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By C. A. Pickles, S. J. Splinter, J. Cameron

The addition of copper oxide to a borosilicate slag resulted in the breakdown of the silicate network and a dramatic decrease in viscosity. With increasing borax to silica ratio the viscosity was reduced by two mechanisms. First, rising sodium oxide content promoted cleavage of the Si-O bonds. Second, increasing boric oxide (B2O3) content increased the number of trigonal borate units that were converted to tetrahedral borate units by sodium oxide and copper oxide. The BO4(4-) tetrahedra decreased the local silicate symmetry, thus disrupting the silicate network and lowering the viscosity. The activation energy decreased with increasing temperature and increasing copper oxide content

Jun 13, 1905

By K. C. Dunham, M. Solomon, T. A. Rafter

Sulphur isotope ratios have been determined for 81 sulphides and S and O isotope ratios for 26 barites from the Alston Block in the northern Pennine ore field. In addition, both isotope ratios have been determined for 29 evaporitic anhydrites of various ages from European and Australian localities. The consistency of the sulphate isotope ratios over a wide area of the northern Pennines, and their similarity to values for Lower Carboniferous evaporites, suggests that the sulphate originated from Lower Carboniferous connate waters. It is suggested that these mingled with warm brines rising through granitic plutons beneath Tynehead and Upper Weardale, the aqueous sulphide ion in these brines having a delta34S value of approximately +10 per mille. The delta34S values for the sulphides range from +15.0 to -5.9 per mille and show an outward zoning with higher values in the central fluorite zones and mainly negative values in the outer barite zones. The wide range of delta34S values for the sulphide S is not characteristic of magmatic S and there is no adequate local source in the Carboniferous sediments. It is suggested that formation waters, probably mainly of connate origin, sank down sufficiently deep to become heated above 200°C before rising through Caledonian granite plutons into the Carboniferous sediments, where they spread laterally to mingle with cooler sulphatic connate water. The rising fluids were hypersaline brines carrying F, Ba, Pb, Zn, Cu and S. Temperatures of deposition calculated from galena-sphalerite isotope fractionation are similar to temperatures previously determined from fluid inclusion studies.

Dec 1, 1971

Discussion of the paper presented at the Manchester Geological and Mining Society's general meeting held in Manchester, April 11th 1916, with Mr. Leonard R. Fletcher, President, in the chair, included questions asked and points for discussion raised by Bramall V., Paton J.D., Fletcher L.R., Siddall F.N., Stoker A. and Stone T., in particular on how to eliminate dust

Dec 1, 1916

By J. A. Every-Brown

Case studies are presented of three derelict sites in Kent and Essex that provide a good cross-section of opportunities for second-generation commercial uses of former chalk, limestone, clay and gravel workings. A 240 ha abandoned chalk quarry at Grays in Essex, now known as Chafford Hundred, is undergoing mixed development to include leisure facilities, a range of housing and commercial areas and an enhanced environment. The 120 ha of Stone Marshes now comprises the Crossways business park and the Dartford international ferry terminal. Reclamation and servicing required more work than had been anticipated and the fact that the area was within the green belt added to the delays, but Blue Circle was eventually able to provide a comprehensive development of the entire area to a high environmental standard. Stone Pit 1 landfill, at Dartford in Kent, is a former chalk quarry 40 ha in area and with an original average depth of 35 m. Landfilling commenced in 1976 and during the period 1979-1984 the site operator designed, developed and installed a gas collection and flaring system. From 1986 a gas plant supplied up to 5 000 000 therm/yr of landfill gas to a local cement works and in 1989 a 1 MW power generation scheme, later expanded to 3 MW, was commissioned. Gas is currently also supplied to a metal refining company for use in internal combustion engines

Aug 1, 1994

By J. A. Finch, Zhenghe Xu, Z. A. Zhou

Whether the microscopic bubbles generated by the high energy dissipation and high feed-slurry velocities in new flotation cells are stable in solution and what roles they play in particle collection are of great interest for the flotation of fines. Experimental work has shown that, with fast flow of liquid through an orifice, stable microscopic bubbles can form in flotation systems by hydrodynamic cavitation in the absence of gas supersaturation. The minimum flow rate at which bubble formation is initiated varies from 8 to 15 m/s, depending on the design of the cavitation tube, which is within the range of feed slurry velocities of some newly developed cells. Feed aeration enhances the formation of micro-bubbles by hydrodynamic cavitation. The study suggests that the fast flotation kinetics of some new cells may be attributed in some degree to the formation of microscopic bubbles

Jun 21, 1905

By J. Drzymala, K. L. Wolters, T. Chmielewski, T. D. Wheelock, D. H. Birlingmair

Microflotation tests were conducted with a modified Hallimond tube equipped with a fritted glass disk and magnetic stirrer to determine whether the results would support an equation that predicts a linear relationship between particle size and the reciprocal of particle density in water for a specified flotation recovery in a given time. Data obtained with the tube for either hydrophilic or hydrophobic solids fit the equation satisfactorily. It was also shown that the natural flotability of molybdenite is somewhat less than that of elemental sulphur and that sodium dithionite is a good depressant for sulphurised pyrite. In addition, it was found that the untreated pyrite and galena used in the study were hydrophilic and did not float by particle-bubble attachment.

Jan 4, 1992

By D. C. Bailey, D. I. Hodson

Paper presented at the annual joint meeting of the IMM and IMinE held in Harrogate, 31 January 1991. The Neves-Corvo copper-tin mine is the highest-grade large-tonnage copper operation in the world and is now arguably the most significant producing base-metal mine in Europe, rating in the top ten world producers of both copper and tin. A description is given of the initial exploration work and the development of the project from the orebody discovery in the Iberian Pyrite Belt of southern Portugal in 1977 to full operating capacity in 1990. The chronological account includes discussion of the main organisational, financial, technical and environmental decisions and of the various difficulties encountered, and the challenges of the future are identified. The project was brought in on schedule and within budget

Jan 1, 1991

By A. B. Holland-Batt

Deposition velocities play an important role in many fields of engineering and an impressive range of measured data has accumulated in the literature. Numerous workers have addressed the problems that are associated with the prediction of deposition velocity because of its particular relevance to the design of pipelines and pumping stations. However, despite this extensive effort, the calculation of friction heads still requires reference to experimentally based graphs to determine Durand factors and there is still scope for improvement in the prediction of the deposition velocity at different solids concentrations. Equations to characterise the relationship between the Durand factor and the volume concentrations of solids in the slurry are presented. A correlation for the prediction of the deposition velocity is also developed and tested against some of the classical experimental data. The application of predicted values of deposition velocity in assessing the potential for the sanding-up of spiral separators is then described and a case study is presented.

Jan 12, 1992

By A. J. Beer, A. Wetherelt

Paper presented at the UK minerals industry conference held in Leeds, UK, 3-5 April 1995. Camborne School of Mines has developed a simple, cost-effective light-sectioning method that has been used successfully in tunnels and small stopes. Light sectioning provides an almost visual examination of the stope's excavated profile. An illuminated section of walls, roof and floor is recorded photographically. Overbreak and underbreak can then be easily quantified by reference to the designed shape. The prototype rig is described. Use of a fish-eye lens to capture a greater field of view is discussed. Calibration was achieved by comparison with images made with a conventional wide-angle lens with nominal distortion. The system is reliable under a range of operating conditions including dust, heat and humidity. It is also simple and easy to use, does not require skilled personnel and is low cost

Jun 18, 1905

By Winmill T. F.

Among the various theories proposed to account for the spontaneous ignjtion of coal, one which has at times been very strongly held is that the initial heating is due to the oxidation of iron pyrites. From the results described in this paper, it is possible to calculate roughly the rate of spontaneous heating of a specimen of finely-divided pyrites, on the assumption that all the heat developed is used in raising the temperature of the pyrites, and that none is lost. It is clear that where finely-divided pyrites occurs in considerable proportion among coal, it may be the chief factor in originating combustion, but that pyrites can only be the cause of a heating when it is present in considerable proportion, and in a very finely-divided state

Dec 1, 1916

By Garforth W.

The chairman announced the new government duties of the out-going President, Sir Thomas Holland, and the formation of a new standing committee on mining to advise the Advisory Council for Scientific and Industrial Research on suitable projects for grants. Some of the potential lines for investigation into the best methods of winning and presenting coal in the best commercial condition include wasteful practices in operating steam boilers, national loss due to neglecting recovery of coal by-products, and the leaving of large areas of coal for fear of spontaneous combustion or as boundary pillars and support

Dec 1, 1916

By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

By R. J. Howarth, P. L. Llowenstein

The errors resulting from field sampling, sample preparation and analysis are investigated for drainage sediments derived from homogeneous sandstone, shale, limestone, basic igneous and granite lithologies as a background to a primary reconnaissance survey of England and Wales. Emission spectrographic analyses of approximately 350 samples for Al, Ca, Fe, K, Si, Ba, Co, Cr, Cu, Ga, Li, Mn, Ni, Pb, Sc, Sn, Sr and V and atomic absorption analyses for Cu, Ni, Mn, Co, Zn and Pb have been treated statistically. For routine broad-scale surveys analysis of the unground -80-mesh sediment fraction proves satisfactory. Sampling error between localities in a stream is shown to be less than spectrographic analytical error for many of the elements considered here, except where mineralisation (contamination) occurs, but exceeds the atomic absorption analytical errors in most cases. Unless it it critical to reduce the amount of between-site variability (having regard to analytical errors) in the regional survey, there appears to be no advantage in the use of a more sophisticated sampling technique. The utility of moving-average maps in reducing the width of the confidence belt around the regional 'geochemical surface', and thus compensating to some extent for the sampling errors, is also demonstrated.

Dec 1, 1971

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

Studies were carried out to examine the effect of introducing varying levels of a pisolitic limonite (Yandi) into an Australian iron ore blend. Compared with other ores in the blend Yandi is more porous. This structure is found to have a considerable effect on the sintering behaviour of the blends. Pilot-scale sintering studies and plant trials showed that sinter plant productivity, sinter reducibility and the low-temperature reduction degradation index altered significantly when the level of Yandi in the ore blend exceeded 15 wt%. The improvement in the reducibility is thought to be a direct result of increased porosity in the sinter and the presence of highly reducible pseudo-relict haematite. Plant trials have also shown that operational changes could be made to the sinter plant to avoid potential deterioration of productivity

Dec 1, 1991

By I. R. Hanby

A simple but comprehensive method has been developed for the simulation of a mechanical-drive dump truck that enables various parameters to be predicted as a function of time throughout its whole cycle. Uses of the simulation results are indicated with specific attention to environmental and operational or economic planning. The output of a sample run is presented. The method can be easily adapted for the investigation of a wide variety of mobile plants.

Jan 4, 1992

By Simons W.

The object of the paper is to describe the standards of quality that should be specified in ordering material ordinarily required for colliery use, and also the qualities most suitable for particular purposes. Tables are presented of British Standard tests for wrought iron grades A, B and C, Admiralty tests for iron in chain, the quality of material for wheels and axles, and the composition and mechanical properties of wrought iron, Armco (ingot) iron and drawbar-gear steel. (Paper presented at the North Staffordshire Institute of Mining and Mechanical Engineers' general meeting held in Stoke-on-Trent, March 27th 1916, Mr. John Gregory, President, in the chair)

Dec 1, 1916

By T. Yalcin

In the Box-Wilson method, the correlation between dependent and independent variables is represented by a polynomial response function, whose constant and coefficients are determined by applying regression analysis to the experimental data collected. The five levels used for each variable consist of a minimum, a maximum and three intermediate values. A study was carried out using Ni-Cu ore from Sudbury, Ontario, in which 15 experiments designed according to the Box-Wilson method were carried out in random order and in duplicate. The two sets of replicate data showed close similarity, with an overall variance of 0.311 for the five parameters studied. The response functions were used to optimise frother dosage, collector concentration and air flow rate and an experiment was then carried out under the optimised conditions; the results agreed closely with those predicted by the response functions

Jun 21, 1905

By I. A. Scott, T. J. Napier-Munn

Size-by-size partition curves for mineral separation in dense-medium cyclones pivot about a single characteristic point. This is defined for stable, non-segregating media by the medium density and the proportion of the medium reporting to the underflow. The pivot point departs from these values for unstable, conventional media. The phenomenon can be represented by an equation with two parameters defining pivot point coordinates and two the Ep value. On the basis of experiments in a 200 mm cyclone using ferrosilicon media, simple regression equations were developed for the separation parameters in terms of operating conditions (the coefficients were likely to be site-specific). The experiments successfully decoupled the effects of medium density and viscosity and showed that the value of Ep was independent of the former but strongly dependent on the latter. A classification model was used to predict the density of the underflow medium, a knowledge of which is required to determine the pivot parameters. The model correctly reflects the performance trends observed in dense-medium cyclone operation and has the potential to be generalised to a wide range of industrial practice.

Jan 8, 1992

By P. H. Davenport, L. W. Nolan

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Geochemical mapping provides a direct approach to delineating areas of epigenetic mineralisation and for relating the regional distribution of this mineralisation to an overall tectonostratigraphic and structural framework, as well as to extensive areas of hydrothermal alteration. Organic lake sediment is a widely available and effective sampling medium for regional geochemical mapping in Newfoundland, that has proved to be valuable in Au, Sb and W exploration

Jul 1, 1991