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By Allen D. Look, Alan A. Sharp

"INTRODUCTION The bottoming of the United Verde sulfide pipe has shortened the expected life of the United Verde mine to a matter of a few years. First located in 1876, this Arizona mine has had a long period of activity, having reached a peak production in 1929 of over 71,000 trans of copper. Through these many years of successful operation, a safety program has evolved in keeping with the proficiency developed in mining the ore body. It is the purpose of this paper to record the safety practices in effect at this mine so that others may have the benefit of lessons ,learned through experience 'and years of work toward an improved accident record.ACKNOWLEDGEMENTSAcknowledgment 'is 'made to ,the Phelps Dodge Corp. for its cooperation in making available data contained in this paper, and to C. E. Mills, general superintendent; W. W. Little, mine superintendent; John Riordan, employment agent; and G. S. Leisk, safety engineer, for their helpful suggestions and information furnished.GENERAL INFORMATIONThe United Verde copper mine is situated just west of Jerome, Ariz., at an altitude of approximately 5,500 feet. Purchased by the Phelps Dodge Corp. in 1935, the mine employs approximately 500 men - 385 underground and 115 on the surface."

May 1, 1949

By W. A. Stickney, J. W. Town

Batch and continuous - circuit flotation , leaching , precipitation , and electrodeposition studies were made by the Bureau of Mines to determine optimum conditions for treatment of complex mercury - antimony sulfide and mercury- arsenic sulfide ores and concentrates . On the Red Devil ore sample over 95 percent of both the mercury and antimony sulfides were recovered in a flotation concentrate containing 35.6 percent mercury and 21.0 percent antimony . By selective flotation a mercury concentrate containing 71.0 percent mercury and 2.9 percent antimony was obtained with a mercury recovery of 90.4 percent . Leaching results show that , with 150 grams per liter of sodium sulfide and 50 grams per liter of sodium hydroxide , 95 to 99 percent of the mercury , antimony , and arsenic sulfides could be extracted from the concentrates treated . Sodium hydroxide reagent consumption was based on the sulfides generated in the dissolution of the sulfide minerals and on the method of metal recovery used . Selective leaching of the antimony and arsenic sulfides with potassium sulfide dissolved more than 95 percent of either of these two sulfides and 0.5 to 5 percent of the mercury sulfide present . Methods for recovering mercury and antimony from solution were electrodeposition of mercury followed by electrodeposition of antimony , aluminum precipitation of both mercury and antimony , or antimony precipitation of mercury followed by antimony electrodeposition . The method used in recovering the mercury depended on the mercury- antimony content of the solution being treated .Batch and continuous - circuit flotation , leaching , precipitation , and electrodeposition studies were made by the Bureau of Mines to determine optimum conditions for treatment of complex mercury - antimony sulfide and mercury- arsenic sulfide ores and concentrates . On the Red Devil ore sample over 95 percent of both the mercury and antimony sulfides were recovered in a flotation concentrate containing 35.6 percent mercury and 21.0 percent antimony . By selective flotation a mercury concentrate containing 71.0 percent mercury and 2.9 percent antimony was obtained with a mercury recovery of 90.4 percent . Leaching results show that , with 150 grams per liter of sodium sulfide and 50 grams per liter of sodium hydroxide , 95 to 99 percent of the mercury , antimony , and arsenic sulfides could be extracted from the concentrates treated . Sodium hydroxide reagent consumption was based on the sulfides generated in the dissolution of the sulfide minerals and on the method of metal recovery used . Selective leaching of the antimony and arsenic sulfides with potassium sulfide dissolved more than 95 percent of either of these two sulfides and 0.5 to 5 percent of the mercury sulfide present . Methods for recovering mercury and antimony from solution were electrodeposition of mercury followed by electrodeposition of antimony , aluminum precipitation of both mercury and antimony , or antimony precipitation of mercury followed by antimony electrodeposition . The method used in recovering the mercury depended on the mercury- antimony content of the solution being treated .

Jan 1, 1964

By Eldon Keith Stanek

This annual report deals with a multi-faceted research effort to increase mine electrical system safety. The project can be broken down into six task areas. Task one deals with the development of tests and instrumentation to perform these test- that are designed to detect incipient faults on mine power systems. This program also encompasses evaluation of the tests and automation of data collection and recording using a microprocessor. Task two concerns the prediction and suppression of mine electrical transients. This program involves digital simulation and suppression hardware evaluation. Task three deals with the reliability and fail safe assessment of various components of the mine electrical system including both the protective system and bulk power system components. Task three deals with theoretical analysis, laboratory testing and in-situ testing in coal mines of power system devices. Task four is an effort to design an optimal mine electrical distribution system. The initial effort is along the lines of refining analytical tools such as the load flow model. Task five is an attempt to optimize the selection of molded case circuit breakers makes or models on the basis of total annual cost. Task six assesses the availability of equipment to satisfy existing federal regulations.

Jan 1, 1977

By R. N. Love, L. Goldman

"INTRODUCTION When tannin is present in a boiler water, it causes certain difficulties in many analytical testing procedures because of its colloidal action in interfering with the removal of suspended matter by filtration and also because of the color it imparts to the boiler water.For example, in any test for phosphate in boiler water the first step is to filter out of the sample all sludge and suspended solids. Calcium phosphate in the sludge would give high results if not completely removed. If tannin is present in the sample, the sludge and suspended matter tend to pass through the filter paper so that it is difficult to remove it all. It may even be that tannin makes some of the suspended material in the sample completely nonfilterable. If this is true, it would be necessary to destroy or remove the tannin from the sample before filtering to get complete removal of calcium phosphate from the sample. In addition, if the test used is a colorimetric one, the tannin causes interference by its own color.As the calorimetric phosphate test is so convenient for control purposes and the use of tannin for boiler water treatment has become common, it has become necessary to develop suitable methods for employing the colorimetric phosphate test for boiler waters containing tannin. In this paper three different methods for doing this arc described and studied."

Oct 1, 1946

By R. E. Head

[This paper embodies the data obtained by a detailed statistical, microscopic analysis of the composite mill feed concentrate, and tailing from the Magne and Arthur mills of the Utah Conger Co. for 1 month in 1929. It is one of a series of papers by the same authors5 dealing with the mineralogical characteristics of the ore and concentration products from various well-known plants. The work was done in the cooperateive microscopic service laboratory at Salt Lake and represents the results of cooperation between the United States Bureau u of Mines, the Utah Copper Co. and the University of Utah.]

Jan 1, 1935

By R. E. Head

This paper embodies the data obtained by a detailed statistical, microscopic analysis of the composite mill feed concentrate, and tailing, from the Magne and Arthur mills of the Utah Conger Co. for 1 month in 1929. It is one of a series of papers by the same authors dealing with the mineralogical characteristics of the ore and concentration products from various well-known plants. The work was done in the cooperative microscopic service laboratory at Salt Lake and represents the results of cooperation between the United States Bureau of Mines, the Utah Copper Co., and the University of Utah.

Jan 1, 1935

The Pittsburgh (Pa.) and Spokane (Wash.) Research Laboratories are among the world?s foremost mining research establishments. Once a part of the former U.S. Bureau of Mines (USBM), which was abolished by the U.S. Congress in fiscal year 96, health and safety research at these laboratories was transferred to the National Institute for Occupational Safety and Health (NIOSH). NIOSH is the Federal agency responsible for conducting research and making recommendations for the prevention of work-related illness and injury. The Institute is part of the Centers for Disease Control and Prevention within the U.S. Department of Health and Human Services. Over the past two decades, the Pittsburgh and Spokane Research Laboratories have produced sustained technological achievements in mining health and safety, including? ? Development of novel respirable coal dust control technologies and more effective monitoring techniques to reduce worker exposure to hazardous mine dusts. ? Improved ground control technologies to warn and protect miners from the dangers of coal mine roof collapses and other hazardous strata conditions. ? Improved ergonomic design criteria and training methods to protect mine workers from injuries and fatalities associated with equipment and manual tasks. ? Development of enabling technologies that allow miners to control their mining equipment from a physically safe, protected work area away from respirable dust, harmful noise levels, and roof collapses. ? Improved mine fire detection and extinguishment techniques. ? Development of smaller, lighter, and safer emergency breathing devices.

Jan 1, 2007

By E. M. Frost

"Helium has great value to the oil and as industry as a tracer gas, according to tests just completed in the Elk Hills Field, Naval Petroleum Reserve No. 1, Kearn County, California. When used as .a tracer gas, small percentages of helium are mixed with natural gas pumped into a reservoir for conservation, repressuring, or cycling purposes. Because minute quantities of helium added to natural gases can be detected by analytical methods and accurately determined, the variations of the helium content of gas withdrawn from various parts of a field when helium has been added to the injected gas give interesting and long-sought data on the movement of injected gas through reservoirs.The Bureau of Mines engineers began their studies of the use of helium as a tracer material in gas-injection operations in the Elk Hills, California, oil field, Naval Petroleum Reserve No. 1, in response to a request by the Navy Department for assistance in connection with an expanded oil-production program instituted in that field. This report discusses the Bureau's work on the problem of determining the direction and extent of migration of injected gas in the Elk Hills reservoir by the use of helium as a tracer gas,The Bureau appreciates the cooperation and assistance of Commodore W. G. Greenman, U.S.N., director, and Commander R. Walling, U.S.N.R., Assistant director, Naval Petroleum .and Oil Shale Reserves, Washington, D. C., Captain H. P. Stolz, U.S.N.R., commanding officer, and Commander F. G. Taves, U.S.N.R.., of the Navy's Elk Hills staff. The Bureau also appreciates the cooperation and assistance given by V. O. Wankowski, F. C. Tratt, Marray Putnam, Dana Champion, and other personnel of the Standard Oil Co., of California, operators of the Elk Hills field.R. A, Cattell, chief, and C. C. Anderson, assistant chief, Petroleum and Natural Gas Division; C. W. Seibel, supervising engineer, Bureau of Mines Helium Plants; and H. H. Hinson, petroleum engineer - all of the Bureau's staff - furnished valuable advice and assistance during the course of the work. H. C. Miller and G. B. Shea of the Bureau's San Francisco Office contributed valuable liaison work. The writer wishes to express appreciation to all these people for their cooperation and assistance."

Jun 1, 1946

By B. Demoulin, J. Fontaine, R. Gabillard, P. Degauque

To realize a radiowave communication along mine galleries a few kilometers long without repeater, we show that it is possible to use a coaxial cable bearing an important surface transfer impedance like a transmission line with an inductive coupling to the transmitter and the receiver. We determine the electrical and geometrical constants of the cable and the optimal frequency.

Jan 1, 1973

By C. H. Fisher

Sulphuric acid of various concentrations has long been used as a reagent in the determination of olefins and aromatics in hydrocarbon oils4 such as gasoline, kerosene, and neutral oils from coal-tar distillates. Despite its long use, however, there is no general agreement as to optimum conditions and concentration of acid, and numerous methods and modifications have been recommended. In most cases, treatment of the neutral oil with 80 to 90 percent sulphuric acid, followed by distillation to the original endpoint to remove olefin polymers, is recommended for the estimation of unsaturated hydrocarbons. The distillate thus obtained is taken as olefin-free oil and used in later stages of the anlysis. Aromatic hydrocarbons generally are determined in the olefin-free oil by suphonation with more concentrated acid (96 to 100 percent and fuming sulphuric acid are recommended), the hydrocarbons not attacked and removed as water-soluble sulphoric acids being considered as saturated hydrocarbons. In some cases the saturates are examined further by differentiating between cyclic (naphthenes) and acyclic hydrocarbons (paraffins), Generally this is achieved by physical methods, although strong sulphuric acid is known to react preferentially with some types of saturated hydrocarbons. It was the purpose of the present work to make a general study of this type of analysis and to investigate the reactions of hydrocarbons under conditions often used in analyses that employ sulphuric acid reagents. Since previous work is not in good agreement, the optimum concentrations of acid for the different stages of the analysis were determined. Several sulphuric acid methods previously recommended and new modifications were compared, two synthetic solutions being used as the reference oil. The results obtained are presented below under separate headings.

Jan 1, 1937

By C. H. Fisher

Sulphuric acid of various concentrations has long been used as a reagent in the determination of olefins and aromatics in hydrocarbon oils4 such as gasoline, kerosene, and neutral oils from coal-tar distillates. Despite its long use, however, there is no general agreement as to optimum conditions and concentration of acid, and numerous methods and modifications have been recommended. In most cases, treatment of the neutral oil with 80 to 90 percent sulphuric acid, followed by distillation to the original endpoint to remove olefin polymers, is recommended for the estimation of unsaturated hydrocarbons. The distillate thus obtained is taken as olefin-free oil and used in later stages of the anlysis. Aromatic hydrocarbons generally are determined in the olefin-free oil by suphonation with more concentrated acid (96 to 100 percent and fuming sulphuric acid are recommended), the hydrocarbons not attacked and removed as water-soluble sulphonic acids being considered as saturated hydrocarbons. In some cases the saturates are examined further by differentiating between cyclic (naphthenes) and acyclic hydrocarbons (paraffins), Generally this is achieved by physical methods, although strong sulphuric acid is known to react preferentially with some types of saturated hydrocarbons. It was the purpose of the present work to make a general study of this type of analysis and to investigate the reactions of hydrocarbons under conditions often used in analyses that employ sulphuric acid reagents. Since previous work is not in good agreement, the optimum concentrations of acid for the different stages of the analysis were determined. Several sulphuric acid methods previously recommended and new modifications were compared, two synthetic solutions being used as the reference oil. The results obtained are presented below under separate headings.

Jan 1, 1937

By G. St. J. Perrott, N. A. Tolch

"The testing of explosives for permissibility for use in coal mines was begun by the technologic branch of the United States Geologic Survey in February, 1909, and continued by the United States Bureau of Mines from July, 1910; this testing has been carried on from year to year as the explosives were submitted by manufacturers. As a result of these many years of testing for permissibility a large amount of data has accumulated regarding the characteristics of permissible explosives. The manufacturer expects a sample of explosive submitted for test to meet the requirements for permissibility, otherwise the sample would not be submitted. However, in spite of the careful regulation and preparation of the formulas a certain percentage of explosives fails to pass the gallery tests. It is therefore interesting to note the proportion of failures at the gallery for a given composition of explosive. The fact should be emphasized that this discussion deals with all explosives submitted for test, both those which passed the tests and those which failed to pass. Explosives that failed to pass the tests were never designated as permissible explosives and have never appeared on any list of explosives permissible for use in coal mines.The Bureau of Mines classifies permissible explosives in two ways, according to the quantity of poisonous gases produced and according to the characteristic ingredient of the explosive.4 In this paper only two types of the latter classification are considered, as follows:"

Dec 1, 1929

By P. M. Gruzensky

Several experiments have been carried out in efforts to evaluate qualitatively a variety of electrolytes for refining bismuth. Most extensive work was done with the basic tartrate, hydrochloric acid, and hydrofluosilicic acid electrolytes. Deposits that are smooth and adherent can be obtained from these three electrolytes if low cathode current densities are employed. All three electrolytes were effective in purifying crude bismuth considerably, with additional purification indicated in each instance by a reelectrolysis step. With the basic tartrate electrolyte best results were obtained when the electrolyte was at 40° C, and contained at least 100 grams of bismuth per liter, An apparent disadvantage was depletion of bismuth from this electrolyte, causing the deposits to become spongy and nonadherent.

Jan 1, 1956

By Arno C. Fieldner

This is the fifth of a series of annual reports4/ of technologic investigations conducted by the Bureau of Mines on the occurrence, properties, mining, preparation, and uses of coal. The research of the Bureau is carefully coordinated with the requirements of the producing and consuming industries, with a view to conservation of resources of coal in mining and use, and conservation of the health and lives of workmen employed in these industries. Such coordination is facilitated by the wide range of specialization of the several groups on engaged in studies concerning coal. Here are reported correlated studies ranging from paleobotanic analysis of the formation of coal as it occurred some millions of years ago to the effect of mechanical methods of mining on present-day employment in mines. As this is a summary of the current work of the Bureau of Mines, so the Bureau likewise has provided a condensed review of the outstanding current work of others on research and technology of coal 5/.

Jan 1, 1940

By J. B. Littlefield

The term "konimeter" is used generally to designate a type of dust-sampling instrument that collects the dust from a small volume of air by impingement on a glass plate prepared aced with an adhesive film. The konimeter was first developed by Sir R. N. Kotze about 20 years ago and was followed a few years later by the circular-type konimeter, by which a number of samples may be collected on a glass disk. The present discussion will be confined to the circular type, as it is used most. Various techniques have been developed for using the konimeter, and many materials, such as petrolatum, mineral oil, and glycerine jelly, have been used in preparing the adhesive film. In South Africa, Australia, and Canada, where the konimeter has been employed most widely, dust samples are treated by ignition and washing before being counted. In Canada the dust samples are collected on a disk of special heat-resistant glass prepared with a film of mineral oil; the disk is then heated to a dull cherry-red in a muffle-furnace to remove the film and organic matter, cooled, and washed with a few drops of 50-percent hydrochloric acid followed by distilled water and alcohol, and then heated again to remove residue left by evaporation of the alcohol. After this treatment, the dust samples are counted under a magnification of 150 diameters with dark field illumination.

Jan 1, 1938

By C. P. Mabie

This report summarizes studies by the Bureau of Mines in developing a simple method for estimating the phosphorus pentoxide (P205) content of finely ground sedimentary phosphate ores and beneficiated products. The method used involved leaching, filtration, and precipitation. The Bureau found that measurement of the volume of ammonium phosphomolybdate precipitate obtained from samples containing 16.8 to 37.7 percent P205 and the use of an appropriate calibration curve permitted estimates of percentage of P205 content accurate within ± 1.1 to ± 2.6 percent, respectively, at the 95-percent confidence limits. Incidental to mineral dressing and petrographic investigations of western phosphate ores in 1959, the Bureau of Mines undertook development of a simple process-control method for rapid on-the-spot evaluation of phosphate-mineral recovery. Because of the fine-grained and obscure character of western phosphate ores, chemical, rather than microscopic or petrographic, techniques were investigated. The described method involves acid decomposition of the ore or product, filtration, addition of ammonium molybdate reagent to the filtrate, and centrifuging and measuring the volume of yellow ammonium phosphomolybdate precipitate produced.

Jan 1, 1961

By B. H. Clemmons

A field method has been devised for rapid determination of heavy minerals occurring in the unconsolidatod beach and dune sands. The method has been proved practical by usage in field evaluations of several hundred beach- and dune-sand samples in the Florida area. The simple equipment required and the techniques involved are described. Other data show that the method is relatively insensitive to variations in the mineralogical content or size distribution of the mixed heavy minerals contained in the samples tested. A modification of this procedure, found to be suitable for plant use in determining the relative purity of heavy-mineral flotation concentrates, is also described. A specific application is determination of the amount of feldspar-quartz in spodumene flotation concentrates. The results of the rapid evaluation techniques closely approximate those obtained by more precise laboratory procedures.

Jan 1, 1957

By C. H. Fisher, Abner Eisner

"INTRODUCTION Sulphuric acid of various concentrations has long been used as a reagent in the determination of olefins and aromatics in hydrocarbon oils 4 such as gasoline, kerosene, and neutral oils from coal—tar distillates. Despite its long use, however, there is no general agreement as to optimum conditions and concentration of acid, and numerous methods and modifications have been recommended. In most cases, treatment of the neutral oil with 60 to 90 percent sulphuric acid, followed by distillation to the original endpoint to remove olefin polymers, is recommended for the estimation of unsaturated hydrocarbons. The distillate thus obtained is taken as olefin—free oil and used in later stages of the anlysis. Aromatic hydrocarbons generally are determined in the olefin—free oil by suphonation with more concentrated acid (96 to 100 percent and fuming sulphuric acid are recommended), the hydrocarbons not attacked and removed as water—soluble sulphonic acids being considered as saturated hydrocarbons. In some cases the saturates are examined further by differentiatingbetween cyclic (naphthenes) and acyclic hydrocarbons (paraffins). Generally this is achieved by physical methods, although strong sulphuric acid is known to react preferentially with some types of saturated hydrocarbons,It was the purpose of the present work to make a general study of this type of analysis and to investigate the reactions of hydrocarbons under conditions often used in analyses that employ sulphuric acid reagents. Since previous work is not in good agreement, the optimum concentrations of acid for the different stages of the analysis were determined. Several sulphuric acid methods previously recommended and new modifications were compared, two synthetic solutions being used as the reference oil. The results obtained are presented below under separate headings."

Dec 1, 1937

By Farrel W. Lytle

An X-ray emission spectrographic method of analysis is presented for determining rare-earth elements in fractions obtained from bastnaesite ore. The method includes determination of yttrium, thorium, lanthanum, and the rare-earth elements in various complex mixtures. The analysis technique is based upon comparing the samples with synthetic standards approximating the composition of the samples. Working curves are plotted on an absolute-intensity basis, with no correction for back-ground. Examples of working curves and the analyses of typical rare-earth concentrates are included. The selection of spectral lines for the various sample matrices is discussed. A special technique is used for samples in which rapid hydration and carbonation occurred. By analyzing synthetic samples of known composition, the accuracy of the method was determined. The average error of analysis was about 3 percent of the amount present in the range from 5 to 100 percent and about 7 percent in the 0.2-to 5-percent range. A maximum of about 40 samples per day may be analyzed for 7 elements each.

Jan 1, 1957

By W. J. Crawford, P. M. Gruzensky

"Several experiments have been carried out in efforts to evaluate qualitatively a variety of electrolytes for refining bismuth. Most extensive work was done with the basic tartrate, hydrochloric acid, and hydrofluosilicic acid electrolytes. Deposits that are smooth and adherent can be obtained from these three electrolytes if low cathode current densities are employed. All three electrolytes were effective in purifying crude bismuth considerably, with additional purification indicated in each instance by a reelectrolysis step.With the basic tartrate electrolyte best results were obtained when the electrolyte was at 40° C. and contained at least 100 grams of bismuth per liter. An apparent disadvantage was depletion of bismuth from this electrolyte, causing the deposits to become spongy and nonadherent.The hydrochloric acid electrolyte had the greatest tendency to yield rough, dendritic deposits. Best deposits were obtained at cathode-current densities below 2 amperes per square decimeter. A small amount of glycerin helped to produce a smoother deposit, and adding sulfuric acid or methyl sulfuric acid retarded the deposition of impurities. Very good results were obtained in electrowinning bismuth from a bismuth trichloride-hydrochloric acid electrolyte.Smooth and adherent deposits were obtained from a hydrofluosilicic acid electrolyte, with very good refining as regards lead and silver impurities; however, higher reagent costs and slow decomposition of the electrolyte have discouraged its use.INTRODUCTIONMethods of recovering bismuth from ores and byproducts were underdeveloped for many years because of the limited uses for bismuth, the pharmaceutical industry being the chief consumer. In the past decade or so additional uses for bismuth, particularly in the metallurgical field, have brought about increased demand for the metal with the result that bismuth is being recovered from byproducts that were once discarded. In addition to such uses as low-melting alloys, solders, bearings, die setting, etc., some interest has been indicated in bismuth as a possible coolant for nuclear reactors. The advent of ductile bismuth and bismuth-alloy thermocouple wire has contributed greatly to temperature measurement, particularly in the below-zero range."

Jan 1, 1956