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A study of the thermodynamic properties of magnesium chloride ammines was carried out with the ultimate objective that the thermal decomposition of the hexammine MgCl2.6NH3 may prove successful on a commercial scale for the manufacture of anhydrous magnesium chloride, which is required for the efficient electrolytic production of magnesium. The experimental data are presented in the form of an equilibrium diagram that aids the understanding of the conditions associated with the thermal decomposition of ammines

Jun 13, 1905

Discussion of the paper presented at the North Staffordshire Institute of Mining and Mechanical Engineers' general meeting held in Stoke-on-Trent, March 27th 1916, with Mr. John Gregory, President, in the chair, included contributions by Gregory J., Cadman J., Hartley J.W., Wain E.B. and Henshaw A.M., followed by the author's reply

Dec 1, 1916

By G. Mellgren, O. Mellgren

The conductivity of a solution is often used industrially to control the salt concentrations of reacting systems, normally using electrodes made of glass fitted with platinised platinum electrodes. When a standard platinum conductivity electrode was used to control the acid fed to the leaching circuit for an ilmenite flotation concentrate at Titania, Norway, a deposit of calcium sulphate (containing some calcium phosphate) covered both the platinum electrode and the external glass fitting, rendering the electrode inefficient in the course of a few minutes. A new electrode consisting of a casing, two measuring tubes and an electrode stem is described and illustrated. A significant advantage of its design is that the useful range of conductivity measurement can be adjusted by adjusting the concentration of the electrolyte in the electrode. It has been in use at Titania for about four years with an electrolyte consisting of 0-1 n HCI. It is robust and demands little maintenance.

Dec 1, 1971

For the convenience of those who are unfamilar with thermodynamics, the following brief description and explanation is given of the thermodynamical terms and methods used in this book. It must, however, be strongly emphasized that the account given below is not an introduction to chemical thermodynamics; its sole purpose is to give the reader a rough understanding of the methods used in the earlier chapters. For further information, reference must be made to the standard textbooks on chemical thermodynamics by Glasstone.

Jan 1, 1953

By D. J. Allan, W. R. Wilson

For conventional aerospace aluminium alloys of the 2000 (copper) and 7000 (zinc, magnesium) series the recycling of process scrap from both metal suppliers and aircraft manufacturers is a well-established, worldwide industry. The recent introduction of a new family of alloys that incorporates lithium has posed a new challenge to the recycling industry owing to the high cost of lithium, its high reactivity to the atmosphere and to refractories and its absence from the specifications of all other registered alloys. Various process options for recycling have been identified, but vacuum distillation has been selected as the most cost-effective and technically feasible solution. Experimental work established that the separation of Li from AI-Li scrap is feasible and an industrial process has been designed. The economics of Li recovery are very sensitive to the AI-Li content of the feed material. Owing to the design of aerospace vehicle manufacturing plants it is expected that the swarf will be mixed with other alloys. A method of enriching this feed has been developed that is based on the control of swarf morphology by thermal and mechanical treatments as a precursor to eddy-current separation. After eddy-current separation and vacuum distillation small proportions of Li are retained in the AI residue. The effects of this on the properties of conventional AI-Si shape-casting alloys were investigated and safe threshold levels have been established.

Jan 4, 1993

By Williams J. A.

"Changes proposed in 1969 to modernize legislation governing the exploitation of mineral deposits in the United Kingdom serve as the basis for a discussion of what is considered to be a desirable framework for future legislative proposals.Proposals with regard to prospecting and exploration, evaluation, and acquisition and exploitation are considered, as are suggestions relating, inter alia, to aerial surveys and land restoration.It is concluded that without legislation along the lines proposed there can be no significant revival of metal mining in Britain."

Dec 30, 1971

By J. H. E. Jeffes, C. Diaz

The heat balance and chemical equilibria involved in the production of blister copper from a chalcopyrite concentrate in a single operation are examined. It appears that two stages—one oxidising and one reducing—will be required. The analysis indicates that on thermal grounds the process is possible with a dry, high-grade chalcopyrite concentrate, if oxygen enrichment to about 30 per cent is used, but that copper losses in the slag will be serious and will require a secondary recovery operation. More extensive data on the activities of copper oxide in slags are required to elucidate this point more effectively

Dec 1, 1971

By R. J. Howarth, P. L. Llowenstein

The errors resulting from field sampling, sample preparation and analysis are investigated for drainage sediments derived from homogeneous sandstone, shale, limestone, basic igneous and granite lithologies as a background to a primary reconnaissance survey of England and Wales. Emission spectrographic analyses of approximately 350 samples for Al, Ca, Fe, K, Si, Ba, Co, Cr, Cu, Ga, Li, Mn, Ni, Pb, Sc, Sn, Sr and V and atomic absorption analyses for Cu, Ni, Mn, Co, Zn and Pb have been treated statistically. For routine broad-scale surveys analysis of the unground -80-mesh sediment fraction proves satisfactory. Sampling error between localities in a stream is shown to be less than spectrographic analytical error for many of the elements considered here, except where mineralisation (contamination) occurs, but exceeds the atomic absorption analytical errors in most cases. Unless it it critical to reduce the amount of between-site variability (having regard to analytical errors) in the regional survey, there appears to be no advantage in the use of a more sophisticated sampling technique. The utility of moving-average maps in reducing the width of the confidence belt around the regional 'geochemical surface', and thus compensating to some extent for the sampling errors, is also demonstrated.

Dec 1, 1971

By J. Ostwald, L. T. Matthews, C. E. Loo

Australia has large reserves of pisolitic limonite. Mining recently commenced on the Yandicoogina deposit to produce a high-grade sintering ore. The ore contains about 10 wt% combined water and simulated sintering temperature profiles indicate that progressive dehydration of ore particles occurs in the temperature range 300-700 degrees C. Studies by optical microscopy show that although the dehyrdrated ore particles contain numerous cracks, there is no change in the microstructure of the ore because topotactic transformation to haematite results in the formation of compact masses of very fine-grained haematite microcrysts. When the ore is held at around 1 200 degrees C for 1 min significant recrystallisation of these microcrysts occurs, resulting in the formation of optically visible, micrometre sized haematite crystallites. Studies to simulate the behaviour of ore particles during sintering (as nuclear particles surrounded by a standard adhering fines mixture) show that the recrystallisation process occurs much earlier at temperatures of about 900 degrees C. Further studies indicate that CaO in the adhering fines mixture enhances the recrystallisation of the ore nuclei. The results of the investigation indicate that the pseudo-relict haematite in sinters produced from ore blends that contain significant levels of pisolitic limonite consists of dehydrated goethite that has undergone significant recrystallisation and grain growth, a phenomenon that is facilitated by the presence of lime derived from the sintering melt.

Jan 12, 1992

The report of the Annual General Meeting of the Institution of Mining and Metallurgy held on Thursday, 20 May, 1971, in the rooms of the Geological Society of London, Burlington House, Piccadilly, London, W.1, at 4 p.m. (Chairman : M. J. Cahalan, President) includes details of awards and prizes presented to William Justin Kroll, Sir Gordon Colvin Lindesay Clark, John Convey, Evert Hoek, Peter Reginald Dawson and Christopher Michael St. John

Dec 1, 1971

By D. D. Lei, H. Sevim

Long-term production planning in open-pit mines requires the determination of cut-off grade, mining and milling production rates, a mining sequence, mine life and ultimate pit limits. Since these variables interact in a circular fashion, a genuine solution to the problem necessitates their simultaneous determination. A methodology with this capability is described. This comprises a group of heuristic algorithms and an unconventional dynamic programming algorithm. The method is demonstrated using data for a gold deposit in the western USA

Jul 1, 1996

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

By Winmill T. F.

Among the various theories proposed to account for the spontaneous ignjtion of coal, one which has at times been very strongly held is that the initial heating is due to the oxidation of iron pyrites. From the results described in this paper, it is possible to calculate roughly the rate of spontaneous heating of a specimen of finely-divided pyrites, on the assumption that all the heat developed is used in raising the temperature of the pyrites, and that none is lost. It is clear that where finely-divided pyrites occurs in considerable proportion among coal, it may be the chief factor in originating combustion, but that pyrites can only be the cause of a heating when it is present in considerable proportion, and in a very finely-divided state

Dec 1, 1916

By I S. Lowndes, K. Moloney

Diesel powered equipment is currently used extensively in mining and tunnelling operations around the world due to its mobility, flexibility and through selective application to enhance productivity. However, the increased use of diesel equipment has exacerbated the pollutant load (including heat, humidity, exhaust gases and particulates) placed upon the environmental systems of many underground operations. This expansion in the use of diesel equipment has prom pted researchers to evaluate m easure ment and control technology. This paper reviews the recent research conducted in various countries.

Jan 10, 1996

By W. R. Donaghue, R. L. Robinson, C. Scott

Whilst spontaneous combustion has never been considered a major problem in south Durham, certain collieries in the area have a history of heatings and precautions are essential. Three collieries are affected - Shotton, Vane Tempest and Seaham - and in the case of the last two, there are huge areas of high quality coal to work under conditions where spontaneous combustion is a real hazard. The seam being extracted has an immediate roof in goaf left by the incomplete extraction of a contiguous seam worked before the turn of the century. The presence of residual coal stocks and old roadways and cavities adds to the difficulty of preventing unwanted air movement. The main preventive measures adopted are the construction of airtight gateside packs and the use of sprayed surface coatings in the gate. Sampling systems and sampling points are described and, in particular the field of continuous monitoring from the surface is examined. The resulting possibility of a quantitative as well as qualitative assessment of the preventative measures required is discussed.

May 23, 1905

By M. J. Russell, W. E. Stephens, D. B. Mohamad, A. B. MacKenzie

Redox front processes in rocks are important in the context of both radioactive waste disposal and the development of orebodies. Results are presented from a study of the distribution of uranium and thorium and the natural decay series equilibrium about redox fronts in a granite at the Criffel pluton and Craignair quarry, Dalbeattie in southwest Scotland. The results are considered in the context of large scale uranium aqueous transport in the region and compared with those from a previous study of highly developed redox fronts at Pocos de Caldas, Brazil. Results show that the Criffel pluton has experienced a recent and rapid removal of uranium from the uppermost section of the granite whereas thorium has remained relatively immobile. The radium and uranium distributions indicate that diffusion processes probably control the distribution of radionuclides about the front. These processes are similar to those observed at Pocos de Caldas. The trends of concentration and activity ratio about the Dalbeattie redox front are less pronounced than those at Pocos de Caldas owing to the shorter time available for the process and the lower intensity of weathering at Dalbeattie.

Jan 12, 1992

By D G. Jefferies

This paper covers National Grid's role in the electricity market, the growth of competition in both generation and supply in that market, and the resulting impact on fuel usage, prices and the environment. It also considers other, external influencing factors on the electricity supply industry, as well as the growing trend towards globalization.

Jan 12, 1997

Discussion at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, on the paper published in Trans. I.Min.E., vol.LI, 1916, p.61-71, consisted of a written comment by Wood P.L. that a larger battery would be the only way to secure reliability

Dec 1, 1916

By R. I. Jeffery, J. W. Summers

An account is given of the verification and calibration of a numerical modelling technique that has been developed for the prediction of subsurface strata deformation following the extraction of coal by longwall mining methods.

Jan 4, 1992

By Briggs H.

The illustrated device uses the principle that the lamp can burn with a smaller inlet passage if the air is rich in O2 and that the size of the inlet can be made a measure of O2 percentage. The appliance consists of an adjustable cut-off applied to the inlet of a safety lamp of the improved Gray pattern. Precision is assessed from tables of calibration tests in air contaminated with blackdamp of CO2:N2 composiiton 1:5.67 at temperatures of 40-70 degrees F. Results are presented of tests at St. Germain's colliery, of tests in air contaminated with pure CO2 and of air contaminated with both blackdamp and inflammable gas; published ranges in mine-air blackdamp compositions are tabulated as ranging from 90.06% N2 to 43.90% CO2. When firedamp is present at 1.25-2.5%, its content must first be estimated by means of the cap and a fifth of its value then deducted from the lamp reading for O2

Dec 1, 1916