Search Documents

By O. C. Blade, E. L. Garton

Louisiana is one of the major oil-producing States of the country. Commercial production of crude oil in the State began in 1902 and has increased to an estimated output of 157,409,000 barrels in 1945, which is the maximum production up to this time and places the State fourth in the nation. The cumulative production for Louisiana through 1944 is 1,544,481,000 barrels, and, adding the output for 1945, the total to January 1, 1946, is 1,681,890,000 barrels. Data on annual production of crude oil in Louisiana and tentative statistics for 1945 are given in table 1. The large production of crude oil in Louisiana and the present trend to utilize petroleum in accordance with its general characteristics make it increasingly important to present analytical data for crude oils. This report is the fifth of a series presenting such data obtained on crude oils from Louisiana according to the procedure used by the Bureau of Mines. Individual analyses are given for 82 samples from 64 fields; many of the samples are from recently discovered fields, and some are from new producing formations.

Dec 1, 1946

By W. L. Falke

Research was conducted to develop methods on a laboratory scale for recovering manganese from manganiferous slimes and limestones . The procedure is a low- temperature modification of the carbamate process , in which manganese is dissolved and the valence reduced by treating slimes and limestones with controlled amounts of sulfurous acid . Manganese ( II) hydroxide is precipitated and leached with ammonium carbamate solution , and manganese carbonate is separated by warming the leach solution . A major portion of the reagents is regenerated and recirculated . About 75 percent of the total manganese in manganiferous slimes , and from 50 to 75 percent of the total manganese in manganiferous limestones , are recovered as manganese carbonate containing 45 percent manganese .

Jan 1, 1964

By F. R. Cattoir, R. E. Cumings

Columbium metal was electrorefined in a fused - salt electrolyte . Excellent results were obtained in lowering the impurity content in a 94 - percent columbium anode feed material to produce a 99.8- percent - pure metal . The reductions of the major impurities follow : Oxygen from 19,800 to 500 ppm , carbon from 9,700 to 25 ppm , iron from 9,200 to 630 ppm , nitrogen from 2,100 to 90 ppm , and silicon from 750 ppm to not detected . Columbium with a purity of 99.9 percent was produced from 99.5- and 99.8 - percent grades of columbium. The investigation was devoted to the evaluation of a fused - fluoride - salt electrolyte ( KF - NaF- K₂ CbF, ) for electrorefining columbium. The effects of the columbium concentration and the voltage upon the product's purity were investigated . The effect on the cathode current efficiency of ampere - hours of deposition and the formation of a dual valence state of the columbium was also investigated .

Jan 1, 1964

By Raymond B. Ladoo

Silica , or silicon dioxide , ( Si0, ) , occurs in a free state chiefly as quartz , but hydrous silica ( amorphous silica carrying a variable amount of combined water , 2 to 13 per cent ) , occurs as opal , flint , diatomaceous earth , tripoli and so on . Quartz is found in many forms , the most important of which are ; As vein quartz; quartzite ; sandstone ; silica sand and gravel ; as crystals or crystalline grains , masses or aggregates in igneous rocks such as granites , dicrites and pegmatites . Commercially silica is used in many ways , but ordinary uses of sand and gravel are so well known that they will not be considered here .

Jan 1, 1922

By D. J. Donaven, Manuel Gomez, W. S. Landers

Bulk density tests were made on a Western U.S. coke oven plant blend to obtain bulk density control data that would be directly transferable to plant practice . Maximum bulk density values were obtained at zero surface moisture . Increase in surface moisture to about 6 percent decreased the bulk density to a minimum value . Increase in the fine grinding of the blend , at constant surface moisture , decreased the bulk density . The effect of oil on bulk density was observed with five oils at concentrations ranging from 1/8 to 1-1 / 2 gallons per ton . Maximum bulk densities were obtained within the 1 / 2- to 1 - gallon - per - ton range . Essentially the same bulk densities were obtained with petrolatum- and nonpetrolatum- containing oils . Storage effects were observed on samples tested at selected intervals from 0 to 56 days . No significant change in bulk density took place if no surface moisture was lost during storage .

Jan 1, 1964

By C. E. Wicks, J. E. Tress, F. E. Block

The Bureau of Mines investigated the effects of gamma radiation on materials and chemical reactions to obtain information that could be of value in modern metallurgical practices . Various combinations of metals and their ores and compounds were irradiated in attempts to effect reactions that might be applicable in the extraction and separation of metal values from minerals and The types of reactions studied included complexing of salts , decomposition of hydrated salts , metal chlorination reactions , leaching of ores and minerals , halogen exchange , and various reducing reactions . All irradiations were performed at the Materials Testing Reactor Gamma Facility of the U.S. Atomic Energy Commission at Idaho Falls , Idaho . Spent fuel elements were utilized as the source of the gamma radiation . Some irradiation - induced changes , ranging from mere color change to participation in chemical reactions , were noted . The greatest value of these investigations , however , was the experience acquired , which should be valuable in future explorations of similar nature .

Jan 1, 1964

By Victor E. Kral

The Valery fluorspar deposit , also known as the Hamilton deposit , is northeast of Lovelock and 4 miles by poor dirt road east of U. S. Highway 40 . It is in the Humboldt Mining District , on the west side of the Humboldt Range , at an altitude of 6,000 to 6,500 feet . The property was examined by the Bureau of Mines on February 83/ and April 8 , 1944.4/ The last examination was made with an engineer of the Geological Survey.5/ Exploring by means of trenches , cuts , shaft sinking , coyote holes off the shaft , and a small amount of prospecting with short drill holes , was begun in January 1945 and was completed June 30 , 1945. An engineer6/ of the Geological Survey visited the property in April and again in June 1945 to complete a topographic map of the area and to note the results of exploration by the Bureau of Mines . Only minor surface exploring had been done on fluorspar occurrences previous to the Bureau's work . No mining equipment or living facilities are on the property .

Feb 1, 1947

By Alfred R. Powell

In another paper the writer has described an investigation in which the forms of sulphur in coke were determined and described. Coke was found to contain four characteristic forms of sulphur- namely, ferrous sulphide, sulphates, ad- sorbed free sulphur, and sulphur held in solid solution in the carbon. While the coke is still in the oven, only two forms of sulphur are present namely, the ferrous sulphide and the sulphur in solid solution in the carbon. During the quenching, however, the sulphur of the coke is subjected to considerable oxidation, a portion of the ferrous sulphide being oxidized to free sulphur and sulphates, while the solid solution form remains unchanged. The coke, however, loses no sulphur during this process, since the free sulphur which is formed ie retained by the coke in an adsorbed form. Since this oxidation of the ferrous sulphide took place so easily, an inves- tigation was undertaken to determine whether this property could not be taken ad- vantage of in some industrial process for the desulphurization of coke. Although it is true that such a roasting process would not touch the solid-solution form of sul- phur, still the removal of the ferrous sulphide sulphur would undoubtedly benefit the coke from the standpoint of the metallurgist. This improvement in the coke would result not only from the decrease in total sulphur, but also from the large decrease in the ferrous sulphide, which is responsible for the contamination of the iron in the upper part of the blast-furnace. The de sulphurization of coke by roasting in air it a new idea, but dates back to the earliest days of coke manufacture. In 1871, Philipparts published the results of some work done by him on the de sulphurization of coke by air, as well as a review of the results of earlier investigators. In the se earlier experiments, nothing was known of the forms in which the sulphur existed in the coke, while the temperature measurements were only approximate, so that altogether the results were not very conclusive nor complete. The de sulphurisation figures given by the se early investigators generally showed a low efficiency for the process, but some extraordinary results were claimed by certain inventors. In the light of our new knowledge concerning the coke sulphur, it seemed to be important enough to warrant investigation.

Apr 1, 1923

By W. H. Ode, W. A. Selvig

In 1938 , the Bureau of Mines cooperated with Subcommittee XV on Plasticity and Swelling of Coal ( C. C. Russell , chairman ) , of Committee D-5 on Coal and Coke , A.S.T.M. , by testing various methods for determining expansion and plastic properties of a series of coals of widely different coking properties . One of the tests made by the Bureau was the British Standard Method for the Crucible Swelling Test for Coal.5/ Briefly , this swelling test consists in heating 1 gram of pulverized coal in a silica crucible over a gas flame under prescribed conditions to form a coke button which is compared in size and shape with a series of standard profiles numbered 1 to 9. These profiles are intended to cover the size and shape of buttons obtained from coals covering a wide range in plastic properties .. The number of the standard profile with which the maximum cross -sectional area of the button most nearly corresponds is recorded as the swelling index . Although the swelling test showed poor relationships with the various tests that were used for measuring expansion or contraction of coal during carbonization , it gave indications of having value in measuring free - swelling and caking properties of coals when burned on fuel beds . An opportunity to investigate this occurred when an engineer of an eastern public utility 'company reported pronounced differences in burning characteristics on grates of various shipments of Pocahontas coal . Some of these coals gave trouble by swelling 'excessively and clogging the grates . Samples were ob- · tained , and it was found that the troublesome coals gave decidedly higher free -swelling numbers than did the coals that performed satisfactorily . Also , it was found that the free - swelling index test gave better differentiation between coals than could be obtained from the coke buttons from the · ´`standard volatile -matter test or from agglutinating - value results . The results of the free - swelling tests were considered by the Subcommittee on Plasticity and Swelling , and a special group of the subcommittee , under the chairmanship of R. A. Sherman , was delegated to study the test method . Ostborg , Limbacher , and Sherman , ofthe Battelle Memorial Institute , ' investigated the various factors affecting the test and found that the swelling index was a good indication of the suitability of coal for performance on residential -type stokers from the standpoint of the coking characteristics of the coal . Data were presented also showing that the indexes wer helpful in the selection of coal for industrial underfeed stokers .

Oct 1, 1946

By Oren C. Baptist, Carlon S. Land, Eliot J. White

The water sensitivity of the oil - gas - producing sandstones in three fields in the Patrick Draw area of southwestern Wyoming was estimated by laboratory testing . The tests used to estimate sensitivity , which is a measure of the loss of well productivity if the producing formation is invaded by fresh water , are : Porosity ; permeability to gas , water , and brines ; saturation characteristics with air displacing water from the samples and by mercury injection ; and identification of clay minerals by X - ray diffraction . Laboratory results indicate that the degree of water sensitivity of the sands in the Patrick Draw, Table Rock , and Desert Springs fields vary , in that order , from moderately sensitive to highly sensitive . The main cause of the sensitivity appears to be the movement of fine particles in the pores , but the swelling of a small amount of an expandible clay mineral may also contribute to the permeability reduction observed in the samples . Laboratory results further indicate that the permeability of the sands to fresh water is seriously reduced if they are first flushed with sodium chloride brine ; calcium chloride brine is less harmful to the sands than sodium chloride brine . The low original permeability of the oil sand in the Patrick Draw field , together with its moderate sensitivity , indicate that the rate of water injection for the secondary recovery of oil will be low . Limited field experience in two pilot - injection wells confirms this prediction .

Jan 1, 1964

By T. Estelle Gardner, A. R. Taylor

Heat capacity measurements were made on sodium bromide ( NaBr ) and sodium iodide ( NaI) in the temperature ranges of 7 ° to 300 ° K and 56 ° to 300 ° K using an adiabatic calorimeter . Smooth values of heat capacity, entropy , enthalpy function , and free- energy function were calculated from the heat capacity data at 10° K intervals and at 273.15° and 298.15° K. Entropy and free energy of formation values at 298.15° K also were calculated for the two compounds using entropy values determined in this study and other data reported in the literature . The entropy values calculated at 298.15 ° K were 20.75 ± 0.06 entropy units (eu ) for sodium bromide and 23.55 ± 0.07 eu for sodium iodide .

Jan 1, 1964

By R. V. Lundquist, H. Leitch

Sodium aluminate is the principal aluminum compound formed in the sinters prepared by the lime - soda sinter process for recovering aluminum from silicate source materials . The properties and characteristics of this compound were studied to improve the efficiency of the process . Crystalline sodium aluminate was prepared by sintering stoichiometric quantities of soda ash and calcined alumina for 1 hour at 1,250 ° C. The extent of aluminum extraction from sodium aluminate was determined in water and in solutions of NaOH and Na₂ CO3 . Nearly complete extraction of aluminum from sodium aluminate was achieved only in solutions containing free NaOH in excess of that supplied by the salt through hydrolysis . About 42.2 to 68.8 percent of the aluminum was extracted in water or in solutions of Na₂ CO . The precipitation of alumina trihydrate from sodium aluminate solutions was shown to be part of a continuous , reversible reaction according to the equation Al (OH ) A1 (OH )3 + OHThe reverse reaction dissolves alumina trihydrate in NaOH solutions to produce sodium aluminate . Approximate equilibrium concentrations were determined for the reaction at 30° , 50 ° , and 70 ° C. False apparent equilibrium conditions for the dissolution reaction appear when only a small excess of alumina trihydrate is present in the NaOH solutions . A large excess of alumina trihydrate must be present before the true equilibrium point is assured . The engineering significance of the data is summarized , showing controls that should be exercised for a successful and efficient process .

Jan 1, 1964

By Scott W. Hazen

This report presents the results of a statistical analysis of a limited amount of sample and assay data from a production panel in an open - pit phosphate mine in the Phosphoria formation in Idaho . A frequency distribution analysis is shown for the assays , sample interval lengths , and products of assay and sample interval length for the millshale , furnace - shale , and main phosphate beds . Correlation techniques were used to show the relationships between assays and sample interval lengths . Within- drill - hole and between - drill - hole correlation were also examined as a means of predicting grade trends in the ore . Simulation methods , utilizing a digital computer , were used to establish assay populations that could be used for estimating grade of ore , cutoff grades , and deposit or bed identification .

Jan 1, 1964

By C. P. Haller, S. J. Aresco, R. F. Abernethy

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash- softening temperature of ash, the free-swelling index, and the hardgrove grind- ability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instruc- tions issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the con- tractor and, if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal. The Government purchased approximately 5-1/4 million tons of coal in fiscal year 1953. In connection with these purchases, the Bureau analyzed 11,435 samples. These are published for the use of Government officials and the public. A series of publications has been completed on coal analyses by States, or, where production is small in any one State, by groups of adjacent States. In addition to analytical data showing composition and quality of coals of the States, the publications con- tain brief descriptions of the geological structure of the coal basins, typical mining conditions in the various districts, the principal economic data of the industry, and the relationship of mine or channel samples to delivered and tipple samples. The present publication covers many States but deals only with the analytical data of the coals. Previous publications in this series are: Bulletin 516, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Years 1948 to 1950 Inclusive); Report of Investigations 4934, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Year 1951); Report of In- vestigations 4972, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Year 1952). Following are the Bureau of Mines technical papers published by States, with their numbers: Alabama, 347; Alaska, 682; Arizona, California, Idaho, Nevada, and Oregon, 696; Arkansas, 416; Colorado, 574; Illinois, 641; Indiana, 417; Iowa, 269 and 706; Kansas, 455; Kentucky, 308 and 652; Maryland, 465; Michigan, North Dakota, South Dakota, and Texas, 700; Missouri, 366; Montana, 529; New Mexico, 569; Ohio 344 (and Bulletin 499); Oklahoma, 411; Pennsylvania Bituminous, 590 (Supplement 645); Pennsylvania Anthracite, 659; Tennessee, 356 and 671; Utah, 345; Virginia, 365 and 656; Washington, 491 (Supplement 618); West Virginia, 405 and 626; and Wyoming, 484.

Jan 1, 1955

By K. A. Fowler, L. W. Higley

The effect of uranium on the transformation kinetics and the hardenability of a low- alloy steel was evaluated . Isothermal transformation curves were developed from metallographic studies , and hardenability was determined by standard Jominy end- quench tests . For the steels investigated , the addition of 0.15 weight- percent uranium was found to produce a significant shift in the isothermal transformation curve and caused a related increase in hardenability . These effects diminished rapidly when the uranium content was increased above 0.2 weight - percent .

Jan 1, 1964

By George H. Holmes

Beryllium deposits in the northern Virgin Mountains , Clark County , Nev . , and Mohave County , Ariz . , about 70 miles northeast of Las Vegas , were investigated by the Bureau of Mines . The investigation indicated a widespread occurrence of beryllium- bearing pegmatites within an extensive belt of mica - schist . Several deposits with significant beryllium mineral concentrations were encountered . Only a few of the samples analyzed contained more than 1 percent beryllium oxide ( BeO ) ; in many of the samples , no beryllium was reported . The average tenor of samples from the more important occurrences was 0.25 percent BeO . Chrysoberyl is the predominant beryllium mineral in the pegmatite sills ; beryl predominates in the more massive bodies . Minute quantities of cesium and lithium minerals also occur , but no columbium , tantalum , or other rare minerals were found . Ore dressing tests on a composite sample containing 0.28 percent BeO which was representative of the pegmatite sills , indicated an 85 percent recovery of the chrysoberyl ( 70 percent recovery of total BeO ) by gravity concentration in a concentrate containing 17.6 percent BeO .

Jan 1, 1964

By H. R. Shell, John L. Miller, M. V. Denny

In the mica research program conducted by the Bureau of Mines at Norris , Tenn . , many micas other than silicon fluorphlogopite have been synthesized . It has been well established since the initiation of the program that synthetic micas are important materials useful for their superior or unique properties as well as substitutes for natural micas . The possibility of controlling the physical properties of synthetic mica by isomorphic substitution of other ions in the fluorphlogopite lattice further emphasizes the importance of these materials . Accurate measurement and reporting of their properties constitute an essential part of the research program . The study of germanium fluorphlogopite is in keeping with the requirements of a comprehensive study on isomorphic substitution , specifically to identify precisely the material -- chemically , structurally , and optically . The X- ray measurements , including indexed powder and single crystal data , with a description of the methods used to obtain these data , are provided . 5 Earlier work on germanium mica by R. A. Hatch et al . (5) gave an estimate of the cell parameters from X - ray powder data , but no attempt was made to index the diffraction pattern or to determine the space group symmetry . Later work by E. A. Schatz and J. C. Withers (9) listed X- ray and optical measurements , but no attempt was made to index the mica or determine its symmetry . Roth (7) found that germanium dioxide having the a - quartz structure , when heated with equimolar percentages of MgO , CaO , Sr0 , or Ba0 at 1,235 ° C , formed ABO3 -type compounds , e.g. MgGe03 isostructural with enstatite (MgSiO3 ) . Geo₂ also has a rutile - type polymorph with Ge ++ ions in octahedral coordination . Germanium was substituted for silicon in the serpentine structure by Roy and Roy (8 ) using hydrothermal techniques . These authors wrote as follows : "The substitution of Ge + for Si + yielded a magnesia - germania serpentine , formed easily in euhedral hexagonal plates which in some instances were visible in the light microscope . Electron micrographs and the sharp X - ray diffraction patterns confirm a plate - like rather than tubular habit . " It has been shown in this investigation that substitution of germanium for silicon in the mica structure is readily accomplished without radically changing the characteristics of the mica . Substitutions in the mica structure take place in three locations : Tetrahedral , octahedral , and interlayer positions . The tetrahedral positions are normally occupied by Sit or by a combination of Sit with Al +3 the most common combination being 2A1 +3 and 6Si +4 · , The octahedral position , which has six - fold coordination in phlogopite , contains a larger cation such as magnesium . In muscovite it contains only 2A1 ions ; therefore , this mica is considered a dioctahedral mica , whereas phlogopite is considered trioctahedral . +3 The interlayer position has twelve - fold coordination with six oxygen ions from each of two adjacent tetrahedral silica layers . This is the cleavage plane of the mica and commonly contains the largest cation in the mica structure (e.g. potassium) .

Jan 1, 1964

By David W. Wisecarver

This report describes a tool to engage and/or place a Bureau of Mines type gage to measure borehole deformation in a horizontal , 1½ - inch - diameter , stress relief borehole . The tool was successfully used at a borehole depth of 105 feet . Practical usage up to borehole depths of 200 feet might be realized . The tool was designed to work inside EX- size ( 1½ - inch ID ) diamond - drill drive casing used as drill rod and through which the deformation gage is guided into an EX- size stress relief borehole . Through laboratory experiments it was found that by exercising a reasonable amount of care the deformation gage could be placed at a point within a ± .01 foot distance of a predetermined depth in a horizontal EX- size hole and that the deformation measuring piston or plunger of the gage could be oriented in the borehole within 0.5 ° of a preselected angle of orientation in a vertical plane .

Jan 1, 1964

By G. A. Burrell, G. W. Jones

As a part of the work which the Bureau of Mines carried out in 1916 and 1917 pertaining to the compressibility of natural gas , it became necessary to de termine the pressure -volume relations of several of the paraffin hydrocarbons of which natural gas is composed . Results of the work on natural gas were published in Technical papers 131 (Burrell , G.A. , and Robertson , I.W. , The compressibility of natural gas to high pressure , Bureau of Mines Tech . Paper 131 , 1916 , 12 pp. ) and 158 (Burrell , G.A. , and Robertson , I.W. , Compressibility of natural gas and its constituents with analyses of natural gas from 31 cities in the United States , Bureau of Mines Tech . Paper 158 , 1917 , 12 pp . ) , and curves were given of pressure volume deviations of the gases , methane , ethane , propane , and carbon dioxide at high pressures . original experimental data on these gases , however , were not published . The In view of many inquiries which the Bureau has received with reference to the original data on the se gases , and the importance of the pressure -volume relations from which it is possible to calculate the deviation of any natural gas who se composition is known , the original data as determined by Burrell and Robertson are pre sented below .

Aug 1, 1921

By C. V. Davis

In the lnvestlg::ìt1on of mAthods for aSS8.7ing platin",. conducted by the Bureau ot MinAs, reoent experiments have d~velopad tha~ with ce..tain orei, especially when thr, quantity Of platinum 1s eonlidarablfl, nit'!le acid w111 not etfßct a iepard-Han of platinum and pa11adium. 'lhe following m;lthod has been found to be accurate and to reiu1 t in a complete S''lun''ation of' th~3:l metals. It is therefo 1" '!eeommei:ed that 1 t ba followed rath::r- than the method of separation with nitrio acid, givèn in Technical Pape'! 270.* At line 22, pagi 14, of that paper, bAglnnlng with ~tarm th,~ metals '.'ith dilute¡ nitrio acid," strikE out the rest of the paragraph, and substttutt~ the pro_t cedure g1 ven below. ?lunder and Thuringer.. have developed mnt¡iods for th"i sflparation of palladium from all the platinum metals exoept platinum bj m ,ans of dlmethy- 19lyoxlme. They state that the~ is no action for several hours if an excess of dimeth¡lglyoxime is added to an aqueous solution of ohloroplatinic acid in the cold, alio that only on boiling is the platinum pTecipi ated ¡~d than only PST't of the platinum i srenoved from the sUut1on. They found that palladium 1s p~ecipi tated quati tat! vely in the oold as (CaH 4N40 Pd) which is insoluble tn water, dilute hydroohlorio acid, dilute acetIc aofd or in 50~ ethyl alcbhol. All of their pT'90ipi tations we~p Carl". ied out ~hile the solutions were being heated. This caused a pal"tia~recipltation of the platinum along wi th the

May 1, 1922