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With shortage of sulfide nickel ores, laterite ore was paid more attention by scientists. Because its grade is commonly lower than sulfide nickel ores, laterite ore can not be utilized effectively be-coming the bottleneck of study. Leaching laterite ores from Yuanjing, Yunnan province, organic ac-ids show better selective than sulfide acid in nickel and cobalt recovery. Organic acid has low de-pendent on pH, keeping leaching capability even higher than 3. On the other side, when pH up to 2, sulfide acid can not leach laterite ores any more. After four kinds of organic acid leaching laterite ores, besides citrate, malate and succinate have good leaching and effectively selective capability. Especially, succinate has the best selective leaching capability of nickel and cobalt in four kinds of organic acids for latter anion purification and separation. Isolated from waste water with sugar, Aspergillus niger (zs1) has great capability to produce organic acids and vigorous growth. Laterite ores have been respectively processed by direct-leaching and indirect-leaching. Indirect-leaching gives a better result than direct-leaching. Extraction of nick-el by indirect-leaching reaches 44.3%, far more than that of direct-leaching. Moreover extraction of nickel at pulp density of 5% is higher than that at pulp density of 10%, reaching 63% in 11 days and extraction of cobalt also is 48.1% in the same period. Compared with nickel and cobalt, iron gives low extraction in solution, containing organic acids produced by Aspergillus niger .

Jan 1, 2014

By Venkataramana Runkana, Pradip Gautham, Beena Rai, Sreedhar Reddy

"IT enabled platforms are the key to provide an integrated view of the business activity or an enterprise as a whole. Attempts to integrate all functions in an enterprise such as mine-to-market initiatives, wherever and to whatever extent implemented, have provided significant benefits to the industry. The transformative potential of IT enabled integration platforms is illustrated in this communication from our own work in this field. TCS PREMAP (Platform for the Realization of Materials and Products) is a knowledge-driven engineering design and development platform which leverages modeling and simulation and artificial intelligence into the engineering design process. We illustrate the customization of this generic platform for the design and optimization of mineral processing plants in an integrated manner. TCS PEACOCK (Process and Equipment Analytics for Optimization and Control) has been developed to enable automation of data analytics in the operating plants. We illustrate its utility and power in improving the plant performance with the help of case studies from our work on pelletization of iron ores and optimization of flotation plants. INTRODUCTION We are living in an exciting digital era. With the advent of cloud computing and social media on the one hand and rapid advances being made in several research areas of interest to us in the minerals and metals industry such as artificial intelligence (AI) & machine learning, robotics, unmanned vehicles including drones, big data analytics, 3D printing, sensor technologies, renewable energies and internet of things (IoT), many disruptive transformations in our industry are on the horizon. Recent advances in information technology (IT) and knowledge engineering, in combination with appropriate domain expertise, that is, our enhanced understanding of the underlying science of mining and mineral processing operations and the availability of a variety of powerful modeling-simulation tools make it possible to address the challenging problems facing the mining and mineral processing industry, in an integrated manner."

Jan 1, 2018

The major components of sylvinite ores, sylvite (KCl) and halite (NaCl), are separated by flotation. Since both these minerals are water-soluble, the process is carried out in a saturated brine, 6~7 mol/L aqueous solution of NaCl and KCl. C16~C22 primary amines, utilized as a collector, are practically insoluble in water. In commercial potash ore flotation operations these amines are melted by heating up to 70~90°C. They are then neutralized with hydrochloric or acetic acids, and such a hot emulsion/dispersion is introduced to the flotation pulp (which is at room temperature). This is immediately accompanied by the appearance of a white precipitate in the system. As our measurements indicate, the Krafft point of dodecylammonium chloride in concentrated electrolyte solutions is much higher than 80°C, and the Krafft point of C16~C22 amines is substantially higher than that. Introduction of a hot amine emulsion into a pulp, at temperature much lower than the Krafft point for the utilized amines, must cause precipitation of the amines. Some of these species are obviously flotation-active. It is interesting to observe that in summertime, when temperatures are high-er, longer chain amines perform better. It demonstrates that the colloidal amine species that precipitate serve as active species in the potash flotation. Therefore, at higher pulp temperatures, when the temperature difference between the pulp temperature and the Krafft temperature of the utilized amine is not sufficiently large, a longer chain amine, the amine with a higher Krafft point, is more efficient. The results reveal that premixing of an alcohol such as MIBC (common frother) with the amine significantly improves flotation performance of the amine. In the presence of such an alcohol the amine disperse system becomes less turbid, and the rheology of the system less non-Newtonian. All this indicates that MIBC, which does not operate as a frother in a potash flotation system, when used as a co-surfactant, enhances the dispersion of the amine colloidal system. The appearing colloidal species perform as an active form of the collector.

Jan 1, 2014

By K. A. Natarajan

Interaction with microorganisms results in significant surface chemical changes on minerals. For example, chemolithotrophs such as Thiobacillus ferrooxidans and Thiobacillus thiooxidans significantly alter the surface chemistry of several sulfide minerals such as pyrite, chalcopyrite, sphalerite and galena. Heterotrophic bacteria such as Bacillus sp. could alter the electrokinetic properties of oxide minerals such as hematite, alumina, silica, kaolinite and calcite. Microbe-mineral interactions could thus be beneficially utilised in mineral beneficiation as different from bioleaching. Microbially induced mineral beneficiation unlike bioleaching deals with interfacial phenomena at mineral-solution-bacteria interfaces and surface chemical changes are brought about at very rapid rates amounting to a few minutes resulting in mineral separations in an aqueous medium.

Jan 1, 2003

The flotation of nickel sulphide minerals is normally difficult in the presence of serpentine minerals due to the coating of serpentine particles on the nickel mineral surface. To improve the flotation, dispersants such as polyphosphate and carboxy methyl cellulose are normally used to remove the slime coating. However, in the flotation using high ionic strength process water, these dispersants are invalid due to their ionic nature. In this study, a new type of non-ionic dispersants, Pluronic triblock copolymers were examined with an objective of improving the flotation of ultrafine pentlandite (a nickel sulphide mineral) in the presence of lizardite (a serpentine mineral) in saline water. Three Pluronic triblock copolymers varying in solubility and hydrophile-lipophile balance (HLB) values were studied by flotation tests, settling tests and froth measurement. It was found that two of the copolymers improved pentlandite flotation against lizardite, and one copolymer deteriorated the flotation. The effect of Pluronic triblock copolymers on the flotation was actually linked to their dispersibility and foamability, which were governed by their physical properties. The two copolymers with a higher solubility or HLB value produced more stable mineral suspensions and more stable froth in the flotation resulting in better nickel grade and recovery in both rougher and cleaner flotation. Keywords: ultrafine particle, flotation, slime coating, dispersion, saline water, triblock copolymers

Sep 1, 2012

By Sathyaprasad Nanjundaiah

The Paper intends to showcase a framework for spatial data collaboration from multiple sources of data, in order to create a single source of truth across the Organization. The framework is targeted to reduce the data duplicity, re-work, time loss due to search of required data and hindrances to fetch or transfer data from various data sources. The spatial data collaboration will provide a single window view of the entire organization with respect to its operations, management, sales, customers and competitors on a spatial reference across various regions in the World. Large Organizations with cross-country operations can standardize the use of spatial data through this framework for ease of data access, increasing the data reliability / integrity and better / on time decision making. Keywords: spatial data, GIS, collaboration, framework, mining, ESRI, tab files, shape files, ETL, reliability, integrity, interoperability, geo data, geo database, single source of truth

Sep 1, 2012

By F. B. Waanders

Coal, as energy resource, possesses numerous characteristics and properties which all have an influence on its gasification behaviour. The two properties considered as critically important when evaluating a coal source for gasification is its mineral content and slagging behaviour. Research has indicated that slagging formation can be inhibited or even prevented by the addition of a fluxing agent. It is thus of great importance to understand the mineral interaction during gasification in order to select a suitable fluxing agent for the prevention of slagging and clinker formation in the gasifier. The aim of the present project is to evaluate the effect of iron as a fluxing agent and study the transformation of the mineral and added iron during gasification. A pre-determined amount of pure elemental iron (between 2wt% and 20wt%) was added to a base case coal sample in order to study the effect of the addition of iron to the coal. The transformation of the iron in conjunction with the possible iron containing minerals present in the coal was studied by means of Mössbauer analyses. Typical characterisation techniques included proximate analyses, ultimate analyses and ash composition analyses. The ash fusion temperature analyses (AFT) were used to study and predict the slagging behaviour of the iron-spiked coal samples. Even though AFT analyses only provide an average flow property, it gives a good indication of the changes that the iron addition induces on coal properties. FactSage modelling was carried out in conjunction with the Mössbauer and AFT analyses. From the proximate, ultimate and ash composition analyses it was clear that the coal used con-formed to the average characteristics measured over an extended time period. From the AFT values it was seen that an increase in the flow temperature occurred with the addition of pure elemental iron to the coal, which can be of importance for operational purposes as to raise the gasifier temperature and not to have slagging problems to occur in the gasifier. The Mössbauer data show that he-matite is the main Fe-component that forms from the pyrite originally present and from the added iron to the coal, consistent with FactSage modelling, which shows that the partial oxygen pressure determines which mineral species will form. This study opens up new possibilities when considering operational problems experienced in in-dustrial gasifiers. Successful completion of this study and a study to look at reducing conditions in the gasifier will also add to the knowledge that already exists regarding fluxing agents.

Jan 1, 2014

By S. Kondratiev

Mechanism of the action of nonpolar physically adsorbed reactants in froth flotation is under discussion in the paper. It is shown that their basic influence on flotation includes removing of the kinetics restrictions of the flotation complex formation. Experimental data and practical evidence reported in the paper sustain the proposed mechanism. There are discussed potential dependence of the kinetics of dixanthogen formation on platinum and its influence on the induction time (IT).

Sep 1, 2012

By Áureo Del Vecchio, Lídia Dely Alves de Sousa, José Pereira

The potassium demand for agriculture purposes has increased in Brazil, which has great deficit of internal demands. Potassium-rich rocks have been used as fertilizers as technological alternatives for agriculture aimed to reduce the amount of chemicals and the sector dependence for such products. Vermiculite tailings from União Brasileira de Mineração - UBM, at Santa Luzia - PB, was studied aiming their application in agriculture by potassium release. The sample was analyzed by XRF and XRD; studies on release kinetic with particles smaller than 2 mm added of organic acids (citric and oxalic) at 10-2 mol/L concentration; samples were analyzed by XRD after kinetic assays. The work was conducted using a shaker incubator at 300-rpm agitation and time variation to better understand the potassium availability in the ground. Results show the presence of K2O at 3.46% concentration. Citric and oxalic acids increased the release speed to almost the same level with speed coefficients (k) of 2.61x10-2 h-1/2 and 2.55x10-2 h-1/2 respectively. In statistical terms for both acids, the linear equation represents more than 99.0% of the experimental assays. Stonemeal was applied to banana seedlings in experiment conducted in a greenhouse. The use of vermiculite tailings in banana seedlings promoted potassium absorption, which influenced its growth. The amount of potassium liberated from vermiculite tailings could be used as a long-term alternative to fertilizers in agriculture cultures.

Jan 1, 2014

By Jonas Addai-Mensah

In this paper, the results emerging from the several basic and applied studies performed to provide fundamental understanding of the interplay between clay pulp chemistry, orthokinetic flocculation performance, particle interactions, applied shear and dewaterability of fine clay mineral dispersions are presented, reconciled, and discussed. Modification of pulp chemistry and behaviour was achieved by using kaolinite and Na-exchanged (swelling) smectite clay minerals, divalent metal ions (Ca(II), Mn(II)) as coagulants and high molecular weight, anionic polyacrylamide copolymers: carboxylate substituted (PAM A) and 2-amido 2-methyl propane sulphonate (PAM S) (PAM S), non-ionic polyacrylamide homopolymer (PAM N) and non-conventional, non-ionic polyethylene oxide (PEO) as flocculants. Clear links between pulp interfacial chemistry, particle interactions and dewatering behaviour, resulting from the influence of hydrolyzable metal ion, pH, temperature, polymer structure type and shear, are established. Optimum conditions for improved, orthokinetic flocculation performance of negatively charged clay particles, reflecting faster settling flocs (>10 m/h) comprised: (i) coagulation, (ii) moderate agitation rate, (iii) shorter agitation time and (iv) anionic rather than non-ionic PAM. The optimum flocculation conditions did not, however, have a significant impact on the final sediment solid content of 20 ? 25 wt%. Further application of shear to pre-sedimented pulps improved consolidation by 5 - 15 wt % solid. Application of the findings and new knowledge gained to real plant tails? case studies for marked improvement in dewaterability through thickening is demonstrated.

Sep 1, 2012

By E. A. Brocchi

This work is dedicated to the chemical treatment of a typical EAF dust by chlorine content agents. The residue contains 48% Fe2O3 and 28% ZnO mainly in the franklinite structural form. The others less compounds are: 4.00% CaO, 2.60% MnO, 2.20% MgO, 1.08% PbO, 0.36% Cr2O3, 0.21% B2O3, 0.03% CdO and 0.01% NiO. The experiments purpose is selectively to remove zinc from the residue leaving the iron behind. Thermodynamics studies have indicated some roasting possibilities. The experimental results have shown that both HCl leaching and carbochlorination will remove iron and zinc without any selectivity. However, either the chlorine or the calcium chloride roasting seems to form, preferentially, the zinc chloride. So, it will be presented how the EAF Dust can be treated by the using of chlorine roastings process such as carbochlorination in order to separate the zinc and iron present in the frankilinite, main EAF dust content.

Jan 1, 2014

By Y. M. Zhu

Lead in environment often causes a serious health hazard. The removal of Pb2+ from aqueous phase is a beneficial project. In this paper, deposited Saccharomyces cerevisiae (S.c.) was chosen as adsorbent, Pb2+ ions as adsorbate, and the process of biosorption was studied. The dynamics of the adsorption was investigated. The adsorption mechanism of Pb2+ by S.c. cells was also investigated by detecting microstructure, zeta potential under different pH value, FT-IR spectra of the S.c. particles before and after biosorption. It was shown that the biosorption of Pb2+ by deposited S. c. is a rapid process, and the adsorbing equilibrium is reached within 10 minutes. The Zero point of zeta potential of S.c. cells is pH=3.3. When 2.0<pH<3.3, there exists biosorption (biosorption rate 76%~88%), which means static bio-sorption been not the only kind of biosorption. FT-IR spectrum analysis showed that groups on bacteria surface were mainly characteristic groups of protein and amylase; oxo-groups and nitric-groups on S.c. cell surface could chelate with heavy metal ions. Chemical adsorption might exist in the process.

Jan 1, 2014

By Wei Sun, Ruolin Wang, Jianjun Wang, Xiaodong Li, Honghu Tang, Yuehua Hu, Anh V. Nguyen, Haisheng Han, Kefeng Chen, Zhao Wei

It is difficult to separate scheelite especially from fluorite with fatty acid collectors because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface. A simplified flotation process using Pb-BHA complexes was developed to replace the energy-inefficient Petrov’s process of using a fatty acid, increasing the recovery of scheelite and reducing the cost. The relationship between surface chemical properties (crystal chemistry, solubility, and Zeta potential) of minerals and flotation by using a fatty acid or Pb-BHA complexes was studied in detail to provide new insights into the selective separation mechanism. The results indicate that the scheelite surface exposes more O atoms than Ca and that they are negatively charged due to the anisometric dissolution of Ca and WO4, which provides the possibility for separation using selective interfacial reaction. The FTIR and Zeta potential results indicate that both chemical and electrostatic adsorption play an important role in the adsorption of Pb-BHA complexes on the scheelite surface. The XPS results of the atomic composition and binding energies confirmed the presence of the adsorbed Pb-BHA complexes and that O and Ca may be the active adsorption sites. Therefore, scheelite was able to be collected by forming either a Ca-O-Pbcollector or W-O-Pb-collector (BHA). However, fluorite was only able to be collected by a fatty acid collector and colloidal [H2SiO3]n -, and a high temperature was needed improve the selective desorption of the adsorbed fatty acid collector by forming Ca-[H2SiO3]n - on the fluorite surface, resulting in serious problems in industry. However, the Pb-BHA complexes significantly contribute to improving the recovery of scheelite minerals, simplifying the flotation process, and circulation of the residual reagents and water. The new process has been applied in Shizhuyuan Mine, and improved the recovery by almost 10%.

Jan 1, 2018

By A. Zangooi

Frothers play major roles in flotation through interaction at the air/water interface. A method of determining frother adsorption density (coverage), i.e., the number of molecules per unit of interfacial area of bubble surface, is introduced. The technique is based on mass balancing the frother around a continuously operated bubble column. The mass balance requires collection of bubbles before they burst. The column design and operating procedure is reviewed, and some preliminary results discussed. Keywords: flotation, colorimetric frother analysis technique, frother mass balance, coverage

Sep 1, 2012

By A. D. Bas

Copper minerals present difficulties during the cyanide leaching of gold ores leading to excessively high consumption of cyanide (and oxygen) coupled with low extraction of gold. Copper cyanide species, if present at high levels, adversely affects the downstream processes such as the activated carbon adsorption and the effluent treatment. In this study, the extraction of gold from a copper-bearing gold ore by ammoniacal cyanide leaching was studied. Furthermore, ammonia leaching as a pretreatment process ahead of cyanide leaching was also examined. Only ~12% of gold was extracted by direct cyanide leaching of the ore. The addition of lead nitrate did not affect the leaching of gold. When ammoniacal cyanide leaching system was used, the extraction of gold was significantly improved to >90%. Similarly, the pretreatment of the ore by ammonia leaching was shown to lead to high gold extractions (98%), in subsequent cyanide leaching with significant reductions in the consumption of cyanide. This appeared to be linked with the ready dissolution/removal of copper during ammonia leaching.

Sep 1, 2012

By Michael Young, Rodrigo Araya, Cesar Gomez, Le Huynh, James Finch

The performance of flotation machines is closely related to the gas dispersion characteristics achieved in their operation. It is known that frothers play a major role not only in the size distribution of the generated bubble population, but also on the swarm rise velocity. A program to characterize frother effects on two-phase hydrodynamics (air-water) of Jameson cells was undertaken in a fully instrumented pilot unit installed at McGill University. Gas dispersion parameters (gas velocity, gas holdup and bubble size distributions) of the gas-liquid mixture generated in the downcomer were measured after its release into the separation chamber. The unit was operated under different conditions including gas velocity, liquid jet velocity and frother concentration (MIBC). Bubble size distributions for concentrations above the critical coalescence concentration (CCC) were narrow with Sauter mean diameter between 0.6 to 1.3 mm. The bubble size followed the general trend as encountered in other types of flotation machines, i.e., rapid decrease with increasing frother concentrations below 10 µL/L, and almost no change in size for concentrations above 30 µL/L. The CCC was between 10 and 15 µL/L. Strong correlations were found between bubble size and air-to-liquid flow ratio (APR), and between the bulk density of the aerated solution in the separation tank and the vacuum inside the downcomer. An equation is proposed to estimate gas holdup in the separation tank from vacuum and bulk density readings.

Jan 1, 2014

By N. Panteleeva, E. Konoplev, I. Michailova, S. Titkov, S. Aliferova, T. Gurkova, T. Chumakova

Cationic flotation using alkylamines and their derivatives as collectors, and characterized by high selectivity of mineral particle separation, is finding ever growing industrial application. In recent years the industrial application has been initiated of new cationic collectors - alkylmorpholines. Efficiency of cationic surfactants operation as collectors is dependent upon their colloid and sorption properties and the availability of silicate .carbonate rock-forming mineral impurities in the ore, which sorb the cationic collector. Investigations have been carried out on the influence of frothers and organic depressors with various compositions upon physical-chemical and flotation properties of alkylamines and alkylmorpholines. On the basis of these investigations requirements for organic depressor were developed and new flotation reagents were proposed (V-1 frother and KS-MF depressor). The use of new reagents enables one to decrease considerably the consumption of expensive cationic collectors and to enhance the floatability of coarse mineral particles. Data of new reagents industrial application is presented. The reagents developed can be used for flotation processing of other ores.

Jan 1, 2003

By M. S. Eygi

This study covers the investigations based on the electrokinetic and rheological properties to explain the interactions between kaolin minerals and commercially available polyelectrolyte in anionic character. Additional adsorption test were also conducted to support the interaction mechanism. Adsorption tests showed that adsorption densities decrease by increasing the solid content. In-creasing the solids contents from 1% to 30% by weight resulted in the decrease on adsorption from 2.14 mg/g to 1.85 mg/g. Because of its difficulty, the solids ratio at 70% was not studied. However, following to trend of the curve plotted adsorption density-solid ratio, an estimation was made and adsorption density at 70% solid content was extracted from the curve as 1.75~1.80 mg/g. The electrokinetic studies pointed out that the presence of polyelectrolyte increase the zeta potential of kaolin from 40 mV to 60 mV which is reasonable conditions to disperse and stabilize the kaolin slurry and lower the viscosity. When these result of the different tests are combined and considered together, 2 mg/g polyelectrolyte concentration was noted as optimal concentration where adsorption density, viscosity and zeta potential of the slurries give maxima and remain constant after this concentration.

Jan 1, 2014

By L. Gutierrez, R. Yepsen, F. Alarcón

Chile is the world's largest copper producer which is mostly in the form of sulfides for which froth flotation is the most efficient concentration process. As a result a concentrate that contains high concentrations of copper sulfides such as chalcopyrite, chalcocite and enargite is obtained. In the last decades processing of ores containing high concentrations of enargite (Cu3AsS4) has continuously increased in Chile, which is related to the fact that ore deposits nawadays are more heterogeneous and complex. Enargite is a mineral that contains arsenic and its presence in the copper concentrates implies severe penalties. In addition, the shortage of fresh water has driven the search for new alternative sources of water, among which seawater has proved to be one of the most attractive. The objective of this research is to study the behavior of the enargite in the process of flotation using seawater, and at the same time to compare its behavior with the results obtained using conventional water. The study was carried thorugh micro-flotation tests using pure samples of enargite, at pH values ranging from 4 to 11, both in fresh and seawater. PAX and MIBC were used as collector and frother respectively. Micro-flotation tests were also done at different redox potential conditions so that the effect of the surface oxidation of enargite was evaluated in seawater. The results indicate that the recovery of copper from enargite is reduced in seawater compared to fresh water, in particular at the pH values close to those of the formation of the first hydroxy complexes of Mg and Ca. In general, the experimental data indicate that the floatability of enargite is strongly affected when seawater is used, in particular at oxidizing conditions. These results suggest that Mg2+ and Ca2+ ions contained in seawater interact with the surface of enargite forming hydrophilic species.

Jan 1, 2018

By K. Saberyan

Zirconium and hafnium are two important elements in nuclear industries. Zirconium is used in fuel rod for its low neutron absorption. Hafnium should be separated from zirconium, because it has higher neutron absorption cross section. In this research, separation process of the mentioned elements from (Zr+Hf)Cl4 mixture produced in the Zirconium production plant (ZPP) of Iran (Esfahan) was studied employing solvent extraction method in the nitric acid medium by using tributylphosphate (TBP) as solvent, and kerosene as diluent. The effects of nitric acid, sodium nitrate and amount of extractant, zirconium concentration in aqueous phase, phase ratio, agitation time, and mixer agitation rate were investigated on the separation process. The process was optimized at 5 M nitric acid, 1 M sodium nitrate, 60% (v/v) TBP. The optimum values for phase ratio, agitation time and agitation rate were 1.5 min and 500 rpm respectively. In this condition, the zirconium extraction efficiency, and separation factor were 65.1% and 205.59, respectively. Finally, we accessed to nuclear grade in this research.

Jan 1, 2014