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By S. Leroy

Grinding is the most energy consuming step in mineral processing, however, it is still poorly understood and its efficiency is difficult to monitor. Mill performances are traditionally measured at the mill discharge, on the basis of a mass percentage passing a certain sieve. This approach does not reflect what happens to the fines through milling. On another hand, if many macroscopic parameters, such as the percent solids of the pulp, its viscosity, or its mean residence time in the mill are known to be related to grinding efficiency, the link between these parameters and particle size distribution (PSD) is still unclear. Here, a methodology is established to understand the effect of ball mill operating conditions on particle size and shape distribution in the grinding process. The study focuses on the particular case of an Upper Group 2 (UG-2) platinum ore concentrator. Due to the very low grade of sulphide and PGM (Platinum group metals) in UG-2, grinding mechanisms are entirely control by gangue minerals. These two minerals have contrasted properties and PGM content and these properties immediately affect the entire recovery process. So, the grinding of both gangue minerals is studied on a size by size basis. At particle scale, three parameters are addressed: particle size, particle composition and particle shape. The specific behavior of chromite and silicate grains is demonstrated. As a conclusion, this study gives some clues to operate ball mills in a more efficient manner regarding chromite issue in the processing of UG-2. Keywords: ball milling control, UG-2, chromite, fine particle, particle shape, segregation

Sep 1, 2012

By J. Jávor

The response of the air/water interfaces to deformation in presence of surfactants is affected by the adsorption/desorption rate, re-orientation and exchange rate of surfactant. These surface properties can be observed using equilibrium and dynamic surface tension and surface elasticity measurements. However, the effect of these parameters on bubble size in dynamic conditions has not been studied due to the difficulty in capturing freshly formed bubbles in dynamic conditions. The paper presents a new experimental set-up designed and built at the Aalto University, called Shear Force Observation Chamber(SOC). The setupallows the monitoring and analysisof freshly formed air/liquid interfaces in dynamic conditions and facilitates the study of the effect of dynamic surface tension and surface elasticityon freshly formed air bubblesin presence of surfactants. The method helps to establish correlation between bubble size and dynamic interfacial properties and bubble-bubble interaction in turbulent flow. Dowfroth 200, Nasfroth 240 and Dowfroth 250 commercial flotation frothers were tested in this study. The results show a marked difference between results obtained in dynamic conditions compared to the static conditions. The results are presented and the reasons and implication to flotation modelling are discussed in the paper. Keywords: shear force observation chamber, flotation frothers, flotation bubbles, critical coalescence concentration

Sep 1, 2012

By C. Gomez, J. Finch, R. Dalhke, J. Torrealba-Vargas

"The dispersion of gas into bubbles is an essential feature of flotation machines. Three measurements have typically been used to describe the dispersion: superficial gas velocity (Jg), gas holdup and bubble size along with the derived quantity, bubble surface area flux. Measurement devices continue to be developed. The McGill Jg sensor based on accumulating bubbles by natural buoyancy comprises a tube with a valve and pressure transducer (Figure 1). The tube is immersed at a desired location and depth (H1) in a flotation cell. On closing the valve pressure increases to a maximum (P1) when the tube is full of air. The Jg is estimated from the slope of pressure-time curve (dP/dt).The relationship between Jg and dP/dt is derived from first principles. Testing the relationship is difficult in a flotation machine as the spatial variation in Jg is generally not known. This problem is overcome using a specially designed experimental setup and the estimated Jg is shown to equal the known Jg.The derivation reveals the importance of bulk density (?b). The sensor was modified to provide an estimate of ?b (Figure 2). A second tube was added immersed to a different depth (H2) and kept full of accumulated air giving a pressure P2. The estimate of ?b is given by (P1-P2)/(H1-H2) (i.e., at the end of collecting the pressure-time data). This two-tube sensor also helps dampen process noise as illustrated by a sudden change in level when collecting the pressure-time curve. Both the original and modified versions have been widely used in plant test work."

Jan 1, 2003

By V. A. Chanturiya

The results of development of new collecting reagents selectively interacting with the metals of platinum group (MPG) are presented. A new approach to the concentration of the platinum minerals from the fine grade platinum containing products with the use of cloud point polymers for the first time proposed for this purpose is discussed. An original method for the investigation of complexing reagents with the platinum under flotation conditions developed by authors is described. The influence of the complexing reagents on the xanthate adsorption and on the electrochemical properties of the platinum arsenide surface (sperrylite) as well with the interaction mechanism between the reagent and metallic platinum were investigated by means of the modern physical and physicochemical methods of the solid and fluid phase studies. The results of tests of some complexing reagents with the rich copper-nickel ore in the cycle of nickel-pyrrhotite flotation are given. The data obtained makes it possible to mark the complexing reagent containing phosphine group as the most effective additional collector for MPG. Cloud point polymers containing thioamide, aminosulphide, and phosphine functional groups were examined. It is shown that all the reagents tested increase the platinum and palladium extraction to the nickel-pyrrhotite concentrate without quality loss. Platinum containing particles flocculate selectively.

Jan 1, 2014

By Chris A. Bennett, Glenn S. Dobby, David A. Bulled

Establishing reagent dosing strategies for new ore bodies has traditionally involved a combination of experience and empirical experimentation using standard laboratory tests. The grade and recovery data resulting from these lab tests have historically been used as direct indicators of plant performance despite the obvious differences between the flotation environments. A reagent scheme selected in this way would subsequently be employed to generate the grade and recovery information for the geometallurgical model which in turn was used for metal production and cash flow forecasts. If the reagent scheme was sub-optimal then so too would be the forecasts and the resulting cash flow.

Jan 1, 2003

By Arkady Senchenko, Yevgeny Zhagun, Yury Kulikov, John Starkey

"The paper contains description of a new project in Russia - gold-processing plant at Aleksandrovskoye deposit (start up in September, 2013). The paper includes a brief description of plant flowsheet, data for material composition and technological properties of ore, as well as information about the achieved parameters of ore processing over the first months of plant operation. The project is interesting because a new semiautogenous mill and a ball mill were purchased on the basis of SAGDesign Consulting Group recommendations after the testing of ore samples characterizing the deposit according to specific years of operation. The plant has relatively small design capacity - 750 000 tpa, but nevertheless is the biggest gold-processing plant in the territory of Zabaikalsky region. Major valuable component in the ore is gold, silver is recovered as a by-product. The ores are very hard to grind. The design grinding flowsheet includes a semiautogenous mill operating in closed circuit with a screen, and a ball mill operating in a closed circuit with hydrocyclones (SAB). Process technology includes gravity processing and flotation with subsequent cyanide leaching of concentrates. Mill operation analysis and conclusions about the compliance of the achieved values to target ones are shown, as well as the accuracy of SAGDesign method when applied to very hard ores of Aleksandrovkoye deposit are presented in this paper. Basic directions of technological flowsheet optimization are also given."

Jan 1, 2014

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"INTRODUCTIONAcid pressure oxidation of high-grade natural acanthite was investigated in the range of 110-150°C and in the sulphate media. High acidity and low pulp density were used to prevent the precipitation of silver.RESULTS AND DISCUSSIONTwo sets of acanthite specimens were obtained from La Valenciana and Ingleterra mines, Mexico. Pressure oxidation tests were conducted on 1 litre scale in a standard 2-litre Parr titanium autoclave.EFFECT OF TEMPERATURE ON THE REACTION OF ACANTHITEThe effect of temperature on the rate of oxidation is presented in Figure 1. The rate of reaction increased with increasing temperature."

Jan 1, 2003

By T. C. Sun

Two wasted activated sludges (WAS), from an industrial wastewater treatment and a sewage treatment plant respectively, and 7 collectors are used to investigate the feasibility of air flotation thickening of WAS by adding the collectors used in mineral processing. The collectors experimented include straight chain fat acids with different chain length, sodium oleate, alkyl sodium sulphonate, sodium dedecylsulfonate, and dodecylamine. The results show that the thickening efficiency varied depending on different collectors. Of the collectors experimented, dodecanoic acid and dodecylamine are best collector for thickening both sludges.

Jan 1, 2014

By Ralph J. Holmes, Victor Sharp, Steven J. Spencer, CSIRO Minerals, Kevin J. Davey, Jonathan J. Campbell, Peter L. Phillips

"Improved measurement tools for monitoring and control of AG/SAG mill performance have a high level of interest in industry. Historically, acoustic emission monitoring has been widely used on SAG/AG/ball mills and hydrocyclones to provide new information on the conditions inside these devices affecting their performance. The current work was focused on a new technique using surface vibration monitoring of a number of pilot-scale and production-scale AG/SAG mills to yield insights into the events occurring in the mills. The development of relationships between signal analysis outputs and mill operating conditions can be used for soft-sensor measurement of mill process variables. The technique used an array of accelerometers mounted on the mill lifter bolts linked to a fast data acquisition system which monitored the surface waves generated during operation. Details of the system are presented. Mill operating variables were adjusted systematically to provide a wide range of operating conditions for surface vibration signal collection. The experimental approach is discussed.The signals acquired during the experiments were analysed using a range of techniques. The results show that strong relationships exist between measured vibration power (both total power and within certain frequency bands) and mill load level/power and mill speed. A new method for extraction of power spectral density and band power information on features of interest in a mill rotation cycle is also presented."

Jan 1, 2003

By Y. F. Hou

This paper reports the results of the study of the influences of concentration and modulus of sodium potassium silicate solution (Na-K activator) and curing mode on the phase composition, mi-crostructure and strength development in the geopolymers prepared using Class F fly ash. X-ray dif-fraction (XRD), Fourier transform infrared spectroscopy (FTIR) and MAS NMR are utilized in this study. It shows that the compressive strength increases while sodium potassium silicate solution modulus increases, but when modulus exceeds 1.7, the compressive strength decreases, and it decreases markedly while modulus is greater than 2.0. The compressive strength improves with increase of sodium potassium silicate solution concentration. When the concentration is 36%, the compressive strength reaches the maximum. Elevated temperature can increase the strength of samples synthesized using sodium potassium silicate solution with 32% concentration and modulus 1.2. Compared to the strength of the sample cured at 50?, the strength of the samples cured at 65? and 80? are higher at 1 day and 3 days, but when cured at 80?, strength is smaller than that cured at 50? for 7 days. When temperature is too high, too long curing time will decrease the strength. Long precuring at room temperature before application of heat is beneficial for strength development, and there is about 10%~50% increase in strength of the samples cured at 1 day precuring and 2 days elevated temperature as compared to the strengths of the samples cured for 3 days at elevated temperature or cured for 28 days at room temperature. The main product of reaction in the geopolymeric material is amorphous alkali aluminosilicate gel.

Jan 1, 2014

By I. Grigoryeva, G. Voiloshnikov, V. Dementyev, N. Moskaeva, N. Voiloshnikova

"Adsorption processes with use of anion exchange resins are widely applied in the gold mining industry of Russia and the former Soviet Union. Anion exchange resin AM-2B and its analogs (with mixed basicity) are used as adsorbents. This paper focuses on the study of weak base anion exchange resin and its comparison with AM-2B resin. Different nature of the ion exchange groups of the adsorbents mentioned above provides essential differences in their properties both during adsorption and elution of gold and silver. Multistage gold elution and resin regeneration procedure is used for AM-2B resin whereas alkaline cyanide solution is used for weak base resin and allows for the reduction Capex and Opex in comparison with AM-2B resin. Anion exchange resins AM-2B and PuroGold S-992 were tested. Weak base resin is sensitive to pH of adsorption medium. Optimal pH value is 10.1-10.3 (at ?? >10.5 gold loading onto resin decreases dramatically). Adsorption isotherms for gold, silver, nonferrous metals, cyanide and thiocyanate ions from synthetic individual metal cyanide solutions were defined. Adsorption of all components onto PuroGold resin was lower than for ??-2? resin. Adsorption of metals from the solution with equal molar metal concentration (0.1 mg-equivalent/L of each metal) was also studied. The affinity of resins to cyanide metals complexes was established. Weak base resin has higher selectivity to gold in comparison with ??-2B resin and is less sensitive to ion composition of cyanide solution or pulp treated. Weak base resin was tested for gold recovery from gold ores. On the base of test results it was recommended to introduce this resin at some new plants in Russia. Commissioning and operation performance of gold plants confirmed efficiency of weak base resin use."

Jan 1, 2014

By Vladimir E. Vigdergauz

"Bubble-mineral complexes could be formatted by an attaching of hydrophobic particles to the surface of air bubbles or by an evolution of bubbles from solution onto hydrophobic surfaces. Measurements of contact angles, detachment forces (DF), induction times (IT), evolution pressures (EP) and flotation recoveries (FR) for the studying of minerals wettability at various pH and electrochemical potentials were used. An analysis of the obtained IT results show that a process of bubble attachment to a mineral surface is a rather slow one and it will scarcely be enough for bubble-mineral complex formation under the conditions of real flotation.The ranges of adhesion potentials obtained by DF measurements, Figure 1, correlate with the data of floatability-potential for pyrite. The ranges of adhesion potentials obtained by DF measurements for galena (-1 ÷0.2V) and chalcocite (-0.5÷1.2V) correlate with the potential ranges of floatability for galena (<0.2V) and chalcocite (>-0.4V). An increase of the DF and the cathodic limit of the adhesion potential with increasing length of the hydrocarbon chain were observed. EP-pH curves for sulfides are a mirror-like to the DF-pH curves, Figure 2. Structure of solid-liquid and liquid-gas borders has a determinative importance for formation of bubble-mineral complexes and subsequently flotation results. Under vacuum on the mineral surface there are produced micro bubbles and preferably they will be appeared on the hydrophobic sites. Water structure breaks near a hydrophobic surface facilitate water mass destruction and formation of gaseous phase embryos under decompression in the impeller zone. It simultaneously reduces a probability of produced micro bubbles dissolution as a result of pressure increasing owing to constant fluctuation of liquid densities into impeller zone. Comparison of Taggart’s evaluation of the suction behind blades of the impeller of an agitation-froth machine and ABEP data on galena, Figure, shows that gas evolution will be observed in the range of 1300-2700 revolutions of impeller per minute for hydrophobic and hydrophilic surfaces successively."

Jan 1, 2003

By Kobus (J. J. ) Rossouw, P. Chris Pistorius, Johannes Sono

"Different coal properties are important in SL/RN (coal-based rotary kiln) direct reduction of iron ore, and in electrical smelting of prereduced iron ore. Laboratory simulation was used to evaluate two candidate coals, which were similar in volatile content and rank, but differed in reactive maceral content. The tests served to evaluate both the reduction rate (during direct reduction) and the dissolution rate of carbon from the coal into an iron bath.Reduction rates of mixtures of magnetite and devolatilised coal were assessed isothermally, using samples of 55 grams. The off-gas analysis was used to follow the extent of reduction. Results are shown in Figure 1 a). Coal B was expected to be more reactive, based on its higher content of reactive macerals (77%, compared with 61% for Coal A). In line with this, Figure 1 a) does show a higher reduction rate with this coal. However, increasing the reduction temperature increases the reduction rate substantially,especially for the less-reactive Coal A.For the dissolution experiments, samples (mass: 250 g) were melted in an alumina crucible (under a nitrogen atmosphere), to give a starting composition around 1%C. When the desired temperature was reached, 25 g of char was added on top of the melt, through a feeding port. Results are shown in Figure 1 b). The more-reactive Coal B was less crystalline (the graphite crystallite size estimated from X-ray diffraction was 4.6Å, compared with 11.4Å for Coal A). This is associated with a lower dissolution rate in iron."

Jan 1, 2003

By L. Gao, X. Gui

Fine coal obtained from Kailuan mine served as the processing object of this study. This material was difficult to separate. A flotation rate experiment was designed to investigate the process distribution characteristics of size and density during fine coal flotation. Size and density analyses of five clean were studied. The mineral morphology of flotation rate experiment cleaning was observed through scanning electron microscopy. The fractions -0.074+0.045 mm and -0.045 mm exhibited the best practical floatability and presented the highest combustible body recovery rates, but the selectivity and natural floatability of these two fractions were the worst. The - 0.074 mm fraction has contaminated the clean coal from the early stage of flotation, and the cumulative clean coal ash of -0.074 mm reached up to 17.20%. The low and middle-density classes displayed varying flotation behavior, but the flotation yield difference was only nearly 3%. The middle-density class caused the clean coal to have high ash content. The poor selectivity of fine coals, middle-density fraction, and fine mud resulted in high-ash clean coals during flotation. Thus, improving the selectivity of fine coal, restraining the flotation of fine mud, and grinding the coal to decrease the middle density mass fraction to liberate clean coals can yield high-quality clean coals through flotation.

Jan 1, 2014

By Zhang Zhonghan

A domestic tungsten-tin ore presents very complex property. How to effectively recover the scheelite, wolframite and cassiterite in the ore has long been a difficult problem to be solved urgently. On the basis of process mineralogy study, a main flow-sheet for effective recovery of tungsten-tin minerals has been developed, which including ?fine grinding of feed?bulk flotation of all sulfides followed by their selective separation?iron recovery by LIMS?tungsten-tin minerals bulk flotation using new technique developed by our institute?tungsten-tin recovery by gravity from above tungsten-tin bulk flotation tailings?. As for the treatment of tungsten-tin bulk rougher concentrate, several flow-sheets of tungsten-tin separation by direct hydrometallurgy or a flow-sheet consisting of scheelite cleaning at elevated temperature followed by the gravity separation of scheelite cleaner tailing?separation of wolframite from cassiterite by dry HIMS or by direct hydrometallurgy are developed. For a low grade head ore, all valuable sulfide, magnetite, scheelite, wolframite and cassiterite are recovered with satisfactory in lab scale test. Keywords: micro-fine cassiterite, tungsten-tin bulk flotation, gravity separation-flotation-dry HIMS combined flow-sheet, hydrometallurgy

Sep 1, 2012

By B. Tora

The new method of evaluation of grindability of hard coal and its blend is shown. Standard Hardgrove test is used as a base to work out this method. The essence of this method consists of simulation of milling process in close circuit (mill-classifier) and determination of energy consumption and quantity of product under the constant feed flow. The research equipment designed specially for this project is described New method of grindability measuring completes standard Hardgrove method withdrawing its faults: ? bigger (c.a. 10 times) and more representative sample is used; ? the milling process is carried out in close circuit (similarly to the industrial condition); ? energy consumption of the milling process is determined for three samples, which differs in grain size. The new method of evaluation of grindability of hard coal and its blend is shown. Standard Hardgrove test is used as a base to work out this method. This method allows us to determine energy consumption of the milling process. The essence of this method consist of simulation of milling process in close circuit (mill-classifier) and determination of energy consumption and quantity of product under the constant feed flow. Our results will complete the Hardgrove method and will help us to better characterise coal. At the same time investigations in industrial scale are carried out. These investigations will verify this new method. Also a new mathematical model of the milling process is being elaborated. It will be used to predict behaviour of coals in industrial conditions.

Jan 1, 2014

By Wantae Kim, Hoon Lee, Kwanho Kim, Sangbae Kim

Mechanochemical activation of starting minerals and their effect on the solid-phase synthesis and properties of ceramics with lower thermal expansion coefficient was examined. The mineral mixture, pyrophyllite-gibbsite-lithium carbonate, was prepared for the synthesis of ?-eucryptite (Li2O•Al2O3•2SiO2). Dry grinding using a planetary ball mill promoted the amorphization of the starting mixtures. XRD and FT-IR results showed that the crystallization of the target materials occurred from the ground mixtures by calcination. The crystallization of them increased with increment of grinding time and calcination temperature. In the synthesis, the trace of undesired phases such as quartz and cristobalite once formed during calcination at the temperature range from 750 to 850 °C almost disappeared and monophase ?-eucryptite was formed in the ground mixture at 950 °C. The lowest liner thermal expansion coefficient (TEC) of ?-eucryptite prepared was -2.5x10-6•°C-1. The thermal expansion behavior characteristics of the calcined

Jan 1, 2014

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

"An estimated 600,000 tons of bentonite clay are used annually in the U. S. as binder for production of iron ore concentrate pellets. Since this is a significant cost item for the plants, and the addition of bentonite to the pellets contributes undesirable silica into the finished pellets, there is considerable incentive for finding methods to reduce bentonite use. One way to reduce bentonite levels is to selectively use those bentonites that are most effective in this application, so that a lower dosage will still produce a sufficiently strong pellet. Unfortunately, there are no satisfactory methods available for accurately predicting which bentonites are actually most effective, short of using them to actually make pellets. One of the popular methods for attempting to evaluate bentonites is the “Plate Water Absorption” (PWA) test. While some plant operators accept the PWA results as indicating the relative quality of bentonites, others disagree and claim that, over a fairly broad range of values, PWA does not correlate with bentonite performance.Since both Ca+2 and Mg+2 ions are known to reduce the swelling and water absorption capacity of bentonite, it was believed that the presence of these ions in plant recycle water could be changing the bentonite performance. Since the standard PWA test uses only distilled water for its measurements, it could not detect these effects. Experiments were therefore carried out on a number of different bentonites using a modified PWA tests, with plant recycle water replacing the distilled water. These experiments showed little effect of the plant water on the PWA value, and chemical analysis of the water showed that the levels of dissolved salts were quite low.Water and accompanying salts were then extracted from a magnetite concentrate filter cake by rinsing with distilled water. Analysis of this water showed an extremely high level of dissolved salts, particularly salts of calcium and magnesium. When concentrations were compared with the recycle water from the plant filters, it was determined that levels of Ca+2 and Mg+2 retained in the filter cake were over 500 times higher than levels in the recycle water. This extreme elevation of soluble salts in the filter cake is believed to be due to adsorption of these ions into the electrical double layer of the magnetite particles."

Jan 1, 2003

By In-Kuk Bae, Kwang-suk You, Joobeom Seo, Kwanghyun Bea, Hyung-Seok Kim

Arsenic in base metal sulfide ores is highly penalized owing to high costs for its control in metallurgical processing. The arsenic element in the lead-zinc ore, which is target ore in this study, has been shown to be in the form of arsenopyrite. Experimental work in this study is about arsenic rejection flotation, using depressant suitable for the removal of arsenopyrite from the Pb concentrate. The arsenic rejection flotation also included the oxidation treatment of Pb concentrate with H2O2. In this study, the Pb concentrates containing 80.7% Pb and 0.25% as was obtained with the additions of aluminosulfate as arsenic depressant. And through IR measurement, it was also known that the addition of aluminosulfate during arsenic rejection flotation formed calcium aluminosulfate hydrates on the surface of arsenopyrite particle, resulting in rendering arsenopyrite hydrophilic.

Jan 1, 2014

By A. V. Kurkov

The secondary action reagents (SAR) are organic diphilic compounds capable of altering ac-id-base and donor-acceptor properties of the main collector and consequently the energy of collector interaction with the mineral?s surface, its hardness and fixation forms ratio through associates formation via the hydrogen bonds. When the basic flotation conditions are being established, convergence of the electronic structure of the collector and the mineral being extracted due to minerals surface preconditioning with modifiers and the most efficient collector choice. At the next stage of the selective flotation condition establishment SAR is selected for a more precise adjustment of the energy of the collector fixation on the mineral. Such an approach makes it possible to solve efficiently various issues of flotation separation of non-sulfide minerals. In particular neutral organic substances containing groupings C==O, S==O, P==O (ethers of carboxylic and phosphonic acids, amides of carboxylic, phosphonic and sulfonic acids) were proposed as SAR. In order to enhance the flotation process selectivity in the conditions of water recycling including the selectivity of carboxylic collectors especially in the environment of high hardness water flotation, it was proposed to use SAR with long hydrocarbonic radical and groups with enhanced electronic density within the molecule: N-methylolamides of alkylphosphoric acids and ethers of methylphosphonic acid. Introduction of small amounts of these compounds alongside with the main fatty-acid collector enhance the performance of fatty-acid flotation of fluorite, beryl, columbite etc., lowers the collector consumption, and completely compensates the depressive effect of recycled water. Di-2-ethylhexyl ether of methylphosphonic acid?CH3P(O)(OC8H17-i)2 (hexarane) was more thoroughly researched as such an agent within fatty-acid flotation process. Following aspects of the flotation system were studied: interaction of oleic acid and sodium oleate with hexarane in the liquid phase (infrared spectroscopy); heat emission under the interaction of hexarane-oleic acid ? sodium oleate ? calcium salts (isoperiboric diathermic colorimeter); colloid-disperse state of the collector influenced by hexarane (nephelometric analysis); dynamics of the mineral surface hydration due to the agents (method of indicator negative adsorption); hexarane effect upon the interaction of fat-ty-acid collector with calcium salts (complexometric method with Trilon-B); floatability of pure minerals (quartz, microcline, beryl, columbite) in Hallimond tube; hexarane effect upon oleic acid (sodium oleate) adsorption (nephelometric method for identification of the residual content of oleic acid and its forms within the solution). Upon the research it can be definitely concluded that the adjusting effect of such compounds as hexarane within the non-sulfide minerals flotation process is mainly determined by their interaction with the main collector both within the pulp and at the mineral surface with associates formation due to the hydrogen bond. The consequence is calcium oleates destruction with the release of the most active collector under flotation in hard water environment which determines the efficiency of hexarane joint application with fatty-acid collector under recycled water supply. Therefore the introduction of the class of secondary action reagents is supported by their operation mechanisms and flotation process function and determines a new approach to the development of efficient conditions of selective flotation separation of non-sulfide minerals.

Jan 1, 2014