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By D. R. Mathews

The solubility of carbon in electrorefined vanadium was determined to be approximately 0.27 wt pct at the eutectic temperature 1,650° C and 0.03 wt pct at 700° C. The tensile strength and hardness of vanadium increased with car-bon content to the solubility limit, but this effect was small, probably because of the narrow solubility range. Between the solubility limit and 0.3 weight-percent carbon, the second phase had essentially no strengthening effect in vanadium. The second phase, observed metallographically at the grain boundaries and within the grains, was shown by autoradiography to contain high-carbon concentrations. This second phase was identified as VgC by X-ray analysis. The VgC in the grain boundaries contributed largely to the poor cold-and-hot workability of vanadium-carbon alloys. Increased concentrations of V2C occurred at the grain boundaries of the high-carbon alloy ingots as a result of homogenization at 1,600° C for 1 hour. Alloy ingots containing more than 0.36 wt pet carbon (a calculated 2.9 wt pct VaC) following homogenization, cracked severely and failed by intergranular fracture upon swaging at 900° C.

Jan 1, 1965

By M. M. Tilman

A series of alloys was laboratory prepared by adding up to 4 weight-percent cobalt to the basic composition of type AM 350 (AISI 633) stainless steel. Aging curves were established for each alloy at 750° F, 850° F, and 950° F for lengths of time up to 100 hours. A series of annealed steels containing as much as 1 weight-percent cobalt was cold-rolled 50 percent and aged for 3 hours at 850° F. No improvement in hardness due to cobalt was observed in the steels transformed by heat treatment. Slight improvements in hardness were observed in the steels transformed by cold working.

Jan 1, 1968

By Stephen R. Iverson

The U.S. Bureau of Mines made an economic appraisal of the Buttermilk study area, Inyo County, California in October 1980. Results of surveys indicate no potential for metallic, non-metallic, or energy resources in the area. However, glacial till covering most of the area prevented bedrock examinations by the appraisal teams or earlier prospectors. No mining claims are known to be in the area. INTRODUCTION Present Studies The U.S. Bureau of Mines, Western Field Operations Center, searched county mining claim records and other data available concerning mineral deposits, claims, leases, production, and mining activity in the area. The Bureau conducted field work in October 1980 searching for prospects and claim locations. Fourteen reconnaissance lode and placer samples taken from the area were analyzed for gold, silver, and tungsten; a spectrographic analysis also was run on selected samples.

Jan 1, 1981

By R. D. Currie

The practicability and dependability of two permissible methane-indicat- in detectors recently developed were proved conclusively by extensive tests in the return airways of all mines operating in the anthracite region in most of which samples and readings were taken with one or the other of the two in- dicating detectors. These detectors roved dependable and accurate within practical limits, and their general use should be encouraged as an aid to bet ter ventilation, more accurate control of air currents, and greater safety in mines.

Feb 1, 1936

By L. H. Wullstein

Bureau of Mines research on methods for reclaiming land disturbed by the minerals sector of the economy has produced a specific procedure for effectively germinating seed of Indian ricegrass, a drought-tolerant plant valuable for reclaiming arid and semiarid sites. This report describes the procedure which consists of acid-treating the seed followed by temperature and light cycling treatments. Use of the procedure resulted in an average germination rate of 29 percent, ranging from 18 to 56 percent. Seed subjected to long cold treatment but with acid treatment yielded an average germination rate of 9.2 percent, ranging from 6.6 to 14.7 percent. Untreated seeds (controls) gave germination rates less than 0.1 percent.

Jan 1, 1979

To reuse chromium, nickel, and molybdenum now lost in stainless and specialty steel-making wastes, and simultaneously to overcome the current environmental problem resulting from landfilling these wastes. Approach A variety of stainless and specialty steelmaking wastes are agglomerated and recharged into the plant's electric arc furnaces. How It Works Stainless and specialty steel-making wastes such as bag-house dust from the electric arc furnace, dust from the argon-oxygen decarburization unit, grinding swart, and mill scale are blended in proportion to the ratio in which they are generated. Next they are agglomerated on a pelletizer with an addition of a small amount of carbonaceous reducing agent, and air-dried in preparation for being recharged into the furnace. Some mixtures of wastes tested in the laboratory required the addition of binders and/or the use of ovens in lieu of air-drying to produce sufficient pellet strength. Although the optimal maximum particle size of wastes being pelletized is 35 mesh, somewhat larger particle sizes were satisfactorily pelletized during in-plant tests. The photograph shows a typical mixture of wastes and the pellets made from them.

Jan 1, 1981

By D. H. Chambers

The Bureau of Mines developed a process for producing high-purity zinc and tin by electrorefining from liquid amalgams. Commercial grade metals were dissolved in mercury to produce saturated amalgams at room temperature. Amalgams were also prepared by electrolytic transfer from soluble anodes of the metals to a mercury cathode. Amalgams formed by both methods were used as anodes in electrorefining cells to produce high-purity cathodes. Metal impurities, excluding mercury, were at levels of less than 5 ppm in zinc and 9 ppm in tin. Mercury content was about 2 to 10 ppm in zinc products, and this was effectively removed by heating the cathodes in a vacuum. Mercury was excluded from tin cathodes by pumping the tin electrolyte through tin turnings and controlling the cell temperature.

Jan 1, 1969

The National Institute of Occupational Safety and Health has classified diesel exhaust as a potential human carcinogen. Though standards for diesel particulate matter (DPM) in the work place have not been established, concern for the health of miners is prompting mine operators to consider methods for reducing worker exposure to diesel exhaust. Approach One of many methods for reducing DPM being investigated by the Bureau of Mines is the use of additives in diesel fuel to improve combustion. Research Results Three fuel additives have been tested in Caterpillar and Deutz diesel engines which are similar to types used in underground mines. One iron-based additive containing ferrous picrate had no effect on emissions. A second iron-based additive containing ferrocene reduced DPM between 5 and 45 pet depending on engine operating conditions. The 37-pct reduction for an 8-minute duty cycle, which includes a wide range of transient loads and speeds, is considered to represent in-mine performance.

Jan 1, 1990

By R. M. GRANTHAM, J. H. SOULE

C. R. Keyes, F. C. Schrader , F. A. Jones ( the first director of the New Mexico School of Mines , whose name was given the deposits ) , and N. H. Darton all described the Jones iron deposits within a decade after their discovery in 1902 . The earliest locations now on record were made in 1927. Interest in iron ores was revived during the second World War . Paul E. Pesonen , of the Bureau of Mines , reported on the deposits in December 1941 and proposed an extensive exploratory program . In March 1942 , the deposit was reported upon by C. H. Johnson , also of the Bureau of Mines , and a definite program of exploration was outlined .

Feb 1, 1947

By R. V. Ramani, C. B. Manula, A. Owili-Eger

• MINE VENTILATION NETWORK PROBLEM (NATURAL SPLITTING; FIXED • QUANTITY BRANCHES; METHANE SIMULATION; NETWORK TOPOLOGY REVISION; • ABSOLUTE PRESSURE) • NFIXB = NO. OF FIXED QUANTITY BRANCHES • DD(I) = AIR QUANTITY ASSIGNED TO FIXED QUANTITY BRANCH I, IN KCFP • NFBPF = NO. OF FIXED QUANTITY BRANCHES PLUS FAN • NFBPFG = NO. OF FIXED QUANTITY BRANCHES PLUS FAN PLUS METHANE • EMISSION BRANCHES • NBWNVP = NO. OF BRANCHES WITH NATURAL.VENTILATION PRESSURE • NVP(I) = NATURAL VENTILATION PRESSURE ASSOCIATED WITH • THE I-TH BRANCH • NF = NUMBER OF FANS • NB = NUMBER OF BRANCHES • MAXIT = MAXIMUM NUMBER OF ITERATIONS • MAXJ = MAXIMUM NUMBER OF JUNCTIONS • NJ = NUMBER OF JUNCTIONS INVOLVED IN THE SOLUTION * NM = NUMBER OF MESHES • NP = NO. OF POINTS TO DESIGNATE FAN CHARACTERISTIC * Q = QUANTITY OF AIR FLOW IN KCFM • R = RESISTANCE OF AN AIRWAY • WIDTH = AIRWAY DIMENSION • LENGTH = AIRWAY DIMENSION • HEIGHT = AIRWAY DIMENSION • SUMNVP = SUMMATION OF NATURAL VENTILATION PRESSURE FOR ANY MESH • X (I) = QUANTITY OF AIR, IN KCFM, ASSOCIATED WITH THE I-TB POINT • ON A FAN CHARACTERISTIC • E = ERROR FOR CONVERGENCE • FF = FRICTION FACTOR • FX(I) = FAN PRESSURE, INS INCHES OF WATER GAGE, CORRESPONDING • • TO A QUANTITY X(I) • H = HEAD LOSS IN INCHES OF WATER GAGE • I = BRANCH NUMBER • J, J1, J2 = JUNCTION, J1 AND J2 ARE TWO NODES WHICH DEFINE A • BRANCH • KEY = NO. WHICH SIGNALS THE TYPE OF FAN CHARACTERISTIC TO BE • EXPECTED

Jan 1, 1975

By R. H. Bedford

"The El Dorado copper mine is situated in the foothill copper-zinc belt of California, which traverses the western slope of the Sierra Nevada with unusual persistence from Butte County to Kern County, a distance of more than 300 miles. Although this area contains such important past producers as the Penn mine, Union, and others, a great part of the current production has been derived from smaller properties, which depend largely on premium metal prices for economical operation. The El Dorado mine is in the latter group, which constitutes an important source of metal in a national emergency.Exploration by the Bureau of Mines by means of eight diamond-drill holes Indicated narrow, intermittent lenses of copper ore along structures boo feet in length. The copper occurs in massive sulfides composed of chalcopyrite, pyrite, pyrrhotite, and minor quantities of bernite. The sulfides have evidently replaced tuffs, which are interbedded with the Mariposa slates and shales.H. A. Weiler and Hal T. Hall, owners of the El Dorado copper property, requested an examination by the Bureau during the latter part of 1914. In December of that year an engineer of the Bureau of Mines visited the mine and recommended the project work undertaken. The purpose was to aid the owners in bringing the property into production of copper and zinc, which at that time was critically essential to the war industries.Complete factual data obtained by the exploration are embodied in this report.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G, Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.Acknowledgment is made to A. O. Johnson, chief, Reno Division, Mining Branch, and Lowell B. Moon, chief, Mining Branch, for their aid and direction."

Jun 1, 1946

Improve the strength and other properties of steel alloys. Approach Research by the U.S. Bureau of Mines indicates that steels melted and solidified under high nitrogen pressure acquire yield and tensile strengths that are up to four times the strengths of comparable stainless steel alloys without nitrogen. Fatigue strength, creep strength, and other mechanical properties are also improved. Strengthening occurs by two mechanisms: (1) increasing dissolved nitrogen in the lattice and (2) formation of dispersed metal nitride phases. Nitrogen Alloying Nitrogen alloying of a steel is generally done by introducing metal nitrides during melting of the steel. The concentration of nitrogen is limited to its equilibrium solubility at 1 atmosphere. For face-centered-cubic (fee) iron, that solubility is approximately 0.4 weight percent (wt%). For body-centered-cubic (bee) iron, solubility is 0.05 wt%. This solubility limitation can be overcome by melting the metal in a pressurized vessel. European steelmakers currently have metal-processing systems that can melt and pour tons of steel under nitrogen pressures exceeding 4 megapascals (MPa) (40 atmospheres). They have achieved nitrogen concentrations as high as 1.0 wt% in these (stainless) steels. The tensile strength is approximately twice the tensile strength of similar steels without nitrogen.

Jan 1, 1992

To restore ventilation and prevent the accumulation of explosive or toxic gases by quickly installing substitutes for stoppings blown down by an explosion. Approach Temporarily replace blown down stoppings with a parachute-shaped brattice which can be erected in minutes. How It Works The self-sealing brattice is secured to the roof, ribs and floor by anchoring its nylon edge strip at several points using extensible poles, shads, or available projections such as roof bolts. The air pressure in the entry pops open the chute of lightweight sailcloth, forcing it tightly against floor, roof and rib. See Figure 1. This emergency brattice has been tested at two locations in the Bureau's Experimental Mine at Bruceton, Pennsylvania. In a test last December, one MESA inspector wearing full rescue apparel (including self contained breathing apparatus) installed a self sealing brattice in an entry at the Bruceton Mine. Although he did not have any previous experience with the device, he easily erected it in slightly less than 10 minutes, using two extensible supports (pogo sticks). Research to improve and refine the self-sealing brattice is continuing.

Jan 1, 1977

By E. C. Perkins

This report describes a ferric chloride trap, based on formation of a low-melting sodium chloride-ferric chloride mixture of near-eutectic composition, and its use in chlorination of impure titaniferous materials. The trap is placed in the hot gas stream between the chlorination reactor and the condenser. Virtually all of the iron is removed by the trap. The condensed titanium tetrachloride is free of suspended solids and contains only a trace of iron. Four examples are given of the use of the ferric chloride trap in chlorination of impure titaniferous materials. INTRODUCTION In the Kroll process, ductile titanium metal is produced by reducing titanium tetrachloride with magnesium metal.4/ In commercial practice, titanium tetrachloride is produced by chlorinating titaniferous materials in the presence of carbon.2/ In 1957 most producers were using rutile, and virtually all plants were designed for its use. About four-fifths of the domestic consumption of rutile was imported from Australia. The Bureau of Mines, under provisions of contract DMP-116 with the General Services Administration, studied electrosmelting of domestic ilmenites and titaniferous magnetites to produce high-titanium slags with pig iron as a byproduct. Under the same contract, chlorination studies also were being made of these slags. Smelting was done at the Northwest Electrodevelopment Experiment Station, Albany, Oreg., and chlorination at the Electrometallurgical Experiment Station, Boulder City, Nev.

Jan 1, 1958

By Walter R. Storms

The Iron Mountain tungsten deposits first were visited by a field party of the Federal Geological Survey in May 1942 while beryllium deposits in that district' were being examined . Later they were examined by F. A. Rutledge , an engineer of the Bureau of Mines , and an exploration project was recommended , work upon which began in March 1943 and was terminated in April 1943 after intensive trenching and sampling had been completed .

Mar 1, 1947

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) measurements provide evidence for the formation of Cr(V) intermediates in the enzymatic reduction of Cr(VI) by glutathione reductase (GSSG-R) in the presence of NADPH, indicating an initial single-electron transfer step in the reduction mechanism. Depending on the pH, at least two different Cr(V) species are generated which are relatively long-lived. In addition, we have detected the hydroxyl (·OH) radical formation during the GSSG-R catalyzed reduction of Cr(VI) by spin trapping, employing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) and a-(4-pyridyl-1-oxide)-N-tert-butylnitrone (4-POBN) as spin traps. Superoxide dismutase (SOD) causes only a minor effect on the ·OH radical and Cr(V) formation, indicating that the ~ - is not significantly involved in the reaction mechanism. Catalase enhances the Cr(V) formation and substantially inhibits the ·OH radical formation, indicating the involvement of hydrogen peroxide (H20 2) in the reaction mechanism. Addition of H20i suppresses Cr(V) and enhances the ·OH radical fonnation. Measurements involving N-ethylmaleimide show that the Cr(V) species, produced enzymatically by the reduction of Cr(VI) by GSSG-R, react with H2O2 to generate ·OH radicals, which might participate in the initiation of Cr(VI) carcinogenicity.INTRODUCTIONC(VI) compounds have been found to exert serious toxic and carcinogenic effects on humans and animals [1-4) and to cause mutations in bacteria and transformation of mammalian cells [5-8). In contrast, most Cr(lll) compounds are relatively nontoxic, noncarcinogenic, and nonmutagenic [9, 10]. Cr(VI) and Cr(lll) oxidation states are different in their metabolic pathways: Cr(VI) ions are rapidly transported across cellular membranes [2, 11-13), while Cr(lll) moieties do not easily penetrate cells and are not oxidized by cellular constituents [3]. Since it is known that the reduction of Cr(Vl) is required for its reaction with DNA [2], the molecular mechanisms for the intracellular Cr(VI) reduction have been the focus of studies during the past decade but the details are still not understood."

Jan 1, 1990

By G. R. Hopkins

A recently completed survey , made by the Bureau of Mines to determine the trend of fuel consumption at refineries in the United States , showed the following outstanding points : A decrease in the use of oil for fuel in 1927 of over 5,000,000 barrels as compared with 1926 ; a decrease in the use of coal of over : 1,000,000 short tons ; small increases in the use of both natural gas and refinery gas ; an increase in the use of petroleum coke . The decrease in fuel - oil consumption was approximately 2,000,000 barrels each in the Atlantic Coast , Texas , and Louisiana- Arkansas districts , with an increase of 1,000,000 barrels in the Indiana - Illinois district , or a net decrease of 5,000,000 barrels . The decrease in fuel- oil consumption by refineries in the Texas and Louisiana- Arkansas areas was offset largely by increased consumption of natural gas and refinery gas , whereas the increased consumption in the Indiana- Illinois region was more than offset by the decrease in coal consumption . The use of coal for fuel declined from 6,052,000 short tons in 1926 to 5,031,000 short tons in 1927. Practically all of this decrease was recorded in the Appalachian and Indiana- Illinois districts , which at the same time showed the largest percentage increase in the use of oil for fuel . It is probable , therefore , that although coal prices also fell off , a considerable quantity of oil replaced coal in this area in 1927. In addition , the group of refineries , which are by location more or less definitely committed to the use of coal for fuel , undoubtedly succeeded in saving a material amount of coal through the use of more efficient fueling methods . A total of 130,815,000,000 cubic feet of natural gas was consumed for fuel at refineries in 1927. This represents an increase of 8 per cent over the 1926 total . Nearly all of this increase resulted from the opening of a line from the Monroe field to Baton Rouge , La . Had this line not been opened , there would have been a decrease in the use of natural gas , as a number of districts , particularly the Rocky Mountain , reported decreases in its use . The use of refinery or still gases for fuel did not change materially during 1927 , there being a total of 52,807,000,000 cubic feet burned as compared with 52,077,000,000 cubic feet in 1926. Refinery gases are largely a product of cracking and , it was probably more than a coincidence that a few districts in which cracking slowed down in 1927 also reported less refinery gas used as fuel .

Jun 1, 1924

By M. R. Geer

Samples of coal from six beds in the Roslyn-Cle Elum field of Washington were subjected to float-and-sink tests to determine their amenability to the production of high-ash boiler fuel for on-site power generation. Grindability tests and analyses of ash were made. All of the coals would require some degree of cleaning to insure a product of 25 percent ash. With two of the coals the entire size range would have to be washed. With the other four, it would suffice to clean only the coarse coal and bypass the raw fines.

Jan 1, 1965

By James S. Browning

Domestic production of lithium minerals, source of the lightest metallic element, has increased from an average of 1,327 short tons of concentrate in the 1935-39 period to approximately 37,830 short tons in 1954. This rather phenomenal growth in production and use reflects growing industrial interest in the metal and its salts. This information circular has been prepared to summarize for the casual technical reader the reserve, mining, processing, and consumption situation pertaining to the mineral spodumene - the principal source of lithium. A relatively complete bibliography is included for those who may need more detailed information.

Jan 1, 1958

By Raymond B. Ladoo

SOAPSTONE

Feb 1, 1922