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By A. Demirag, F. Burat

"The most important metals in the jewelry sector are undoubtedly gold and silver. As a result of workmanship work done in the jewelry industry, the tiny metal and jewel fragments and metallic powders are scattered. Given the prices of gold and silver on the market, the dust that emanates from these workshops is of great importance. Gold recycling has become as important as raw material production within the mass market and gold production industry. In 2016, 29% of the world gold supply has been obtained through recycled gold production. Waste derived from jewelry activity is included in this category, and represents an essential component of this percentage. In the scope of this study, the recovery possibilities of Au and Ag from jewelry sweeps floor sample was investigated using flotation method. In the experiments, optimum pH value, particle size, the effect of dispersant, type and amount of reagent were investigated. As a result of these studies, it was determined that the optimum pH value was 6.5 and the particle size was -212 microns. It was observed that the most suitable reactive combination was Aero 242 and Aerophine 3418A and Na2SiO3 has no positive effect on recovery of Au and Ag as a dispersant agent. As a result of tests, a final concentrate containing 268 ppm Au and 2122 ppm Ag was obtained with 81.4% and 74.5% recovery respectively. INTRODUCTION Because of the softness of pure gold, it is usually alloyed with base metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. On the other hand, gold has some special chemical properties which in normal conditions, don’t react with water, dry or humid air, oxygen, ozone, nitrogen, hydrogen, fluorine, iodine, sulfur and hydrogen. In these days, gold is used in different sectors like jewelry, electronics, finances and investing, dentistry, medicine, aerospace, awards & status symbols. According to Deutsche Bank Research, the primary usage of gold is jewelry. It has been used to make ornament and jewelry for thousands of years. In this sector craftsmen learned that alloying gold with other metals like copper, platinum and silver to increase gold’s durability. Alloying gold with other metals changes the color of the products. Another significant sector of gold is electronics. Modern electronics want the use of noble metals, like gold, especially in the areas of information processing, telecommunications, and military and space electronics (Habashi, 1997). Electronic devices use very low voltages and currents which are easily interrupted by corrosion or tarnish at the contact points. Gold is the highly efficient conductor that can carry these tiny currents and remain free of corrosion. Electronic components made with gold are highly reliable. Gold is used in connectors, switch and relay contacts, soldered joints and connecting wires. Every sophisticated electronic device have a considerable amount of gold. This includes cell phones, calculators, personal digital assistants, GPS units, and other small electronic devices. Most large electronic appliances such as television sets also contain gold. Humankind has known silver since prehistoric times like gold because silver occurs in native form. The metal is found in the Earth's crust in the pure, free elemental form native, as an alloy with gold and other metals, and in mineral such as argentite. Most silver is produced as a byproduct of copper, gold, lead, and zinc refining. Silver is very soft metal like gold also, it is the highest electrical conductivity, thermal conductivity, and the lowest electrical contact resistance of all metals (Habashi, 1997). Silver is used in different sectors like industry, jewelry, electronics, photography silver good, and coins. The main usage of silver is supplied by electronics. Silver's unsurpassed thermal and electrical conductivity among metals means it cannot easily be replaced by cheaper materials. In addition to silver is using in ener"

Jan 1, 2018

By Robinson Irarrazabal, Edison Collinao, Rodrigo de Carvalho, Patricio Davila, Marcelo Tavares

"In recent years, DEM (discrete element method) softwares, along with 3D laser measuring equipment, have become powerful tools to describe mill charge behavior, as well as forces acting on the liners of SAG mills. With the aim of contributing to streamline this application of the advanced technologies ME Elecmetal and Universidade Federal do Rio de Janeiro, UFRJ, proposed a new approach to improve the design of mill liners using elements from mechanistic modeling of grinding. The paper presents a methodology for continuous improvement of liner design, which uses information from the DEM collision energy spectra in the mill discriminated for the different components (ore and steel balls), as well as information on the breakage properties of the ore being ground. From these it proposes the concept of "effective collisions", which corresponds to the collisions that are of sufficient magnitude to cause breakage, thus allowing to discriminate from impacts that do not cause breakage either in a first impact or after repeated loading. It also tracks the collision of steel balls against the shell in order to assess their potential damage to the liners. An industrial case study is presented of a 38’ diameter SAG mill, which was experiencing challenges associated to liner breakage and low efficiency with the old liner design. Through a modification of the liner design, simulations demonstrated the potential benefit associated to reduction in ultraprojection and improvement in mill capacity. Implementation of the new design in the SAG mill was carried out, resulting in increase in daily throughput from 6 to 12%. Further, the time spent in liner change was reduced by 47% given the reduction in the numbers of parts. This operation also benefited from having no stops due to unplanned shutdowns to replace broken tiles. These demonstrate the benefit of coupling advanced computational tools to sound engineering principles in continuous improvement of liners."

Jan 1, 2014

By M. P. Krasteva

The froth flotation process for separation of mineral ores depends on the establishment of care-fully controlled froth. The formation of very stable froth in the flotation circuit is a problem that may occur in many plants, resulting in down-time, low quality and grade of final product and considerable expenses. Froths build up on the top surfaces of thickeners, tanks and flotation cells until they overflow, or until the efficiency of the circuit is impaired. A similar problem exists in Assarel concentrator, Assarel-Medet PLC, Bulgaria. Copper and copper-pyrite ores are dressed in Assarel concentrator. They are characterized with variable and complex mineral and physical composition. During the flotation cycle, resilient and difficult to break-down froth is formed, which subsequently impedes the process of thickening and clear overflow obtaining. Due to this problem continuous sampling in the cycle of thickening was conducted. The mineralogical, chemical composition, particle size distribution and solid phase content of the products were determined. It was established that the solid phase of the froth build up on the top surface of the thickener differs considerably from this one of the thickener underflow. The data clearly indicates that a separation process takes place on the top surface of the thickener ? fine particles of chalcopyrite are concentrated in the froth. The role of chemical reagent addition in the break-down of the flotation froth is investigated in terms of surface chemical phenomena involved in the stabilized froths. Measurements of the coper minerals wettability and surface tension at the air/liquid interface were performed. The surface active agent AERODRI® dewatering aids were laboratory tested. Bench-scale froth collapse tests were conducted. Reagent addition into pulp-froth system promotes and leads to a bubble coalescence, an improvement of the wetting of the mineral particles and a decrease of the surface tension at the air/liquid interface. The results of the laboratory experiments showed that the presence of the surface active agent leads to considerably decrease of the froth stability and the destruction of the deleterious froths build up on the top surface of the thickeners in Assarel concentrator.

Jan 1, 2014

By L. Stamenov, H. Bouzahzah, S. Gaydardzhiev, D. Naumov

"The Chelopech epithermal arsenic bearing high-sulphidation, copper-gold deposit located in Bulgaria is often referred as the richest European gold deposit currently under exploitation. Key points from the flotation circuit of the processing plant have been sampled and selected physicochemical parameters measured. Plant survey has followed with selected samples being submitted to chemical and mineral liberation analysis (MLA). Quantitative analysis has enabled to link the flotation response of the main copper bearing minerals with the physiochemical parameters (Eh, DO, EDTA extractable Cu and Fe) being measured. Data from mineral liberation analysis have highlighted an important process-relevant information explaining the variable floatability in the various granulometric classes.The low chalcopyrite recovery could be linked to the non-sufficient amount of dissolved oxygen measured in the copper selective flotation circuit. Given the finely-disseminated copper bearing minerals, the observed copper losses inside the flotation could be also explained by the insufficient degree of liberation of the mineral grains. Suggestions for improvement in metallurgical recovery are therefore proposed.INTRODUCTIONThe Chelopech deposit is a high sulphidation (HS) volcanic-hosted epithermal gold-copper one (Bonev et al., 2002; Kouzmanov et al, 2009; Strashimirov, et al. 2002). It is considered as one of the largest and economically most important ore deposits in Bulgaria, and often is referred to Europe’s largest currently mined gold resource. It is located in the Srednogorie zone which falls within the central sector of the extensive Tethyan–Eurasian copper belt formed during Mesozoic–Cenozoic time along the southern margin of Eurasia. The Srednogorie zone has the features of a subduction-related, Late Cretaceous island arc, with development of a calk-alkaline to sub-alkaline volcano-plutonic magmatism and associated hydrothermal ore deposits (Bonev et al., 2002).Ore mineralisation occurs as veins, mineralised breccia, and massive sulphide replacements and disseminations. Three mineralisation stages have been identified at Chelopech deposit. An early pyrite–marcasite mineralisation (stage I), characterised by disseminated to massive pyrite followed and partly brecciated by enargite– luzonite and tennantite–chalcopyrite–bornite (stage II) mineralisation. The gold is met in ores belonging to the stage II. Sphalerite and galena veins characterise stage III, best developed below and adjacent to the pyrite–enargite– chalcopyrite ore bodies. Advanced argillic altered volcanoclastic rocks commonly host this mineralisation (Chambefort and R. Moritz, 2014)."

Jan 1, 2018

The flotation behavior of kaolinite and diaspore using N, N-diethyl dodecyl amine (DEN12) and N, N-dimethyl dodecyl amine (DRN12) as collector have been investigated through flotation experiments. The mechanism of adsorption of two tertiary amine collectors on surface of kaolinite and diaspore were investigated by FTIR spectral, Zeta potentials measurements and calculation of molecular orbital energy. It has been found that DEN12 and DRN12 have stronger collecting power to kaolinite and weaker collecting abilityto diaspore than DDA. Kaolinite and diaspore in bauxite ores can be separated by using DEN12 and DRN12 as collectors at pulp pH below 8 and 6, respectively. The results of zeta potentials and calculation of molecular orbital energy indicated that the adsorption strength on kaolinite surface is in the order DEN12>DRN12>DDA and the adsorption strength on diaspore surface is in the order DDA>DEN12>DRN12. FTIR spectral analysis and Zeta potentials approve that the action between kaolinite and tertiary amine collector is strong electrostatic adsorption and that of diaspore is weak electrostatic adsorption in the range of pH 5~6.

Jan 1, 2014

By A. O. Gapchich, T. N. Matveeva, N. K. Gromova

"Tin sulfide ores and aged man-made products obtained after their processing are distinguished by a complex material composition and uneven impregnation of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin ore (cassiterite). Enrichment of such ores is performed through sophisticated multistage schemes using not only gravitational methods, but also gravity flotation, flotation, magnetic separation techniques. Tin ores also contain rare and precious metals (indium, scandium, silver), characterized by fine dispersity and microscale to nanoscale fineness of mineral formations. During flotation concentration these metals are extracted along with the main ore minerals into concentrates (tin, copper, tungsten, etc.), however, up to 10-20 % of them are lost with final tailings. The aim of the work is an experimental study of the modification of the surface of sulfide minerals and cassiterite by stable metal-collector complexes to increase extraction of fine tin, silver, copper and other metals from complex tin ores. Triamide cyanuric acid (TCA) was studied as a thin silver flotation modifier. Thermophilic polymer with a functional group of phenylphosphine TMPPh was used as a selective flocculant. For experimental studies of the physical and chemical effects of collecting agents on the surface of minerals the following analytical techniques were used - the analytical scanning electron emission ASEM (LEO 1420VP INCA OXFORD ENERGY 350) and laser (KEYENCE VK-9700) microscopy, measurements of electrode potentials of mineral anthills by potentiometric titration, monomineral and pulp flotation. New data on formation of the adsorbed layer of DBDTC on the surface of chalcopyrite, galena and arsenopyrite were obtained, and the dimensions of the reagent films and the strength of their adsorption. The indiscriminateness of cassiterite to DBDTC ensures its selective separation into a chamber product during the flotation of sulfides. It is shown, that modification of the sulfide surface by stable complexes Me-DBDTC and Ag-TCA-TMPPh will increase the recovery of non-ferrous metals and silver into a collective sulfide concentrate and will provide a high-quality tin concentrate for flotation of tin sulfide ores.The studies were perfomed with the aid of the Russian Science Foundation (Project No. 17-17-01292).INTRODUCTIONTin sulfide ores and aged man-made products obtained after their processing are distinguished by a complex material composition and uneven impregnation of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin ore (cassiterite). Enrichment of such ores is performed through sophisticated multistage schemes using not only gravitational methods, but also gravity flotation, flotation, magnetic separation techniques. Tin ores also contain rare and precious metals (indium, scandium, silver), characterized by fine dispersity and microscale to nanoscale fineness of mineral formations. During flotation concentration these metals are extracted along with the main ore minerals into concentrates (tin, copper, tungsten, etc.), however, up to 10-20 % of them are lost with final tailings. In this regard, it seems advisable to use new varieties of flotation reagents in order to increase extraction of finely dispersed tin, silver, copper and other non-ferrous and precious metals from multi-metal tin ores (Bocharov and Ignatkina, 2007; Khanchuk etal., 2012; Wu and Zhu, 2006; Yusupov etal., 2016)."

Jan 1, 2018

By V. Vogt

During the phosphating of car bodies containing aluminium, the employed phosphating chemicals zinc, manganese and nickel are, for thermodynamic reasons, only used to a limited extent for the desired surface coating. The major proportion of these metals is discharged together with the incidental cryolite-containing phosphating sludges and the rinse water. Commissioned by the German Federal Ministry of Education and Research (BMBF), the Institute of Mineral and Waste Processing, Waste Disposal and Geomechanics at the Clausthal University of Technology has developed a two-stage process for the production-integrated recovery of the dragged out chemicals and for closing the rinse water cycle for Audi AG. During the first stage, the phosphating chemicals are recovered by means of leaching. In the second stage, the rinse water is treated by means of electroflotation followed by an ion exchanger.

Jan 1, 2014

By K. D. Mehta

Copper concentrate containing complex sulphides of Cu-Ni with 14.13% Cu and 10.04% Ni besides impurities such as 0.33% Co and 0.71% Mo, is not acceptable to the copper smelters due to the smelting problems. Selective bioleaching of nickel from the concentrate can be considered an an option to make it suitable for copper smelter. Effect of elemental sulphur and pyrite on the bioleaching of Ni and Co has been investigated using a mixed culture of Acidithiobacillus ferrooxidans (A.f.) and Acidithiobacillus thiooxidans (A.t.). Parameters such as pH, temperature, particles, size etc. were optimised to understand the role of additives in the bioleaching. With 2% S at 308K, 2.0 pH, 5% pulp density and 200µm size particles while shaking at 100 rpm, 79% Ni, 41% Co and 5% Cu were bioleached as compared to the leaching of 81% Ni and 45% Co in presence of 10 wt% pyrite in 60 days; 27% Ni, 24% Co and 4% Cu were recovered in sterile experiment. The selective dissolution of nickel and cobalt as compared to copper may be explained by galvanic interaction between chalcopyrite: pentlandite / pyrrhotite. Bioleaching was facilitated by strong oxidizing conditions due to higher Fe3+/Fe2+ ratio/redox potential (ESCE) as a result of improved interaction of minerals through biooxidation of sulphur and accelerated galvanic interaction by pyrite. The mechanism of selective leaching of Ni and Co was established by XRD phase identification.

Sep 1, 2012

By S. Groudev

Acid drainage waters generated in the uranium deposit Curilo, Bulgaria, were treated by means of a pilot-scale passive system consisting of a permeable reactive multibarrier and a constructed wetland connected in a series. The multibarrier had a total volume of 23 m3 and consisted of an alkalizing limestone drain and an anoxic section for microbial dissimilatory sulphate reduction, bio-sorption and additional chemical neutralization. The waters had a pH in the range of about 2.5 ~ 4.0 and contained radionuclides (uranium, radium), heavy metals (copper, zinc, cadmium, lead, nickel, cobalt, iron, manganese), arsenic and sulphates in concentrations usually much higher than the relevant permissible levels for waters intended for use in agriculture and/or industry. The water flow rate through the multibarrier varied in the range of about 1 ~ 17 m3/24 h, reflecting water residence times of about 300 ~ 18 hours. An efficient removal of pollutants was achieved by the multibarrier during different climatic seasons, even during cold winter days at external air and water temperatures close to 0oC. The multibarrier effluents were enriched in dissolved organic compounds and in some cases still contained manganese and iron in concentrations higher than the relevant permissible levels. These pollutants were removed in the constructed wetland as a result of the activity of different heterotrophic microorganisms, including some bacteria able to oxidize the bivalent manganese and iron ions to Mn4+ and Fe3+, respectively.

Jan 1, 2014

By Y. B. Zhu

Soil reconstruction and improvement trials and vegetation experiment is carried out at Shuilong-shan acid rock waste dumps at Dexing Copper Mine in China. pH value, Cu2+, Pb2+, Zn2+, etc. concentration in acid rock drainage (ARD) is also monitored every month since 2005. The results of experiment show that: Lime and topsoil stripped from open-pit is appropriated soil improvement material. Full cover soil improvement method is suitable for flat area, contour soil improvement method and hole soil improvement method is appropriate for slope area. The optimal plant species is ligustrum lucidum Ait,Lespedeza bicolor, Paspalum notatum, Veti-veria zizanioides, Eragrostis pilos and Neyraudia reynaudian. It is the best for Arbor, shrub and grass to be arranged in pairs or groups in order to remold optimal landscape. Pilot sites, covering 3ha, is established. Vegetation coverage reaches 90% in platform area, 40% in slope area. pH value in ARD increased slightly, Cu2+, Pb2+ concentration in ARD decreased, Zn2+ concentration in ARD decreased and varied slightly.

Jan 1, 2014

By M. Holuszko, I. Mikhalev

"Previous studies described by Galvin et al. (2017) have shown that for Australian bituminous coal fines, both in batch and in continuous process, the new improved oil agglomeration procedure based on the use of high-internal-phase (HIP) emulsions, as compared to the conventional “pure oil” agglomeration process, enables a significant reduction in the amount of oil while reaching a high yield of clean coal (approximately 90% of agglomerates greater than 355 µm in size) in a significantly shorter time. The HIP emulsion used in these experiments comprised up to 95% vol. aqueous solution of sodium chloride (3% wt. concentration) and for the rest, a mixture of kerosene (oil) and sorbitan monooleate (SMO emulsifier) in a 1:1 ratio as a binder. This study evaluates the applicability of the new HIP-oil agglomeration process to treat Canadian bituminous ultra-fine coal and Russian sub-bituminous coal fines and compares results from agglomeration to the flotation response of both coals. Oil agglomeration is known to be sensitive to surface properties of coal. Since surface properties of coals depend not only on the rank of coal but also on their origin (depositional environment) and mineralogical composition, both the applicability of this new improved agglomeration process to the non-Australian coals and its efficiency became the motivation for this study. To evaluate the applicability of the new process to both Canadian bituminous and Russian sub-bituminous coals, a series of bench-scale tests were carried out under conditions similar to those described by van Netten et al. (2016) for the Australian coals. Based on the results obtained in this research, new boundary conditions for the application of the HIP emulsion-based oil agglomeration process have been outlined and conclusions on the viability of the new process to treat ultra-fine coal from Western Canada and Russian sub-bituminous coal fines have been reached.INTRODUCTION In most cases, to meet the market requirements, the mined coal has to be processed to reduce the ash content by the removal of mineral matter and thus to increase the quality of the coal products (van Netten et al., 2016). Generally, flotation is used for processing fines from high rank coals; however, there are high losses of very fine coal due to the inefficiency of this process. Furthermore, difficulty in dewatering the fine coal results in excessive moisture levels causing coal handleability issues, which increases costs in the coal-cleaning industry (Capes & Darcovich, 1984). Much of the development that has occurred in fine coal cleaning has taken place with higher-value coal, often metallurgical (Klima et al., 2012). If the fine coal is deemed to be too difficult or expensive to process, it may be discarded as waste (van Netten et al, 2014). Such disposal not only creates an environmental liability but may also result in the loss of a valuable, high quality product that is better liberated than the coarser fractions of coal."

Jan 1, 2018

By Edgar Schach, Tom Leistner, Markus Buchmann, Urs A. Peuker, Martin Rudolph, Marius Kern

"In this study, the flotation characteristics of a cassiterite-bearing fine-grained and complex skarn ore from a deposit in the Ore Mountains is investigated. The tests are performed using an oil-assisted column flotation approach to process very fine ore fractions and avoid losses of cassiterite into the tailings. First, process parameters are obtained for a finely ground artificial mixture of quartz, magnetite and cassiterite, simulating the real ore. Thereby, magnetite is used, as iron oxides can have a detrimental effect on the flotation due to a similar flotation behavior. In addition, they can act as a source of multivalent ions, which are known to reduce the concentration of collector molecules, active for flotation. Based on the results, selected parameters are further tested for cassiterite skarn ore from the Hämmerlein deposit including a pre-conditioning and a water exchange step to remove ionic contaminants. The process response is analyzed in detail by XRF (X-ray fluorescence) and MLA (mineral liberation analysis) to get a better understanding of the behavior of the single ore components. Sulfosuccinamate type surfactant is utilized as the collector, emulsifier and to reduce the froth destabilization through nonpolar oil. Sodium hexafluorosilicate is added as the depressant.INTRODUCTION Complex skarn ore deposits containing considerable amounts of tin, indium and other metals are located in the Ore Mountains region (Germany). In this study, a skarn ore from the Hämmerlein deposit was investigated. Due to the finely disseminated nature of this ore, past beneficiation attempts failed, and the ore was considered economically unprocessable. However, increasing resource demands brings it back into focus (Schuppan and Hiller, 2012). Cassiterite is the main tin bearing mineral in this ore. Due to its high density (~7 g/cm³), the predominant beneficiation technique is gravity separation (Angadi et al., 2015). Tin ores from disseminated deposits have to be extensively comminuted to reach a sufficient degree of liberation of the cassiterite grains. As cassiterite has a brittle nature, it is preferable enriched in small size fractions, during comminution (Angadi et al., 2015). Gravity separation methods become more and more inefficient for particles smaller 40 µm (Falcon, 1982), causing tin losses of up to 30 to 40wt.-% (Angadi et al., 2015). Thus, froth flotation of cassiterite was first utilized in Altenberg in the Ore Mountains as an additional processing step to reduce the cassiterite losses into gravity separation tailings (Bulatovic, 2010; Gruner and Bilsing, 1992). Although the reported lower size limits for an effective cassiterite floatability are often smaller compared to other minerals, the flotation performance is in general decreasing for small particle sizes < 10 µm (Trahar and Warren, 1976). Therefore, different approaches have been already investigated for the flotation of such fine cassiterite fractions to overcome the limits in particle size. Bilgen et al. investigated the shear flocculation of cassiterite with a sulfosuccinamate collector (Bilgen et al., 1994). The agglomeration flotation of cassiterite has been tested by Schubert et al. (Schubert et al., 1966), in which the selective coagulation of fine hydrophobic particles and oil droplets leads to an increase of the effective particle size. Recently, Leistner at al. investigated an oil-assisted agglomeration flotation for ultra-fine cassiterite ore fractions (Leistner et al., 2016). However, a poor response due to an increased concentration of Fe and Ca ions, unselective oil/gangue coagulation and froth instability, that is caused by oil/frother interactions, has been observed."

Jan 1, 2018

By Leonardo Soto, Fernando Villanueva

"Antofagasta Minerals S.A. (AMSA), for its Centinela District Project, is currently developing, at a first stage, a new 90 ktpd Concentrator Plant incorporating Esperanza Sur (ESP Sur) and Encuentro (ENC) ores. In order to dimension properly main equipment, specifically for grinding circuit, a final decision has been taken using geological and metallurgical (comminution) data from both body ores. Data was analyzed internally within AMSA and its consultants to get a final proposed circuit for further engineering studies. Specific Energy Consumption (SEC) parameter is one of the main key factors for proper dimensioning. To get an accurate value different tests have been made and modelled to ESP Sur and ENC ores. Also, operational data from Esperanza operation has been taken into account due to its similar ore characteristics to ESP Sur ore and incorporated as input data for design. Depending on data, quality and amount, it is possible to estimate accuracy for project investment and risk level, hence investment decision can be taken under good and reliable information."

Jan 1, 2014

By Pawel Strzalkowski, Marta Baszczynska, Urszula Kazmierczak

The paper presents issues related to interference of mining activities with the environment. Exploitation of mineral resources causes primarily a modification of the landscape. All of the negative impacts on environment are short-lived and last as much as it takes to exploit the raw material. After the mine closure reclamation is necessary during which all aspects that reduce harmful effects of the mining activities on the environment must be taken into account. Current ways of reclamation allow recreating natural environment, which is different from the original and enriched in diverse new values. This requires propositions of new forms of converted land development through a detailed analysis of technical, natural, planning, economic and social sphere requirements. Before making final decisions regarding selection of direction of reclamation, a thorough analysis of the key factors has to be carried out. All steps related to the implementation of the reclamation project are shown in the paper using Limestone Mine "Górazdze" located in the south-western part of Poland as an example. This paper also presents an analysis of current ways of post-mining reclamation towards agricultural and forestry landscape, along with our own suggestion for their extension in order to preserve biodiversity. For choosing optimal solutions the most relevant criteria were considered: existing natural values and possibility of their protection. Taking into account the economic and social aspects, supported by natural potentials, implementation of tourism and recreation in this area were proposed. It was shown that this proposition would not interfere with the current trends of the natural landscaping. Finally, after completion of reclamation and land development in the considered mine area, creation of a geo-park was proposed along with appearance of geotourism in the area. To illustrate the proposed forms of post-mining land development in the form of maps, an ArcGIS(ESRI) software was used.

Jan 1, 2014

By Sergey Dyachenko

"Following the adopted strategy for making the production modern, efficient and environmental friendly the Company completed a stage of the integrated program aimed at reconfiguration of its processing capacity.Upgrade of the Talnakh Concentrator with commissioning of two start-up facilities (SF) allowed an increase of 30% in its ore processing capacity up to 10 mtpa. In addition to a new high-tech equipment installed, a new concentration process was adopted offering the main advantage of 25-30% reduction of sulfides in concentrate. New concentration technology enabled the total amount of produced nickel concentrates (from Norilsk and Talnakh Concentrators) to be processed at upgraded smelting facilities of Nadezhda Metallurgical Plant and allowed decommissioning of smelting capacities of Nickel Plant resulting in emissions reduction by 30%.Nornickel plans to boost the capacity of Talnakh Concentrator to 18 mtpa by 2022, after commissioning of the 3rd SF. This will provide a shorter route for ores transportation from Talnakh mines along with improvement of cost/performance ratio of ore processing through the usage of the modern equipment and optimized concentration flow scheme. Total capacity of Talnakh Concentrator will be sufficient to process ores from Talnakh deposits with planned upstream assets development taken into account. Volume of ore mined from Norilsk deposits to be processed at Norilsk Concentrator will be also increased.Upgrading the crushing section at Kola MMC Concentrator in 2015 provided finer particles of the crushed ore, resulting in 6.6% increase in specific capacity of ore mills as well as 1% higher recovery of non-ferrous metals due to improved liberation of ore minerals.In 2015-2017 the Company was actively engaged in optimization of existing process flow schemes and parameters of Kola MMC, new high-performance reagents were adopted for concentration process, namely, collectors, depressors, flocculants. These measures allowed the Concentrator to reduce its annual operating unit costs and ensure sustainable production of concentrate with the lower grade of the incoming feedstock.Launched in October 2017, Bystrinsky GOK’s Concentrator was 3D designed and received a range of advanced technological solutions.All design process procedures and technologies rolled-out at the Company’s concentrators were developed by Russian R&D institutes, with the key role of Gipronickel Institute, R&D Service of Kola MMC and Polar Division's in-house Engineering Support Centre."

Jan 1, 2018

By Auhin Kumar Maparu

Metal oxide nano-particles are used as additives in various industrial applications such as pigments in paints, additives in adhesives, plastics, cosmetics, functional coatings, personal care and health care products, for antibacterial applications and more recently in heat transfer applications. In most of these applications, usually dry nano-particle powders are added to the formulations. However, often it becomes difficult to achieve a uniform and stable dispersion of nano-particles in the given formulation. Thus, a scalable and commercially viable process for in-situ production of stable nano-particles suspensions in the desired medium will certainly be more beneficial. Ultra-fine grinding in high energy mills (planetary mill, stirred media mill) has been used to produce fine particles (sub-micron size). However, in order to obtain nano-particles (particle size <100 nm), the choice of appropriate dispersant and solvent is crucial, since freshly generated nano-particles tend to agglomerate due to their high surface reactivity. We have employed molecular modeling (MM) based selection methodology to arrive at the most suitable solvent?dispersant combination for preparation of the given metal oxide nano-particles. Molecular modeling techniques are employed to compute the interaction energy of a given dispersant with surface of the metal oxide particles in the presence of the dispersion medium. The interaction energy helps identify a dispersant that has strong affinity for the metal oxide surfaces allowing for strong dispersant adsorption and hence a more stable dispersion. For example, in case of aqueous nano-titania suspensions, poly-carboxylic acids like citric acid provide better dispersion than mono-carboxylic acids like lauric acid, mysristic acid, and oleic acid. While in non-aqueous medium like ethanol, p-hydroxybenzoic acid and glycerol trioleate perform better. The suspension is produced in-situ by ultra-fine grinding of the metal oxide powder in the presence of the selected dispersant and dispersion medium in a planetary ball mill. By careful selection of various process parameters such as percent loading of powder, jar filling, grinding media to powder ratio, time and amount of dispersant addition, both aqueous and non-aqueous suspensions of metal oxide nano-particles with average particle size less than 100 nm are produced. The aqueous suspensions of alumina and titania produced in presence of citric acid dispersant exhibit median particle size of 83 and 62 nm, respectively. These suspensions have been found to be stable for nearly 3 years. The nano-particles thus produced are used in the preparation of nano-fluids?advance heat transfer liquids, which show enhanced heat transfer capabilities and unaltered stability and performance even after several heating-cooling cycles. The nano-particles are also utilized for making efficient photo catalysts, which are found to be highly effective under sunlight. Keywords: stability, nano-fluid, milling, grinding, thermal conductivity, nanocoolant, photocatalyst

Sep 1, 2012

By Arman Ehsani, Ersin Yazici, Haci Deveci

The downstream treatment of chloride leach solutions of WPCB for recovery of base and precious metals by a combination of adsorption and precipitation processes were carried out. A synthetic leach solution (1 M HCl, 116.5 g/L Cl-, 30 g/L Cu2+, 2.5 g/L Fe3+, 5 mg/L Au3+, 10 mg/L Ag+ and 20 mg/L Pd2+), which was prepared based on the composition of the pregnant leach solution obtained in the previous study was used in the tests. The leach solution was initially subjected to activated carbon (AC) adsorption (20 g/L AC, 80°C) in which gold was selectively recovered over silver and palladium i.e., 88% Au recovery at 0.5 h (92% at 3.5 h) compared with only 3-6% for Ag/Pd. Copper and iron were also observed to adsorb on AC as indicated by 1.4% and 17% decline, in their respective concentrations. Following the adsorption and filtration stage, metallic copper was added into the gold-barren solution to allow reduction of Cu2+ to Cu+, and to cement Pd on metallic copper. Over the mixing period (1 h), 93% of the Pd was recovered while only 1.4% of silver was cemented onto metallic copper. Subsequently, the leach solution was gradually neutralised by NaOH to pH 4, 7.5 and 9.5 for the precipitation of copper as cuprite (Cu2O). It was found that 41% and 46% of Cu and Ag, respectively, were precipitated at pH 4 at which iron was almost totally (99.8%) removed from solution. Precipitation of copper and silver was increased further at high pHs. At pH 9.5, cumulative recoveries for copper and silver were 91% and 85%, respectively. XRD analysis of the precipitates confirmed the presence of cupric copper oxides/hydroxides and revealed that copper losses occurred at pH 4 was due to the undesired presence of cupric copper in the solution.

Jan 1, 2014

By Achilles Dutra, Everton Santos, José Oliveira

The beneficiation of phosphate ores by froth flotation is the most efficient process used to separate apatite from gangue minerals like calcite, dolomite and quartz. However, the similarity of surface properties between apatite and calcite generally lead to non-selective adsorption of reagents, rendering the selective separation of these minerals a worldwide problem. The phosphate deposit of Itataia, State of Ceará, Brazil, studied in the present work, presents a complex mineralogical composition having uranium associated with the apatite mineral. The main gangue minerals are calcite and quartz. The bulk flotation of apatite and calcite with anionic collectors in an alkaline medium followed by the selective flotation of calcite at pH 5.5 using phosphoric acid as well as citric acid as depressant have been suggested for this ore. This paper presents the results of contact angle measurements obtained using jojoba oil, a natural reagent composed mainly of gadoleic acid (C20:1) and long-chain fatty alcohols (eicosenol and docosenol), as an alternative collector for the selective separation of apatite and calcite minerals. The hydrophobicity studies were carried out using a computer controlled contact angle goniometer. Additionally, the collector adsorption was evaluated via electrophoretic mobility and FTIR measurements. The results indicated that a high selectivity can be obtained by using jojoba oil as collector in a slightly acid pH range, without the use of depressant. The best results were achieved with a jojoba oil concentration of 200 mg.L-1 at pH 6.5, where the apatite was fully hydrophilic and calcite showed a high hydrophobicity (? > 60 º).

Jan 1, 2014

By F. Concha

A robust theory of sedimentation-consolidation evolved and was accepted by researchers world-wide in the last two decades of the 20th century. This theory provides a reliable method of thickener design and simulation. However, a process model, simple or sophisticated, empirical or phenomenological, is useful only if it is possible to determine, in an objective way, its experimental parameters. Research workers at the University of Concepción, together with Cettem Mineral Technology Center, created an integrated system of thickener design, simulation and control, including instrumentation, algorithm and software, which can be used by personnel in industry without specialized knowledge of thickening theory. In the paper, the development of three instruments for the measurement of pulp concentration, solid flux density and sediment compressibility is described. Each instrument uses software for data input, parameter calculation and results display. The paper also describes software for the optimization of the experimental parameter and for the design and simulation of industrial thickeners. Finally, mathematical algorithm and control strategies based on the phenomenological model are presented and compared with classical feedback control.

Jan 1, 2014

By G. Mucsi, F. Kristály, Á. Rácz, É. Gregus, K. Bohács

"Stirred media mills are widely used in the industry for fine grinding. Most of the applications work in wet mode, however dry grinding in stirred media mill comes forward more frequently nowadays. The present paper deals with the differences and similarities of the wet and dry grinding in stirred media mill from energetic and mechanochemical point of view as well. Grinding experiments in batch stirred media mill were carried out with different materials. During the experiments zeolite and kaolin were used as feed material. The grinding experiments were carried out at different stress energy and stress number values; the grinding work was measured during milling. After grinding X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), particles size analyzes by laser scattering were carried out on the ground materials. As a result of the systematic grinding and analytical measurements a comprehensive comparison was carried out on the wet and dry grinding and their usefulness for mechanical activation in stirred media mill. INTRODUCTION The natural zeolites are crystalline hydrated aluminosilicates of alkali and alkaline earth characterized by the structure that contains frameworks responsible for the high cation exchange capacity (CEC) and absorption capacity. The frameworks are interconnected by cavities and resided by cations variable in size, coordinated by water molecules. Since zeolite comprises SiO4 and AlO4 tetrahedra interlocked by oxygen atoms that are situated in the structural nodes, their characteristics differ due to the varieties in the structure-directing agents and Si/Al ratio (Colella and Wise, 2014; Malekian et al., 2011; Terzic et al., 2017). The most common natural zeolite occurring in high amount, of industrial importance and involved in milling and MA is the clinoptilolite, in the literature equivalent to “natural zeolite” designated for high clinoptilolite bearing volcanic tuffs. Its amount in the host rock must reach ~ 40 % by weight to obtain the CEC and adsorption desired in its applications. In the highest quality rock might reach 80-90 % by weight (Favvas et al., 2016), but most often is the 40-60 % by weight content, associated with smectites, improving the CEC and adsorption of the tuffaceous rock. The application of such natural zeolites is problematic in many cases due to high silica (quartz, cristobalite and volcanic glass) content and beneficiation (concentration and extraction of pure zeolite) are not feasible. Thus, mechanical activation is a possible way to alter the other than clinoptilolite minerals generating high specific surface area and functionalized particle surfaces to enhance adsorption, reaction or particle adhesion. The zeolites easy availability and the utilization cost-effectiveness have prompted the research on their physicochemical and structural properties (e.g. adsorptive and molecular-sieve activity, heat resistance, and microporous cage structure) and finding new options for their application (Kusuma et al., 2013; Musyoka et al., 2014; Rida et al., 2013; Terzic et al., 2015b). Apart from the presence of exchangeable framework cations which are crucial for the adsorption ability, and a certain degree of pozzolanic reactivity. The thermal stability of dehydrated phases is another important characteristic for use of the zeolite in composite materials that are exposed to high temperature. Thereby, the zeolites found a wide application possibility in the design of the construction composites (Albayrak et al., 2007; Najimi et al., 2012; Vejmelková et al., 2015), as well as for resolving of the environmental protection issues like wastewater refining or heavy metal elimination (Gómez-Hortigüela et al., 2014) even from contaminated groundwater using passive methods like permeable reactive barriers (Gombköto et al, 2016). The grinding treatment of zeolite is a common and frequently applied procedure, both on laboratory (Bohács et al. 2017, Faitli and Czél, 2014)"

Jan 1, 2018