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By I. Gombköto, G. Mucsi, S. Nagy, F. Kristály, Á. Rácz, R. Szabó, B. Egyed

"Present paper deals with the investigation of a Hungarian pumice. Grinding experiments were carried out in a stirred media mill for various residence time. Ground samples were tested with laser particle size analyzer to determine and calculate the material fineness (particle size distribution and specific surface area). The lime adsorption capacity was measured to monitor the reactivity. Alkali activated cement paste was prepared using ground pumice with various alkali activators. Cube shaped specimens were produced from the paste and the uniaxial compressive strength was measured at the age of 7 days. The resulted alkali activated material structure was investigated by XRD and FTIR. The results of the experiments show that pumice fineness has strong impact on its hydraulic activity, hence on the compressive strength and the structure of the resulted binder. Relationships between grinding fineness, material structure and strength of the raw and mechanical activated material as well as the alkali activated cement were revealed. INTRODUCTION Pumice is a natural pozzolan which can be used as raw material for cementitious materials in limited portion owing to its low reactivity. Furthermore, due to its mineralogical composition it can be used for developing a new environmental friendly binder, namely alkali activated cements (AAC) which are inorganic alumina-silicate materials with good cementitious properties (Almalkawi et al., 2017; Özodabas and Yilmaz, 2013; Najimi et al. 2018; Yadollahi et al., 2015). Despite being a rather recent research topic, many papers and books have been published focusing on various aspects of alkali activation. There is great variety of raw materials that can be utilized for AAC production. However, primary raw materials are very expensive and secondary materials are heterogenous in composition. Therefore, a more homogeneous and low price silicate would help to balance the properties and cost of resulting cement and easing the way for commercialization of AAC. However, the control of its reactivity is of great importance which can be realized using mechanical activation by grinding (Juhász and Opoczky, 1990; Djobo et al., 2016; Mádai et al., 2015). The goal of present paper is to investigate the effect of mechanical activation of pumice on the properties of the resulted alkali activated cement."

Jan 1, 2018

By Eduard Stefanescu, James M. Mwase, Egon Sehner, Stoyan Gaydardzhiev

"The study is focused on investigating the production of synthetic rutile of 95% purity or higher from a Norwegian ilmenite ore concentrate. This was to be achieved using a sequential process involving oxidative-reductive roasting at 975°C, followed by magnetic separation to further concentrate the sample and finally leaching with 20% HCl to remove mostly Fe-based impurities leaving behind synthetic rutile. The key process parameters considered were roasting time (1 and 2 hrs), leaching temperature (100, 125 and 145°C), pulp density (15 and 25wt%) and leaching time (3 and 6 hrs). The option of directly leaching the concentrate without pre-treatment was also evaluated. Test work was conducted using samples screened to a size fraction of 105-212 µm. Samples were leached in a 1 L glass autoclave. The reactor was hermetically sealed and thus the resulting pressure was not controlled but was dependent on the process temperature. The product from leaching was calcined and analysed via XRD and SEM to determine the purity of the product. The magnetic separation step was found to be ineffective and discontinued early in the study. Thus far a product with 97% synthetic rutile purity as analysed by SEM has been produced by directly leaching the concentrate at a temperature of 145°C, pulp density of 25wt% and leaching time of 6 hrs.INTRODUCTION The study investigates the use of a process route comprising oxidative-reductive roasting, followed by magnetic separation and then hydrochloric acid leaching and calcination to produce synthetic rutile from ilmenite concentrate. The grade of synthetic rutile produced should be suitable for chlorination to produce pigment grade TiO2. Hence the proposed process should produce a product consisting of no less than 95% synthetic rutile. Additionally, the product should have no more than 1.5wt% combined content of CaO and MgO (Zhang et al., 2011) as they tend to form high-boiling-point chloride leading to the malfunctioning of fluidized bed chlorinator (Cardarelli, 2008). Finally the product should have no more than 2.1wt% of Fe2O3."

Jan 1, 2018

By Danfeng Xu

The majority of the world?s nickel (Ni) resources occur as laterite ores, which are exceptionally complex, lower grade (<1.5% Ni) and expensive to treat using conventional smelting and high temperature/pressure autoclave methods. Heap leaching is a promising, less costly, alternative technology for processing low grade nickel laterite ores. However, significant technical challenges remain with Nickel laterite heap leaching, preventing its general adoption. This paper presents some highlights of laboratory column leaching studies undertaken to characterise, evaluate and optimise sulphuric acid leaching behaviour of Nickel laterite agglomerates. They provide basic but valuable information regarding Nickel laterite agglomerate structure stability and leaching performance under industrially-relevant, continuous acid irrigation conditions. In particular, Nickel and other key metals? (e.g. Co, Fe, Al and Mn) extraction rates, free acid concentration, bed slump and structural changes were determined at a given acid percolation rate as a function of time. Potential implications of the findings, for devising strategies for improved Nickel laterite plant heap leach operations are discussed. Keywords: nickel laterite, column leaching, agglomerates, leaching kinetics, acid consumption

Sep 1, 2012

New technology for on-line particle size analysis of mineral slurries has opened up new applications for particle size measurement. In some cases the particle size distribution of the final concentrate is an important quality issue. This paper discusses established on-line particle size analysis technologies and presents experiences on the use of a new technique employing laser diffraction in several minerals processing operations. The main innovations in the new instrument are a simple dilution system and multiple scattering correction algorithm, which allows wide solids content variations of diluted sample in the measurement cell. Representative sample for laser measurement is produced by a simple and reliable dilution system. The applications discussed are; Blaine number measurement of Fe concentrate before pelletizing, grinding of variable batches of ore and paste thickener control.

Jan 1, 2014

By C. Igathinathane

Coal is the most widely used fossil fuel in the world, providing more than 25% of world?s electrical power. Since, the behavior of coal particles in crushing and grinding circuits, concentration operations, and solid-liquid separations is strongly dependent on size, a reliable and accurate measurement of particle size and particle size distribution (PSD) is a vital aspect in coal cleaning. This paper presents a method for the characterization of ground coal particles using image analysis. We utilized a machine vision (MV) approach that used a document scanner as the imaging device and a user-coded ImageJ plug-in that processed the image and automated the PSD analysis and output results in textual and graphical forms. This approach used a sum of volumes (SVolume) as weighting factor for particle length as the primary dimension of analysis and was successfully applied to ground coal. The plug-in was further improved for computational performance in this study. Mechanical sieving (MS) was also used to compare the MV results. MV results showed that the PSD of ground coal followed a uni-modal normal distribution, and the log-normal plot against particle size exhibited a linear trend for most of the range. MS results, however, had three linear segments, when the width-based sieving results were transformed to lengths by applying the shape factor (width/length), but a definite deviation between the PSD plots was observed. This study demonstrates successful application of the MV SVolume approach for PSD analysis of ground coal, which can be extended to similar particulate minerals and products. Keywords: dimension, fiji, image j, image analysis, coal, particle size, plug-in

Sep 1, 2012

By G. K. Nimal Subasinghe

The establishment of grind size that optimally liberates the valuable mineral for efficient down-stream processing is of great importance for most mineral processing operations. Reasonably accurate comminution models as well as models of downstream separation processes may be found in the literature but their use in optimizing grind size is limited without an associated liberation model. In this work, an attempt has been made to address the above shortcoming by demonstrating how the effective parameters of the downstream flotation process may be predicted from the liberation characteristics based on the ore texture data for a disseminated nickel ore. In this regard, the liberation model based on linear intercept distributions of mineral and gangue proposed by King (1979) and its application to predict the flotation performance of an industrial plant demonstrated by Schaap (1979) may be considered useful contributions. However, while the model proposed by Schaap is simplistic enough, it is based on several assumptions due to the non-availability of intercept length measurements on the parent rock, in particular, on the extent of mineral exposure on the surface of comminuted particles. In this work, the linear mineral and gangue intercepts on polished specimens of a binary ore, comprising darker pentlandite as the valuable mineral and lighter barren host rock were measured using an image analyser. The resulting intercept distributions followed negative exponential distributions. Using the mean sizes of mineral and gangue intercepts, the proportion of liberated, compo-site and mineral occluded particles of a given size, the extent of mineral exposure on the surface of particles and their mean mineral contents were calculated using principles of renewal theory. The rock was then crushed and ground and different size fractions were floated. It has been shown that the parameters of observed recovery data based on 1st order kinetics such as the associated rate constant and ultimate recovery agrees well with those predicted from the quantities calculated above. This work has important practical implications since it can indicate variations in flotation performance arising from changes in mineralization within a large ore body.

Jan 1, 2014

By l. Bokányi, T. Varga

"The recycling of waste car tyres is a very important environmental task. The waste tyres usually are re-used or recycled by thermal processes like pyrolysis, gasification or incineration. The main problem associated with these processes is the sulphur content of waste tyres originated from the vulcanisation process, which pollutes the environment and the valuable products (i.e. pyrolysis oil) as well. In our research the desulphurisation of waste, mechanically prepared tyre sample was systematically investigated by the biosolubilisation with Acidithiobacillus thiooxidans, strain Karitas. Parallel, the experiments with sterile 9K nutrient medium were also carried out. It was found that the vulcanisation sulphur can be solubilised due to both the bio- and the chemical leaching, although the bioleaching is more effective. The solubilised vulcanisation sulphur then forms precipitates. The precipitates are forming in the bulk solution, as well as on the surface of rubber particles. The origin of the precipitates was investigated using XRD and scanning microscopy with micro probe. The origin of the precipitates is different: while in the process of the vulcanisation sulphur solubilisation with 9K medium the jarosite (KFe3+3(SO4)2(OH)6) forms, the course of the biosolubilisation with Acidithiobacillus ferrooxidans Karitas is accompanied by the formation of the jarosite and the halotrichite (FeAl2(SO4)4 · 22H2O) as well. The formation of the latter is the biomineralisation. The mechanisms of the bio- and chemical solubilisations are rather different as it was found and experimentally proved by several tests, and depends on the retention time of the solubilisation. Special efforts were done to elaborate the proper separation of the precipitates from rubber particles. Combination of intense dynamic stirring and recycling flotation process to remove the precipitates was applied for this purpose. The surface properties of synthetic jarosite were revealed using zeta-potential measurements at different pH and in presence of collectors. The parameters of the flotation were chosen based on the revealed surface properties of the precipitates. Finally, the sulphur recovery of the recycled rubber was achieved as low as <0.5%, sulphur content of it 0.17%, 12-times lower than that of the waste tyre sample after mechanical preparation."

Jan 1, 2018

By Y. Q. He

The dynamic behaviors of the air bubbles in the dense gas-solid fluidized bed have a significant effect on the performance of dry coal separation. The combined method of experimental measurement and numerical simulation were conducted to conduct the research of the mean diameters and rising velocities of the bubbles in the fluidized bed. The calculation models of mean diameter and rising velocity of the single bubble were proposed. The results indicate that the models of the mean diameter raised by Rowe (1976) and the rising velocity raised in this work could be used to predict the bubble dynamic parameters in gas-solid fluidized bed. With the Geldart B type of magnetite powder as the medium solids and while the gas velocity of 1.5Umf=U=2.2Umf, the mean bubble diameter along the bed height is 36mm<Db<45mm, and the mean rising velocity of the single bubble is distributed in 40~65cm/s. The results of experimental measurement, numerical simulation and model predication provide well agreements finally. Based on the uniform fluctuations of air bubbles diameters and their rising velocities, the separation experiments of 50~6mm dry coal using the mixture of 0.3~0.15mm magnetite powder and <1mm fine coal as medium solids were carried out. The results show that the probable error, E is 0.06, which indicates a good separation performance by using the gas-solid fluidized bed. Keywords: dense gas-solid fluidized bed, bubble dynamic behaviors, numerical simulation, separation performance

Sep 1, 2012

By D. Szyszka

During passing gas bubbles through mineral suspensions, some mechanical carryover of fine particles to the froth layer always takes place. The entrainment of mineral particles is influenced by many parameters, mostly by the particle size and the concentration of the frother. The paper deals with influence of selected frothers (methylisobutylcarbinol (MIBC), a-terpineol, and hexadecane tricosaethyleneglycol ether (C16E23)), common laboratory flotation frothers, on the mechanical car-ryover of quartz, a typical gangue mineral component of ores. Entrainment tests were carried out in a laboratory Mechanobr flotation machine with quartz particles suspended in aqueous frother solu-tions. The mechanical recovery of quartz in the presence frother was increasing with time and reached plateau after about 20 minutes of flotation. The plateau level of quartz recovery depended on the frother concentration. Initially an increase of the plateau with frother concentration was observed until the plateau reached the highest level called the maximum recovery emax. The emax can be used as a parameter to characterize the ability of frothers to entrainment. In the studied quartz-frother flotation system the maximum entrainment was 32%, 50% and 80% for methylisobu-tylcarbinol (MIBC), a-terpineol, and monohexadecane tricosaethylene glycol ether (C16E23), re-spectively. A comparison of the maximum entrainment factor emax with other, known from literature, indices such as bubble critical coalescence concentration (CCC), dynamic foamability index (DFI), Jw, e =25%revealed, except DFI, their similarity.

Jan 1, 2014

By Edgar Schach, Tom Leistner, Markus Buchmann, Urs A. Peuker, Martin Rudolph, Marius Kern

"In this study, the flotation characteristics of a cassiterite-bearing fine-grained and complex skarn ore from a deposit in the Ore Mountains is investigated. The tests are performed using an oil-assisted column flotation approach to process very fine ore fractions and avoid losses of cassiterite into the tailings. First, process parameters are obtained for a finely ground artificial mixture of quartz, magnetite and cassiterite, simulating the real ore. Thereby, magnetite is used, as iron oxides can have a detrimental effect on the flotation due to a similar flotation behavior. In addition, they can act as a source of multivalent ions, which are known to reduce the concentration of collector molecules, active for flotation. Based on the results, selected parameters are further tested for cassiterite skarn ore from the Hämmerlein deposit including a pre-conditioning and a water exchange step to remove ionic contaminants. The process response is analyzed in detail by XRF (X-ray fluorescence) and MLA (mineral liberation analysis) to get a better understanding of the behavior of the single ore components. Sulfosuccinamate type surfactant is utilized as the collector, emulsifier and to reduce the froth destabilization through nonpolar oil. Sodium hexafluorosilicate is added as the depressant.INTRODUCTION Complex skarn ore deposits containing considerable amounts of tin, indium and other metals are located in the Ore Mountains region (Germany). In this study, a skarn ore from the Hämmerlein deposit was investigated. Due to the finely disseminated nature of this ore, past beneficiation attempts failed, and the ore was considered economically unprocessable. However, increasing resource demands brings it back into focus (Schuppan and Hiller, 2012). Cassiterite is the main tin bearing mineral in this ore. Due to its high density (~7 g/cm³), the predominant beneficiation technique is gravity separation (Angadi et al., 2015). Tin ores from disseminated deposits have to be extensively comminuted to reach a sufficient degree of liberation of the cassiterite grains. As cassiterite has a brittle nature, it is preferable enriched in small size fractions, during comminution (Angadi et al., 2015). Gravity separation methods become more and more inefficient for particles smaller 40 µm (Falcon, 1982), causing tin losses of up to 30 to 40wt.-% (Angadi et al., 2015). Thus, froth flotation of cassiterite was first utilized in Altenberg in the Ore Mountains as an additional processing step to reduce the cassiterite losses into gravity separation tailings (Bulatovic, 2010; Gruner and Bilsing, 1992). Although the reported lower size limits for an effective cassiterite floatability are often smaller compared to other minerals, the flotation performance is in general decreasing for small particle sizes < 10 µm (Trahar and Warren, 1976). Therefore, different approaches have been already investigated for the flotation of such fine cassiterite fractions to overcome the limits in particle size. Bilgen et al. investigated the shear flocculation of cassiterite with a sulfosuccinamate collector (Bilgen et al., 1994). The agglomeration flotation of cassiterite has been tested by Schubert et al. (Schubert et al., 1966), in which the selective coagulation of fine hydrophobic particles and oil droplets leads to an increase of the effective particle size. Recently, Leistner at al. investigated an oil-assisted agglomeration flotation for ultra-fine cassiterite ore fractions (Leistner et al., 2016). However, a poor response due to an increased concentration of Fe and Ca ions, unselective oil/gangue coagulation and froth instability, that is caused by oil/frother interactions, has been observed."

Jan 1, 2018

"The Circular Economy (CE) will play an important role in shaping a resource-efficient society. Enabling this transformation from a linear to a CE requires precise quantification of resource efficiency and thus the economic viability of the system. Based on the development of simulation tools of classical minerals processing and process metallurgy, the Outotec (2018) HSC simulation platform could be further developed (gleaning from many academically published works of the author listed below), permitting the simulation of the CE system and to subsequently calculate its resource efficiency. It enables the estimation of a simulation-based Recycling Index (RI) from a product’s Bill of Material (BoM) and Full Material Declaration (FMD). It is a unique methodology for Design for Recycling (DfR) based on minerals engineering linked to a deep understanding of minerals and metallurgical process engineering. A key to this simulation is a detailed understanding of the mineralogy (both geological and designed) of the CE system and its many products, materials and systems, both in a geological mineral and a product-designer-mineral sense. In addition, a detailed understanding and quantification of the thermodynamic properties of the system (both energy and exergy/entropy) is key to understanding its economics and its limitations. With this approach, the actual losses of the CE system are shown and thus highlights the limits of the CE as defined by minerals and metallurgical process engineering principles. INTRODUCTION From the dawn of the industrial era up to today, many of our products have been created according to the principles of a linear economy: we find resources, make a product, and then dispose of it when we are done using it. But in recent years, there has been a growing awareness of the need to move to a Circular Economy (CE), an approach that aims to maximize the usefulness of products, components and materials across the entire lifecycle. In terms of recycling, this means achieving maximum recovery of materials once products reach the end of their usable life while also maximizing resource efficiency. Of importance is therefore also not only the recovery of critical technology elements that make the CE system run, but also the criticality of the metallurgical infrastructure that must be present to recover these elements economically. Ellen Macarthur (2017) defines the CE as “Looking beyond the current ""take, make and dispose” extractive industrial model, the circular economy is restorative and regenerative by design. Relying on system-wide innovation, it aims to redefine products and services to design waste out, while minimising negative impacts. Underpinned by a transition to renewable energy sources, the circular model builds economic, natural and social capital.” However, when translating this significant message to images, it is striking that the key extractive industry is not depicted in the Ellen Macarthur as well as EU depiction of a CE (EU 2015). Other CE discussions are also wanting in their fundamental detail and description e.g. Accenture (2015) and Beaulieu et al. (2016)."

Jan 1, 2018

By Petrus van Staden, Dragan Milanovic, Francisco Sánchez, Eero Kolehmainen, Carlos Frias

"Currently there is no economical and viable process for on-site metal extraction from Low Grade, Complex or Poly-metallic deposits, and even more, there is not any industrial process or technology able to deal with polymetallic or bulk concentrates containing Cu+Zn+Pb base metals and also precious metals. Traditionally, metals recovery from polymetallic sulfide deposits is performed by mining, selective flotation to separate Cu, Pb and Zn concentrates, and finally, smelting/refining of those concentrates to obtain the refined metals. In many cases, selective flotation of that kind of complex ores produces low metals recovery and low concentrate quality containing impurities such as Hg, As, Bi, etc., which results in high penalties in treatment and refining charges, and consequently, worsening the economy of the mining business. Recovery of the valuable metals from Polymetallic, Complex or Low Grade ores could then be maximised by producing bulk concentrates or middling flotation products to feed novel hydrometallurgical processes, like the integral metallurgical system that is currently under development within the INTMET project. For example, producing bulk concentrates would increase more than 100% Cu+ Zn+Pb cumulative recovery versus conventional selective flotation. Founded by the Horizon-2020 EU Programme, the INTMET Project was started in February 2016 and will be running over three years. The INTMET consortium is led by Cobre Las Cruces (Spain) and integrates twelve partners from seven EU countries, and including Serbia and South Africa as well. The INTMET project represents a challenging opportunity to develop suitable technological solutions to deal efficiently with difficult, polymetallic and complex sulphide ores that are abundant in Europe and worldwide. Main activities carried out during the first 18 months of the INTMET project development includes: (i) An atmospheric leaching pilot plant having a capacity of 300 kg/h bulk concentrate which has been installed and operated continuously for nine months at the Las Cruces mine; (ii) Pressure leaching test work developed by Outotec; (iii) Bioleaching test work performed by Mintek in collaboration with MMI Bor. Prior test work was applied on bulk concentrate samples supplied from Spain, Portugal and Serbia. Some of the results of these technological developments have been very positive and are presented in this paper."

Jan 1, 2018

By Larry A. Cramer

"Three primary drivers are setting the trend for base and precious metal processing . they are: continued low real base metal prices, environmental concerns, and continued high prices for PGM.s. Low base metal prices are increasing the search for economies of scale and company consolidation as well as the development of some hydrometallurgical technologies. Environmental concerns are pushing for continued reductions in SO2 emissions and hydrometallurgical technologies. The high prices for PGM.s are driving major expansions and a focus on minerals processing recoveries and, to a lesser extent, reductions in the refining metal lockup.In nickel, HPAL operations on laterites have failed economically but Inco is still pursuing some alternatives. BHP-Billiton and others are developing bioleaching alternatives for nickel laterites and sulphides.Copper continues to be dominated by the hydrometallurgical and pyrometallurgical debate; new hydrometallurgical developments are being tested at several sites whilst the pyrometallurgists continue to make competitive cost and environmental improvements.Gold processing developments are dominated by the use of improved gravity recovery equipment and by the development of thiosulphate as a more environmentally acceptable lixiviant.PGM processing trends are the use of fine grinding technologies, higher power input flotation cells, and new pyrometallurgical technologies. Hydrometallurgical options for some applications are being sought.OVERVIEW The metals industry has remained under price pressure for some time; low and decreasing real prices for most metals have become an expected scenario. Occasional price spikes give some relief but invariably bring expansions and new entrants into an already oversupplied commodity market, thus leading to the continued price pressure. Technical innovation, economies of scale, and improved work systems are continually sought, so as to improve the competitive position of each individual company in such a climate; however, these developments add to the downward price pressure. In such a situation the application of scarce funds to research and development is a difficult task. Excess funding is not available in tight economic times and yet the main route to higher profits is clearly the application of technical developments to lower the cost of producing a metal commodity. Many technical centers have closed as a cost saving exercise and some have coalesced to obtain economies of scale. The Australian based AMIRA research organisation has grown to serve the R&D part of the market well in Australia and in South Africa by acting as the catalyst to form research partnerships between a number of industry players and as an administrator to direct the funding of research projects towards the various applicable research institutions. AMIRA has developed closer ties to Camiro (Canadian Mining Research Organisation) through the appointment of Camiro.s metallurgical processing research director as AMIRA.s North American based director. AMIRA is continuing discussions with MIRO (Minerals Industry Research Organisation) in regard to a merger, with a report outlining the merger proposal expected in March of 2003. Company focused research centers continue to be effective at Anglo American Research Labs, Teck-Cominco Research, Falconbridge Research center, Inco Research and some others."

Jan 1, 2003

By G. Rajesh

Mathematical modeling of bioremediation has gained importance as it is used as an optimization tool for the remediation process involved in contaminated sites. The bioremediation of Cr(VI) has been studied taking into consideration the initial Cr(VI) concentration Cr(VI)ini, bacterial growth substrate concentration (S), maximum growth rate (µmax), yield coefficient (Y), half saturation constant (Ks), and inhibition constant (KI). As the enzymatic reaction is also affected by initial substrate concentration (Sini) and Ks, different ratios of (Ks/Sini) are analyzed. As the inhibition constant (KI) is not constant for all the enzyme reactions and it varies with Cr(VI)ini, the correlation between (KI) and Cr(VI)ini is developed. A set of differential equations pertaining to bioremediation of Cr(VI) has been solved using FORTRAN 90 program adopting the model developed. The results are verified with the experimental data from the literature and a good correlation has been obtained between the experimental data and the model predictions. Keywords: bioremediation, hexavalent chromium, mathematical model, inhibition kinetics

Sep 1, 2012

By Fengnian Shi

In the current energy-sensitive world, sustainable development in the mineral industry will require new, better and more efficient processes. Novel comminution methods, which offer the prospect of achieving the required outcomes of size reduction and mineral liberation at lower energy consumption, are continually being sought. In the past five years, extensive research using high voltage pulse electrical comminution technology has been carried out at the Julius Kruttschnitt Mineral Research Centre (JKMRC), in collaboration with selFrag AG. The major outcome of this research is the development of the concept of pre-weakening ore particles by electrical comminution procedures to reduce the energy consumption in the downstream grinding circuit. The research has also verified the preferential liberation of valuable minerals by electrical comminution. Given the advantages, several potential applications of electrical comminution in the mineral industry are proposed, including AG/SAG mill feed pre-weakening, pebble treatment, ball mill feed pre-weakening, early recovery of the liberated valuable minerals, crack/micro crack generation for improved leaching, and smelter slag treatment. For the mineral industry to utilize electrical comminution, two emerging issues identified from the research need to be address. They are the energy consumption by electrical comminution in the locked cycle treatment and the facilities scale up necessary to move this technology from the laboratory to the plant. Keywords: high voltage pulses, electrical comminution, energy efficiency, mineral liberation

Sep 1, 2012

By Peter Scales, Ricardo Jeldres, Fernando Concha, Pedro Toledo, Shane Usher, Anthony Stickland

The impact of several electrolytes present in seawater on the rheological properties of flocculated mineral suspensions was assessed using the creep test. Flocculated suspensions were obtained by adding polymer flocculant to a cylinder of mineral suspension and aggregating the suspension using the plunger method. The suspension was allowed to sediment and the supernatant liquid decanted prior to tests for the viscoelastic properties of the resulting sediment. The solid used was alumina AKP-30 both, below and above the isoelectric point. The polymer used was AN934SH, an anionic flocculant with high molecular weight. Salts analyzed were MgCl2, CaCl2 and NaCl, known as water structure makers, and KI and KCl, known as water structure breakers. A high salt concentration of 0.5 M was used to approach the ionic strength of seawater. For both pH’s studied, the sediments demonstrated a viscoelastic non-linear behavior observed as a non-linear relationship between yield strain and applied stress. In the absence of flocculant, it was observed that the viscosity and yield stress of a suspension increase in the presence of structure maker salts for the case of both silica suspensions and alumina suspensions. These results were explained using hypernetted chain statistical mechanics models describing the interaction of ions with solvated surfaces. In contrast, with the presence of flocculant, the shear yield strain of alumina suspensions increases with the breaker character of the salts, however, this result has been explained by an extension of the results from the models. The work has significant implications for the flocculation of mineral suspensions in the presence of seawater.

Jan 1, 2014

By E. V. Bratygin, E. G. Dmitrieva

The aim of the research was to study the thermodynamic characteristics of high-temperature processing of ilmenite concentrate deposits "Central" in a neutral and oxidizing atmosphere, as well as its interaction with alkaline additives. The research was conducted using a scanning colonoscopy on thermogravimetrical analyzer NETZSCH STA 449 F3. A sample of the test material weighing 10 mg was placed in a crucible and heated at a rate of 10 °C/min to 1200 °C in argon or air. Studies have been conducted pure ilmenite concentrate and its mixtures with 5 % and 12.5% of sodium carbonate. The results of the analysis of the thermogravimetric curves it was found that the recovery of the concentrate carbon will come from ulvospinel, not pseudobrookite, and the reaction recovery is possible at temperatures above 900°C. While removing produced in the decay ilmenorutile of iron oxides in an inactive form, for example, iron (III) oxide, it is possible to reduce the quantity of the solution of ilmenite formed during the restoration of the melt anosovite. The analysis of data obtained during heating of ilmenite concentrate with sodium carbonate in concentrations of 5 and 12.5% transition pseudobrookite in ulvospinel is missing, it just breaks down into hematite and titanium oxide, which, in turn, react with N?2??3. It should be noted that increasing the concentration of sodium carbonate in the sample contributes to more complete interaction of iron oxides and N?2??3 with formation of ferrites of sodium. This can ensure full recovery of iron oxides in the concentrate, which is part of secondary ilmenite can not be dissolved in the melt formed by the lower oxides of titanium. In addition, the increase in the content of soda in the mixture significantly reduces the temperature of the initial melting point of the slag and facilitates the coagulation of metallic iron.The obtained results were used for laboratory studies of the solid-phase sintering of briquettes from ilmenite concentrate with additives of sodium carbonate and a reducing – coal, as well as for the development of technological mode of solid-phase sintering of the concentrate with the aim of obtaining product recovery with a titanium dioxide content of more than 75 %.

Jan 1, 2018

By Bruno Michaux, Markus Reuter, Martin Rudolph

"It is relatively well-established in the literature that the flotation of calcium minerals using fatty acids as collector is very sensitive to the process water composition. In particular, hard waters have often been reported to strongly reduce the target mineral recoveries due to the formation of insoluble compounds such as calcium and / or magnesium dioleate, thus reducing the amount of collector available for adsorption onto the mineral surface. In this study, the flotation of a fluorite pre-concentrate was performed with tall oil, an industrial collector essentially containing fatty acids. The tests were performed in a variety of synthetic waters to simulate multiple degrees of water hardness, and to differentiate the role of magnesium and calcium ions on the flotation performance. The flotation tests revealed that, under the studied conditions, a significant difference between flotation in calcium-rich and magnesium-rich waters was observed, suggesting strong ion-specific effects in the system. Specifically, calcium-rich waters slightly improved the fluorite recovery, whereas magnesium-rich waters caused a decrease in recovery by as much as 20%. This paper is focused on the flotation kinetics aspect of the system. This approach highlighted the interesting finding that calcium ions did not simply increase the fluorite recovery, but also significantly increased its flotation kinetics. The magnesium ions, on the other hand, had the exact opposite effect.INTRODUCTIONAs the mining industry is facing an increasing number of issues related to its fresh water consumption, the idea of using alternative water sources for mineral beneficiation is gaining significant momentum. As a result, a proper understanding of the role of water chemistry in flotation is becoming more and more urgent, leading to an increasing number of studies on this topic."

Jan 1, 2018

By Lei Pan, Roe-Hoan Yoon

"Direct force measurement for bubble-particle interaction has been difficult due to bubble deformation, which makes it difficult to know the separation distances between the two macroscopic surfaces. In the present work, we have developed a method of monitoring the deformation accurately, while directly measuring the interaction forces. In effect, we can ‘see’ bubbles interacting with mineral surfaces under different hydrodynamic and chemical conditions and determine both the hydrodynamic and surface forces involved. In the present work, a high-speed camera has been used to record the optical interference fringes of a thin liquid film (TLF) of water formed on a mineral surface. The recorded fringes are then used to reconstruct the spatiotemporal profiles, from which one can determine the hydrodynamic pressure using the Reynolds lubrications theory. From the forces directly measured in the present work and the hydrodynamic pressures obtained from the fringes, we have determined the disjoining pressure. The results show that air bubbles interacting with hydrophilic surfaces form stable TLFs with zero contact angles. The TLF formed on a hydrophobic surface thins fast, form a ‘pimpled’ film, and ruptures to form a finite contact angle. The new information obtained in the present work may be useful to better understand the role of hydrodynamic and surface forces affecting bubble-particle interactions."

Jan 1, 2014

By Sepideh Javanshir

The process of liquid?liquid extraction of gold from chloride solution is complicated by the presence of many variables acting simultaneously in an unknown non-linear fashion for the determination of the final extraction efficiency. In practice, it is quite difficult to develop a model for predicting various properties of such process. Therefore, an alternative approach based on Artificial Neural Network (ANN) is considered to assist in the simulation process. Artificial neural networks (ANN) are powerful tools that can be used to model and investigate various highly complex and non-linear phenomena. This paper presents application of Multi-Layer Perceptions (MLP) to construct relationship that will be employed to develop a quantitative method for the estimation of the extraction efficiency as a function of hydrodynamical parameters such as stirrer speed, [AuCl4]- and DBC concentration, organic and aqueous flow rate. The model is shown to be in excellent agreement with the experimental data (R2 value for training and testing data was 0.9992 and 0.9915 respectively). Therefore, it can be used to optimize the parameters of liquid?liquid gold extraction with dibutyl carbitol (DBC).

Sep 1, 2012