Mario Palominos

"The mining industry is currently facing significant challenges to identify and adopt sustainable collector chemistry that effectively recover value minerals in difficult-to-process low-grade resources. These are typically characterized by complex mineralogy and the presence of significant amounts of penalty gangue sulfide minerals, especially pyrit which is a challenge to separate from value minerals at many major mine operations. Three chemical strategies for dealing with gangue sulfides and penalty elements are: a) selective flotation of value minerals while rejecting penalty minerals in the whole circuit, b) rejecting penalty minerals in an appropriate part of the circuit using selective depressants, c) using a combination of selective collectors and depressants in appropriate parts of the circuit. This paper will evaluate different strategies for dealing with those penalty elements and propose the most efficient alternative. New products and application technologies have been developed in the past 25 years by Cytec for implementing these strategies as dictated by the particular needs of a given plant. However, in recognition of the growing interest in meeting the sustainability challenges, Cytec Research and Development have been focused in the development of greener products (collectors, modifiers and frothers) and processes using FLOTATION MATRIX 100TM approach used to develop the optimal collector system for each specific ore. An overview of these new developments is given in this paper using case studies of application of selective collectors and polymeric modifiers including the newer, greener chemistries."

Jan 1, 2014

By B. S. Moroney

Elemental distribution varies widely in the ores, minerals and beneficiated products depending on the constituents. Accurate analysis of each element present in various beneficiated products is utmost required to assess the grade in view of zero waste technology. Hence, the suitable methods and instrumental technique is of prime importance as the distribution of various elements differs in the beneficiated products. Conventional classical technique of analysis is absolute and due to this, it has not become obsolete. Besides, it is much needed for making standards for various relative techniques. Instrumental techniques comprising of X-ray fluorescence, Induced Coupled Plasma Analyzer, Carbon-Sulphur Analyzer, Atomic Absorption Spectrometer etc. are important for quick and accurate analysis. However, the selection of these instruments depend on the nature of material to be analyzed. This paper highlights the importance and use of various methods/techniques and instruments involved in the analysis of various ores, minerals and beneficiated products. Keywords: wet classical, x-ray fluorescence, induced coupled plasma analyzer, atomic absorption spectrometer

Sep 1, 2012

By S. H. Shahcheraghi

The four operational parameters including collector dosage, frother dosage, conditioning time and pH, are the most important parameters effective on the flotation kinetic. The present study has been done at the Miduk Copper Complex in the province of Kerman. The effect of operational parameters on the flotation kinetic of copper minerals were studied and analyzed, so the optimum conditions for flotation kinetic of copper sulfide minerals were obtained. Under the obtained optimum operational conditions, the recovery of copper sulfide flotation at the 95% confidence level was estimated to be between 92.76% and 95.48% and the copper sulfide flotation kinetic constant was estimated to be between 1.40 and 1.45 min-1. Results showed that the consumption of the X231 collector (O-isopropyl-N-ethylthionocarbamate) and the A65 frother (Polypropylene glycol) could decrease up to 35% and 50% respectively while the copper sulfide recovery increases about 1 up to 2% at the laboratory scale. Keywords: flotation kinetics, sulfide copper, optimization, the Miduk Copper Complex, response surface method

Sep 1, 2012

By P. Pourghahramani

Several structural characteristics change during intensive milling such as chemical composition, phase transformation, crystallite size, lattice strain, lattice parameter (s) and solid reactivity etc. The creation of defects enhances the stored energy (enthalpy) in the solids and consequently causes a decrease of activation barrier for the process and/or subsequent processes. In this paper, the effects of milling on the structural changes of hematite have been investigated using dry millings. The structural changes have been characterized using a combination analysis of BET surface area measurements and X-ray diffraction (XRD) analysis. Besides, the hydrogen reduction behaviors and kinetics of mechanically activated samples and initial sample were studied using simultaneous thermal analysis (STA). The methods of Williamson-Hall and Warren-Averbach were used for analyzing of XRD patterns to resolve and extract the microstructural characteristics of hematite phases. It was concluded that the breakage and aggregation of particles take place mainly in the starting and prolonged stages of dry grinding, respectively. The BET surface area enlarged steadily over the grinding processes whatever milling methods were utilized. The characterization of structural changes revealed that the hematite milled under various conditions did not undergo any significant reaction or phase transformation during milling processes. In addition, X-ray amorphous phase con-tent increased gradually with extending the grinding intensity. The maximum X-ray amorphous phase exceeds about 81% after 9 hours of milling in both tumbling mill and vibratory mill. The Williamson-Hall plots revealed the anisotropic character of line broadening for deformed hematite and changes in the trend of microstructural characteristics as a function of milling time. It was found that the surface weighted crystallite size decreases and lattice strain increases over the grinding periods. The minimum surface weighted crystallites were calculated about 17.3 nm, 12.2 nm for the products of tumbling and vibratory mills respectively. The maximum lattice strain,, in the grinding with tumbling and vibratory mills was calculated about 4.44×10-3 and 3.95×10-3respectively. 21/210nmLe=<> The non-isothermal kinetic analysis of the products revealed that Fe 2O3 reduced to Fe in a two-step process via Fe3O4. Intensive grinding resulted in improved resolution of overlapping reduction events. It was also established that the mechanical activation had a positive effect on the first step of reduction. The prereduction step in the activated samples initiated and completed at lower temperatures than that in non-activated samples. The activation energy of reduction decreased at the first step of reaction with increasing the grinding intensity. Intensive milling increased slightly the average activation energy of the second step of reduction due to the present of finely agglomerated particles and intensive sintering of the particles in higher temperature ranges.

Jan 1, 2014