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By V. Krupa, E. Lazarova

A method is proposed for the continuous calulation of a rock mass in real time while tunnelling with a TBM. Rock properties are investigated through models of the fracture stress under the disc cutters, the quasi-shear stress between the disc cutters and the specific energy of cutting under the disc cutters. Comparison of theoretical and monitored data of cutting specific energy can be used to determine theoretically the prevailing shape and size of the bulk debris. The shape and size of the chips from a given rock vary with the boring parameters. Introducing shape and volume corrections into the models of the evaluated stresses suppresses the influence of the boring regime and allows the rock properties to become dominant

Dec 1, 1996

By A Cox

It has been demonstrated that all the cadmium from spent batteries, typically 4 g per battery, can be recovered by burning polyvinyl chloride waste to yield hydrogen chloride; this reacts to produce volatile calcium chloride, which can then be condensed and collected in a separate reactor. Alternatively, chlorine may be used to chlorinate the cadmium with equal efficiency. There is also a prospect of using very low concentrations of these gases, less than 1%, to effect the separation. The Cd was recovered more quickly when exposed to sustained, controlled flow rates of chlorinating gases, whereas when PVC was burnt most of the gas was produced in a very short time, not allowing complete reaction. This problem can be overcome by recirculation of the gas into the reactor. The technology is efficient and clean and the equipment used is simple, enhancing the prospects for a pilot-scale version of the process

Jun 21, 1905

Errors in ore reserve estimation can occur during drilling and sampling, sample preparation and analysis, geological logging and modelling, database construction, statistical or geostatistical evaluation, selection of economic parameters, selection of ore reserve method and assessment of mining constraints. Core sample recovery can be a major source of error, and it is proposed that the modelling of grade, metal accumulation and thickness should be accompanied by the modelling of core recovery (or core loss) so that for each ore block a weighted block recovery factor is obtained. This gives a good indicator of the reliability of a reserve estimate. It is suggested that a resource reliability rating (RRR) system be established to quantify what is meant by geological assurance and to combine this with an estimate of the precision of estimation as gained by geostatistical analysis. Proven and probable minable reserves would be those with an RRR better than 50% and a precision of estimation better than 20%

Dec 1, 1996

By P. J. Baguley

The model has been developed on the basis of the observation that the partitioning behaviour of a particle is related to its calculated terminal velocity. It utilises a theoretical calculation of the terminal velocity of each particle class. This is then correlated with the observed partition data for a plant separator using empirically-derived functions of operating conditions which take into account effects such as bath turbulence, holes in drum lifters and feed arrangements. The model successfully decouples the effects of medium density and viscosity and is appropriate for any bath-type separator. The correlation between calculated terminal velocity and actual partitioning behaviour was established and modelled using data obtained from two Wemco drums treating Fe and Mn ores. The model can be used to predict the prevailing size-by-size partition curves and the separation (product grades/recoveries) given the washability of the feed and operating conditions. Simulations are used to show that, for the treatment of Fe ore, there is a maximum medium density beyond which product grades fall and that this maximum decreases as the proportion of magnetite in the medium increases. This is attributed to the dominant effect of viscosity at higher medium solids concentrations

Jun 18, 1905

By S. L. R. Lenharo, H. Kahn, H. Born

Different ore types result from the irregular spatial distribution of the associated alkaline/carbonatite rocks and the zoned alteration profile within which apatite may have undergone reprecipitation. Different flotation responses are caused by their mineralogy, iron oxide impregnation and grain-size characteristics. Samples from seven deposits were crushed, screened and separated before being studied by chemical analysis, optical microscopy, X-ray diffraction, FTIR spectroscopy, cathodoluminescence and scanning electron microscopy. Two main apatite varieties with peculiar crystal morphology were identified: hydroxy-fluorapatite as the primary phase and carbonate-fluorapatite as the reprecipitated phase. The former occurs as prismatic or ovoid grains and the latter as polycrystalline aggregates or crusts on the primary grains; both are associated with iron oxide coatings (primary) or intergrowths (secondary). Microflotation tests showed variations in flotability for particular apatite associations as well as intensity of iron oxide coatings. The differences in flotation behaviour can be related to morphological properties and chemical substitution in the apatite structure

Aug 1, 1996

By B. B. Dhar

Slope stability at the proposed mine in Rajasthan was analysed in two dimensions using a finite difference code. The properties of the rock material were determined in the laboratory and subsequently modified to approximate those of the in situ rock mass. Geotechnical mapping was undertaken to determine the critical orientation of structural discontinuities. The results of the work indicated that an open pit 148 m in depth would be stable with overall slope angles of 60 degrees

Aug 1, 1994

By D. M. Milne, P. J. Lunder, R. C. Pakalnis

During the mining of an open stope, deformation of the hanging-wall and the potential for dilution generally increase with the size of the exposed hanging-wall. Excluding discrete structures that may delineate unstable blocks, the mechanisms that drive hanging-wall deformation and possible dilution comprise several factors which can include elastic, plastic and discontinuum deformation. These stages of deformation are not mutually exclusive and at any point during mining all three of these mechanisms may be acting on the hanging-wall rock mass. Computer modelling techniques are available to analyse the three stages of deformation, but the difficulty lies in trying to obtain realistic rock mass properties for input and in determining when each stage of deformation is acting. Instrumentation data can be used to predict the effect of continued mining. However, it is often difficult to calibrate numerical models against field data owing to the large number of input parameters required. An empirical approach is recommended that uses two new parameters, the radius factor and the effective radius factor. A method is proposed for predicting the effect of continued mining from existing deformation and dilution data for a given hanging-wall

Apr 1, 1996

By L. E. Mordberg, E. N. Nesterova

Geochemical studies of the bauxite deposits show that the primary composition is gibbsitic. Some trace elements were relatively mobile during bauxite formation with the content of Th, U and Zr increasing and that of Rb, Ni and Co decreasing. Y and Pb were relatively immobile during lateritisation; their contents and ratios were inherited from different types of underlying rocks. The supply of Ni and Co took place at the diagenetic or epigenetic stages; their ultimate source was the crystalline basement in the region. The studies support the view that the bauxite was likely to have originated as a result of in-situ lateritisation and not through sedimentary transport and redeposition

Jun 18, 1905

By B. J. Breen, C. S. Mogg

Considerable borehole investigation work has been completed at a proposed site at Sellafield in Cumbria, supplemented by seismic surveys, other geophysical sensing and geological mapping. The focussing of investigation on the rock mass itself will be achieved by means of the planned underground rock characterisation facility, giving access to depths of about 800 m in the strong, low-permeability basement rocks of the Borrowdale Volcanic Group. Characterisation work undertaken during the sinking phase and interaction with continuing surface-based exploration and monitoring should permit a firmer assessment of the long-term safety of a repository. Key considerations in the choice of a design for the repository include the waste handling method, underground inlet cell, underground vaults, vault environment and environmental effects

Aug 1, 1994

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

By P. E. J. Pitfield, S. D. G. Campbell

The regional shear zone runs along or near the southern margin of the Chinhoyi greenstone belt. It hosts four of the seven mines in the southern part of the belt with recorded production above 100 kg Au, including the top two current producers. Displacement occurred in the late Archaean, producing a shear zone with a trend ranging from northeast at Golden Kopje to east at Muriel. The orebodies at the two mines formed synchronously with the shearing and show strong but contrasting structural controls on mineralisation. The Golden Kopje orebodies plunge to the southwest, parallel to the intersection of curved foliation with discrete shear planes and sub-perpendicular to local stretching lineations. The Muriel orebodies plunge steeply west but parallel to local stretching lineations. The greatest fluid flow during mineralisation of the shear zone was along either the intersection of fabrics (Golden Kopje) or the extension direction (Muriel). There is no unique relation between the orebodies and the extension or shear direction. Where earlier mining has not established the directions of the oreshoots it is essential to understand the possible structurally controlled geometries of orebodies before planning a drilling programme to evaluate their potential

Apr 1, 1996

By S. P. Singh

The purpose of the cut is to provide a free face to which the remainder of a development or breasting round can break. The results of field testing in drifts and at a quarry face were used as a basis for a description of the rock breakage and flushing mechanism in the cut. It was concluded that the important features of a cut design are proper hole spacing, sufficient relief volume, drilling accuracy and relief holes slightly longer than the planned length of the round. The void space provided by the relief holes should be about 15% of the cut volume, with more required in weak, highly fissured rocks. The importance of drilling accuracy increases with round length, an error being magnified by the small blasthole spacing. The first hole pulls only about 20% of the round length, 4-6 holes having to be fired before the cut is pulled close to its design depth. The first four blastholes should be fired with a minimum inter-hole delay of 100 ms to provide progressive relief of burden and avoid the superimposition of ground vibrations. The earliest-firing charge should be closest to the relief area and act laterally, while the first of the vertically-fired charges to be detonated should be the uppermost. Problems during cut-pulling include sympathetic detonation, dynamic pressure desensitisation, charge disruption and freezing of the cut

Dec 1, 1995

By M. K. Abd El-Rahman

A complete chemical analysis of the waste showed that it contains 15.64% P2O5; X-ray diffraction analysis revealed that it is composed mainly of francolite, calcite, pyrite, quartz and dolomite. The phosphate values were recovered and the settling rate of the wastes enhanced by the use of hydrocyclone and flocculation techniques. The hydrocyclone produced an underflow enriched in phosphate and an overflow enriched in clays. The former represented 39.8% by weight of the phosphatic clay waste and assayed 26% P2O5 at a recovery of 66.36%. The results of flocculation of the phosphatic clay waste showed that both the degree and rate of settling were increased and that the process water could be recycled. The settling rate was 37 times greater when anionic polyacrylamide A130 was used

Jun 21, 1905

By W. R. Paterson, W. Morton, D. B. Cameron

The Massbal II computer simulation program has been used to develop a general framework for the building of thermochemical models of metallurgical processes. The framework allows the rapid, simple construction of complex models of process equipment for use in flowsheet design, planning and plant operation. Application of the program to model the iron-making blast furnace and a flash smelting process is described

Apr 1, 1991

By G. S. Pauley

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993 (original title: Case-based reasoning can be a catalyst for improvement). A new computer software technology known as Case Based Reasoning (CBR) can be used to produce small decision support systems that are economically viable. This is because the knowledge that they contain can be owned and maintained by their users. A CBR tool has been used to perform a pilot study with Anglesey Aluminium Metal Ltd. The results are encouraging. They suggest that a combination of CBR and participative design and implementation techniques (such as Checkland's Soft System Methodology) can achieve sustainable improvement in mineral processing functions. An explanation is presented of why traditional, rule based systems are often an ineffective way to implement support systems. It is shown that CBR may provide an appropriate technology solution. Methods of achieving sustainable benefit are indicated. The pilot study with Anglesey Aluminium Metal is used as a practical illustration of the development of a CBR application. A review of potential application areas and some observations about the implementation are presented

Apr 1, 1994

By Bakker J. de, P. A. Leest, W. L. Dalmijn, H. J. Glass

The test facility at the Delft University of Technology, in the Netherlands, was characterised. Advantages include the possibility of separating particles with high but different densities up to 9 g/cm3, the ease of adjustment to any required separation density and the absence of moving parts. Simultaneous separation of more than two types of particles is possible and the magnetic fluid is safe and convenient to use compared with other heavy liquids. Disadvantages include loss of magnetic fluid with outgoing particles (cost approx US $10/l) and degeneration of fluid due to bacterial activity, reaction with particles and with surroundings. Only non-magnetic materials can be separated, there is limited potential for scaling up and high investment is required on account of the cost of magnets. Future improvements in the design of the apparatus and the properties of the magnetic fluids can only enhance its attractiveness for commercial applications

Jun 18, 1905

By P. H. Morris

Nineteen field trials of the co-disposal of fine coal tailings and coarse coal wastes were conducted at the dual Goonyella-Riverside mine in Queensland and at the Hunter Valley No. 1 and Warkworth mines in New South Wales, Australia. The profiles of and the sorting that occurred on the co-disposal deltas are described and an existing theory of subaerial deposition, originally developed for mine tailings alone, is shown to apply to the co-disposed wastes. This enables the dimensionless profiles of large deltas, which may take years to deposit, to be predicted from data obtained from a small delta formed in a few days or even hours

Jun 19, 1905

By E. Niehuis, J. Y. Kim, H. G. Cramer, S. L. Chryssoulis, K. G. Stowe, C. Bendel

TOF-SIMS was used to detect, identify from parent molecular ions and determine the relative concentrations of collectors sorbed on the surface of mineral particles in concentrate and tailings samples from three Canadian concentrators. In the Kidd Creek Zn circuit, sphalerite lost to tailings carried on average a quarter of the amount of isobutyl xanthate present on that recovered to Zn concentrate; amyl xanthate, which is not reported as added to the circuit, was also detected on floated sphalerite and pyrite. At Brunswick, sphalerite particles lost to the scavenger tailings had ten times less amyl xanthate and isobutyl xanthate than those recovered to the Zn final concentrate, while both xanthates were detected on sphalerite floated to the Cu-Pb cleaner circuit. At Matagami, significantly more isopropyl xanthate and isopropyl dithiophosphate were detected on sphalerite recovered to the final Zn concentrate than on that lost to the Zn rougher tailings

Dec 1, 1995

By M. Foguenne, A. van Lierde, P. Henry

Leaching experiments were carried out on a spent catalyst sample with a honeycomb structure, containing 47.5% Ti, 5.8% Mo, 2.7% Si, 2 035 ppm As, 52 ppm Pb and 8.8 ppm Hg. More than 93% of the Mo and As was removed by direct alkaline leaching after grinding to 80% -36 micrometres. The residue contained 0.3% Mo and 60 ppm As. To obtain a TiO2 matrix with 30 ppm As, acid leaching at controlled pH with 90 kg/t Al scrap was followed by oxidising alkaline leaching. Treatment of the direct alkaline leach solution or of the mixed solutions from the two-stage process involved two successive operations: purification by neutralisation with Al(OH)3 addition to raise the Al concentration to 4 g/l, and ion exchange on Amberlite IRA 94 S resin. Whatever the type of solution treated, elution with 200 g/l NH4OH solution gave an eluate of very high purity containing 164 g/l Mo, less than 70 mg/l V and less than 2 mg/l As

Jun 19, 1905

By S. J. Parry, D. M. Evans, D. L. Buchanan

The reef is a PGE-enriched sulphidic zone, stratigraphically associated with and overlapping the C1d chromitite layer, that was formed by magmatic processes at the 1e-1d subunit boundary. Two distinct patterns of PGE enrichment are related to the presence or absence of Cr2O3 oversaturation during sulphide liquation that occurred during a complex sequence of changes at this boundary

Apr 1, 1996