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By A. B. Needham

Graphite is a raw .material of considerable importance in both waxy and peace. Two types of graphite, classified according to particle size as flake and fines, are used, but the former is in much greater demand. The principal wartime use of graphite is in the manufacture of crucibles for melting brass and special alloys of copper and steel. Other uses in both peace and war are as lubricants, for foundry facings, and in paints, electrodes, batteries, motor and generator brushes, and a variety of other commodities. . This paper describes the operations of the Southwestern Graphite Co. of Los Angeles, Calif., which produces both flake and fine graphite from a property in Burnet County, Tex.

Jan 1, 1946

By W. J. Kroll

This report on the bibliography of zirconium has been confined to those publications and patents that appear to be useful in the commercial development of the metal, both the malleable and the nonmalleable. The methods of production have been stressed and special attention has been given to the alloys. Compounds of importance, like the oxide and chloride, for the manufacture of the metal or of the alloys have been considered. The use of the oxide in refractories anal in the glass and porcelain industries has been omitted. The present survey is critical; that is to say, an attempt has been made to evaluate the effectiveness of suggestions made in the literature. The exhaustive work of Marden and Richy, Bureau of Mines Bulletin 186, published in 1921, has been taken as a base to start from with the intention of bringing the subject up to date with material published in the last 24 years. During this time there was considerable 'advance in the preparation of the metal and Its alloys, and in the development of new uses. On the other hand, there was little progress in the methods of decomposing the ores, so that the chapter on this latter phase is necessarily short.

Jan 1, 1946

By A. Visnapuu

The U.S. Bureau of Mines investigated the oxidation of American Iron and Steel Institute (AISI) Type 304 stainless steel (SS) during annealing in simulated combustion products from several air-CH4 fuel ratios. Atmospheres representing air-CH4 ratios of 14:1 and 18:1 contained free 02, while atmospheres representing 10:1 air-CH, ratio did not. A Cr203 layer formed on SS samples annealed in atmospheres containing free 0, while a Cr-Fe spinel layer formed in atmospheres with no free 02. The Cr203 layer was adherent and presented a protective barrier to metal diffusion, effectively limiting oxidation of the metal substrate. The Cr-Fe spinel was not protective and allowed the diffusion of Fe through the spinel to the gas-oxide interface where it was oxidized to magnetite, which spalled from the surface. This resulted in thick scale layers on samples annealed in atmospheres containing no free 02, as compared to layers formed on samples annealed in atmospheres containing free 02. These results confirmed and explained industrial operators' observations that thick, smoky (fine spalled magnetite) scales form on SS annealed in low free-02 atmospheres, while thin protective oxide layers form on sheets in atmospheres containing free 02.

Jan 1, 2010

By Ellis S. Hertzog

The relatively large amount of phosphorous occurring in many iron ores limits their usefulness aid sometimes renders them valueless under present conditions of nip-iron manufacture. A practical method for removing the phosphorus would be valuable to the iron and steel industry. Gravity concentration has been of little value as far as the removal of phosphorous is concerned, because the compounds of this element are, as a rule, disseminated very finely. Removal of the phosphorous by leaching is not a new idea and has been the subject of some investigation,3,4/ out for data :lave been published. W.R. Crane published analyse of various ore bodies in the Birmingham ham district. The hard or unleached ores a .re much higher in phosphorous than the Soft, leached ores along the outcrops. This fact indicates that as mild a leaching agent as water removes phosphorus effectively if enough time is allowed for it to react. As the forms in which phosphorous occurs in the iron ores are important in the consideration of any leaching operation, much time was expended in devising a method for determining them. According to Professor McVey, University of Alabama, the phosphorous-bearing minerals in the red iron ores of Alabama have not been positively identified by any microscopic methods.

Jan 1, 1935

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1954 was made under a co-operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 101 samples of aviation gasoline. Data also are given for 30 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers I 1954 production in their laboratories and the results submitted to the Bureau of Mines for compilation. The products of 19 manufacturers of aviation gasolines and of 15 producers of aviation jet fuels are represented.

Jan 1, 1955

By Jack L. Henry

A laboratory and a pilot-plant-scale investigation has been conducted by the Bureau of Mines to examine possible sources of nitride defects in the production of magnesium-reduced titanium sponge. The production of alpha-stabilized nitride inclusions in hot-rolled titanium plate from air contamination of sponge during its manufacture has been experimentally demonstrated. Magnesium-reduced sponge prepared from air-contaminated magnesium or when contaminated by an air leak during reduction, vacuum distillation, or inert gas sweep, shows very large variations in nitrogen content. Refractory nitrides, delta TiN and epsilon Ti2N have been identified in this sponge. The highest incidence of inclusions resulted from sponge that was reduced by air-contaminated magnesium and from sponge subjected to air contamination during the vacuum distillation cycle and during helium sweep. Air contamination of sponge during the reduction cycle was not nearly as effective in producing inclusions. Tests showed that color and texture may not be reliable criteria for locating defects during sponge inspection. Maintenance of good vacuum-tight integrity, filtration of molten magnesium prior to charging into the reduction retort, and mechanical attrition of sponge to pulverize and disperse nitrides are suggested as practices to lower inclusion incidence in commercial titanium ingots.

Jan 1, 1974

By H. M. Cooper

Many analysts have had difficulty in obtaining accurate and consistent determinations of the volatile matter in low-temperature coke when the usual standard method for coal was followed. The tendency is toward too-high results, due to mechanical losses which are extremely difficult to avoid or control. With cokes there also may be an error due to excessive oxidation of the fixed carbon. Much of the earlier experimental work on the volatile-matter determination in coal, such as that of Parr,5 Fieldner and Davis,6 and others, 7 has been on the effect of time, temperatures, shape and size of crucibles, method of applying heat, and type of furnace, all of which data has evolved the present A.S. T. M.8 standard method for volatile matter in coal and coke. It is not the purpose of this investigation to deal directly with the above phases of the procedure, but rather to study some of the factors affecting she results in those types of fuel which give erroneous results due to mechanical losses.

Jan 1, 1932

By J. R. Alldredge

This Bureau of Mines report presents a computer code that has been developed for describing and testing the statistical distribution of general continuous data sets. The statistical distributions used include the normal, lognormal, exponential, chi square, gamma, and uniform. Histograms for observed and expected values are plotted for each distribution. An example using geologic data obtained from a study of the geometric properties of natural fractures in oil shale rock illustrates the use of the computer program, GDIST.

Jan 1, 1977

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

By Ellis S. Hertzog

[The relatively large amount of phosphorous occurring in many iron ores limits their usefulness mid sometimes renders them valueless under present conditions of pig-iron manufacture. A practical method for removing the phosphorus would be valuable to the iron and steel industry. Gravity concentration has been of little value as far as the removal it of phosphorous is concerned, because the compounds of this element are, as a rule, disseminated very finely. Removal of the phosphorous by leaching is not a new idea and has been the subject of some investigation,3,4/ but few data have been published. W. R. Crane published analyses of various ore bodies in the Birmingham district. The hard or unleached ores are much higher or in phosphorus than the soft, leached ores along the outcrops. Tips fact indicates that as mild a leaching agent as water removes phosphorus effectively if enough time is allowed for it to react.]

Jan 1, 1935

"There seems to be some confusion between the terms carbon black and lamp black, although in American lampblack is generally understood to be a soot formed by the smudge process. In this process oil, coal tar, resin or some solid, or carbonaceous substance is burned in an insufficient quantity of air, while on the other hand carbon black is a product resulting from the incomplete combustion of gas and is deposited by actual contact of flame upon a metallic surface.The various carbons, such as gas retort coke, oil retort coke, graphite, carbon black, lampblack, vine black, wood-pulp,black, willow charcoal, and blacks made from refuse material such as leather have different characteristics as to flocculence strength of color, and physical structure. These blacks are made by one of the following methods:(1) Formation by direct contact of a flame upon a depositing surface.(2) Production by combustion of an oil, tar, etc., in an inadequate supply of air; the soot is allowed to slowly settle out on the floors and the walls of the collecting chambers.(3) Carbonization of solids and subsequent reduction to a state of small subdivision.(4) Production by heating carbonaceous vapors or gases to a decomposition temperature by external heating with or without air in the forming chamber. This is usually referred to as cracking or thermal decomposition."

Mar 1, 1920

By J. R. Thoenen

In Progress Report 1,4/ a number of facto mere demonstrated and conclusions drawn from experimental tests and records made during commercial blasting operations at a number of quarries. For example, the tests showed (1) that vibrations received on outcrops were of comparatively

Jan 1, 1938

By C. E. Julihn, Lowell B. Moon

"INTRODUCTION To increase the supply of ore needed to produce steel the Bureau of Mines has explored 187 mineral deposits containing chromium, iron, manganese, cobalt, nickel, fluorspar, tungsten, vanadium, or coal during the fiscal years. 1940-44, the deposits thus explored were selected from several thousand that were first examined to appraise their possibilities. The objective of the exploration was to determine the tonnage and grade of ores upon which mining, operations might be based, and the metallurgical processing that was most suitable for their utilization.Most of these deposits were sub-marginal by pre-war standards; hence there had been no incentive for their exploration, yet many such deposits were known to exist that probably contained ore sufficient in grade and amount to be utilized as war reserves.Some of the Bureau's exploration projects have disclosed substantial or even very large amounts of ore, much of which is fairly high in grade. In a few of them bodies of high-grade ore have been found, though in others the tonnage has proved to be too small or too low-grade for utilization."

Mar 1, 1945

By L. E. Schultze

[The Bureau of Mines conducted bench-scale studies to develop techniques for stripping tetravalent cerium from tri-n-butyl phosphate solutions. Experiments were conducted in a constant-temperature bath using beakers and mechanical stirring. Ninety-five pct of the cerium was stripped from a 50-pct tri-n-butyl phosphate 50-pct kerosene solution containing 0.18 M cerium in 15 minutes at 50° C using 0.11 M aqueous formaldehyde.]

Jan 1, 1974

By Warren D. Longwill

All known resources within the four proposed RARE II additions to the Yolla Bolly-Middle Eel Wilderness in northwestern California occur in the Gig Butte-Shinbone study area (fig. 1). No mineral resources are Figure 1.--NEAR HERE. known in the East Fork, Murphy blade, or Wilderness Contiguous units. About 2,400 tons (2,177 t) of subeconomic manganese resources averaging 9.5 percent manganese have been estimated at the Blue Jay Mine in the Big Butte-Shinbone unit. In addition about 9,700 tons (8,793 t) of subeconomic chromium-nickel-cobalt resources in thin laterite soil at the Grubstake Prospect contain about 1.27 percent chromium oxide, 0.45 percent nickel, and 0.03 percent cobalt. Adjacent Ultramafic rock outcrops have pods averaging 2.5 percent chromium oxide (Cr203); one pod contains about 40 tons (36 t) of indicated subeconomic resources.

Jan 1, 1981

By Mulligan John J.

The Bureau of Mines investigated lode tin deposits on Potato Mountain, Seward Peninsula, Alaska. Tin was found to occur as cassiterite associated with quartz, tourmaline, pyrite, arsenopyrite, and earthy clays, but the deposits lack the varied accessory minerals commonly found in tin districts. The tin-bearing deposits are in metasediments along minor breaks and bedding planes but not in the crushed earthy filling of major faults. Cassiterite and sulfides occur with quartz in veins, both with and without earthy clays, and disseminated through tourmalinized wall rocks. The deposits are characterized by irregular segregations containing 1 to 10 percent tin within zones averaging not over 0.25 percent tin. The largest segregation exposed is on the summit of a low hill on the east-central slopes of Little Potato Mountain; most of the outcroppings are in an area trending east to west, roughly 10 to 30 feet wide and 300 feet long. Sample values ranged as high as 12 percent tin, but the average grade may be about 1 percent tin. The extreme irregularity of both grade and composition precludes a more exact determination. Similar concentrations are scattered for over 1,000 feet to the west and north, but these are smaller and lower in grade. Elsewhere on Potato Mountain, generally similar deposits occur as clusters of veinlets at widely separated points in the metasedimentary walls of major faults.

Jan 1, 1965

By Patrick D. Plumb

The Bureau of Mines (BOM) has begun a project to increase the understanding of the relationships between ecosystem health and its functions, and minerals development. The BOM, Juneau Branch, Alaska Field Operations Center, is providing support for ecosystem based land-management decision-making and the development of ecosystem based regulations by documenting the effects of mining on ecosystems and demonstrating the tools used to assess and analyze those effects. This is done by reviewing the data available on ecosystems and the environment at a mining site, the Greens Creek Mine near Juneau, Alaska, and applying available Geographic Information System modeling tools to assess the impacts of the mine on components of the pristine ecosystem. Habitat Capability Models for wildlife indicator species are used in this examination. Wildlife indicator species are used as indicators of ecosystem health by the U.S. Forest Service and the Alaska Department of Fish and Game, who developed these models for southeast Alaska. Analysis techniques from the U.S. Fish and Wildlife Service's Habitat Evaluation Procedures (HEP) are also used in this report. By applying available models and analytical techniques to the Greens Creek area, the benefits gained through mitigation of potential impacts become apparent. These or similar techniques are useful for cost/benefit analysis of mitigation alternatives. Also apparent from this analysis is that the degree to which potential impacts are observable will depend upon the ecosystem scale considered. This demonstrates the importance of defining the ecosystem and scale before performing impact and cost/benefit analysis. The watershed scale is found to be useful for assessing impacts to ecosystem components at the Greens Creek Mine. Much progress remains to be made in the modeling and prediction of impacts to ecosystems from mining activity.

Jan 1, 1994

By N. Greninger

The Bureau of Mines conducted a laboratory study of the measurement of the water and rock dust (RD) contents of synthetic mine-type coal dust (CD) mixtures using a commercial unit for measuring water content and several prototype radiometric units for measuring the RD content. The RD content ranged from 50 to 100 wt pct and the added water (AW) ranged from 0 to 15 wt pct. The total water (TW) content (intrinsic (IW) and AW) of a small dust sample could be readily measured automatically by essentially untrained personnel using a commercial unit. The RD content of a sample containing only IW could readily be measured by moderately trained personnel using several radiometric units. With gamma-ray devices, about 300 g of sample is needed. With the improved beta-ray device, about 25 g of sample is needed. With dry mine dust samples, the estimated RD error range for gamma-ray devices is 0.8 to 2.3 pct and 0.5 to 1.0 pct for beta-ray devices. However, the radiometric measurement of RD content was questionable if the dust mixture also contained AW or if it was uncertain whether the dust mixture contained AW.

Jan 1, 1988

By Richard A. Andre, R. Larry Grayson, Thomas Simonyi

"INTRODCICTIONThe search for the cause(s) of coal workers' Pneunoconiosis continues despite the vast amount of research that has been undertaken over the past forty to fifty years. Good correlation between the mass of dust inhaled over workers' lifetimes and the incidence of the disease has led to the development of effective environmental standards and implementation of good procedures for the control of dust generation and dispersion in the working place. Research has only begun, however, to uncover the biochemical mechanisms involved in initiating the disease.Correlation between the rank of the coal seam in which miners worked and disease incidence and severity is acknowledged worldwide, but the agents in the higher rank coal seams which cause CWP arc still not defined. The basic components of the coal seams, i.e., the elements and minerals, are generally known, but the way in which they interact with human pulmonary cells is largely still a mystery.The process of disease development is a biochemical one which depends on the characteristics of the pulmonary cells within their immediate biochemical environment and the characteristics of invading respirable coal mine dust particles, probably both chemical and physical ones. The cell-particle relationship, therefore, must be defined, and both cells and particles must be characterized according to properties which potentially are involved in the disease process.Following such characterization, specific respirable dusts from different coal seams, which appear to have different effects on coal workers, must be obtained or constructed and then used in experiments designed to determine dust toxicity or the response of animals exposed to the dusts.The results presented here focus on characterizing properties of respirable coal mine dust particles collected from operating longwalls in West Virginia and Virginia Longwall panels were selected for analysis because the respirable dust in the coal face areas is largely uncontaminated by rock dust and analysis of the dust yields results unconfounded by rock dust."

Jan 1, 1990

By V. R. Spironello

The Bureau of Mines is conducting studies of the slags related to ferrous technology to evaluate acceptable substitutes for the auxiliary flux, mineral fluorspar, in foundry operations. This work is directed toward the Bureau's goal of minimizing the Nation's dependence on scarce and critical minerals Comparative basic practice cupola (18-inch-ID) trials were made to evaluate a waste material called "used potlining," which contains significant levels of fluorine, sodium, and aluminum in various compounds. Used potlining is recovered from alumina reduction cells after its useful life, and was supplied by the Aluminum Co. of America (Alcoa) to the Bureau for evaluation. The material in the lump and pelletized form (with limestone) provided extremely fluid slags based on visual observation during cupola operation. No adverse effects were found on cupola performance, metal and slag chemistry, the environment, or mechanical properties of the castings produced. Fluorine recovery in the slag was equal to, or higher than, that of fluorspar; fluorine losses to the scrubber water and solids were lower. The acidity of the scrubber Hater was somewhat neutralized. No difference was observed in furnace-refractory attack, as determined by the level of magnesia in the slag and visual inspection. The recovery of sodium in the slag, presumably as the oxide, significantly increased slag fluidity, suggesting that less than equivalent fluorine may be required. There was no contamination of the gray iron by the aluminum from the used potlining. Used potlining was completely satisfactory as a substitute for fluorspar in cupola ironmelting.

Jan 1, 1981