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By Chen Xia

Iron separation from rare earth elements has always been an essential operation in almost all steps of rare earth element recovery and purification processes. As RE3+ and Fe3+ behave similarly in many operations the separation can sometime be either difficult or cost-inefficient. This article attempts to review the methods and options for removing the iron content within the process, with the focus on the existing or proposed precipitation and solvent extraction technologies. The precipitation of iron from REE solution as iron hydroxide, jarosite, goethite, hematite, or phosphate are briefly introduced. Methods for precipitating REE from solutions leaving iron impurities in the aqueous phase are discussed. Some proposed solvent extraction flow sheets for separating iron from REE are conceptually reviewed in this article.

Jan 1, 2013

By Boyd R. Davis

Like many pyrometallurgy researchers, Ralph Harris? work extended over both light metals (lithium and magnesium) and base metals. His work looked at feed preparation, primary production, and secondary treatment. The thermodynamic principles of chemical metallurgy allowed Ralph to move between these two groups of metals. However, these metals have few similarities when projects are being developed. The traditional ?deposit-based? drivers for base metal operations do not apply to the same degree with light metals projects. While high purity, low cost feed is important to light metals projects, it should not be considered as the main reason for a smelter project. While it is clearly understood that technology (energy costs) is the driver for aluminum production, it is less considered for other light metals. This paper will look at the break down of base and light metals? production costs to try to quantify the balance between feed costs and technology for each metal group.

Jan 1, 2013

By S. A. Shipilov

In this paper, the annual direct cost of corrosion in Canada is estimated to be approximately $41 billion. The figure does not include the indirect (user) costs of corrosion, sometimes referred to as social costs, which would essentially double the amount. Also, corrosion is shown to be a major contributor to environmental pollution, including when it results in the leakage of hazardous materials from pipelines, vessels and nuclear reactors. Industrial accidents caused by corrosion kill and injure hundreds of people annually. At present, corrosion is at the core of safety and risk analysis in several major industries such as energy generation, oil/gas production and transportation, chemical processing and petroleum refining. With the recent steam pipeline explosion during rush hour in New York killing one man, the collapse of the bridge in Minneapolis killing 13 people and another two years ago in Montreal when 5 people were killed, infrastructure corrosion is increasingly being acknowledged as a public safety concern.

Jan 1, 2009

In view of the increasing environmental regulations that have been promulgated all over the world in the last 30 years, non-ferrous smelters and refineries have learnt and adapted to treat effectively metals'-containing process waste streams that need to be bled from the plant. However, anions such as sulfates, chlorides and fluorides-presently not a major problem ?are coming under increasing scrutiny and need to be addressed in the near future. The current paper reviews options for waste water treatment with reference to: a) types of waste streams processed b) process chemistry c) discharge options d) recovery and reuse of water and e) solids disposal. Methods to obtain zero liquid discharge ?a possible solution to eliminate discharge of above anions and residual heavy metals- are discussed with case studies. The long term goal of any non-ferrous smelter plant should be to have a zero liquid discharge philosophy-an approach that would become an epitome of water reuse and conservation.

Jan 1, 2009