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By G. G. Roy, R Shekhar

Pachuca tanks are extensively used for the cyanide leaching of gold and the carbonate leaching of uranium, processes in which oxygen mass transfer plays a very important role. Experiments were carried out to clarify the effect of design and operating parameters on oxygen mass transfer. Parameters such as the ratio of tank height to tank diameter, the ratio of draught-tube diameter to tank diameter and the tank design were found not to influence oxygen mass transfer. Results also showed that equal superficial gas velocities may be used as a criterion for scaling up oxygen mass transfer in both full-centre-column and free-air-lift Pachuca tanks with clear water. A volume-averaged, volumetric gas-liquid mass-transfer coefficient (k'av) was used to characterise oxygen mass transfer in full-centre-column tanks. The axial dispersion model was used to determine k'av. The resulting model used only tank geometry and air flow rate as inputs for the prediction of k'av in industrial-scale tanks. Predictions from the model show clearly that "local" mass-transfer coefficients, measured at one or two locations, may not adequately represent gas-liquid mass transfer in industrial tanks. It is therefore necessary to obtain an estimate of k'av

Jun 18, 1905

By J. Plant

Stream-sediment sampling undertaken to define the regional geochemistry of northern Scotland is described with particular reference to the errors involved. The region is underlain essentially by Moine schists, Caledonian granites and Old Red Sandstone sediments, which are generally characterized by low geochemical relief. Factors in the secondary environment obscure the relationship between trace-metal concentrations in stream sediments and bedrock geology. Investigation of sampling and sample preparation methods indicates that the -100-mesh material is the optimum size fraction for the regional survey of this area: it provides adequate geochemical contrast: it reduced the incidence of spurious high values in the samples investigated and it is available in amounts which are adequate for all the analyses required. Grinding samples improves precision and reduces the preferential volatilisation of metals coprecipitated with hydrous manganese and iron oxides for the optical emission spectroscopic method used initially. A study of the dispersion of metals in the drainage system of an area of Pb-Ba-Mo mineralisation and an area of U-Pb mineralisation, respectively, indicates that a sampling interval of 1 per 2 km2 based on second- or third-order streams is adequate to define anomalous metal concentrations. Regional variation can also be represented on the same interval. Modifications to the sampling procedure to reduce the effects of the secondary environment are complicated by the primary association of Mn and Fe with mineralisation in the area. The ratio of analytical and sampling error to regional variance shows that procedural precision is adequate to prepare regional geochemical maps of northern Scotland, with the exception of Cr, Cu at low concentrations and Pb.

Dec 1, 1971

By J. R. Budden, P. A. Spencer, J. Barrett

The initially produced arsenic (III) is very toxic to the unconditioned culture but the mixed culture has the capacity to oxidise it to arsenic (V) in the presence of iron (III). It was possible to build up the resistance of the culture through progressive sub-culturing on arseno-pyrite until it could tolerate steady-state concentrations of 30 mM arsenic (III) and 200 mM arsenic (V). With some samples tested in the continuous systems the final arsenic concentrations reached 330 mM. It proved possible to use the laboratory batch data to establish the optimum operating conditions for continuous test systems with capacities of up to 32 m3. Data on the residence time, oxygen uptake rates and gold extraction from the bio-oxidised residues could then be confirmed by continuous testing without the need first to use empirical means to determine optimum conditions for continuous bio-oxidation. The data on residence time, oxygen uptake rate, solids density and neutralisation could be used to estimate the capital and operating costs of treating any given tonnage of the concentrate of interest. It was established that the arsenopyrite concentrates can be suitably bio-oxidised to cause the liberation of at least 90% of the gold content. The method is simple to operate and is flexible over a wide range of external conditions

Apr 1, 1991

By M. Feely, W. G. O'Keefe, C. O'Reilly, M. P. Holdstock

A petrographic and microthermometric study of fluid inclusions in the Kentstown Granite, crosscutting quartz (VI) and calcite+quartz (V 2) veins in the granite and calcite+quartz (V 2) veins in the overlying sediments was performed on samples taken from the borehole. Comparisons of the type 1, type 2 and type 3 fluid inclusion populations recorded in the present study with those from other Irish Caledonian granites strongly suggest a similar fluid evolutionary history. Furthermore, the low-temperature CaC12-rich brines (type 5) of this study, which must be syn- to post-Lower Carboniferous in age, have correlatives both in Irish Caledonian granites and in the Lower Carboniferous base-metal deposits of the Irish midlands

Jun 19, 1905

By H. Y. Sohn, Hang Goo Kim

Computer simulations were carried out using calcium ferrite slags containing 25 wt% CaO, and the results compared with those obtained using fayalite slags. There was little difference in overall elimination of Pb and Bi, but elimination of Sb and As was much lower with calcium ferrite slag. When calcium ferrite slag is used only in the converting stage and fayalite slag in the smelting stage, as in the Mitsubishi process, the contents of Sb and As in the blister copper can be kept to reasonable levels. This allows advantage to be taken of the considerably higher iron oxide-holding capacity of calcium ferrite slag than of fayalite slag at the high oxygen potential under converting conditions, thus preventing precipitation of magnetite. Satisfactory agreement was obtained between predicted values and observed data from a Mitsubishi converter

Jun 18, 1905

By S. G. Tsimas, A. K. Moutsatsou, G. K. Parissakis, M. A. Komiotou

For Greek kaolin producers, a considerable proportion of whose output is from deposits containing more than 4 wt% Fe2O3, the colouring resulting from iron oxide impurity represents a serious problem that necessitates upgrading of the ore to meet commercial specifications. Autoclave leaching with oxalic acid for 1 h at 120 degrees C and 5-6 bar was shown to reduce Fe2O3 by up to 90% without affecting the structure of the kaolin, which maintained its physicochemical properties. The iron oxalate product can either be removed from solution or precipitated as iron hydroxide with recycling of the oxalic acid

Aug 1, 1995

By D. M. Evans, D. L. Buchanan

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. The Zinca area was chosen as a suitable location for an investigation of the weathering and secondary dispersion of platinum group metals from the Zone. It was concluded that platinum is immobile while within weathered rock, its mineral phases tending to alter from primary sulphides and tellurides to secondary Pt-Fe alloys. Palladium is variably mobile in weathered rock. In stream sediments Pt occurs mainly as small, dense, discrete particles, giving rise to a nugget effect, whereas Pd probably occurs as much finer particles or chemically adsorbed on to a suitable substrate. Pt shows a rapid decrease in sediments downstream from mineralisation, whereas Pd has a much slower downstream decay

Apr 1, 1994

By Bakker J. de, P. A. Leest, W. L. Dalmijn, H. J. Glass

The test facility at the Delft University of Technology, in the Netherlands, was characterised. Advantages include the possibility of separating particles with high but different densities up to 9 g/cm3, the ease of adjustment to any required separation density and the absence of moving parts. Simultaneous separation of more than two types of particles is possible and the magnetic fluid is safe and convenient to use compared with other heavy liquids. Disadvantages include loss of magnetic fluid with outgoing particles (cost approx US $10/l) and degeneration of fluid due to bacterial activity, reaction with particles and with surroundings. Only non-magnetic materials can be separated, there is limited potential for scaling up and high investment is required on account of the cost of magnets. Future improvements in the design of the apparatus and the properties of the magnetic fluids can only enhance its attractiveness for commercial applications

Jun 18, 1905

By Haldane J. S.

Discussion of a paper presented at the Institution of Mining Engineers' general meeting held in London on 8th June 1916 included oral contributions by Louis H., Mowat D.M., Lupton A., Bailey T.H., Blackett W.C. and Gerrard J., and written contributions by Collis E.L., Carlow C. and Wilson W.B., with the author's oral and brief written responses

Dec 1, 1916

Discussions of the papers with a written contribution on Paper No. 11 and authors' written replies. Also brief obituary of Dr. T. David Jones on p146.

Jan 1, 1947

By R. J. Gochin, G. D. Schena, R. Spencer

The impact of a mineral project in a developing country is evaluated in the broad context of its economy using input-output models. Minimum economic theory is used to develop simple numerical models. Sets of technical coefficients are exploited in the development of linear models of the productive element of an economy. The analysis allows assessment of the overall economic consequences of a mineral development in which issues broader in scope than financial objectives need to be incorporated in the evaluation. In part 1, the framework for the development of the input-output model is presented. The model is refined to incorporate country-specific behaviour. The increased flexibility of the enhanced semi-input-output model permits a more confident investigation of the economy-wide effects associated with a new project in the mineral sector of a developing country. The relevance of the models is illustrated using an example from Namibia

Sep 1, 1991

By P. A. Davies

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 11pp., 15 refs. Hazards such as vibration, dust emission and fragment projection can result in an area called the Danger Zone being set around a blasting site. Traditionally Danger Zones have been set solely on the basis of consequences (e.g. based on the maximum distance of rock projection or expected ground vibration plus a defined safety margin). Advances in risk assessment and its growing acceptance as a safety management tool have led to the setting of Danger Zones based on both consequences and frequency of occurrence. This allows distances to be optimised on the basis of acceptable risk levels rather than the potential consequences of infrequent events. The setting of a flyrock Danger Zone is used to demonstrate a risk-based approach compared with a traditional consequence approach

Aug 1, 1995

By Briggs H.

Initial discussion of the paper presented at the Mining Institute of Scotland's general meeting held in Edinburgh, 12 February 1916, with D.W. Mowat, president, in the chair, included comments by Masterton J. (HM Inspector of Mines) and Sim J., and the author's reply

Dec 1, 1916

By Seong-Taek Yun, Chil-Sup So, Seung-Jun Youm

The greisen-bordered quartz veins are spatially, temporally and genetically associated with a late Cretaceous granite intruding an early Palaeozoic, limestone-rich formation. Paragenetic data indicate three stages of hydrothermal mineralisation, the first typically in or within 500 m of the granite stock and showing vertical zoning between deeper Mo and higher W, the other two more abundant in the upper and outer parts of the mineralised area. Fluid inclusion and stable isotope data indicate that hydrothermal veins formed over a temperature range of 120-395 degrees C from low-salinity fluids. Early wolframite and molybdenite deposition in stage I occurred at temperatures of 300-395 degrees C from magma-derived, low-salinity, CO2-rich fluid, mainly as a result of fluid boiling and associated CO2 effervescence. Progressively larger volumes of local meteoric water entering the system led to the successive deposition of scheelite in stage I vugs, stage II base-metal sulphides and stage III fluorite-carbonates. Remobilisation of W and its later deposition of scheelite in the outer and shallower portions of the system occurred at 215-275 degrees C and stage II and III mineralisation from lower-temperature fluids that became progressively lighter in stable isotopes. It is concluded that the influx of meteoric water increased with distance from the cooling pluton

Jun 18, 1905

By L. J. Cabri, J. M. D. Wilson, R Lastra

An image analysis program can search for gold minerals in polished sections by scanning about 100 x 100 back-scattered electron images at a magnification of x400, allowing gold grains as small as 1 micrometre in diameter to be detected. Typically, a c.15 h overnight search of a product smaller than 45 micrometres will scan c.1 500 000 particles, providing data that are not easily obtained through manual operation of an optical microscope. The program locates grains of the correct brightness, acquires gold X-rays from them by wavelength-dispersive spectrometry, filters the data to remove artefacts and record the images and stage locations for subsequent retrieval. At the end of the run, the program allows the operator to verify and identify the grains found. Industrial studies at Canmet have included determining the nature of gold in cyanidation tailings, checking the mineralogy and size of gold grains in samples from an Indonesian Cu-Au concentrator and locating and measuring gold liberation and grain sizes in an ore

Jun 21, 1905

By G. D. Schena, M Zanin

A numerical approach is presented for predicting the liberation of phases during comminution, with direct calculation of a liberation spectrum giving the fraction of the particulate system in each narrow size-composition class. The numerical model uses a Poisson flat process for stochastic generation of the non-convex three-dimensional Poisson polyhedral textures and the system of fractures that give rise to convex fragments. With this numerical approach, there is no need to assume random uniform isotopic fracture (lack of selective liberation); only computational geometry primitives are exploited for the derivation. The agreement with relationships obtained previously under the random uniform isotopic fracture hypothesis demonstrates that the approach is capable of deriving full liberation spectra directly. Both volumetric and superficial composition can be calculated

Jun 21, 1905

By G. D. Schena, C Chiaruttini

The feasibility is demonstrated of reconstructing the volumetric distribution of liberated particles and middlings by use of a damped, weighted least-square regularisation method. This allows a precise mass balance to be obtained around a separation/concentration unit, permitting evaluation of the partition curve (Tromp curve) of the separator. Areal grade measurements are made on polished sections of feed, concentrate and tailings and a kernel-based inversion technique is then used to obtain the volumetric grade distribution of the three assemblages. A plain kernel (number of occurrences) and a weighted kernel (each occurrence counted with its area) are used for the solution. Testing of the method on computer-generated synthetic areal grade measurements indicates that it offers a valid alternative to the tedious conventional procedure of conducting experiments with heavy liquids

Jun 21, 1905

By C. M. Lesher, R. R. Keays

"The komatnte-associated Fe-Ni-Cu sulphide mineralization at Kanihalda, Western Australia, is generally believed to be magmatic in origin, but a number of postmagmatic processes significantly modified the original distribution, structure, texture, mineralogy and chemistry of the ores. Two important types of mobilized magmatic sulphides are interpillow/interbreccia sulphides and hydrothermal vein-type sulphides. Interpillow and interbreccia sulphides occur interstitial to pillowed or volcaniclastic footwall metabasalts beneath or adjacent to the stratiform contact ore horizons. They are mineralogically and compositionally similar to massive ores (and are similarly depleted in PGE relative to the compositions of bulk samples of mined ores), but normally do not contain the distinctive chalco-phile ferrochromites characteristic of contact ores. They are interpreted as magmatic sulphides that have been mobilized from the overlying or adjacent massive sulphide layer during peak tectono-nietamorphism.Hydrothermal sulphide-quartz + albite veins also occur in the footwall metabasalt and contain unannealed deformation fabrics indicative of emplacement during retrograde metamorphism. The high Ni and Pd contents of these sulphides (7-13% Ni, up to 70 ppm Pd) indicate that the metals have been derived from the spatially associated komatiites and/or contact ores, consistent with the Pd depletion previously inferred for massive ores. Very low Ir contents and high Pd/Ir ratios of the vein-type sulphides confirm an aqueous transportation-deposition mechanism; hydrothermal transfer of PGE results in strong decoupling of Pd from Ir.There appears to be a complete continuum of sulphide mobilization at Kambalda ranging from whole-scale phy sical dislocation (fault offset ores) and selective mobilization (stringer sulphides) through nietamorphie replacement (interpillow/interbrec- cia sulphides) to jiydrothermal dissolution and redeposition (vein-type sulphides)."

Jan 1, 1984

By S. Al-Hassan

The deposit has been exploited for Mn oxide and carbonate since 1916. Known reserves of MnO, however, are almost depleted and the survival of the mine will depend on the exploitation of the carbonate. Kriging, inverse distance weighting (IDW) and cross-sectional methods have been applied to the evaluation of the carbonate resources and reconciliation of the estimates obtained shows that kriging and IDW give almost identical block values. A comparison using conditional probability indicates that there is virtually no difference between the global reserve estimates derived from the cross-sectional and kriging methods. The physical causes of these similarities are highlighted and the problems of dealing with multimodal distributions are discussed together with the difficulties of semi-variogram modelling

Jun 19, 1905

Studies were carried out to examine the effect of introducing varying levels of a pisolitic limonite (Yandi) into an Australian iron ore blend. Compared with other ores in the blend Yandi is more porous. This structure is found to have a considerable effect on the sintering behaviour of the blends. Pilot-scale sintering studies and plant trials showed that sinter plant productivity, sinter reducibility and the low-temperature reduction degradation index altered significantly when the level of Yandi in the ore blend exceeded 15 wt%. The improvement in the reducibility is thought to be a direct result of increased porosity in the sinter and the presence of highly reducible pseudo-relict haematite. Plant trials have also shown that operational changes could be made to the sinter plant to avoid potential deterioration of productivity

Dec 1, 1991