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By Chen Xia

Iron separation from rare earth elements has always been an essential operation in almost all steps of rare earth element recovery and purification processes. As RE3+ and Fe3+ behave similarly in many operations the separation can sometime be either difficult or cost-inefficient. This article attempts to review the methods and options for removing the iron content within the process, with the focus on the existing or proposed precipitation and solvent extraction technologies. The precipitation of iron from REE solution as iron hydroxide, jarosite, goethite, hematite, or phosphate are briefly introduced. Methods for precipitating REE from solutions leaving iron impurities in the aqueous phase are discussed. Some proposed solvent extraction flow sheets for separating iron from REE are conceptually reviewed in this article.

Jan 1, 2013

By T. Johnson

Hydrometallurgical processes can be exceptionally corrosive. This is particularly true in acid leaching processes for copper, cobalt, nickel and rare earth elements. In the last five years, several large hydromet plants have been built in North America (Vale - Long Harbour, Baja Mining ? El Boleo and MolyCorp - Mountain Pass). Hundreds of storage tanks, extraction vessels and electrowinning cells along with miles of piping were designed and fabricated to withstand the aggressive environments inherent in these processes. One key element all three projects had in common was the extensive use of FRP in equipment design. As a material of construction, FRP provided equal if not improved durability relative to alternative corrosion resistant alloys at a considerably lower cost. This paper will highlight the extensive use of FRP in these three world scale projects and why it was chosen for each process.

Jan 1, 2013

By A. D. Dalvi

With the current economic situation, the demand for nickel and other base metals has fallen significantly. More than 440 kt/yr world nickel capacity has been taken out of production within the last year, or more than 25% of the total [1]. This situation is similar to that at the end of 1970?s and it will take a number of years for the demand to recover to the levels before the economic downturn. In the meantime, the challenges facing the industry have increased due to diminishing ore grades, more inaccessible and complex deposits, mounting capital and operating costs and the various external pressures which include socio-economic, environmental, and energy challenges. All industries will be faced with paying the ?total ownership costs? in the future. This will only increase the burden on the industry. How to cope with this in what Thomas Friedman calls the ?Energy-Climate Era? [2] will be the most pressing challenge for the next generation of metallurgists and managers. It will force us to take a broader view of the problems and the solutions beyond mere technical. The metallurgists, engineers and project managers will have to look at the overall projects and their objectives in designing the solutions, requiring a top-down strategic approach.

Jan 1, 2009

By B. Wasmund

Success in implementing new technology for metallurgical processes is not a foregone conclusion: This paper includes a survey of 23 new technology-based metallurgical plant start-ups, in which the authors have identified 7 successes, 9 difficult start-ups, and 7 failures. Success is defined not only as meeting the schedule and budget to the end of mechanical completion; the key goal is a fast ramp up to the full design production level, with minimum plant and equipment modifications required after start-up. This paper sets out the key factors that underlie achievement of a quick production ramp up curve, as determined from the authors? project experiences and a quantitative analysis of over twenty metallurgical plant start-ups, both pyrometallurgical and hydrometallurgical. Thorough test-work and pilot plants, plus appropriate scale-up to the full commercial plant, are key determinants of success in implementing new technology in metallurgical processes. Another critical factor is the number of new elements and their interactions. Project phasing is also particularly important for new technology projects, with appropriate review after each phase to develop a risk mitigation plan for the subsequent phase. New technology projects need committed champions to advance the project in the face of sceptics, but also require dispassionate and unbiased experts to ask the hard questions. As a project evolves, it is important to periodically question the appropriateness of assumptions, as well as to re-assess the relevance and completeness of data from test-work / pilot plants / industrial analogues. Sufficient human and financial resources are required to complete the often arduous implementation phase. During the ramp-up period, the operation generates little positive cash flow; however, significant expertise and capital are required for the de-bottlenecking projects that are often necessary to reach the plant?s design output level.

Jan 1, 2011

By D. L. Jones

CESL has developed a novel hydromctallurgical process for treating Cu and Ni sulphide concentrates, including bulk concentrates. Both Cu and I\i are leached efficiently into solution, using a proprietary pressure oxidation process, along with other base metals, notably Co. A previous publication has described the Cu recovery from a low grade bulk concentrate, Mesaba, using this CESL Process, including an extensive piloting campaign. Ni and Co recovery from the same solution was investigated at the time, but not finalized. This paper will describe the latest work at CESL on Ni and Co recovery from the same concentrate.

Jan 1, 2009

By C. Walker

Since the 1950's, production of ferronickel from laterites has predominantly been achieved using the Rotary Kiln -Electric Furnace (RKEF) process. The productivities of kilns and furnaces have increased steadily over the years and metallurgical smelters can now rely on a smaller number of high-powered, reliable units to meet production objectives at much lower capital and operating costs per tonne of production. Modem RKEF plants are characterized by one or more process lines consisting of one large kiln feeding one large furnace. The current benchmark is one RKEF line with a high capacity kiln feeding an 80 MW furnace to process approximately 1.3 million tonnes per year of new laterite ore. It is proposed that a single RKEF line comprising one kiln producing 240 t/h of calcine feeding a 120 MW furnace could process 2 million tonnes per year of dry new ore which, for an ore grade of 2% nickel, is equivalent to 36,000 t/y of nickel per line. The plant could also be twinned to double the capacity to 72,000 t/y of nickel. This paper reviews recent developments in kiln and furnace technology, which enable substantial increase in productivity of an RKEF plant. The reduction in the capital and operating costs of a single-line, 2 million tonne of ore per year nickel laterite facility, and accompanying improvement in energy efficiency and environmental performance compared to existing operations, are also highlighted.

Jan 1, 2009

By D. G. Tisdale

A pilot plant was installed and operated at the Xstrata Nickel Sudbury Smelter 10 demonstrate the CANSOLV SO2 Scrubbing System. A 350 m3/h slipstream (through a 10cm pipe) was drawn from two different industrial gas streams to test the performance and robustness of the scrubbing system. The system achieved high sulphur capture, typically above 99%, and proved tolerant 10 varying gas strength and dust content in the feed gas.

Jan 1, 2009

By Mark Kennedy

New technology projects, particularly those involving first-of-a-kind metallurgical facilities, have a poor track record of achieving their overall financial targets, as they incorporate technological risks in addition to normal project risks. Traditional project management tools focus on risk from concept development through implementation, but typically fail to address the additional risks associated with a new technology project including slow start-up, slow ramp-up, and failure to achieve design performance (quality or throughput). These additional risks affect future cash flows produced by the project and hence its value, typically measured as net present value (NPV) or internal rate of return (IRR). Common accounting practice is to reduce the present value of future cash flows by applying a chosen discount rate, often reflecting the corporation?s cost of capital. This discount rate does not contain an allowance for technological risk, which is often underestimated or misunderstood by both the financial and engineering project managers. This paper will focus on the topic of project risk and new technology, and how these play a role in the probability of achieving the predicted future cash flows. By properly addressing technological risk in the form of risk-weighted returns, marginal projects can be prevented from proceeding, while sound projects can be given the additional time and resources required to achieve the optimal level of front-end-loading (the level which returns the maximum risk-weighted net present value). A simple set of mathematical tools should enable engineers and financial professionals to establish a common level of understanding, thereby leading to a more accurate assessment whether a new technology project is ready to pass through its next level of approvals.

Jan 1, 2013

In view of the increasing environmental regulations that have been promulgated all over the world in the last 30 years, non-ferrous smelters and refineries have learnt and adapted to treat effectively metals'-containing process waste streams that need to be bled from the plant. However, anions such as sulfates, chlorides and fluorides-presently not a major problem ?are coming under increasing scrutiny and need to be addressed in the near future. The current paper reviews options for waste water treatment with reference to: a) types of waste streams processed b) process chemistry c) discharge options d) recovery and reuse of water and e) solids disposal. Methods to obtain zero liquid discharge ?a possible solution to eliminate discharge of above anions and residual heavy metals- are discussed with case studies. The long term goal of any non-ferrous smelter plant should be to have a zero liquid discharge philosophy-an approach that would become an epitome of water reuse and conservation.

Jan 1, 2009