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By J. C. Edwards

To have the capability to predict the development of localized spontaneous heating within a porous coalbed that is subjected to forced air ventilation or in an otherwise quiescent environment in which buoyancy develops, the Bureau of Mines developed three time-dependent mathematical models, which were used to calculate the temperature increase associated with chemisorption of oxygen by the coal. In each model, spontaneous heating is driven by an Arrhenius first-order reaction between the oxygen and coal. Two models are two-dimensional, and one is one-dimensional. In the first two-dimensional model, a constant-velocity forced convection airflow is specified; and in the other, buoyant flow is allowed to develop in the absence of forced convection. The third model evaluates the airflow from Darcy's law and a specification of the pressure at the surface of a one-dimensional porous coalbed. Numerical computations demonstrated how each model could be used to predict the onset of spontaneous heating when the porous coalbed was subjected to constraints of an imposed internal heat source or a high temperature airflow. The effects of particle size and coalbed compaction upon spontaneous heating were examined with the third model.

Jan 1, 1990

By John C. Gagliardi

The U.S. Bureau of Mines, in cooperation with Carter Mining Co., conducted vibration tests of four off-road vehicle seats. The purpose of the tests was to determine which seat provided the best vibration attenuation under laboratory conditions. Laboratory tests were constructed to simulate the mining vibration environment within the limitations of the test equipment. The acceleration test levels and corresponding response of the seats were low compared to ISO 2631's fatigue-decreased-proficiency time limits. Two of the seats employed mechanical suspensions and two seats employed air suspensions. The seats were tested using a 22,241-N (5,000-lbf) electrodynamic shaker. Mechanical suspension seats were tested with various preload-to-mass ratios (PMR's) and cushion densities. Air suspension seats were tested with various air pressure levels and seat cushion densities. Air suspension seats provided good vibration attenuation if pressurized greater than 552 kPa (80 psi). Mechanical suspension seats' attenuation performance decreased if the PMR exceeded 9.8. Seat cushions of lower density provided less vibration damping.

Jan 1, 2010

By E. C. Lane

The motor gasoline that is bring marketed in the United States this stunner is slightly more volatile than that sold a year ago. During the past eight years the Bureau of Mines has made semi-annual surveys of the gaoline marketed in the United States, the survey just completed being the sixteenth in the series. The cities in which samples have been collected have been chosen as representative of the more important marketing territories as it is obviously impracticable to obtain a sample of every gasoline sold in the entire country.

Jan 1, 1927

By C. C. Hwang

The Bureau of Mines formulated a method for calculating the concentration of entrained dust from a dust deposit by a turbulent gas stream. In particular, a diffusion equation is used to calculate dust concentrations in a channel following an explosion. Dust leaving the channel walls was treated as originating from stationary or moving, and single or multiple material sources. Formulas and sample computations for various types of dust sources in circular and rectangular channels are given, based on experimental entrainment rates. The analysis predicts the dust concentration as a function of time and channel space. The results appear to agree with the physical characteristics of explosion-driven dust dispersion in a O.6-m-diameter, 50-m-long explosion tunnel. The analysis is also applied to simultaneous and consecutive dispersion of coal and rock dust from simulated coal mine surfaces (walls, floor, roof, and ribs).

Jan 1, 1974

By Ernest Ph. Hérivel

The mine and treatment plant of the Teziutlan, unit of the Mexican Corporation, S. A., are located at Aire Libre, in the District of Teziutlan, near the northwest edge of the State of Pueblo, Republic of Mexico. The property is leased from the Teziutlan Copper Co. The town of Teziutlan is the terminus of a branch railroad starting from Oriental Junction or the Mexico-Jalapa-Veracruz narrow-gage system of the National Railways of Mexico. A branch line 18 km in length from Teziutlan to Aire Libre belongs to the Teziutlan Copper Co. and is leased and operated in conjunction with the mine.

Jan 1, 1933

By A. G. Starliper, H. Kenworthy

A procedure was developed for the separation of lead and sulfur in industrial concentrates of galena by a combination of chlorination and fused - salt electrolysis . Galena could not be satisfactorily electrolyzed in the various media tried ; however , when it was treated with chlorine the resulting lead chloride could be effectively separated electrically into lead and chlorine . An apparatus was designed and constructed to chlorinate galena and to volatilize simultaneously most of the chloridized impurities . By electrolyzing the chlorinated concentrate , a high percentage of lead was recovered . Anodic chlorine was drawn from the cell and was used to chlorinate new feed . In many runs , the recovered metal analyzed from 99.8 to 99.9 percent lead . Lead was also distributed as a chloride in the bath , and a small portion was in the volatile fraction produced during the chlorination step . During a tinuous operation , only 0.1 percent of the total lead was discarded ; 99.9 percent was accounted for in the metal , electrolytic bath , and washed or leached chlorination condensate which was essentially lead chloride . About 95 percent of the sulfur from the galena was recovered as a byproduct of over 90 - percent grade .

Jan 1, 1964

By Howard F. Carl

"INTRODUCTION Talc is a hydrous magnesium silicate mineral found throughout the world in deposits of economic importance. This mineral occurs in different physical forms and varying degrees of purity, both of which affect its ultimate commercial usage. Talc is used in finely ground condition by the ceramic, paint, paper, rubber, cosmetic, and other industries. Most domestic talc production is of this type. Talc also occurs, although much less frequently, in massive, fine-grained, fairly homogeneous bodies; the impure varieties are the familiar soapstones, and the purer form is frequently called ""steatite."" Because of certain properties, the purest grades of this massive variety have a monetary value about 20 times that of the ground talc.One desirable property of this massive talc is its amenability to accurate cutttng, machining, and working in many ways, similar to a hard wood or soft metal, and then firing without warping or appreciable shrinkage into a hard, refractory ceramic body. Consequently, shapes that cannot be formed conveniently by molding and pressing can be produced readily with ordinary machine tools. When talc is fired to about 1,100° C., it is converted to a ceramic body with certain very desirable physical properties. This fired material has a hardness and toughness frequently superior to steel. It is a refractory and an exceptionally good electrical insulator. When formed from a high-grade talc essentially free from iron, it has unusually low dielectric losees, even at very high frequencies."

Feb 1, 1945

By John C. Edwards

To have the capability to predict the development of localized spontaneous heating within a porous coalbed that is subjected to forced air ventilation or in an otherwise quiescent environment in which buoyancy develops, the Bureau of Mines developed three time-dependent mathematical models, which were used to calculate the temperature increase associated with chemisorption of oxygen by the coal. In each model, spontaneous heating is driven by an Arrhenius first-order reaction between the oxygen and coal. Two models are two-dimensional, and one is one-dimensional. In the first two-dimensional model, a constant-velocity forced convection airflow is specified; and in the other, buoyant flow is allowed to develop in the absence of forced convection. The third model evaluates the airflow from Darcy's law and a specification of the pressure at the surface of a one-dimensional porous coalbed. Numerical computations demonstrated how each model could be used to predict the onset of spontaneous heating when the porous coalbed was subjected to constraints of an imposed internal heat source or a high- temperature airflow. The effects of particle size and coalbed compaction upon spontaneous heating were examined with the third model.

Jan 1, 1990

By H. J. Lechtenberg

Preliminary results are given of solvent stimulation of two wells producing viscous oil (14°-17° API) from the Tar zone in the Wilmington field, California. The solvent (coker oil, an intermediate refinery product) was injected into the formation, and after a soak period, the well was returned to production. Data are given on crude oil properties, solvent properties, determination of volume of solvent in the produced oil, rate of oil production before and after stimulation, volume of additional oil produced, and volume of solvent recovered. Although further study and improvement of the method arcs needed, cyclic solvent stimulation appears to be an unqualified success in one well and a moderate success in the other.

Jan 1, 1972

By E. H. Denny

"IntroductionOn May 27, 1927, a coal-dust explosion occurred at the Palagua No. 5 mine of the Victor American Fuel Company, Delagua, Colorado, resulting in the loss of even lives and in and in considerable damage to the main slope and to several overcasts the explosion did not extend into the mine working where 125 additional men were employed but escaped uninjured. It is believed that the saving of these 125 men and the evidence of large property loss were due in a large measure to coal-dusting and of other sanity measures taken by the coal company management. A number of features connected with the explosion and mine safety practice seem worth the attention of the mining public and grateful acknowledgment is made to the Victor American Fuel Company for its aid in assembling the data herein contained."

Nov 1, 1927

By E. G. Valdez

Laboratory research demonstrated that ceramic wall and floor tile can be produced from electric furnace phosphorus slags composed of calcium silicates. Grinding the slag in a pebble mill, followed by magnetic removal of deleterious magnetite, produced a raw material that could be compounded and formed into wall tile by dry pressing, sintering, and glazing. The effects of process variables such as forming pressure and sintering temperature were investigated. Wall tile bodies produced by this method were comparable to commercial tile. The tiles were readily glazed to a smooth shiny finish and met ASTM Specifications C34-62 for structural clay load-bearing tile. The estimated cost of producing wall tile by this method compared favorably with the retail market value for similar wall tile. Addition of borax or other additives to the ground slag followed by dry pressing and firing likewise produced a commercial grade of floor tile.

Jan 1, 1974

By George H. Schnakenberg

This Bureau of Mines publication describes a passive personal sampling device for N02 in air, developed by the New York University Medical Center under Bureau Grant G0133066. The sampler has been successfully demonstrated in the field and in the laboratory. In corroborative laboratory trials the agreement with reference method is excellent. The overall accuracy is approximately ±5 pct of reading to a precision of about ±l pct. All evidence indicates that these samplers should indicate the time-weighted-average N02 concentration to the above accuracy and precision equally well in the field since effects of wind velocity and relative humidity are negligible and the effects of temperature are about 0.1 pct per °F. The duration of exposure and the approximate temperature are the only data that need to be collected in the field. A two-step analysis procedure in field or service laboratory is then used to obtain the total cumulated exposure to N02 in parts per million-hours (ppm times hours), which can be converted to the time-weighted-average concentration of N02 in ppm by dividing cumulated exposure by the duration of the exposure.

Jan 1, 1976

By Stephan Stecura

Crystallographic modifications and kinetics of solid-state phase trans-formations were determined for five rare-earth" sesquioxides--La2O3, Nd2O3, Sm2O3, Eu2O3, and Gd2O3. Oxides used for crystal modification studies were prepared by thermal decomposition of the following high-purity salts of the five rare-earth elements--carbonates, chlorides, fluorides, nitrates, oxalates, and sulfates. X-ray diffraction patterns of the cubic and hexagonal oxides were indexed by a graphical method and patterns of the monoclinic oxides by Ito's method. The kinetics of crystallographic transformation were determined by high-temperature X-ray diffractometry. The kinetic data were interpreted using a shrinking sphere model. All of the transformations followed first order kinetics. Activation energies were calculated by application of the Arrhenius equation. These solid-state phase inversions were concluded to occur by a reconstructive transformation mechanism.

Jan 1, 1965

By John D. Corrick

The environmental and nutritional characteristics necessary for maximum copper extraction from a low-grade ore by Ferrobacillus ferrooxidans have been explored as have many of the limiting parameters. Criteria considered were oxygen consumption, copper extracted, soluble copper concentration, temperature, pH, particle size, nutrients, and other inorganic salt concentrations. A set of environmental and nutritional conditions were developed for E. ferrooxidans Which supported cell reproduction and maximum microbial oxidation of a low-grade copper sulfide ore. Percolator tests conducted under these optimum conditions resulted in an 18 percent increase in the quantity of copper microbially extracted over that extracted under conditions considered to be standard. Manometric tests determined those extremes of environmental conditions and nutritional factors Which were detrimental to the extraction of copper by E. ferrooxidans.

Jan 1, 1965

By David Oyler, Craig Compton

The The National Institute for Occupational Safety and Health (NIOSH) Pittsburgh Research Laboratory (PRL) is continuing to investigate the behavior of fully grouted roof bolts in the weak roof rock of the Safety Research Coal Mine (SRCM). This paper describes the results of three studies: • A series of 24 pull tests of bolts installed fully grouted and overcored to leave 12 inches of grouted bolt. The tests compared the pull-out performance of offset-head roof bolts with that of standard 5/8-inch bolts; • A second series of 24 tests that compared the pull-out loads obtained by bolts installed with 1 ft of resin (a Short Encapsulation Pull Test or SEPT) to that of fully grouted bolts overcored to leave only 12 inches of grouted bolt, and; • An investigation into the pressures generated during the installation of fully grouted resin bolts. All of the bolts installed and pulled were overcored and removed from the roof after the pull tests to allow inspection of the resin. The first study found that there was no significant difference in pullout load between the offset-head bolts and the standard bolts. The second study, comparing the SEPT bolts and the partially-overcored fully grouted bolts, indicated that SEPT can significantly underestimate bolt anchorage grip factor, suggesting that the SEPT is a conservative measure of actual bolt performance. Significant loss of resin to cracks in the roof was observed in the bolts overcored in the SRCM. The third study explored one possible explanation for the resin loss, high pressures generated during bolt installation. These tests employed bolts installed in strain gauged steel tubes. The results confirmed that significant pressures (greater than 4,000 psi) can be generated during bolt installation. The results of the pressure tests, combined with the observations of resin loss in bolts installed in the SRCM, suggest that under some circumstances resin loss and under-encapsulation could take place and lead to degraded bolt performance. Glove fingering was observed in all recovered bolts to various degrees. The limited comparative data suggested that the effect of glove fingering ranged from slight to moderate. Complete mixing of the resin was observed on all of the 40 bolts recovered (28 fully grouted and 12 SEPT). Australian and U.S. resins were compared and the Australian resins were observed to have much smaller catalyst compartment areas and lower resin viscosities. These differences are suggested as potential explanations for occasional resin mixing problems noted in Australian resin bolt installations.

By Gordon E. Fletcher

This Bureau of Mines report outlines the atomic absorption analysis of oilfield brines for barium, calcium, copper, iron, lead lithium, magnesium, manganese, potassium, sodium, strontium, and zinc, using the method of additions. The advantages of using atomic absorption are discussed. The method of additions was chosen to overcome large matrix interferences usually found in brines; techniques of overcoming chemical, ionization, and background interferences are also described. The method was used to analyze several hundred oilfield brines and found to be rapid and reasonably accurate. A solvent extraction method was used to concentrate lead, copper, zinc, and iron in low-level samples.

Jan 1, 1974

By D. E. Shanks

As part of its goal to help maintain an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines, U.S. Department of the Interior, is investigating a fused-salt electrolytic procedure for producing zinc metal. A previous report described preliminary, small-scale work on the fused-salt electrolysis of ZnC12. The present report covers a more detailed investigation of the properties of ZnC12-alkali metal chloride electrolyte systems in relation to the production of zinc metal and also discusses electrolysis in largescale, internally heated cells. The effect of composition on bath stability, current efficiency, cell voltage, and liquidus temperature was determined for the ZnCla-NaC1-KC1, ZnC12-NaC1-LiC1, and ZnC12-KC1-LiC1 electrolyte systems. An electrolyte com-posed of 38 mole-pct ZnC12, 31 mole-pct NaC1, and 31 mole-pct KC1 gave the best overall results. Sludge (ZnO) formation in the ZnC12-NaC1-KC1, ZnC12-KC1-LiC1, and ZnC12-KC1 systems was investigated during prolonged electrolysis. The ZnC12-KC1-NaC1 electrolyte showed the least sludge formation. A 1,500-amp cell was operated using the ZnC12-NaC1-KC1 electrolyte at 500° C. Zinc metal was produced at the rate of 4.0 lb/hr with a current efficiency of 95 pct.

Jan 1, 1979

By Robert H. Merrill

This Bureau of Mines report summarizes the design and tests of a gage that will simultaneously measure the deformation of a borehole along three diameters 60 degrees apart; the measurements are in a single plane normal to the axis of the borehole. The inherent errors in measurement are considered together with the problems associated with the use of the gage in the relatively severe environments in and around mine openings. These problems were treated in the design and tests of the gage and the results establish that the gage can be used to satisfactorily is determine estimates of the stresses in rock.

Jan 1, 1967

By John P. McDonnell

Coal mine bounces and bursts are major problems facing U.S. mine operators. Bounces and bursts have the potential to inflict severe injury on mining personnel, damage equipment, and cause mine closures. High- stress conditions, at or near the working face, are the common denominator in the burst problem, If mine operators can locate high-stress and potentially burst-prone zones, they can then use stress-relief methods to control the burst condition. One method of locating the high-stress zone is the probe-hole-drilling or drilling-yield method. Probe-hole drilling is used frequently in Europe, the U.S.S.R., and Japan as a means for locating potential burst zones. Consequently, the Bureau of Nines performed tests in the laboratory and in a deep, burst-prone western mine to analyze probe-hole drilling. The in-mine method, very simply, involves drilling a hole into the coal seam and measuring the volume of cuttings obtained. A certain volume of cuttings can be expected from a certain diameter and length drill hole. A significant increase in the volume of cuttings means the zone around that particular hole is highly stressed. In-mine use of the drilling yield method has shown it to be a useful tool for locating highly stressed and potential burst zones. Results from laboratory testing confirm that high stress applied tri-axially to a cube specimen will cause a significant increase in the volume of cuttings from a small-diameter drill hole in the specimen.

Jan 1, 1988

By M. S. Seehra, R. S. Pandurangi

"A comparative study of the intensities of the IR modes in the pjlotoacoustic and. FrIR spectroscopy of amorphous and crystalline SiO2 particles is presented. It is observed that in photoacoustic spectroscopy of amorphous SiO2, IR modes of surface species are enhanced by over an order of magnitude compared to the bulk IR modes of SiO2. This effect, though not yet understood, may find applications in surface science.Since the publication of the Rosencwaig-Gersho theory of the photoacoustic effect in solids in 1976 [1], a great deal of attention has been paid to the development .of photoacoustic spectroscopy (PAS) into an analytical technique for condensed matter studies, especially when combined with the modern Fourier transform infrared (FTIR) spectrometer [2-8]. PAS has now been applied to a variety of experimental situations [2, 3] and it is particularly suitable for opaque powders and for cases where ~ample preparation (e.g. mixing with KBr as is usually done in FTIR spectroscopy) is not desirable. Another area of interest is the depth profiling feature of PAS, which is studied by varying the modulation frequency of the incident radiation [2-8]. The one-dimensional Rosencwaig-Gersho theory for non-porous samples has been extended to other cases [9-12]. Recently it has become known [11, 12] that for porous samples with porosity the IR modes are enhanced by a factor proportional toe. This enhancement is due to the pressure wave set up in the interstitial gas in the porous sample and this enhancement has been reported by a number of groups [12-14].In this Letter we report the observation of anomalously large enhancement of the PAS signal for certain surface IR modes on the surface of amorphous silica particles. This observation differs from the previous reports in that certain surface modes are enhanced by over an order of magnitude compared to the bulk IR modes. Although the reasons for this enhancement of the surface IR modes in PAS are not understood at present, this observation may open up new approaches to the study of surfaces. Results of these initial observations are given in this Letter. ·Experimental studies reported here were carried out on an FTIR spectrometer (Mattson Instruments, Model Cygnus 100) equipped with an MCT detector. The same instrument was used for PAS studies in conjunction with an MTEC (Model 100) PA cell. The sample cell and the spectrometer are continuously flushed with dry, CO2 free air obtained by the use of Balston Instruments Air Dryer Filter System (Model 75-60). Usually data were collected for 32 scans at 4 cm-I resolution, although both scan and resolution can be varied. For FTIR studies, samples were mixed with IR-grade KBr and pelletised. For PAS, no sample preparation is necessary and data are ratioed against dry carbon black [4, 5]."

Jan 1, 1989