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By V Radmehr

Ammonia and Amonium salts have been recognized as effective leaching agents in hydrometallurgical processes due to low toxicity and cost, easy recovery and high selective recovery of metals. New research findings of considerable advantages of leaching by these agents and elimination of problems associated with acid leaching has resulted in a new approach in the world to this method. The investigations in this field indicate more frequent use of this method for extracting copper from ore and concentrate relative to other basic metals. In this paper, we have attempted to describe the basis and different ammonia leaching methods and present the major research activities in this field for copper. We have also presented the latest findings and related novel processes. Comparative assessment of advantages and disadvantages of this method relative to acid leaching method, kinetic study of copper ammonia leaching and evaluation of Eh-pH diagrams in a system containing water and ammonia are other parts of our study. Finally, by describing the studies on copper extraction from the resulting pregnant solutions, the applicable extraction agents have been reviewed.

Sep 1, 2012

By M. Pelser, C Aldrich

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.Several processes are reviewed for the control of calcium and magnesium. Of these, fluoride precipitation was selected for experimental investigation. This method involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments showed high selectivity for calcium and magnesium over the base metals. The experiments also showed magnesium precipitation to dominate for calcium to magnesium molar ratios greater than 1:3.To avoid the domination of magnesium precipitation, a flow sheet is proposed whereby only a portion of the base metal stream is subjected to fluoride precipitation. For the precipitation, a 10% excess of ammonium fluoride is used to remove the maximum amount of calcium and magnesium. After precipitation and solid-liquid separation the split-stream is returned to reduce the overall calcium and magnesium concentration of the base metal stream."

Jan 1, 2003

By Fiona Sofra, Briony C. Ruse, David B. Boger

"The sustainability of the mining industry must be addressed through improving tailings management. The use of thickened tailings and pastes stems from a paradigm shift towards designing tailings disposal sites to suit their surrounding environment, rather than manipulating the environment to accommodate the tailings. Thickened tailings and pastes usually exhibit non-Newtonian behaviour, so a thorough understanding of the rheological characteristics of the material is required in order to determine the disposal plant operating conditions.Full Cost Accounting techniques may be used to provide financial justification for the implementation of alternative tailings disposal techniques through the calculation of a disposal cost per tonne of tailings over the life of the facility. Improved disposal methods such as thickened tailings disposal involve additional initial capital expenditure but reduce environmental impacts. The cost savings associated with environmental impact mitigation are reflected in Full Cost Accounting outcomes.Rheological characterisation is significant as a design basis that may be analysed using Full Cost Accounting to justify the initial capital expenditure of dry disposal systems for improved environmental performance."

Jan 1, 2003

Copper nickel separation is performed by mineral processing techniques both pre and post smelting in Copper Cliff at Vale Canada?s Operations. The separation at Clarabelle Mill takes advantage of the ore mineralogy to affect a separation on the rougher concentrate where chalcopyrite and pentlandite exhibit high liberation and high recoveries thus their separation is simple although incomplete. The copper concentrate comprises only 50% of the copper in ore with the remaining copper being separated post smelting in the Matte Separation plant where the slow cooled Bessemer Matte is again treated by mineral processing operations using flotation to separate the chalcocite and heazlewoodite and magnetic separators to remove a metallic nickel alloy. This paper discusses the mineralogy, separation processes and work currently underway to improve the separation of copper from nickel in these plants.

Sep 1, 2012

By Massimiliano Zanin, William Skinner, Owusu Clement, Jonas Addai-Mensah, Daniel Fornasiero

This paper highlights the importance of pulp aeration in the selective separation of chalcopyrite from chalcopyrite/pyrite mixtures of varying pyrite content (20-80 wt.%). Laboratory batch flotation studies and oxygen demand tests were performed to predict the optimum amount of air required for the selective separation of chalcopyrite from pyrite. The pulp oxygen demand was shown to increase with increasing pyrite content but decrease with time as more air is introduced into the system. Complementary batch flotation tests showed significant improvement in chalcopyrite flotation under moderate pre-aeration of the pulp. However, a continuous decrease of chalcopyrite flotation was observed under highly aerated conditions. The amount of air required to achieve maximum chalcopyrite flotation recovery correlated positively with the mass fraction of pyrite in the pulps. The greater the wt.% of pyrite in the chalcopyrite/pyrite pulp, the longer the aeration time required. The optimum aeration time was established as the time before which the oxygen consumption rate constant reaches a bottom plateau. Surface analysis (XPS) indicated that the continuous decrease in pyrite recovery observed with increasing aeration time was due to the formation of more iron oxy/hydroxide on its surfaces, the same species accounting for the decrease in Cp recovery after prolonged aeration.

Jan 1, 2014

By N. V. Ramana Murthy

Utilisation of Low-Grade Iron Ore Fines after concentration not only helps in conservation of the mineral wealth, but also substantialsly improves the economics of iron ore mining. There has been need to develop suitable beneficiation process for upgradation of low-grade iron ores towards their rational utilisation. Presently the circuit adopted for processing iron ores has limitations in reduction of alumina. The depletion of high-grade reserves, utilisation of low-grade reserves coupled with in-creasing market pressure for improved product quality necessitates re-examination of the process flow sheets and evaluate alternative or supplemental processing routes. The main objective of the Process amenability studies for utilisation of Low-Grade Iron Ore Fines (-10mm) is to get Pellet grade concentrate with +65% Fe (min), SiO2 1.8% (max), Al2O3 1.8% (max) and other proportionate constituents by adopting suitable beneficiation techniques and to collect the relevant data (Quality and Quantity of the Products) for the process development. In an effort to formulate a conceptual process flow sheet, the Process amenability studies for utilisation of Low-Grade Iron Ore Fines (-10mm), which is lying at a mine site in India, samples were collected and taken up for the study. The efforts of R & D of NMDC are discussed in this paper. Low-Grade Iron Ore Fines (-10mm) sample assayed 60.10% Fe with 3.48% SiO2 Aland 4.48% 2O3from 40 microns to 300 microns. The sample consists of hematite as the chief ore mineral followed by minor amounts of maghemite. The gangue minerals include quartz and ferruginous clay in which quartz occurs as medium grained where as ferruginous clay occurs as fine to sub microscopic size mineral. The economical processing route evolved out of the studies finally could yield a final concentrate constituting 58.63% by weight along with Iron unit?s recovery of 63.51% assaying 65.10% Fe with 1.48% SiO2 and 1.85% Al2O3route that adopted comprises the following operations. Making slurry in a sump pump followed by grinding in close circuit with 48mesh size Screen. The -48 mesh size product was subjected o the Cycloning to remove slimes. The Cyclone Underflow product was subjected to Floatex Density Separation (FDS) to separate fine heavy minerals from the gangue minerals. The FDS Underflow was collected as concentrate. The FDS Overflow product was further subjected with Wet High Intensity Magnetic Separation (WHIMS) to recover more Iron units as magnetics. A conceptual process flow sheet was evolved, which may become the prelude to the subsequent finalisation of the process flow sheet for commercialisation.

Jan 1, 2014

By Yuhua Wang, Haitao Zheng, Guangli Zhu, Yuehao Zhao, Fushun Yu, Dongfang Lu

"Spodumene, feldspar and quartz possess similar surface properties, which make the difficult to separate spodumene from other silicate minerals by flotation. The differences of crystal structure, surface property and floatability of three minerals were studied by various technical means. The results show that Li-O and Al-O bonds in spodumene structure are not strong and easy to be broken. However, Al-O and Si-O bonds in feldspar and Si-O bond in quartz are very strong and not easy to be broken. High contents of Al and Li on spodumene surface were found by XPS measurements, which is benefit for the adsorption of anionic collector. The surface energies of main cleavage planes of spodumene (110), feldspar (001) and quartz (001) are 1.88 J/m2, 2.97J/m2 and 2.68J/m2, respectively. Hence, the exposed surfaces of feldspar and quartz are not saturated and easy to adsorb OH- ions from solution and cause the lower IEP than spodumene. The contact angles of three minerals in water are lower than 16º, suggesting that the hydrophilicity of three minerals is high, and the order of hydrophilicity is quartz > feldspar >spodumene. Correspondingly, contact angles and flotation recoveries of spodumene are bigger than that of feldspar and quartz in presence of a combined anionic and cationic collector named YOA.INTRODUCTION Flotation technology plays most important role for the recovery of spodumene from pegmatite ore. Generally, spodumene with fresh surface is easy to be floated using soap and oleic acid as collector, and the best flotation pH range is 4.0 to 9.0. However, the flotability of spodumene will become worse when its surface was polluted by slime which produced by the weathering of spodumene and other silicates (Dresler et al. 1998; Moon and Fuerstenau 2003; Menéndez et al. 2004; Yu et al. 2015). In addition, the species of Ca2+, Fe3+, Mg2+ and other metal ions in pulp can not only activate the flotation of spodumene, but also the activation of gangue minerals, and then the flotation selectivity of spodumene from gangue minerals became wores (Wang and Yu 2007; Yu et al. 2014). In order to eliminate the negative effects of slime and metal ions on the flotation of spoddumene, the desliming and long time scrubbing with the addition of NaOH and Na2CO3 were adopted. Usually, NaOH shows the activation for spodumene flotation, and the recovery of spodumene increases with the increase of NaOH dosage. Na2CO3 can eliminate the non selective activation of Ca2+, Fe3+, Mg2+ ions in the pulp, and the concentrate grade of spodumene increases with the increase of Na2CO3 dosage. Anionic collectors such as chelants, hydroxamic acid, oxidized paraffin soap, naphthenic acid and oleic acid were widely used for the flotation of spodumene (Dresler et al. 1998; Moon and Fuerstenau 2003; Menéndez et al. 2004; Yu et al. 2015)."

Jan 1, 2018

By M. Ghiani, R. Peretti, S. di Giovanni, G. Zonnedda, A. Serci, A. Zucca

"Beneficiation of the epithermal gold mineralizations associated with an extensive alteration zone in the Serrenti-Furtei region on the island of Sardinia, is proving a complex issue. Experimental investigations have in fact demonstrated that while the ores contained in the upper parts of the deposit are amenable to conventional cyanidation, the gold contained in the refractory ores in the lower portions needs to be recovered by means of flotation, combined with leaching where necessary.The results of commercial heap leaching, carbon-in-leach (CIL) processing and flotation, designed on the basis of the experimental findings and applied to the oxidized portions and transition zones of the deep sulphide mineralizations, confirmed the expectations emerging from the laboratory tests."

Jan 1, 2003

By Pat Turner, Abrie Schutte, Tim Olson, Roman van Ommen

The key to good cyclone circuit design and operation in primary grinding circuits will be discussed. Cyclone circuit design issues include individual cyclone design features such as cone angle or materials of construction, as well as orientation and manifold configuration. Cyclone performance issues as well as maintenance considerations will be detailed in an effort to achieve consistent cyclone operation with minimal coarse solids in the overflow. The new gMAXTM. cyclones will be introduced and evaluated using operating circuit data in closed circuit grinding applications

Jan 1, 2003

Over the last four years, a major collaboration between CSIRO-MIS, UCT and JKMRC has produced two significant advances in the modelling of comminution. The Universal Comminution Model (UCM) uses parametric SPH/DEM studies of comminution and separation devices to calibrate mathematical models which are suitable for industrial use. The Virtual Comminution Machine (VCM) uses the same computationally intensive techniques based on discrete element modelling (DEM) and smoothed particle hydrodynamics (SPH) to directly model any comminution device by combining a CAD file describing the machine design, sophisticated ore characterisation methods and advanced particle scale flow and breakage simulation. The UCM should be useful for process analysis and optimisation of existing equipment and circuits while the VCM should make a major contribution to the evaluation and development of new machines. Progress to date is encouraging with several processes now well described using DEM. This paper also reports on progress towards combining DEM for particles with a realistic slurry model based on SPH for different types of comminution devices. In due course, this combination should allow accurate modelling of particle transport in wet mills to be combined with DEM models.

Jan 1, 2014

By I. Gombköto

To sustain the growth of industrial production necessitates the increasing of the amount of processed mined raw and secondary materials. As a side effect of raw material production, the amount of tailings material, - coming from mineral processing operations ? increases as well. Using wet technology, these tailing materials are generally transported and stored with the water used for previous operations. This habit could lead to dangerous situations. Enough to remember the disasters had happened to the last decade, safe tailings operations need to remove as much water from the solid as possible. Environmental, technical and economical needs should meet, therefore using a technology combining these specific needs could be necessary. Paste technology was introduced generally into tailings operations at the last ten years, as an answer to the call of the above mentioned challenges, however there are still many questions to answer within the frame of using it. The Institute of Raw Materials Processing and Environmental Process Engineering of the University of Miskolc has been dealing with mechanical process engineering, especially by the support of the EU project TAILSAFE Contract nº EVG1-CT-2002-0066 and the NKFP 3A/068/2004 Hungarian fund extensive research has been carried out about paste technology. Different test methods and materials were applied. Tested tailings materials were as follows: different fly ashes from coal power plants from Pécs ? Hungary, Gyöngyös ? Hungary, Neyvil ? India, different Croatian ashes, hazardous waste incineration plant ashes from Dorog ? Hungary, different kind of sands from Hungary, fine glass sand from Fehérvárcsúrgó ? Hungary, flotation ore processing tailing from Gyöngyösoroszi ? Hungary. Different additives, as gypsum, bentonite and cement were tested as well. The applied test methods were as follows: physical material testing (laser sizer, piknometer, different microscopes), X-ray diffraction analysis, settling columns, the three measuring pipes tube viscometer (16~27 mm pipe diameter), a hydraulic test loop with different pumps (40~53 mm pipe diameter, 0.2~4 m/s average slurry velocity range, 0%~52 % volumetric concentration range), rotational viscometer, Cassagrande yield locus tester and the slump cone test. This paper summarizes and systematizes the results of the aforementioned research as well as reports about the developed paste pipe transport design method based on the fine suspension ? coarse mixture model. The paper also reports about a systematic experimental series with different materials to establish criteria when high concentration suspensions behave like paste.

Jan 1, 2014

By Peter Ay, Elena Geldt, Satyanarayana Narra, Claudia Glaser

"As part of an extensive research and development project, the technical and technological implementation of the patents DE 10 358 245 B4 and WO/2006/056172 was developed with the goal to present a system for the innovative roll- agglomeration method exhibiting a) a modular setup, b) high productivity and c) suitability for the use of fibres of different applications and product qualities (high technical availability). The processability of the rarely adapted raw fibre materials into high-value intermediates brings forward their application in various processing industries dealing with the production of fibre reinforced plastic composites, heat and sound insulation materials as well as with the gas and liquid cleaning systems. The innovative fibre agglomeration presented in this work is performed by a combination of rolling and pressing the fibres inside a geometrically pre-defined roller table, in which the fibres are forced to bound through entanglement / interlocking and develop into agglomerate. The agglomeration process is carried out in a circular roller path with a rectangular cross-section. For improving the adhesive properties, and thus the quality of the agglomerates, the boundary surfaces can be covered / patterned / lined / coated with various materials. The resulting roll-agglomerates are characterized by different quality parameters such as mass, shape, porosity and stability. The properties of the agglomerates can be modified based on the end-product requirements by slightly modifying the process parameters such as filling ratio, residence time, roll-geometry, procurement of the boundary surfaces, etc. as well as the input material properties such as fibre type, fibre fineness, fibre length, etc. This work carries extensive work on the roll-agglomeration system to assess the effectiveness and the variability based on the product specifications. Agglomerates were produced with wide variations of system parameters with varying roller table liners and based on evaluation of the produced agglomerates with respect to their mass, the geometrical dimensions, their porosity and stability."

Jan 1, 2014

By Kari Niiranen

LKAB (Luossavaara-Kiirunavaara AB) is operating iron ore mines, concentration plants and pelletizing plants in Northern Sweden. The largest of the apatite magnetite deposits and the mines are Kiirunavaara with annual production rate of approximately 27 Mt crude ore underground. LKAB produces two varieties of pellets: blast furnace pellets and direct reduction pellets (LKAB DR Oxide Pellets). Meanwhile the concentration process in a sequence of the low intensity magnetic separation (LIMS) and flotation at the concentration plant. In spring 2007 there were noticed great fluctuations of SiO2 grade in the crude ore. The high SiO2 grade is particularly problematic in the case of direct reduction pellets. In consequence, a project was started (called Silica in the Mine) to define exactly the problem related with silica and to find out, if possible, the reason for the great fluctuation of SiO2 grade in the crude ore going to the processing plant. A further target of this project was to develop a simplified method at the laboratory scale, to predict SiO2 grade in the magnetite concentrate in the future, but also predict the physical properties of the ore with respect to mineral processing. The essential stage of systematic characterization of the ore body for mineral processing properties is the estimation and simulation of different parameters from the laboratory scale to the large scale at the concentration plants using empirical data collected at the mineral processing by LKAB in Kiruna. Further a target was also to find useful physical parameters for mineral processing and implant those parameters into the existing geological 3D-model of the deposit. This information will be used for making prognosis of the future mining and the quality of the crude ore. It will also give better control and improve the production planning in the mine and the performance at the concentration plant in Kiruna concerning the decrease of the SiO2 grade of the magnetite concentrate.

Sep 1, 2012

By T. Khonthu

The purpose of this investigation was to evaluate the relationship between different milling procedures, viz. a ball mill and an IsaMill respectively, and the flotation performance of the different mill products. Two ores were used, viz. a base metal sulphide (BMS) and a platinum group mineral (PGM) UG2 ore. Flotation was used as a diagnostic to investigate whether the different milling procedures may have different effects of the floatability of the particles. The present study is part of a research programme investigating this question using a wide range of comminutiondevices and procedures. Similar particle size fractions from the different milling procedures were used in the flotation tests. The particles were characterized in terms of particle size distribution, morphology (using scanning electron microscopy and image analysis software) and rheology tests. The results have shown that in general when comparing similar feeds to flotation in terms of equivalent particle size distributions as indicated by the d80 value, the ball mill generally yielded better recoveries and grades in the case of the BMS and lower chromite recoveries in the case of the UG2 ore compared to the IsaMill. No significant differences were observed in the morphological or rheological characteristics of the particles subjected to the different milling procedures. Although the results appear to indicate that IsaMilling is less advantageous than ball milling in terms of the flotation performance for the two ores studied it should be emphasized that these results do not take into account the relative advantage which IsaMilling has over ball milling in terms of direct and indirect energy consumption and GHG emissions nor, most importantly, does it consider the platinum group element recoveries in the case of the UG2 which may have increased significantly as a result of the finer grind which the IsaMill produces after 4 passes compared to the ball mill after 64 min. Such results which will be reported is due course may show that the greater liberation expected after IsaMilling of the PGMs outweighs any disadvantages indicated in this study.

Sep 1, 2012

By David Dreisinger

"The leaching of base and precious metal ores and concentrates continues to progress in both laboratory study and industrial application. These developments are being driven by the need to respond to difficult ores and concentrates that are not amenable to conventional treatment. In many cases alternatives are being developed to conventional treatment (e.g. Pyrometallurgy) for technical and economic reasons.In this paper, a brief general review of some new developments in leaching will be followed by a more detailed explanation of three process developments that have either been industrially applied or are expected to be applied in a short time frame. The three processes to be reviewed in detail are the Mt. Gordon Copper Process, the Anglo American Corporation/University of British Columbia Copper Process and the PLATSOL Process. These leaching processes operate at low (90°C), medium (150°C) and high (220°C) temperature and are successful in quickly and completely extracting metal values from ores and concentrates."

Jan 1, 2003

By I. Grigoryeva, G. Voiloshnikov, V. Dementyev, N. Moskaeva, N. Voiloshnikova

"Adsorption processes with use of anion exchange resins are widely applied in the gold mining industry of Russia and the former Soviet Union. Anion exchange resin AM-2B and its analogs (with mixed basicity) are used as adsorbents. This paper focuses on the study of weak base anion exchange resin and its comparison with AM-2B resin. Different nature of the ion exchange groups of the adsorbents mentioned above provides essential differences in their properties both during adsorption and elution of gold and silver. Multistage gold elution and resin regeneration procedure is used for AM-2B resin whereas alkaline cyanide solution is used for weak base resin and allows for the reduction Capex and Opex in comparison with AM-2B resin. Anion exchange resins AM-2B and PuroGold S-992 were tested. Weak base resin is sensitive to pH of adsorption medium. Optimal pH value is 10.1-10.3 (at ?? >10.5 gold loading onto resin decreases dramatically). Adsorption isotherms for gold, silver, nonferrous metals, cyanide and thiocyanate ions from synthetic individual metal cyanide solutions were defined. Adsorption of all components onto PuroGold resin was lower than for ??-2? resin. Adsorption of metals from the solution with equal molar metal concentration (0.1 mg-equivalent/L of each metal) was also studied. The affinity of resins to cyanide metals complexes was established. Weak base resin has higher selectivity to gold in comparison with ??-2B resin and is less sensitive to ion composition of cyanide solution or pulp treated. Weak base resin was tested for gold recovery from gold ores. On the base of test results it was recommended to introduce this resin at some new plants in Russia. Commissioning and operation performance of gold plants confirmed efficiency of weak base resin use."

Jan 1, 2014

By P. Saha, D. M. Chakrabarti, J. P. Srivastavam, P. Bhattacharyya, B. R. Sarkhel, Banerjeem B.

The phosphatic soil deposit at the Sukulu hills region of Uganda contains 10-12% P2O5. The ore occurs as a naturally degraded soil deposit containing a very sticky slime composed of earthy lateritic minerals. Desliming of the ore, which is imperative for its further beneficiation, is an extremely difficult hurdle to overcome for its commercial utilisation. Earlier studies on samples of the same ore at the National Metallurgical Laboratory (NML) and abroad established that it was necessary to pass the ore through a series of three stages of desliming, each consisting of a step of vigorous attrition scrubbing followed by hydrocycloning, for effective elimination of the sticky slime. In the present paper an innovative use of the very strong shear-fields created inside a hydrocyclone has been discussed, that could effectively eliminate the stubborn slime from the ore. The standard design of the hydrocyclone was suitably modified to increase the shearing effect on the slurry. It was possible, through the application of this modified hydrocyclone, to not only totally eliminate all the stages of attrition scrubbing, but also to reduce the subsequent stages of hydrocycloning. The modified technique yielded a concentrate of grade comparable to that obtained by employing the earlier more complex flow sheet, with about 25% higher P2O5 recovery.

Jan 1, 2003

By O. Celep, H. Deveci, Ersin Y. Yazici, F. Ahlatci

"There are increasingly stricter environmental regulations imposed for use of cyanide leaching for the extraction of gold from ores. Alternative lixiviants to cyanide, preferably with low toxicity, have been extensively studied. Thiosulphate has emerged as one of the most suitable alternative leaching agent in place of cyanide due to its low toxicity and technical attributes e.g. fast leaching kinetics, high gold extractions from carbonaceous ores in particular. High solubility of most copper minerals in cyanide solutions results in low gold extractions due to excessively high consumption of cyanide. In contrast, low reactivity of copper minerals in thiosulphate solutions makes thiosulphate leaching potentially suitable alternative for treatment Cu-bearing gold ores. The extraction of gold/silver from a copper-bearing pyritic gold concentrate (62 g/t Au, 110 g/t Ag and 0.3% Cu) in thiosulphate solutions was investigated in this study. The concentrate is composed of predominantly quartz (25%) and pyrite (32.7%) as well as sphalerite (5.37%), galena (2.12%) and anglesite (1.13%). Other minor minerals are arsenopyrite, chalcopyrite, covellite and bournonite. Previous studies by the authors indicated that the concentrate did not respond well to cyanide leaching (i.e. 45-46% Au/Ag at 1 g/L NaCN). The effects of concentration of ammonia (0.2-1.5 M NH3), thiosulphate (0.1-0.75 M S2O3) and copper (0-20 mM CuSO4) on the extraction of gold and silver over 8 h. was investigated. Increasing the concentration of thiosulphate and ammonia substantially improved the rate and extent of gold leaching while high copper levels produced an adverse effect particularly at low concentration of thiosulphate (i.e. 0.1 M). Complete extraction of gold was achieved under suitable conditions. In contrast to gold, silver extractions remained consistently at low levels (i.e. 28%). These findings demonstrated that thiosulphate leaching could be used to achieve acceptable levels of gold extraction from the copper-bearing pyritic gold concentrate."

Jan 1, 2018

By Andrzej Wieniewski, Cezary Regula, Bozena Skorupska, Krystian Cichy

"In this paper, experiences from Polish non-ferrous metals ores enrichment plants in the copper and blende concentrates quality improvement are discussed. The blende concentrate being produced in ZGH Boleslaw S.A., with Zn content of about 54,5% is characterized by the relatively high magnesium content reaching a level of 1% resulting from the dolomite presence, while for the zinc production by electrowinning a concentrate in which magnesium content should not exceed 0,3% is required. The implemented new technology for the quality improvement of blende concentrate is based on the leaching of zinc concentrate with sulfuric acid aimed at dissolving of the contained dolomite, and then flotation of the leached concentrate. It allows to obtain a concentrate with magnesium content below 0,1% at the simultaneously increased zinc content to about 57,5%. In the paper, laboratory tests results on the development of optimal flotation flowsheet for the gypsum removal and the industrial tests results concerning the process optimization of this flotation are discussed. In turn, the copper concentrate being produced in Polish copper ore enrichment plants KGHM PM S.A., is characterized by the increased organic carbon content - above 8%. It creates problems with the smelting of this concentrate because of difficulties with the heat removal derived from the combustion of organic carbon in the flash smelting process. The implementation of segregating flotation to the industrial practice allows the effective production of two concentrates with the differentiated chemical compositions - a concentrate with increased copper content and reduced organic carbon content for the flash smelting process, and a concentrate with lower copper content and increased organic carbon content for the shaft smelting process. In the paper, conditions of the segregating flotation and the achieved results are described."

Jan 1, 2014

By C. Carrasco

"Over the last 30 years the average grade of mined ore bodies has significantly decreased while the proportion of waste removal has in many cases more than doubled. This has been identified as prime reason of a major increase in energy consumption and decrease in productivity across mining operation. Metal coarse preconcentration of ROM feed grades by size rejects low grade gangue/waste material in the size range of 10-100 mm prior to grinding, typically before primary crushing. This relies on propensity of metal to preferentially deport in the fine size fractions after breakage. Metal preconcentration by size has the potential to increase energy efficiency and therefore improve mining productivity on unit of metal basis. Results of an extensive belt cut sampling campaign conducted at a major Australian Au-Cu mine operation show that for some samples between 90% of Au and 80% of Cu is in 40% of the mass at -50 mm fraction. This indicates that low grade coarse material can be removed from the circuit, doubling feed grade at half of the tonnage and therefore improve energy efficiency per unit metal produced. This response, however presents significant variability in the same order as other processing attributes such as impact hardness and flotation recovery. This has led to development of geometallurgical laboratory tests using blast hole chips and drill core facilitating mapping and population of coarse metal preconcentration signatures in long term resources and short term production models. Preferential Cu deportment by size at drilling scale can be recognised, however scales up factors are required to transform laboratory results to production responses. At 50 % of mass the drilling products underestimate the belt cut responses by 20-30 %. Bulk sampling campaign with blast hole and drill core samples spatially related was also conducted to investigate in more detail the difference between production scale and drilling scale preconcentration responses."

Jan 1, 2014