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By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

By L. J. Cabri, J. M. D. Wilson, R Lastra

An image analysis program can search for gold minerals in polished sections by scanning about 100 x 100 back-scattered electron images at a magnification of x400, allowing gold grains as small as 1 micrometre in diameter to be detected. Typically, a c.15 h overnight search of a product smaller than 45 micrometres will scan c.1 500 000 particles, providing data that are not easily obtained through manual operation of an optical microscope. The program locates grains of the correct brightness, acquires gold X-rays from them by wavelength-dispersive spectrometry, filters the data to remove artefacts and record the images and stage locations for subsequent retrieval. At the end of the run, the program allows the operator to verify and identify the grains found. Industrial studies at Canmet have included determining the nature of gold in cyanidation tailings, checking the mineralogy and size of gold grains in samples from an Indonesian Cu-Au concentrator and locating and measuring gold liberation and grain sizes in an ore

Jun 21, 1905

By M. J. Matos, W. Patruk

The correct version of Equation 1 is represented and Tables 3 and 6 are revised to consider all size fractions, including those coarser than 300 micrometres, in calculating the total liberation from King's fractional liberation

Jun 18, 1905

By S. J. Parry, D. M. Evans, D. L. Buchanan

The reef is a PGE-enriched sulphidic zone, stratigraphically associated with and overlapping the C1d chromitite layer, that was formed by magmatic processes at the 1e-1d subunit boundary. Two distinct patterns of PGE enrichment are related to the presence or absence of Cr2O3 oversaturation during sulphide liquation that occurred during a complex sequence of changes at this boundary

Apr 1, 1996

By S. P. Ball, A. J. Monhemius

In a laboratory study under acidic oxidising conditions, the thiocyanate system gave results at least as good as cyanide and considerably better than thiourea, with modest consumption of SCN (less than 1 kg/t ore). For both cyanide and thiocyanate lixiviants a residence time of about 24 h was required for maximum gold extraction, which was generally in the range of 92-96%. The adsorption of gold from thiocyanate leach liquors was found to be rapid, but activated carbon catalyses the autoreduction of ferric iron to ferrous iron in thiocyanate solutions, suggesting that ion exchange may be a better recovery route

Dec 1, 1995

By V. Distler, E. F. Stumpfl

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. The massif contains large chromite bodies of "Alpine-type", ophiolitic affinity. Orebodies reach thicknesses of 150 m and sizes of more than 150 000 000 t chromite ore with average grades of 55-60 wt% Cr2O3. Chromites in the Main ore field are low-Al, high-Cr spinels which exhibit some variation in their Mg-Fe distribution. This differs markedly from high-Al spinels in peridotite host rocks and in narrow chromite pods which occur in the western and northern parts of the massif. Chromites carry silicate inclusions, often hydrous silicates such as amphibole. Chromites in massive chromitites contain micron size inclusions of platinum group minerals (PGM). Composite grains containing two PGM and, occasionally, a hydrous silicate are common. Os-Ir alloys rimmed by PGM sulpharsenides occur in narrow serpentine veinlets that cut chromite and are evidence for the reconcentration of PGE concomitant with introduction of As, probably during serpentinisation. Whole-rock PGE contents are highest in massive chromitites of Diamond Pearl mine (totals of 500 ppb). Chondrite-normalised PGE patterns of chromitites show negative slopes which are typical for ophiolitic, podiform chromitites in mantle sequences. The PGE patterns of host rocks are flat and rather depleted compared with those of chondrites and chromitites. Petrological data from unaltered host peridotites suggest a high temperature overprint leading to sub-solidus re-equilibration of olivine and spinel and to the growth of pargasitic and edenitic amphiboles

Jun 16, 1905

By A. M. R. Neiva

The WNW-ESE-trending hydrothermal veins cut alternating mica schists and quartzites of mainly Ordovician age and, to the west, a Hercynian muscovite-biotite granite. They have been prospected and developed to a depth of 300 m and reserves of 20 t Au estimated. The paragenetic sequence and chemical compositions of the ore minerals are generally similar to those at Jales to the south. Gold, electrum and aurian silver form inclusions in arsenopyrite, pyrite, galena, sphalerite, pyrrhotite and quartz and also occur in veinlets that cut these minerals. Silver has been found in gold, electrum, aurian silver, tetrahedrite, freibergite and the Ag-Pb-Sb sulphide owyheeite. Early arsenopyrite crystallised at an estimated 480 degrees C and the more common, later arsenopyrite in which Au and Ag are generally included at 430-300 degrees C. Sphalerite crystallised at 307-100 degrees C. Monoclinic pyrrhotite may have been formed by the inversion of hexagonal pyrrhotite at 248 degrees C

Jun 16, 1905

By R Adamian, F. T. Da Silva, D. H. Gameiro

Schytill and Geldart diagrams were developed for the TiO2-C-Cl2 system at 1 073 and 1 273 K, so as to define the hypothetical relations between particle sizes and chlorine velocity for simultaneous fluidisation of mixtures of anatase concentrate and charcoal for carbochlorination. It was concluded that the operating limits on chlorine gas velocity will be controlled by the behaviour of the reducing agent, mainly because of its lower density. An increase in temperature from 1 073 to 1 273 K will have only a small influence on the fluid-dynamic behaviour of the mixture. For bubble fluidisation, the maximum sizes 0.413-0.478 mm for anatase and 0.529-0.611 mm for charcoal will be adequate. When the particle size distribution is large, fluidisation will be feasible only if conducted in two stages, otherwise the residence time of the small particles in the reactor will be very short. New diagrams will be needed for the gaseous chlorides in the second stage

Jun 21, 1905

By H. Forster, F. H. Koenemann, U. Knittel

The greenstone belt developed along the Sandawana line, an anastomosing, transcrustal shear zone. The lode gold is concentrated in veins and along brittle-ductile shear zones and other faults. Gold contents of 200 rock samples were found to be well below economically significant levels, excluding purely syngenetic deposit formation. Average gold content of unmineralised banded iron formation decreases from 7.3 ppb in the east (Manica) to 1.6 ppb in the west (Odzi), where depletion reflects hydrothermal leaching. The mineralising fluids may have been generated during deep crustal deformation, metamorphism and magmatism. Gold was hydrothermally deposited during carbonatisation and sericitisation of ultramafic and mafic rocks and during hydrothermal overprinting of banded iron formation and felsic rocks. It is present in native form and as microscopic to submicroscopic inclusions in pyrite, arsenopyrite and pyrrhotite. Argentiferous galena and other sulphides are commonly observed. Rezende, which produced over 38 t Au, is hosted by a granodiorite stock. By-product gold was produced from Cu-Ni sulphides at Mundonguara. The deposits are related to the older, but not the younger, of the granitoids intruding the belt's supracrustal sequences; the estimated age of mineralisation is 2700-2600 Ma. Odzi district, with 61 mines, has produced only 3.5 t Au as its higher-level host rocks have apparently been eroded. Mutare (formerly Umtali) district, with 133 mines and 9 placers, has produced 68 t Au (65 t from Rezende and adjacent deposits), and Manica district, with 23 mines and 8 placers, 12 t Au. Estimated reserves for the Rezende area are 20 t Au and for Manica district 4 t lode Au and 19 t placer Au

Apr 1, 1996

By T. D. Jones

Describes the facilities in South Wales for routine control and research work on all the various aspects of the dust problem. Considers mining and medical research, inspection and control, education, and plans for the future.

Jan 1, 1947

By I. L. Whyte

apparent density and drag coefficient of porous ores on

Apr 1, 1995

By M. Gallego, R. Oyarzun, L. Ortega

Evidence of metallogenic activity in an area dominated by Upper Precambrian and Palaeozoic metasediments was partially explained in the 1980s when drilling and a geophysical survey detected hidden intrusions, but questions remained to be answered about the nature of the fluids. Sb mineralisation at El Juncalon vein-type deposit was selected for geological, geochemical and fluid inclusion studies as a model with a relatively simple quartz-stibnite-pyrite paragenesis. Many of the characteristics were those of Chinese-type vein Sb deposits, which can be regarded as atypical of the epithermal type as they are hosted by clastic rocks

Aug 1, 1995

By P. H. Morris

To achieve the full potential of sub-aerial co-disposal the properties of the co-disposed wastes must be known and understood. A description is given of the morphology and properties of waste deposits that were formed during 19 field trials of sub-aerial co-disposal at the dual Goonyella-Riverside mine in Queensland and at Hunter Valley No.1 and Warkworth mines in New South Wales

Jun 19, 1905

By S. Kelebek, J. A. Finch, Zhenghe Xu, S. R. (Ram) Rao

To improve SO2 emission compliance, pyrrhotite from Sudbury copper-nickel ores is being depressed with DETA. To understand the mechanism of depression, the role of complexing in controlling metal-ion activation of pyrrhotite was investigated. DETA was found to remove Cu and Ni ions but leave hydrophilic ferric species on the pyrrhotite surface. The metal:DETA ratio appeared to be 1:2. Cu was more readily removed than Ni, but the combination of DETA with sulphur dioxide was equally effective for both metal ions. Certain combinations of DETA, Ni ions, xanthate and dithionite (S2O4) or dithionate (S2O6), as representative derivatives of SO2 in water, produced hydrophilic precipitates. These may enhance pyrrhotite depression

Jun 19, 1905

By T. Guyaguler

An analytical technique using computer-based multiple-regression methods was employed to determine the relation between the dust-producing index and inherent rock properties of typical samples from a coal-producing area, one of the aims being to provide a preliminary predictive tool for practical use. The investigation demonstrated that factors varied in their influence under different conditions, the brittleness:toughness ratio and the hardness being the most significant inherent properties with hardness showing the highest positive correlation coefficient

Jun 13, 1905

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By D. L. Buchanan, ed. sci.

The issue comprises 10 contributions on PGE mineralisation, of which 9 were presented at the symposium organised by the IAGOD Commission on Ore Deposits in Mafic and Ultramafic Rocks and the BRGM-CNRS University of Orleans research group. The editor's introduction and summary of the papers is presented together with the title page, contents list and cover photograph of a harzburgite ridge, dunite boundary and chromite quarry in the Shetland ophiolite on Unst

Apr 1, 1994

By W. Doherty, P. C. Lightfoot, V. A. Fedorenko, N. S. Gorbachev, V. I. Kunilov, A. J. Naldrett, Z. Johan

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. A model is presented which regards the Lower Talnakh- and Talnakh-type intrusions as part of the plumbing system for the overlying lavas. As magma ascended along the Noril'sk-Kharayelakh fault it was forced to spread out within sedimentary strata immediately beneath the obstruction of the accumulated volcanic sequence. Here it was severely depleted in chalcophile elements by sulphides, which were then trapped by their high density and remained behind in the main arteries to form the central, elongated zone of maximum thickness. Subsequent magma also lost Ni, Cu and PGE to the sulphides as it flowed through. The Lower Talnakh-type intrusions represent part of the plumbing system that became blocked at an early stage, before the influx of much mokulaevsky-type magma rich in chalcophile elements. The model accounts for the high metal content of the ores in comparison with the size of their associated intrusions, the extensive metamorphic aureoles, the chalcophile depletion of some overlying volcanic suites, the presence of the ore in near-surface intrusions rather than deep magma chambers, and the sulphur isotopic composition of the ore

Apr 1, 1995

By P. E. J. Pitfield, S. D. G. Campbell

The regional shear zone runs along or near the southern margin of the Chinhoyi greenstone belt. It hosts four of the seven mines in the southern part of the belt with recorded production above 100 kg Au, including the top two current producers. Displacement occurred in the late Archaean, producing a shear zone with a trend ranging from northeast at Golden Kopje to east at Muriel. The orebodies at the two mines formed synchronously with the shearing and show strong but contrasting structural controls on mineralisation. The Golden Kopje orebodies plunge to the southwest, parallel to the intersection of curved foliation with discrete shear planes and sub-perpendicular to local stretching lineations. The Muriel orebodies plunge steeply west but parallel to local stretching lineations. The greatest fluid flow during mineralisation of the shear zone was along either the intersection of fabrics (Golden Kopje) or the extension direction (Muriel). There is no unique relation between the orebodies and the extension or shear direction. Where earlier mining has not established the directions of the oreshoots it is essential to understand the possible structurally controlled geometries of orebodies before planning a drilling programme to evaluate their potential

Apr 1, 1996

By Emanuel Shinwell, Douglas Hay

"Opening statements relating to the health and welfare of underground workers and the nature and prevention of silicosis and pneumokoniosis. During 1945-47, 10,500 UK coal-miners were certified by the Silicosis Medical Board to be suffering from pneumokoniosis and suspended from work in the industry. Over 80% of cases occurred in the South Wales coalfields. Silicosis and pneumokoniosis also occur among metalliferous miners, such as the tin-miners of Cornwall. The slate-quarries of North Wales are also troubled by these conditions as are the haematite mines of the North-West of England."

Jan 1, 1947