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By Li Shibo, C. Halls

The compositions of olivine, pyroxene and chromite from the Proterozoic ultramafic complex are analagous to those of cumulate ultramafic rocks of tholeiitic origin, suggesting that the parent magma may have been tholeiitic rather than komatiitic. The complex contains economically significant Ni-Cu sulphide mineralisation. The high sulphide/silicate ratio is best explained in terms of the segregation of sulphides from a large volume of magma, of which all but the ultramafic cumulate fraction has since been eroded. Platinum-group minerals that have been identified include sperrylite, moncheite, native platinum, froodite, merenskyite, michenerite and Pd-rich pentlandite lamellae exsolved from pyrrhotite. They are characteristically found in close association with chalcopyrite, either along the contacts between hydrosilicate and sulphide grains or in cracks within pentlandite and chalcopyrite, which may also be intergrown with galena. Crystallisation from a Cu-rich residual magmatic liquid also enriched in Pt, Pd, As, Sb, Bi, Te, Zn and Pb is postulated.

Jan 12, 1993

By P. Danson, D. A. White, S. Bashir

Composite ion exchange materials made of SnO2, TiO2 and MnO2 can be used to remove radioactive contaminants from nuclear waste streams. In several cases their selectivity and capacity are enhanced by mixing hydrous silica into the matrix. MnO2-SiO2 materials are especially useful for a number of reasons, such as their selection of heavy elements over caesium. Distribution constants and determinations of exchange capacities show that in many instances the properties of the composites are better than those of the oxides alone, while the presence of a chelating agent has been found to reduce the uptake of nuclides considerably. Methods are being developed for the bulk manufacture of the materials. Further work on sorption mechanisms is required to explain anomalous results, particularly the variation in exchange capacity for different elements and the ability of the oxides to sorb colloidal material in alkaline solution.

Jan 8, 1992

By R. J. Pine

Procedures are described for the application of risk analysis or probabilistic methods to mining geomechanics. The methods are widely applicable to existing mine design models. Detailed examples are given of plane slope failure and of pillar design based on displacement-discontinuity stress modelling and empirical strength assessment. The modelling techniques assessed are the Latin hypercube sampling method, incorporated in a spreadsheet environment, and the general point estimate method (GPEM), programmed in TurboBasic. An example GPEM program listing is included. Both methods are very convenient to use. Probabilistic acceptance criteria for slope stability after Priest and Brown are examined and alternatives are proposed where output distributions of factor of safety are approximately normal or lognormal and output distributions of safety margin are normal. The reliability index is included as a useful measure of variability with proposed acceptance criteria.

Jan 12, 1992

By A. L. W. Lips, B. P. J. Stevens, T. J. R. Barclay, E. Rothery, S. H. White

Discussion by B.P.J. Stevens of the paper, published in Trans. IMMA, vol.104, 1995, p.B1-B17, is presented together with the authors' response. Stevens questions the authors' radically different interpretation of the structural geology of the Broken Hill Block, considering that the descriptive part of the paper is a useful addition but that the conclusions are unwarranted on the basis of the data presented. A number of major points of disagreement are outlined and half a dozen additional minor points listed. In response, the authors admire Stevens's contribution to unravelling the geology of the area but defend their attempts to take the regional studies a step further, pointing out that he has misquoted what they wrote and arguing that because of the assumptions underpinning the derivation of the present stratigraphy it cannot be used to constrain structural models. With regard to shear zones, they cite the extensive earlier literature and refer to horizontal displacements shown on maps produced by Stevens et al. Detailed discussion follows of the stratigraphy and of the stratigraphic correlation problems resulting from failure to recognise the presence and significance of shears, particularly those parallel to stratigraphy. The remobilised position of the Pb mineralisation in the North Mine open cut is reiterated. It is concluded that there is an urgent need for systematic isotopic dating in the area to constrain the stratigraphy

Apr 1, 1996

By Ruddle R. W.

An outline account is given of the smelting of copper and the chemistry of the process. A table provides compositions of the more important minerals from which copper is won by smelting. Roasting is discussed as is smelting using reverberatory furnaces, blast furnaces and flash smelting. A brief discussion of converting covers the upright (Great Falls) converter and the horizontal (Peirce-Smith) converter.

Jan 1, 1953

By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By W. S. Fyfe, G. V. Albino, Ekawat Sitthithaworn

The mineralisation is associated with a composite diorite to quartz monzonite stock of Permian to Triassic age that intrudes Devonian carbonate strata. In the intrusive rocks it is associated with potassic alteration and in the carbonate wall rocks it is hosted by prograde garnet-rich and retrograde epidote-rich skarn. Both porphyry and skarn mineralisation include disseminated and fracture-controlled mineralisation, the latter probably accounting for the major part of the contained minerals. Copper, gold, silver and zinc are strongly positively correlated within the mineralised zones, although there are small differences in metal ratios between the different ore types; molybdenum appears to be negatively correlated with copper and gold. Ore minerals include chalcopyrite, magnetite and pyrite in porphyry-type mineralisation and bornite, chalcopyrite, pyrite, magnetite and lesser haematite in skarn.

Jan 12, 1993

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

By A. Ludkin

The paper presents the history of the occurrence of spontaneous combustion in the north area, together with the associated problems. These are examined and a description is given of the methods used to combat the danger, including the use of modern scientific instrumentation. Detailed reference is made to the underground trials with pack injection and sealant coatings which were carried out at Seafield Colliery following the formation of a working group to assess the performance, in the same underground conditions, of (1) sandbagging, (2) pack injection, (3) surface coating. Based on these trials, an improved and more economical method of prevention has been established. There is, however, still scope for further improvement in techniques which would take into account the problems of gradient, transport, manpower and cost.

May 23, 1905

By P. R. Ineson, D. W. James

For a criterion to be useful it must either demonstrate directly the role of exhalative processes in the formation of a deposit or describe a unique attribute of exhalative deposits. Few of those employed in previous investigations entirely satisfy either condition. The limitations of three of the most frequently employed criteria are illustrated by studies of the geology of the King Island Scheelite deposit in Tasmania.

Jan 12, 1993

By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

By Fergusson E.

An account is given of the history and operation of the Straits Tin market and the Penang price. The procedure by which the official ruling tin price is determined is presented and the way in which bids are treated is outlined: the price declared in Penang is the result of a joint operation by the two Malaysian smelters and is arrived at by finding the highest price at which the whole of the day's offerings for sale can be sold, thus reflecting the marriage of the offerings of the individual mine producers with the demand for Straits Tin from the consuming countries of the world. A system of accurate weighing, sampling and assaying of concentrates delivered to the smelters' premises enables the various ore-buying agencies of the two smelters to notify their central offices promptly of the estimated tin content of the concentrates their customers wish to price that day, so that by 11.00 a.m. both smelters will have exchanged with each other figures giving the total quantity of metal they have for inclusion in the day's market, at the same time exchanging particulars of the bids they have received. Miners are encouraged to sell regularly for cash and an evenness is thus achieved which avoids large daily fluctuations in overall quantity.

Dec 30, 1971

By D. G. Skinner, M. SC. Griffiths

"The natural difficulties associated with the size evaluation of dusts render absolute measurement difficult, or indeed, impossible. Assuming that the desirability of gravi­ metric sampling be conceded, it appears likely tha,t the most suitable means available for physical evaluation are the method of total turbidity measurement, to give a con­ ventional value for specific surface, together with microscopical examination, the great merit of the latter being that in the hands of an experienced operator, semi-quantitative discrimination between coal and other particles is possible.The pipette method, as modified by Fryer, probably-deserves more attention than it has received up to the present. Whatever method is used, it is recommended that in view of the lack of medical knowledge, as much information as possible should be obtained with reference to the total mass concentration, the surface area of the total dust,' and the mass and area of the particles below 5μ in size."

Jan 1, 1947

By A. Paulin, A. W. D. Hills

The work has shown that packed-bed behaviour can be predicted from the results of single-particle experiments, total reaction times being predicted somewhat more accurately than gas and solid temperatures and gas compositions. A small laboratory packed-bed reactor was built and used to study the decomposition of beds of specially prepared CaCO3 spheres, steps being taken to minimise the effects exerted by the walls of the bed on processes occurring within the bed. Gas and solid temperatures and gas compositions were measured at various points in the bed and compared with theoretical predictions based on kinetic data determined in previous single-particle experiments. The measured solid temperatures and total reaction times agreed remarkably well with the values predicted theoretically. Gas and solid temperatures measured after the reaction had finished at any point in the bed did not agree with the theory. This was because solid temperatures in the bed rose very rapidly once the reaction was completed and the walls of the bed could not be heated at a sufficient rate for their temperatures to rise as rapidly; thus some loss of heat from the bed to the walls was inevitable, and this could not be accounted for in the theory. In addition, the theory did not allow for the conduction of heat within the bed, and this resulted in some further slight discrepancy between the measured and predicted values, particularly after the reaction was completed. Gas compositions measured in the bed were rather scattered, but, even so, they agreed moderately well with the predictions of the theory.

Dec 1, 1971

By J R. Leeming

The paper describes a technique that has been developed by the Health and Safety Executive (USE) to make an assessment of the effectiveness of Health and Safety (H and S) management at complex sites. The paper then describes how the technique was adapted and used for the first time at a large coal mine. The results highlighted certain deficiencies in the safety management system, allowing directed advice to he given to management.

Jan 4, 1997

By Zhengya Lu, F. Lawson

The surface tensions of lead and lead alloys with very low concentrations of silver, tin and copper were measured by the sessile-drop method. The enrichment of silver and tin in the surface of liquid lead alloys at temperatures close to the freezing-point of lead was confirmed, which may explain the unusual behaviour of small amounts of silver and tin in lead bulllion during the sulphur-drossing step of the refining process. From the limited data available copper also appears to concentrate at the surface of the liquid alloy

Dec 1, 1991

By J. H. E. Jeffes, C. Diaz

The heat balance and chemical equilibria involved in the production of blister copper from a chalcopyrite concentrate in a single operation are examined. It appears that two stages—one oxidising and one reducing—will be required. The analysis indicates that on thermal grounds the process is possible with a dry, high-grade chalcopyrite concentrate, if oxygen enrichment to about 30 per cent is used, but that copper losses in the slag will be serious and will require a secondary recovery operation. More extensive data on the activities of copper oxide in slags are required to elucidate this point more effectively

Dec 1, 1971

Discussion of the paper presented at the Manchester Geological and Mining Society's general meeting held in Manchester, April 11th 1916, with Mr. Leonard R. Fletcher, President, in the chair, included questions asked and points for discussion raised by Bramall V., Paton J.D., Fletcher L.R., Siddall F.N., Stoker A. and Stone T., in particular on how to eliminate dust

Dec 1, 1916

By R. Winand, P. Harlet

he cathodes produced are of electrorefined grade; metallographic structure and surface roughness are controlled to a depth of 1.3 cm (single-side deposits); silver levels in the cathode are regulated by the presence in solution of Cl- and Br- ions; organics must be used at very low concentrations (around 0.1 mg/l with a consumption of about 0.01 mg/l/hr). The required concentrations of additives were established according to a well-defined strategy based on the consumption of organics at the cathode by a mass transfer limited-process.

Jan 4, 1992

By D. D. Lei, H. Sevim

Long-term production planning in open-pit mines requires the determination of cut-off grade, mining and milling production rates, a mining sequence, mine life and ultimate pit limits. Since these variables interact in a circular fashion, a genuine solution to the problem necessitates their simultaneous determination. A methodology with this capability is described. This comprises a group of heuristic algorithms and an unconventional dynamic programming algorithm. The method is demonstrated using data for a gold deposit in the western USA

Jul 1, 1996