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By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By K. M. Connor, O&apos

Variations in overburden geology must be considered in applying subsidence prediction methodologies developed by the U.S. Bureau of Mines (USBM). To characterize rock mass overlying high-extraction coal mines, the USBM utilizes a computer spreadsheet program and modified Rock Mass Rating (RMR) system. The spreadsheet calculates an RMR based on a bed's engineering properties determined from core logs and laboratory tests. An in situ deformation modulus and a bending stiffness are computed for each bed. Stiffness-versus-depth plots identify groups of beds with similar stiffness. Large variations in stiffness between adjacent beds are considered significant horizontal discontinuities where slip is likely. Time domain reflectometry (TDR) is used to verify this hypothesis by measuring shear displacement along such discontinuities. A model of the overburden is built by assuming that a near-surface laminated beam exists above a transition zone in which large plastic slip occurs along horizontal discontinuities. Increasingly thicker groups of beds are modeled to determine the most probable beam thickness based on a comparison with measured deflection profiles. The inverse of maximum beam deflection is an index parameter known as "bridging potential," a single value that incorporates both overburden geology and mine geometry.

Jan 1, 2010

By R. Karl Zipf, Z. T. Bieniawski

"Fracture mechanics plays an important role in studies of geologic materials such as rock and coal. Yet fracture data are scarce for rock and most limited or unreliable for coal. A testing system was developed which can apply mixed mode loads to a crack tip in many rocks and geologic materials. It is possible to subject the test specimen to pure mode I, various mixed modes and a nearly pure mode II fracture load. The system is currently used to study the mechanics of fine fragment formation in various coals. Experimental measurements include KI and KII' fracture velocity and acoustic emission.INTRODUCTIONA major research program at The Pennsylvania State University is directed to understanding the fundamental mechanics of fine fragment formation in various coals. The program represents an effort to reduce the incidence of coal workers pneumoconiosis (black lung) in coal miners. The principal source of the respirable coal fragments is the cutting operation which forms and liberates the particles by a fracture process. Present understanding of the mechanics of the events which form and liberate these particles is meager (Cook, 1982).Current knowledge of the fundamental mechanisms of coal dust generation and entrainment in terms of the underlying fracture mechanics is critically needed to improve and possibly control the processes involved. Whether the cutting operation is done with a 'continuous miner' cutting machine, a plow or a longwall shearer, it is fundamentally a problem of mixed-mode crack propagation. When a cutting tool interacts with coal, it causes numerous cracks to propagate through the intact material. Numerous larger fragments are broken free, but another quantity of undesirable fine fragments is also created. The formation of these respirable fragments may be a direct result of the crack propagation process; hence, a thorough understanding of the fracture mechanics of coal is required to minimize production of the unwanted fine fragments.In most rock engineering applications, the rock material properties are of secondary importance to the rock mass properties; however, for rock fragmentation and rock cutting problems, it is rock material properties such as fracture toughness which are of prime interest (Bieniawski, 1980). Several rock cutting and rock failure theories have been proposed, but it is only very recently that fracture mechanics concepts have been successfully applied to the study of rock cutting mechanics. All cutting models seek to predict the cutting forces and the cutter geometry necessary to cause rock breakage and chip formation given some fundamental mechanical properties ~f the rock. Such models have wide applications in drilling, tunnel boring and mining problems. Nelson et al., (1985, 1986) has provided a very useful correlation between the laboratory measured fracture mechanics properties of rock and the performance of the disk cutters on tunnel boring machines."

Jan 1, 1989

By A. F. Baker

Tests were conducted in commercial foundries to determine the suitability of calcined anthracite as a cupola fuel. The calcined anthracite performed satisfactorily at two of the three foundries where iron-melting tests were conducted. Performance at the third installation was unsatisfactory because metal temperatures deviated widely and, in general, were lower than is desirable for the type of castings being made.

Jan 1, 1963

By Jeffrey Y. Foley

The Bureau of Mines sampled surface exposures of podiform chromite in the Caribou Mountain-Melozitna ultramafic belt in the Kokrines-Hodzana Highlands, central Alaska. Fieldwork began in 1979 as part of an assessment of the mineral potential of lands adjacent to the trans-Alaska pipeline corridor, for the Bureau of Land Management, and continued through 1981 as a Bureau of Mines investigation. The belt comprises six complexes of which the three closest to the pipeline corridor were investigated. Concentrations of chromite disseminated in dunite host rock make up mineralized intervals ranging in thickness from less than an inch to 5 ft and in grade from 3 to 23 pct chromium. The largest occurrence has an exposed strike length of 80 ft. Bulk surface samples were collected from 10 of these exposures, and beneficiation tests on the samples produced concentrates of metallurgical, refractory, and subindustrial grades. Part I--this report--describes the fieldwork; part II--1C 8916--describes the beneficiation work.

Jan 1, 1983

By John R. Shattuck

The Shasta and California Iron-ore deposits are 14 miles northeast of Redding, Shasta County, Calif.; and since 1907 have produced more than 300,000 short tons of exceptionally pure iron ore. Although some ore was mined and smelted from 1907 through the First. World War, most of it has been produced from 1942 through 1945 for use in making heavy ship ballast and concrete anchorages for mines. Irregular masses of magnetite, ranging from lumps of a few tons to pods containing about 25,000 tons, occur associated with skarn near the contact between the McCloud limestone and a younger granitic intrusive. Some of the deposits are low-grade, whereas others are nearly pure magnetite. Selective mining and hand sorting are necessary to produce a high-grade product. Investigation of these deposits by the Bureau of Mines included 2,910 feet of diamond drilling, some surface sampling of the principal mineralized zone and beneficiation tests. Resulting factual data are given in the body of this report.

Jan 1, 1948

By E. C. Perkins, R. S. Lang, D. M. Taylor, H. Dolezal

The amenability of titaniferous slags and domestic mineral concentrates to chlorination was determined in a 6 - inch diameter fluidized bed chlorinator . Ilmenites from Valley County , Idaho ; Aiken , S.C ,; Trail Ridge , Fla .; and MacIntyre , N.Y .; and a titaniferous magnetite from Iron Mountain , Wyo . , were used in preparing the slags . The domestic minerals tested were an ilmenite concentrate from Valley County , Idaho , and a rutile concentrate from Magnet Cove , Ark . A high - grade Australian rutile was used as a standard for comparison . The impurity content of the slags and minerals tested , which was the most critical factor affecting their performance , was dependent on the geographical source of the material . All of the materials tested were amenable to chlorination in a fluidized bed although some required special operating conditions . Titanium extractions and chlorine utilization were over 90 percent for most of the slags and the Australian rutile . The Valley County , Idaho , ilmenite performed well in the reactor despite its 34 percent iron content .

Jan 1, 1963

By Richard G. Burdick

The Bureau of Mines conducted this research to determine the feasibility of using soil redox measurements, a relatively new method in mining geophysics, to locate or define a variety of conditions that are hazardous or otherwise of interest to the mining industry. The method was used in three widely separated areas in an attempt to de- fine subsurface concentrations of methane, the edges of coal-burn areas, and a hydrothermal vein set. Both a description of the method used and test cases are given in this report.

Jan 1, 1982

By Roy L. Wilfong, LeRoy R. Furlong, Louis P. Domingues

The bulk and apparent densities , particle size , and surface area of ceria powders derived from the ammonium sulfate , carbonate , nitrate , oxalate , and sulfate salts and heated at 950 ° to 1,500 ° C for 1 to 24 hours were studied . The bulk and apparent densities and particle size generally increased , and surface area decreased with increase in temperature and time of heating ; surface area was more sensitive to changes in temperature and time than the other properties studied . These properties of the ceria powders had a marked dependence on temperature and a lesser dependence on duration of heating at a given temperature ; and the source of oxide and thermal treatment cannot be considered optional in the preparation of refractory powders by thermal decomposition . The ammonium sulfate and sulfate salts heated at 950 ° and 1,200 ° C produced oxide powders with the lowest bulk density , the smallest particle size , and the highest surface area . The highest apparent densities were achieved for oxides resulting from the carbonate and the sulfate but the carbonate - derived material was considerably coarser . The surface areas of ceria powders derived from cerium salts decrease in the order of sulfate , ammonium sulfate , nitrate , oxalate , and carbonate . The observation of these physical properties are useful in predicting the sintering behavior of various oxide powders .

Jan 1, 1964

By G. C. Price

This study traces the development of the bucket-wheel excavator, points out the differences in the German- and American-type wheels, and gives the major design criteria and the advantages and disadvantages of bucket-wheel operations. A computer program, written in FORTRAN IV for use with an IBM 360 computer, simulates the operation of the digging components of a bucket-wheel excavator. By supplying certain mining dimensions, soil characteristics, and machine design specifications, this program will print out a time study of the various components of an operation, power calculations for the operation, and production data. This program, when combined with a truck, belt, or rail program, should be helpful in planning a complete mining system In material suitable for a bucket-wheel excavator operation.

Jan 1, 1973

By W. H. Ode, W. A. Selvig

Briefly, this swelling test consists in heating 1 gram of pulverized coal in a silica crucible over a gas flame under prescribed conditions to form a coke button which is compared in size and shape with a series of standard profiles numbered 1 to 9. These profiles are intended to cover the size and shape of buttons obtained from coals covering a wide range in plastic properties. The number of the standard profile with which the maximum cross-sectional area of the button most nearly corresponds is recorded as the swelling index. Although the swelling test showed poor relationships with the various tests that were used for measuring expansion or contraction of coal during carbonization, it gave indications of having value in measuring free-swelling and coking properties of coals when burned on fuel tests. An opportunity to investigate this occurred when an engineering company reported pronounced differences in burning characteristics on grates of various shipments of Pocahontas coal. Some of these coals gave trouble by swelling excessively and clogging the grate. Samples were obtained, and it was found that the troublesome coals gave radically higher free-swelling numbers than did the coals that performed satisfactorily. Also, it was found that the free-swelling index test gave better differentiation between coals than could be obtained from the coke buttons from the standard volatile-matter test or iron agglutination-value results. The results of the free-swelling test were confirmed by the Subcommittee on Plasticity and Swelling, Coal, a special group of the Subcommittee, under the chairmanship of R.A. Shuman, worked along with the test method. Estberg, Limacher, and Shuman of the Battelle Memorial Institute investigated the various factors affecting the test and found that the swelling index was a good indication of the suitability of coal for performance on residential-type stokers from the swelling characteristics of the coal. Data were presented that also showed that the index was helpful in the selection of coal for industrial underfeed stokers.

Feb 1, 1948

By D. A. Rice

As part of its mission, the U.S. Bureau of Mines continues to develop technologies that will enable cost-effective compliance with environmental requirements. To this end, investigations to improve the kinetics of chalcopyrite dissolution by simultaneous grinding-leaching in ferric sulfate solution were conducted using the Bureau-designed turbo mill. The development of such a hydrometallurgical process would provide a nonpolluting alternative to conventional smelter technology. The effects of mill rotational speed and volume percent solids on the leaching time and energy required for copper extraction from chalcopyrite were evaluated. The results of this laboratory study have shown that the simultaneous grinding-leaching of chalcopyrite concentrate using the turbomill is technically feasible with essentially 100 pet extraction of copper being possible at 90° C. An optimal energy consumption of 1,153 kW?h/st of copper leached was found in batch testing with the mill operating at 400 rpm with a slurry containing 35 vol pet chalcopyrite. This energy consumption, while higher than other proposed leaching processes (about 600 kW?h/st), is of the same order of magnitude. Further refinement of the energy requirements would require additional testing using a continuous circuit. Leaching times of less than 1 h, for 80 pct copper extraction, are achievable using the turbomill grind-leach process.

Jan 1, 2010

By P. S. Lewis

Shortage of natural gas is reviving interest in low-Btu fuel gas made by gasifying coal in fixed-bed producers. The Bureau of Mines gasified strongly caking Pittsburgh bed coal over test periods lasting four days in an experimental gas producer located at Morgantown, W. Va, Mechanical stirring throughout the fuel bed was effective for keeping the fuel moving and this stirring made the operation successful; hence, the gas producer was named the stirred-bed producer. Nuclear density gages were applied as control instruments to indicate coal flow and fuel level, and to record the frequency and location of void spaces in the bed, The gas, of nominal 140 to 165 Btu/scf calorific value, could be burned in a boiler for generating steam.

Jan 1, 1972

By W. E. Cassan, W. L. Eaton, James Westfield, W. M. Romisher, Karl Hughes, S. H. Ash

"INTRODUCTION Funds were made available to the Bureau of Mines, United States Department of the Interior, for anthracite investigations during the fiscal year ended June 30, 1945. One of the approved projects was to conduct inquiries and scientific and technologic investigations having a bearing on the anthradite mine-flood problem. The investigative work done from July 1,1944, to June 30, 1946, is described in previous reports (5, 8, 10, 24, 28). 6/Purpose of Report The purpose of this report is to describe the investigative work conucted by the Anthracite Food-Prevention Section, Safety Branch, Bureau of Mines, during the period July 1, 1946, to June 30, 1947,Scope of WorkInvestigative work during the fiscal year ended June 30, 1947, was conducted under the direction of D. Harrington, chief, Health and Safety Division, and S. H. Ash, chief, Safety Branch, Bureau of Mines, Washington, D. C.The broad objective of the investigative work was to obtain factual day on: 1. Anthracite reserves of Pennsylvania.2. Underground water pools.3. Barrier pillars.4. The ""buried valley"" of the Susquehanna River.5. Infiltration of surface water into underground mine workings.The above-mentioned investigations are being continued during the fiscal year July 1, 1947, to Juno 30, 1948.In addition to the investigative work covered in this report, Ash end Eaton presented a paper on barrier pillars, which proposes a method for designing barrier pillars and has been Published by the American Institute of Mining and Metallurgical Engineers (5);"

Apr 1, 1948

By Frank Parrish

THIS REPORT by the Federal Bureau of Mines presents data on water-supply wells used by waterflood operators in North Texas and shows the distribution of permeable source sediments. Averages of well characteristics, including static fluid levels, working fluid levels, net thicknesses, producing rates, and depths, are presented and discussed. Essentially all water used in waterflooding is mineralized water from consolidated sediments. This study is concerned with the geology and distribution of these mineralized source sediments, whereas previous work in this area was predominantly a study of shallow sources of potable water. Tables, isopachous maps, and electric-log cross sections are included to describe the several source aquifers. In general, water-producing capacity increases with depth of the sediments. Wells completed in Cretaceous sediments 82 to 600 feet deep yield 50 to 600 barrels of water daily, whereas those completed in Pennsylvanian sediments 360 to 4,110 feet deep yield 100 to 7,000 barrels daily. Although deeper formations are used where oil and water are produced conjunctively and where large withdrawal rates are required, insufficient well data prevented mapping of deeper formations.

Jan 1, 1961

By D. G. Kesterke

The electrolytic reduction of uranium dioxide to molten uranium in fluoride baths at approximately 1,200° C was demonstrated. Electrolyte constituents were BaF2, UF4, and either MgF2 or LiF. Preliminary laboratory-scale experiments were made in which the uranium oxide was added continuously for 3 to 5 hours to the cell during electrolysis. Over 1,000 grams of metal of 99-8 percent purity was made in some tests, Major impurities were aluminum, barium, iron, silicon, carbon, and oxygen. The effects of cell design, geometry, and bath composition were investigated. Electrode arrangement was the most important factor in cell performance.

Jan 1, 1963

By N. Kumar Kittusamy

The purpose of this study was to assess the adequacy of the cab design and to determine the percentage of musculoskeletal symptoms among operators of mobile equipment used in mining and construction. A questionnaire was designed to assess demographics, work information, job history, and musculoskeletal symptoms in operators of heavy mobile equipment. Information concerning equipment included design of the seat/chair, levers, pedals, bothersome vibration, quality of ingress/egress from the equipment, proper preventative maintenance and repairs, and age of the equipment. The body regions that were evaluated included the neck, middle/upper back, low-back, shoulder/upper-arm, elbow/forearm, wrist/hand, hip, knee, and ankle/foot. Five hundred and eighty six operators completed the questionnaire. The results indicate that these workers are at risk for developing musculoskeletal disorders, and the need to quantify risk factors (i.e., whole-body vibration and static sitting postures).

Jan 6, 2006

By Clinton C. Knox

Attention of mine operators and engineers in the Picher zinc-lead field has been drawn increasingly in recent years to marginal ore deposits lying at greater than normal depth below surface in the marked structural depressions known as the Miami and Bendelari troughs. Not only mining but prospect and development drilling is relatively costly in the bottoms of the structural depressions known as the. Miami and Bendelari troughs which cross the center of the Picher field. Nevertheless, operations by various mining companies in recent years have shown that no insuperable problems exist, and with the gradual lowering of grade cut-offs throughout the field, certain potential deep-ore areas, previously only partly explored seemed worthy of further investigation. Some such areas were called to the attention of Bureau of Mines engineers by lease holders and operators, while others were noted in the course of Bureau's systematic investigation of Tri-State ore reserves. The writer was assigned to make a study of. those possible "trough extensions," in the course of which all available nine maps, drill logs, and prior reports were assembled. Subsequently 41 churn drill holes were bored by the Bureau in the periods October 1944 to May 1945 and October 1946 to April 1947. The general area under investigation this project is indicated on figure 1, which likewise shows its relation to nearby towns, roads, and railroads. The location of individual deposits included in the report is indicated more clearly on figure 3. Minable ore was found in only two holes, and the structural information procured by drilling was less encouraging than anticipated. This report, however, presents all factual data obtained, in the belief that they may be useful in subsequent prospecting and development projects in the areas investigated. There are also set forth some of the stratigraphic data relative to the Picher field ns a whole and the Miami and Bendelari troughs which were assembled in the preliminary investigation of this project.

Jan 1, 1949

By A. B. Hooker, L. C. IlsLey

"Observation of the use of trailing cables in ""mines shows that the chief limiting factor in the life of the cables and their safe use is the smashing or crushing of the cables in service, together with the effects of consequent splicing.Trailing cables are crushed when run over by cars, mining machines; and locomotives or when hit by falls of roof. Crushing damages the insulation and may cause failure at once or in later use. Failure may be either by short circuit between the conductors or by grounding to the track. The failure of a live cable causes electric arcs capable of igniting explosive mixtures of methane and air. Every cable failure in a gassy or dusty mine is, therefore, a real or potential hazard.Some mine operators do not allow the splicing of trailing cables for use in gassy mines, bet require that a damaged cable be immediately replaced and if repaired that it be used only in nongassy mines. Other operators allow the making of temporary splices to permit completion of the shift but require that such splices be remade and vulcanized before the cable is used again.Still other operators allow the continued use of temporary splices, which in general means that a cable is used until the splices give trouble in reeling, or overheat, or pull apart. Then the spliced sections are either cut out or the whole cable is replaced.Splices often determine the useful life of a cable. A splice poorly made may pull apart ueder mechanical strain and cause arcing that burn* the surrounding cable or ignites as or coal-dust. If it has lower conductivity a splice is the first part of the cable to heat; it may become so hot under load that it will burn apart and damage other parts of the cable, or, if it be a soldered splice, the solder may melt and allow parting of the cable. A poorly made splice often has insufficient insulation which may alloy short-circuiting between conductors or permit external contacts capable of giving an electric shock to one handling the cable. The splice is sometimes bulky from too much insulation and takes up too much room on the reel, causing uneven reeling; also by catching on the spooling device the oversized splice may receive expressive pulls and wear. Splicing is therefore a very important factor in the use of trailing cables."

Mar 1, 1932

By J. W. Jensen

Alloys of manganese and copper containing from 65 to 80 percent manganese possess mechanical strength and vibration-damping capacity in an unusually high degree. The success of their use in reducing vibration in structures depends, to some extent, on their fatigue properties. This report describes the results of fatigue tests on alloys of four compositions. Three metallurgical conditions were investigated for each alloy. Or the basis of the data in this report, the general rule that vibration-damping manganese-copper alloys are comparable to mild steel in hardness and strength may be extended to include fatigue strength. Methods for casting and fabricating these alloys were described in a previous report,4 which contained data on the mechanical and damping properties of the solid-solution alloys, and on alloys aged for 2 hours at 450° C. The aging heat treatment of solution-treated alloys results in optimum mechanical and damping properties throughout the range of specified composition. However, in the present work, measurements also were made on alloys aged for 2 hours at 500° C., because it was theorized that the additional precipitation of a-manganese under these conditions might have a pronounced effect on the fatigue strength of the alloy.

Jan 1, 1961