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By W. Doherty, P. C. Lightfoot, V. A. Fedorenko, N. S. Gorbachev, V. I. Kunilov, A. J. Naldrett, Z. Johan

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. A model is presented which regards the Lower Talnakh- and Talnakh-type intrusions as part of the plumbing system for the overlying lavas. As magma ascended along the Noril'sk-Kharayelakh fault it was forced to spread out within sedimentary strata immediately beneath the obstruction of the accumulated volcanic sequence. Here it was severely depleted in chalcophile elements by sulphides, which were then trapped by their high density and remained behind in the main arteries to form the central, elongated zone of maximum thickness. Subsequent magma also lost Ni, Cu and PGE to the sulphides as it flowed through. The Lower Talnakh-type intrusions represent part of the plumbing system that became blocked at an early stage, before the influx of much mokulaevsky-type magma rich in chalcophile elements. The model accounts for the high metal content of the ores in comparison with the size of their associated intrusions, the extensive metamorphic aureoles, the chalcophile depletion of some overlying volcanic suites, the presence of the ore in near-surface intrusions rather than deep magma chambers, and the sulphur isotopic composition of the ore

Apr 1, 1995

By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

By N. T. Moxon, D. Mead, S. B. Richardson

A laboratory and theoretical study of air decks was carried out to assess the effects of the size and location of air-decks on fragmentation. The degree of fragmentation was found to depend on both factors. As the size of the air-deck increases the degree of fragmentation is reduced relative to a full column charge. However, the reduction is relatively small until a critical size is exceeded. The critical size depends on the strength and structure of the surrounding material. A critical air-deck length of 30-35% of the original explosive column was determined for the model materials used in the study. A theoretical explanation of the results was derived based on pressure decay rate relationships. The location of the air-deck also influences fragmentation. The interaction and oscillation of the two shock fronts from the top and bottom charges mean that mid-column air-decks produce better fragmentation for the same air-deck length and explosive loading as top-column or bottom-column air-decks.

Jan 4, 1993

By A. J. Naldrett

"Synorogenic mafic intrusions are a common feature of the northern Appalachians. Two sulphide-bearing intrusions in central Maine that have been investigated revealed a number of important features that illustrate sulphide-silicate interaction that relates to magmatic sulphides. The Moxie Pluton is a large mafic intrusion emplaced during the Devonian Acadian orogeny. The Katahdin gabbro is a small mafic body that is probably genetically and temporally related to the Moxie Pluton. Both intrusions were formed bv the intrusion of variably fractionated magmas into irregular chambers and feeder zones. The southern half of the Moxie Pluton contains three small sulphide accumulations, whereas the Katahdin gabbro hosts a large, predominantly massive, sulphide body. Textural evidence clearly documents the magmatic origin of these sulphides.The three Moxie Pluton sulphide bodies are located at or very close to the intersection between the intrusion and the sulphidebearing Hildreths Formation. Sulphur assimilation, suggested by this relationship, is supported by the isotopically light (634S = —8 to —25) and the selenium-poor (S/Se - 25 000-48 000) character of the Moxie sulphides and correlation with the Hildreths Formation sulphides (S34S = —25, S/Se = 25 000-48 000). Isotopically light sulphur (534S = —20 to —21) and high S/Se ratios indicate that the majority of sulphur in the Katahdin sulphide body was also derived from an unexposed country rock source. The volume of sulphide in this example illustrates the potential efficiency of the sulphur assimilation process—so efficient in this case that marked dilution of the economic chalcophile elements resulted from the addition of so much external sulphur.The three Moxie Pluton sulphide occurrences are all impoverished in Ni and Cu (1.87-0.44% Ni; 0.72—0.32% Cu in massive sulphide), but contain normal Co contents (0.22-0.13%) relative to typical magmatic sulphides. The Katahdin sulphides show a greater Ni and Cu impoverishment (0.2% Ni; 0.1% Cu in massive sulphide) with similar Co (0.17%). The Ni content of the Moxie Pluton olivines document the fractional removal of sulphides during crystallization of the host magma, which resulted in the progressive depletion of the chalcophile metals in this magma. Modelling that involved the fractional crystallization of the magma coupled with the fractional removal of a specified proportion of sulphide has successfully duplicated the Moxie Pluton sulphide compositions. A similar magmatic model has been postulated for the Katahdin sulphides with a greater degree of sulphide fractionation. This latter model is again supported by extremely low Ni/forsterite ratios in olivines, though the compositional range is insufficient to document fractionation. These magmatic models are not unique, but they provide a relatively constrained and consistent explanation for the sulphide compositions.The Ni contents of olivines are the most important indicator of sulphide-silicate interaction in mafic magmas and have exploration potential. They provide a means of assessing the timing and extent of sulphur saturation in an intrusion and are a guide to the Ni content of a sulphide accumulation in equilibrium with olivine. In the Maine examples they provide strong evidence of the magmatic origin of the sulphide accumulations and justification for magmatic modelling."

Jan 1, 1984

By C. J. Kirkland

25th Julius Wernher memorial lecture given at Tunnelling '91, sixth international tunnelling symposium held in London, 14-18 April 1991. The title gives the lecturer a chance to share some of the lessons he has learnt in a lifetime of tunnelling and particularly in the last six years of his involvement with the Channel Tunnel and the International Tunnelling Association. These included: the difficulties of split contracts but the problems arising with Eurotunnel over the need to create a single owner to whom the banks could lend; the peripatetic nature of tunnellers who built London's underground in the 1960s and returned to build the Channel Tunnel from Egypt, Singapore, Hong Kong and Australia; the increasing requirement for strategic planning resulting in tunnels between European countries and the need for engineers to deal with decision-makers; EU work on harmonising regulations so that there need no longer be, for example, arguments over which regulations should be followed for temporary electrical equipment in the section of the UK tunnel that is technically in France; the huge improvements in safety standards and attitudes; the enormous increase in the scale of undertakings and individual contracts, with an accompanying change in attitudes to logistics; technological advances to cater for the high performance now required of equipment; and the rising importance of environmental issues. The lecturer also briefly touches on the work of the International Tunnelling Association

Jun 13, 1905

By Tawsaporn Nuchanong, Ian Nichol

Investigations of the dispersion of gold in soils and stream sediments associated with three gold deposits in Thailand indicate the existence of different geochemical dispersion patterns in the three areas, demonstrating the need for the adoption of a variety of exploration techniques. The three gold deposits which were investigated were the Phu Tham Phra-Phu Thong Daeng copper-gold prospect, the Doi Tung and the Huai Hin Lab gold prospects. Overall the investigations at the three localities demonstrate clearly that the chances of exploration success can be significantly enhanced if composite soil samples are analysed to ensure a more reliable estimation of the gold content in soils and if both the 63 micrometre fraction and the field-panned concentrates of stream sediments are analysed because of the variable grain size of the gold characterising different gold deposits and surface environments.

Jan 4, 1992

By J. A. Finch, D. Lin

The robustness of the large-sections correction procedure, Hill's fast approximation, Barbery's correction and the PARGEN correction was examined by comparing their ability to reconstruct the true liberation distribution using sectioning data from computer-generated spheres. The results indicate that the flexibility of a correction procedure is related to the assumptions it makes about the continuity of the liberation distribution, locked-particle characteristics and ore texture. Overall, the large-sections procedure appeared to be the most generally applicable. The Hill fast approximation performed well, but this was probably because it partially incorporates the sphere model; the performance of the PARGEN and Barbery corrections varied from case to case.

Dec 1, 1995

By A. Berckmans

The key variables in the financial analysis of a mining project include the metal price and the quantities of ore and metal. In general, if the metal price drops, the cutoff grade is increased so as to increase the average grade. This causes recovered tonnages of ore and metal to drop. Discussion is presented of the development of a new method to evaluate the relationship between the cutoff grade, z, the ore tonnage above cutoff, T, and the metal quantity above cutoff, Q. Detailed information is provided on the QTz curves for lognormal and inverse gaussian (Sichel's) distributions. Both these distributions are used as models for the grades in different types of ore bodies, and they are both T-symmetric. The geometry of the QTz curves is simplified, making it easier to work out the impact of minor variation in the parameter values for each distribution

Dec 1, 1996

By Ruddle R. W.

Although copper has been smelted for many years, relatively small attempt has been made in the past to examine the fundamental physical chemistry of the processes involved. Therefore, technological developments apart, slow progress has been made with the development of improved or new principles of smelting. The methods at present in use in the majority of the world’s smelters are essentially those employed at the beginning of the present century; it is significant that many of the textbooks on copper smelting, written some 50 years ago, are still regarded as standard works. The book is divided into seven chapters. In the first the fundamentals of modern smelting processes are briefly outlined for easy understanding of the subsequent sections, while the next two chapters are confined to the more theoretical aspects of the constitution of mattes and slags. Some problems of considerable practical importance are discussed in the remaining four chapters; these are (1) magnetite formation, (2) copper losses during smelting, (3) the recovery of sulphur from the smokes produced during smelting, and (4) the elimination of impurities. A collection of thermodynamic data relevant to copper pyrometallurgy is presented in an appendix, and, for the convenience of readers not well acquainted with thermodynamics, a brief explanation of the thermodynamic terms and methods employed is given in a second appendix

Jan 1, 1953

Thermodynamical data of importance in connection with copper smelting have been reviewed and a collection of the most reliable information is presented in Tables XXV-XXVIII and Figs. 67 and 6 8 (folding plate). The data given in these figures and tables consists of (i) graphs and equations showing the variations in the temperature range 0-2000°C. of the standard free energies of formation of most of the oxides and sulphides met with in copper smelting (Table XXV and Fig. 67); (ii) equations showing the temperature variation of the free energy of formation of iron silicates (Table XXVI); (iii) graphs showing the variation with temperature in the range 1000°-1600°C. of the standard free energies of the principal reactions occurring in the smelter (Fig. 6 8 ); (iv) the standard heats of formation at 1200°C. of the main iron and copper compounds and gases reacting in the smelter (Table XXVII); (v) the standard heats of reaction at 1200°C. of a few of the reactions for which the free energy relationships were given in Fig. 6 8 (Table XXVIII). The data presented are discussed in more detail.

Jan 1, 1953

By J. C. Griffiths

There are two kinds of problems concerning the elements of a population : the first is to estimate the proportion of some specific kind of element in the population, e.g. the amount of gold in a block of ground (equals population) or the proportion of mercury in a sample; the second is to estimate the length, breadth, volume, etc., of a specific kind of element, e.g. the grain size of quartz grains in a beach sand or the size, shape and arrangement of lenses of ore in an ore deposit. Given a specific objective, a bounded population, identified elements and the element characteristics of interest, it is then necessary to select a sample of the elements from the population and the problem of sampling requires a decision on how to select the sample. It is also necessary to establish, either by heuristic analysis or empirically, based on long experience, the model frequency distribution of the desired element characteristics: in general, constant-probability models are used as models, the binomial or Poisson for count data and the normal distribution for measurements (or their transformed equivalents). The objective of sampling then becomes to obtain an appropriate statistical estimate of the desired population parameter: for example, the estimators may be the mean (X) and variance (a2): these should be unbiased sufficient estimators of their corresponding parameters (u, a2, respectively). Statistical tests are performed in order to determine that the estimators are of the appropriate kind: all statistical tests are designed to test against bias of a specific kind, although they are stated as tests against randomness. Given a random sample of some population, the estimators are usually stable and adequate to solve the sampling problem. Random samples are simple to define but exceedingly difficult to achieve in practice: in selecting a sample, if every element in the population has an equal chance of occurring, then the sample is a random sample. Interaction between the arrangement of elements in a population, i.e. its structure, and the sample selection process frequently introduces bias—that is, some elements have more chance than others of appearing in the sample and, hence, the sample is not random. An algorithm for dealing pragmatically with this aspect of the sampling problem offers one way of achieving random samples and, therefore, adequate estimators. Examples of the use of this algorithm on various kinds of geological populations, in both field and laboratory, illustrate the requirements for solving sampling problems and the achievement of appropriate estimators.

Dec 1, 1971

The mineralogical composition of the ore was determined and the mineral phases with which nickel is associated were identified. The ore was prepared by grinding to -420 micrometres and classification into granulometric fractions. Prior to the main series of experiments the effect of agitation rate on nickel recovery was investigated. The influence of sulphuric acid concentration, temperature and particle size on the kinetics of nickel extraction was then studied, both quantitatively and qualitatively, over fixed value intervals. Application of the initial rate method enabled determination both of the order of reaction with respect to sulphuric acid concentration and the activation energy for the dissolution of nickel. The results indicate that a physical mechanism can be ruled out as the rate-determining step in the extraction of nickel from the ore and that a chemical mechanism is more likely

Dec 1, 1991

By P Shead, M A. Tuck

Both climate and methane control have been a prime concern in the development of the workings within the Deep Soft seam at Harworth Colliery. This paper describes the numerous methods employed over the past 15 years to effect control over these two major environmental pollutants at Harworth and describes a future method of working which will enable the output levels required to be achieved, whilst effecting the required level of both climatic and methane control. Firstly, the paper gives a broad historical overview of the steps taken since 1981, when production started in the Deep Soft seam at Harworth Colliery, to effect control over the main environmental pollutants in the seam. Secondly, the paper details the results of planning exercises undertaken to assess the various options with respect to panel layout, to achieve environmental control in future production districts. Finally, the recommended method of panel design to achieve the levels of production required is detailed.

Jan 7, 1997

By A. B. Holland-Batt

Deposition velocities play an important role in many fields of engineering and an impressive range of measured data has accumulated in the literature. Numerous workers have addressed the problems that are associated with the prediction of deposition velocity because of its particular relevance to the design of pipelines and pumping stations. However, despite this extensive effort, the calculation of friction heads still requires reference to experimentally based graphs to determine Durand factors and there is still scope for improvement in the prediction of the deposition velocity at different solids concentrations. Equations to characterise the relationship between the Durand factor and the volume concentrations of solids in the slurry are presented. A correlation for the prediction of the deposition velocity is also developed and tested against some of the classical experimental data. The application of predicted values of deposition velocity in assessing the potential for the sanding-up of spiral separators is then described and a case study is presented.

Jan 12, 1992

By R. Scheepers, J. E. Misiewicz, A. C. Fitzgerald

Discussion by A.C. Fitzgerald of the paper, published in Trans. IMM A, vol.104, 1995, p.B121-B135, is presented together with the authors' response. Fitzgerald points out a number of problems with the idea of mineralising fluids leaving no trace in the large volumes of rock traversed before depositing all minerals of value in a particular horizon or rock type with which the required isobaric or isothermic surface also coincides. He suggested that in the case of the Rooiberg tin deposits, the Lebowa Granites may be batholiths that reached the surface and were capped by sheets of their own volcanics. The authors agree that they had considered a possible syngenetic origin for the stratabound deposits, explain that no conclusive evidence for this could be found, discuss the relative ages of the sediments and volcanics of the Rooiberg Fragment and explain the role of its low-intensity deformation and flat dip in the coincidence of an isobaric-isothermic surface with the lithological stratification

Jun 18, 1905

By F. G. Bell, S. E. T. Bullock

The investigation was undertaken as part of the environmental management programme that must be implemented on mine closure. It involved sampling and analysis of water from boreholes, the tin mine workings, trenches and pits as well as soil and dumps. Both ground- and surface water in the immediate vicinity of the mine was found to have been affected to varying degrees, mainly due to acid drainage from the pyrite dumps. Metal ions and toxic salts are taken into solution with increased acidity and precipitated in the soil when the pH rises again; there are concentrations of metal ions in the soils around the main dumps, but these do not seem to pose a major threat in a regional context. The low groundwater gradients, together with the dyke system in the vicinity of the main dumps and the impermeable nature of the Boschoffsberg rocks, make it unlikely that affected groundwater will migrate further than 1 000 m to the north and north-east. Nonetheless, it has been decided to remove the pyrite dumps

Dec 1, 1995

By Z Hu

The technique of reclaiming disturbed land by use of a hydraulic dredge pump (HDP) (which is a set of hydraulic machines for earthwork), termed 'digging deep to fill shallow has been used in the reclamation of subsidence areas in Chinese coal mines. This paper discusses the operational principle of the technique and summarises its reclamation procedures, which are being used in current reclamation practice. The soil condition reclaimed by the HDP was studied. The results showed that the pioneer crops to be planted in the reclaimed soil should be the ‘pulse’ family crops, and that improvements to the reclaimed soil and the HDP technique itself are needed. Bused on the analysis of the previous technical processes, a new rational technical model for the HDP reclamation method is presented in this paper.

Jan 4, 1996

By L. T. Matthews, C. E. Loo

During sintering, porous ore particles are easily assimilated by liquid melt. Two simple models of the process are considered: the dissolution of a solid by a liquid and the penetration of a liquid into a porous solid. Laboratory sintering studies covering a range of experimental conditions were undertaken to characterise the assimilation of large particles of ore and flux by melts formed from different mixes of fines. For ores, the process appeared to be complicated by the detachment of fines from the ore surface prior to melt formation, according to the mass of adhering fines and surface roughness of the particle. This delayed the onset of assimilation and sometimes reduced it, although melt penetration was fast and effective. Studies using different temperature profiles suggested that the assimilation of haematite was controlled by the transport of Fe2O3 away from the surface of ore particles. The assimilation of limestone depended more on thermal conditions than on the three magnesia-bearing minerals considered. Changing the composition of the initial melt significantly altered the extent of assimilation of ores and limestone, but again had a less marked effect on the magnesia-bearing fluxes.

Jan 8, 1992

By S. P. Mishra, G. R. Chaudhury

The adsorption of Cu2+ ions by Penicillium sp. displayed a dual rate, with an initial faster phase followed by a slower one. The adsorption rate increased with increasing pH due to chemical and biochemical reactions. The Cu-loading capacity of the biomass increased at higher initial Cu2+ concentrations. Above 40 degrees C the adsorption rate decreased which may be due to partial hydrolysis of biopolymers which are essential constituents of the cell wall. Adsorption kinetics followed the Freundlich isotherm and the equilibrium concentration that was calculated on the basis of the isotherm matched the observed value well. A series of theoretical adsorption curves were produced using mathematical correlations between the mass transfer coefficient, the Cu2+ ion concentration at equilibrium and at time t. The correlation between the theoretical and observed adsorption rates for different experimental conditions was good. It was concluded that the results from the study were best explained using a mass-transfer adsorption model

Aug 1, 1995

By B. D. Rayment, J. D. Wilson, G. R. Davis

Wheal Jane, situated between Truro and the Carnmenellis granite, is under development by Consolidated Gold Fields, Ltd., as a tin producer. The main or B lode comprises a complex cassiterite-sulphide ore located in shear zones along the footwall of the lowest of a series of porphyry dykes (elvans) which strike ENE and dip 35° north. Minor mineralisation follows other elvan contacts and sets of later steeply dipping fractures. The localisation and overall geometry of the deposit is explained in terms of the complex structural geology of the Lower Palaeozoic metasediments and the shape and manner of emplacement of the invading Hercynian granite of Cornwall. Variations in the thickness and grade of the orebody, and in the nature of the mineralisation, are shown to be structurally controlled by undulations of the footwall contact of the B elvan. Wallrock sericitisation is present and is applied in exploration for ore

Dec 1, 1971