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By C. Carrasco

"Over the last 30 years the average grade of mined ore bodies has significantly decreased while the proportion of waste removal has in many cases more than doubled. This has been identified as prime reason of a major increase in energy consumption and decrease in productivity across mining operation. Metal coarse preconcentration of ROM feed grades by size rejects low grade gangue/waste material in the size range of 10-100 mm prior to grinding, typically before primary crushing. This relies on propensity of metal to preferentially deport in the fine size fractions after breakage. Metal preconcentration by size has the potential to increase energy efficiency and therefore improve mining productivity on unit of metal basis. Results of an extensive belt cut sampling campaign conducted at a major Australian Au-Cu mine operation show that for some samples between 90% of Au and 80% of Cu is in 40% of the mass at -50 mm fraction. This indicates that low grade coarse material can be removed from the circuit, doubling feed grade at half of the tonnage and therefore improve energy efficiency per unit metal produced. This response, however presents significant variability in the same order as other processing attributes such as impact hardness and flotation recovery. This has led to development of geometallurgical laboratory tests using blast hole chips and drill core facilitating mapping and population of coarse metal preconcentration signatures in long term resources and short term production models. Preferential Cu deportment by size at drilling scale can be recognised, however scales up factors are required to transform laboratory results to production responses. At 50 % of mass the drilling products underestimate the belt cut responses by 20-30 %. Bulk sampling campaign with blast hole and drill core samples spatially related was also conducted to investigate in more detail the difference between production scale and drilling scale preconcentration responses."

Jan 1, 2014

By E. Emelyanenko, P. Solozhenkin, J. Yagudina, O. Ibragimova

"To recover tetrahedrite-tennantite series minerals from porphyry copper-pyrite ores by the froth flotation method, further research on thiol collectors is launched to promote the utilization efficiency of copper ores. In the present paper the adsorption mechanism of the collectors on tennantite surface has been investigated by computational modeling and FTIR-spectroscopic analysis, which have revealed that the decrease in prognosis of collector activity evaluation (PCAE) for tennantite is in the following order: BX (-0.34318), AEROPHINE 3418A (- 0.61756), AERO 5100 (-14.18857). The lower PCAE the stronger the ability of the collector to interact with the mineral surface of tennantite and form the stable complex. More kinetic reliable conditions to form suitable adsorption layer and rupture of the liquid interlayer with AERO 5100 have been observed by FTIR spectra due to decrease of the intensity and stretching and bending vibrations of water (less than 20 and 65%, respectively). In order to verify the feasibility of AERO 5100 as a collector the industrial flotation tests have been conducted. Flotation performance has improved significantly with the stadially grinding and preflotation of tennantite in intercycle copper flotation that allows to avoid desliming of the fragile mineral and minimize loss of Cu and As in tailings. The recovery of copper in copper concentrate increases by 3.9% with the grade maintained.INTRODUCTIONCopper is one of the first metals extracted and the main material of choice for different high-technology applications today. Currently 80% of the world's copper comes from copper sulfide ores. However, due to the depletion of high-grade copper ores in the world and constantly growing demand for copper, the need to develop processes and technologies to treat copper resources from additional sources such as mine tailings, low grade deposits, industrial wastes and deposits with high impurity levels such as As and Sb will continue to increase (Miller and Craig, 1983). The beneficiation processes of copper-pyrite ores consisting of tennantite-tetrahedrite series minerals are generally complex. Tetrahedrite-tennantite minerals occur as fine anhedral grains intermixed with grains of galena, sphalerite, chalcopyrite, pyrite and other sulfides (Saharova, 1966). The mineralized zones of Southern Urals, Russia deposits correspond with these ore types but tennantite-tetrahedrite series are more abundant in ores at the Uzelginskoye deposit, some samples of which contain 70% of copper in tennantite form (Seravkin et al., 1994). This deposit differs from other similar copper-pyrite ores by thin mutual ""germinating"" minerals and higher content of arsenic (up to 0.8-1 %) which create additional considerable problems in enrichment (Solozhenkin et al., 2016)."

Jan 1, 2018

By T. C. Sun

Two wasted activated sludges (WAS), from an industrial wastewater treatment and a sewage treatment plant respectively, and 7 collectors are used to investigate the feasibility of air flotation thickening of WAS by adding the collectors used in mineral processing. The collectors experimented include straight chain fat acids with different chain length, sodium oleate, alkyl sodium sulphonate, sodium dedecylsulfonate, and dodecylamine. The results show that the thickening efficiency varied depending on different collectors. Of the collectors experimented, dodecanoic acid and dodecylamine are best collector for thickening both sludges.

Jan 1, 2014

By J. Yianatos, C. Matamoros, F. Díaz

The non-selective entrainment of fine solids in flotation equipment has a detrimental effect on the concentrate grade. Reduction of solids entrainment (upgrading) is typically related with a loss in recovery of valuable minerals. For improving the froth transport characteristics and flotation cells design, a better understanding and quantification of the actual solids drainage and entrainment processes are required. In this work, the study of solids transport in the froth of a two-dimensional flotation cell was performed. The prototype cell represents a radial section of an industrial flotation cell (130m3) and was operated at steady state. Experimental tests consisted of adding a small amount of radioactive solid tracer (0.3g) near the top-of-froth or near the bottom of froth (close to the interface). The solid was selected as a non-floatable mineral (gangue) in order to evaluate both the solid entrainment into the concentrate as well as the solid drainage into the collection zone. Solid tracer consisted of fine or coarse gangue particles, P80 of 35 and 120 µm, respectively. Twelve collimated sensors located along the froth and collection zones allowed the evaluation of the solid transport in the froth, and the solid drainage from the froth to the collection zone, after tracer addition at different distances from the discharge lip. Results showed that longer distances to the froth discharge lip, as well as higher particle sizes, promotes higher solid drainage from the froth to the pulp zone, while decreasing the solids entrainment into the concentrate. The same result was observed for the solid located near the top-of-froth as well as near the bottom of froth. This information was complemented by the froth surface velocity measurements, using the Visiofroth system, showing a good agreement between the froth bubbles velocity and the solid transport velocity, measured near the discharge lip.

Jan 1, 2018

By Alejandro Uribe-Salas, Fabiola Nava-Alonso, Gloria Dávila-Pulido

This paper presents results of an experimental study performed on the role of calcium sulfate present in flotation water on sphalerite flotation in the Pb/Cu circuit (non Cu-activated sphalerite) and in the Zn circuit (Cu-activated sphalerite). In the Pb/Cu circuit calcium ions adsorb on the negatively-charged sphalerite favoring xanthate adsorption and therefore making sphalerite floatable; experimental measurements show sphalerite contact angle increases with calcium concentration while xanthate adsorption onto sphalerite increases with the increase of pH and calcium concentration. Gypsum (CaSO4·2H2O) eventually present due to calcium sulfate precipitation is not detrimental to flotation at this stage since it is negatively charged at pH 9 and therefore, does not adhere onto the surface of negatively-charged sphalerite. In the zinc circuit, Cu-activated sphalerite decreases its negative charge (or even becomes positively charged) and develops some hydrophobicity due to the polysulfide produced by Cu-activation. At this stage calcium ions do not interact with the mineral surface and therefore do not favor xanthate adsorption; nevertheless, precipitated gypsum particles do adhere onto the mineral surface, greatly affecting its floatability (e.g., contact angle). Addition of sodium carbonate to dissolve gypsum and to precipitate calcium as calcium carbonate, which disperses in the bulk of the suspension, effectively restores mineral hydrophobicity. SEM observations coupled with EDS analysis clearly illustrate and support the above sequence of events.

Jan 1, 2014

By József Faitli, Barnabás Csoke, Károly Solymár, Zoltán Hatvani, Dimitri Papanastassiou

"Grinding has a significant economic impact on ore dressing/processing, therefore the sizing of mills has an outstanding role.In most cases, the sizing of dry or wet mills for ore processing is primarily based on the determination of the Bond grindability index, using the Bond-Kjos-Rowland relations. In several cases, grinding takes place under conditions different from these and the grinding conditions have a great influence on the post-grinding process. This is particularly true for the grinding of bauxites where grinding takes place in alkali, often in higher temperature (up to 100 ºC) in alkali Liquor. So it is necessary to develop a testing method providing a reliable grindability index even under these special circumstances (grinding in alkalis medium at different temperatures) and allowing a more precise mill sizing. The new heated mill is suitable to determine the grindability index under temperature-controlled circumstances, in liquids with different temperatures (water, alkali). This paper presents in detail the equipment, the conditions (parameters) of the testing process for wet and alkaline grinding, the measuring results and the conclusions."

Jan 1, 2003

By Ingvar Ymén, Anders Sandc, Jan Rosenkranzc, Lisa Malma, Ann-Sofi Kindstedt Danielssonb

The understanding of particle surface properties is essential for the study and evaluation of froth flotation phenomena, particularly in the investigation of various chemical or reagent effects. Dynamic Vapor Sorption (DVS) is a method used for the analysis of surface properties of powders for instance in the pharmaceutical industry. To the knowledge of the authors, it has however not been used before in applications related to mineral processing. The DVS technique involves measurement of the water uptake of a relatively small amount of sample as a function of the relative humidity (% RH) in a temperature-controlled environment. The purpose of this work was to evaluate the method and investigate how it can complement existing techniques for surface characterization in mineral processing. Four samples (feed, CuPb concentrate, Cu concentrate and Pb concentrate) from the Cu – Pb flotation process in the Garpenberg concentrator, Sweden, were analyzed by DVS and the traditional capillary absorption technique (Washburn capillary rise). This enabled comparison between the two methods and evaluation of their respective advantages and disadvantages. Both methods give the expected ranking of the hydrophobicity for CuPb concentrate, Cu concentrate and Pb concentrate, but a discrepancy was observed for the feed. Washburn gave a value for the contact angle which was in the same range as for the CuPb concentrate, whereas DVS gave a value for the moisture uptake which was much higher than for the CuPb concentrate. Thus, DVS ranks all samples correctly, but with an unexpectedly high value for the feed whereas Washburn gives good ranking for three samples out of four. Potential reasons for the discrepancies are discussed.

Jan 1, 2018

By Alexey P. Tatarinov

Under modern economic conditions in Russia, gold heap leaching is the most effective way of investing into gold-mining industry. Gold is recoverable from small-size deposits, low-grade ores from oxidation zone, cut-off grades, and overburden rocks using heap leaching. This technology is cost-effective and allows a saleable metal to be obtained within the first year of operation. The investments for heap leaching are lower than those of for a traditional plant technology. Production cost per one gram of Au is 5-7 times lower than that of during a plant flow sheet. A seasonal development of mines can be possible. With reference to this, heap leaching resembles the technology of placer deposits development. One of the major advantages of heap leaching is the form of the product. Gold can be obtained as dissolved in a clarified PLS, which allows the further quick treatment. The amenability of ores to heap leaching depends on their mineralogical composition. Oxidized porous ores with a good access of a lixiviant to valuable particles can be treated without pre-crushing. Clayish minerals are often found in oxidized ores with free gold. In order to build ground for heap, several major methods combined with various pad materials are used. These methods have been used at many plants and are reliable. The development of heap leaching technology for gold ores for the deposits from Yakutia, Zabaikalsky region, Primorye region, Uzbekistan, Tadjikistan, and Kazakhstan began in the 70s. However, it has been commercially used only since 1990. The first heap leach plants were built and commissioned in the USSR in 1991 at Vassilkovsloye deposit (Kazakhstan) and at Maiskoye deposit in Russia in 1994. Pilot plant testing was conducted in 1996 using ores from Kuranakh ore field, deposits Phiskulturnaya-Kholodnaya and Lopukhovskoye from the Aldan region. After the first successful commissioning of heap leaching plant in Russia, this technology has been commercially applied for deposits. Every year 1-2 heap-leaching plants were commissioned. More than 30 heap-leaching plants have been commissioned both in Russia and in the former Soviet Union using technologies developed by IRGIREDMET. Keywords: cyanide leaching, heap leaching, ore, percolation, solutions, lime technology

Sep 1, 2012

By O. A. Bascur

"In recent years, metal producing companies have increased their investment in automation and technological innovation, embracing new opportunities to enable transformational change. Internet of Things (IoT) is one of many transformational initiatives, which can fundamentally revolutionize how industrial complexes operate. Whatever the issue, the answer is in the abundant and growing quantity of real time data and events collected in the grinding and flotation circuits in a mineral processing plant. Based on earlier work, today a grade recovery model permits identifying the best operating conditions in real time. We will review the strategy for increasing the value of the abundance instrumentation in current plants. An optimal Gaudin size distribution model provides augmented information from traditional sensors to find the optimal grind cut to reduce metal losses in the flotation circuits. The large amount of sensors in a flotation circuits permits to estimate the recovery and to find the optimal froth depth and aeration using an air holdup flotation model. The paper will describe the strategy of classifying data for on line generation of insights to using operational intelligence tools. We will discuss the implementation Recovery/Grind strategy with industrial examples in non-ferrous mineral processing and iron beneficiation.INTRODUCTIONThe declining supplies of high grade ores and increasing consumption of mineral and metal products have demanded higher operational efficiencies with minimum capital investments. The objective of copper flotation objectives are based on maximizing the dollars return on the concentrate produced. The economic efficiency is maximized by manipulating the circuit along the grade/recovery curve relationship. To achieve such objective improved stabilization of the grinding and flotation circuits are required (Oosthuizen, Craig, and Jamsa-Jounela, 2017)."

Jan 1, 2018

By P. T. Nguyen

The analysis of particle capture by an air bubble by two separate phenomena of collision and attachment has been difficult due to the uncertainty in determining when and where the two phenomena begin and terminate at the bubble surface, respectively. Therefore, a unified analysis was developed by solving the motion equation for the particle capture as one process. No distinction be-tween collision and attachment was made. Both the liquid film described by the micro-hydrodynamic resistance functions and the surface forces were included in the new model. The model predictions with the DLVO (Derjaguin-Landau-Verwey-Overbeek) surface forces did not agree with the experimental trajectories of latex and silica spheres. The model predictions with the inclusion of the non-DLVO attractive surface force agreed with the experimental data. The non-DLVO force reduced the repulsion between the non-attaching particle and the bubble, and significantly increased the attraction between the attaching particle and the bubble. The unified analysis is capable of predicting particle capture without the use of the induction time. The unified analysis also shows significant influence of the short-range hydrodynamic interactions on the collision which has been previously ignored.

Jan 1, 2014

By S. J. Neethling

"This paper examines the impact of several key variables on the performance of flotation cells. The study makes use of a simulator for the froth phase of the flotation vessel, as the main purpose of this study is to separate the impact of different variables from one another. In experiments it is very difficult to separate the effect of variables from one another as a change in a singe input parameter, such as air rate, invariably also affects many of the other key variables, such as bubble size and bubble bursting rates.In order to achieve this a base case simulation that is typical of many of the rougher cells found in sulphide flotation circuits was carried out. Four key variables, air rate, incoming bubble size, surface bubble size and the fraction of the bubbles flowing out of the cell unburst, were varied in order to obtain the system.s response.The most significant results were obtained when the bubble size was varied. An increase in the incoming bubble size has the effect of reducing the pulp zone recovery, but increases the froth zone recovery. If it were possible to vary the incoming bubble size without influencing the overflowing bubble size, the impact of the change would be unclear because of these two competing effects. The effect of a change in the overflowing bubble size has an opposite effect on the froth recovery, with larger bubbles resulting in lower froth recoveries.A final interesting result is that all the effects examined affect the process to a similar degree, which implies that none of these variables can be disregarded, either in industry or in further research."

Jan 1, 2003

By M. Roy

Coke combustion during sintering process is significantly governed by coke breeze size distribution, which in turn affect sinter quality i.e. sinter granulometry, Tumbler index, Reduction Degradation Index and Reducibility Index of sinter. To know the effect of microfines of coke breeze on sintering process parameters, pot sintering tests were conducted and it was found that when microfines are eliminated and optimum coke size (1-3mm) is used yield of sinter increased by more than 7%. Similarly productivity increased by 9%, the strength of sinter i.e. ISO Tumbler Index increased by 2.3% and +10mm sinter size increased by 5.5%. Controlling of microfines during crushing and by improving crushing index will result in improved quality and productivity of sinter with lesser amount of coke breeze. This paper describes that how to optimize solid fuel i.e. coke breeze consumption in sintering process through granulometry control. Keywords: iron ore sintering, coke breeze granulometry, productivity of sinter, quality of sinter

Sep 1, 2012

By Vinay Jain, Dharmendr Kumar, Beena Rai, Venugopal Tammishetti

"Selective dispersion-flocculation is considered to be an effective process for the beneficiation of ultrafine particles. This process is based on the preferential adsorption of a flocculant on the mineral particles to be flocculated, leaving rest of the mineral suspended. It has been successfully implemented at plant scales for the beneficiation of ultrafine particles of iron ores, for which conventional methods such as gravity separation, magnetic separation and flotation do not work efficiently. However, the key element responsible for the success of any selective flocculation process is the appropriate choice of the flocculant used for achieving the desired selectivity. At our lab, we are working on design and development of such selective reagents for mineral processing applications, including the beneficiation of iron ore slimes, using a combined molecular modeling and experimental approach. In this study we have employed density functional theory (DFT) to calculate the interaction energies and explain the interaction mechanisms of chitosan with the main minerals present in iron ore slimes, namely, hematite [a-Fe2O3], goethite [a-FeO(OH)], gibbsite [a-Al(OH)3] and kaolinite [Al2Si2O5(OH)4]. The magnitudes of the computed interaction energies follow the trend: Hematite > Goethite > Gibbsite ~ Kaolinite Al-OH terminated > Kaolinite Si-O terminated Analysis of the optimized geometries and electronic structures reveals that the O & N atoms of chitosan molecule form coordinate bonds with surface Fe-atoms of hematite while only weak hydrogen bonds are formed in the case of goethite, gibbsite and kaolinite surfaces thus explaining reasons behind the stronger interactions with the hematite surface. The theoretical findings were validated by performing selective flocculation experiments using chitosan as a flocculant. The selective flocculation experimental results show that a final concentrate of ~60% Fe can be obtained from a feed containing 53.13% Fe with Fe recovery of 74%. The mineral estimation in the obtained concentrate indicated that hematite and goethite are recovered in concentrate while gibbsite and kaolinite are rejected in the tails. These observations were consistent with our theoretical findings. Our work highlights the promising role molecular modeling techniques such as DFT can play in the design and development of selective reagents for beneficiation of alumina-rich iron ore slimes."

Jan 1, 2018

By M. P. Krasteva

The froth flotation process for separation of mineral ores depends on the establishment of care-fully controlled froth. The formation of very stable froth in the flotation circuit is a problem that may occur in many plants, resulting in down-time, low quality and grade of final product and considerable expenses. Froths build up on the top surfaces of thickeners, tanks and flotation cells until they overflow, or until the efficiency of the circuit is impaired. A similar problem exists in Assarel concentrator, Assarel-Medet PLC, Bulgaria. Copper and copper-pyrite ores are dressed in Assarel concentrator. They are characterized with variable and complex mineral and physical composition. During the flotation cycle, resilient and difficult to break-down froth is formed, which subsequently impedes the process of thickening and clear overflow obtaining. Due to this problem continuous sampling in the cycle of thickening was conducted. The mineralogical, chemical composition, particle size distribution and solid phase content of the products were determined. It was established that the solid phase of the froth build up on the top surface of the thickener differs considerably from this one of the thickener underflow. The data clearly indicates that a separation process takes place on the top surface of the thickener ? fine particles of chalcopyrite are concentrated in the froth. The role of chemical reagent addition in the break-down of the flotation froth is investigated in terms of surface chemical phenomena involved in the stabilized froths. Measurements of the coper minerals wettability and surface tension at the air/liquid interface were performed. The surface active agent AERODRI® dewatering aids were laboratory tested. Bench-scale froth collapse tests were conducted. Reagent addition into pulp-froth system promotes and leads to a bubble coalescence, an improvement of the wetting of the mineral particles and a decrease of the surface tension at the air/liquid interface. The results of the laboratory experiments showed that the presence of the surface active agent leads to considerably decrease of the froth stability and the destruction of the deleterious froths build up on the top surface of the thickeners in Assarel concentrator.

Jan 1, 2014

By M. Pelser, C Aldrich

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.Several processes are reviewed for the control of calcium and magnesium. Of these, fluoride precipitation was selected for experimental investigation. This method involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments showed high selectivity for calcium and magnesium over the base metals. The experiments also showed magnesium precipitation to dominate for calcium to magnesium molar ratios greater than 1:3.To avoid the domination of magnesium precipitation, a flow sheet is proposed whereby only a portion of the base metal stream is subjected to fluoride precipitation. For the precipitation, a 10% excess of ammonium fluoride is used to remove the maximum amount of calcium and magnesium. After precipitation and solid-liquid separation the split-stream is returned to reduce the overall calcium and magnesium concentration of the base metal stream."

Jan 1, 2003

By M. Illikainen

Limestone is used for neutralization of acid leachates in a number of hydrometallurgical processes. The aim of this study was to clarify how limestone ground to different particle sizes can neutralize sulfuric acid. The laboratory scale ball mill was used in grinding experiments carried out using ball sizes of 20, 30 and 40 mm and volumetric slurry densities of 30, 40 and 50 percents. Varied grinding times were used in order to produce limestone samples with different particle size classes on which the neutralization potential and rate were determined. The results of the study showed that the neutralization potential of limestone is not dependent on its particle size between 5 and 120 µm. However, the particle size strongly affected the neutralization rate of sulfuric acid: The smaller the particle size, the higher the rate of neutralization. Thus, when optimizing the cost efficiency of the process, the optimal degree of grinding should be considered taking in account the required residence time in neutralization phase.

Sep 1, 2012

By Q. X. Li

The state discharge standard for arsenic-containing wastewater which is the first kind of pollution is less than 0.5 mg/L. In fact, in a certain company, the acidic arsenic-containing wastewater in non-ferrous smelting was as high as 860 mg/L, which is far beyond the state discharge standard. Obviously, the direct release of this wastewater without further treatment would result in great hazards to the ecological environment. To aim directly at the characteristics of acidic arsenic-containing wastewater, in this study, two steps of treatment including oxidation-flocculation and removal fluoride by mixing alkaline neutralization were suggested. Through analyzing various influencing factors in treatment effects, the optimum technical conditions were obtained. The sediments after treating were recyclable and the secondary pollutions can be avoided. Moreover, the results also show that, all indexes of the effluent after treating are lower than the First Grade Standard of Integrated Wastewater Discharge (GB 8978-1996). This novel method has advantages of short flow sheet, easy operation and low cost.

Jan 1, 2014

By K. Takahashi

Generally speaking, wastewater coming from the metallurgical process for recovering precious metal contains precious metals such as gold (Au), platinum (Pt), palladium (Pd), Silver (Ag), etc., which concentration is about 10 mg/L. In addition, there are other metals such as copper (Cu), iron (Fe), which concentration varies from several mg/L to more than 10,000 mg/L. It should be noted that the concentration of metals in wastewater is relatively high, considering the fact that these metals of similar concentration can be found in ores. However, most of these valuable metals are not treated, due to the high processing cost and technical problems. Within this frame, the authors put forward a new process that includes neutralization/reduction, precipitation and fusion. The idea is to recover and recycle Au, Ag, and Pd metals as well as protecting the environment by saving the resources. It was found that this new process was able to recover more than 90% of Au, Ag and Pd.

Jan 1, 2014

By Silvia França, Hudson Couto, Renata Barbosa

"The flotation process, largely used for mineral concentration processes, which is based on air bubble adhesion to the dispersed solid phase, is also being used for wastewater treatment purposes. Dissolved air flotation (DAF) is based on the separation of the solid-liquid phases with the aid of small air bubbles (10-100 µm), with high values of interfacial contact area, improving the process efficiency. In the process, the air bubbles and particles or flocs form aggregates, which rise to the surface of the flotation cell to be collected. The advantage of producing small bubbles is directly related to the fact that smaller bubbles result in greater bubble-particle interaction. Wastewater produced in alumina refinery - from the red mud filtration step - has a red colored aspect due to the presence of very fine particles of red mud and also dissolved matter that still remain in the filtrate. This wastewater might be treated, aiming to reuse the water in the refinery or discharge it properly in the environment. The aim of this study was to evaluate the DAF process efficiency for the treatment of red mud wastewater in order to decrease suspended particles and dissolved solids contents, in addition to mitigate the high causticity of this wastewater. The process efficiency was evaluated by comparing turbidity removal and total solids concentration in the treated wastewater to the feed. The influence of important variables of the DAF process as type and concentration of coagulant and flocculant were evaluated. It was possible to obtain good turbidity removal efficiencies (up to 90%) using low concentrations of coagulant (50 mg/L) and flocculant (0.5 -1.0 mg/L). In addition, for most of the experiments, the specification for effluent diposal, according to the Brazilian environmental regulation 430 (Conama, 2011): pH range 5 to 9 and turbidity < 40 NTU, was attained. These results emphasize the possibility of using the DAF as an alternative technique to settling and filtration process, that are traditionally used, for treating wastewater from the alumina industry, allowing the reuse of water in the plant or adequate discharge with less environmental impact."

Jan 1, 2014

By A. E. Sobolev

The kinetics of hydrochemical oxidation of antimonite in solutions of nitric acid was studied using the rotating disk method and the factor experiment design. The dependences of the antimonite?s oxidation rate on concentration of nitric acid solutions, temperature, disk rotation frequency, and duration of interaction were determined. The adequate kinetic models allowing calculating the specific oxidation rate at any combination of the values of the influencing factors were obtained. The oxidation process is found to proceed in a mixed mode, close to chemically controlled. Gradually, as the sediments of elemental sulphur and Sb2O5 accumulate on the disk surface, the process becomes controlled by internal diffusion. The observed high (more than second) order of the oxidation rate with respect to the concentration of nitric acid was explained by the autocatalytic action of the acid reduction products. The apparent activation energy depends on the stage of interaction. At the initial stage (in a mixed mode of the process proceeding), it depends on nitric acid concentration and varies from 31.5 kJ?mol?1 (in 2 M HNO3) to 36.1 kJ?mol?1 (in 10 M HNO3). This trend indicates the weakening of diffusion limitations with a nitric acid concentration increase. When the process is controlled by internal diffusion, the apparent activation energy was found to be 14.5 kJ?mol?1. The obtained kinetic characteristics enlarge the database on hydrochemical oxidation kinetics of sulphides and can be used for the elaboration of the recommendations for the effective comprehensive exploitation of antimony-bearing ores and concentrates.

Jan 1, 2014