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By J. M. Davidson, F. Fraas, J. E. Conley

"A number of Reports of Investigations pertaining to the extraction of potash from cal¬cined polyhalite have been made by various members of the Nonmetallic Minerals Experiment Station of the United States Bureau of Mines. These reports describe results obtained in the study of samples of polyhalite (2CaS04.K2S04.MgS04.2H20) from deposits of possible com¬mercial importance in Texas and New Mexico.3Storch and Clarke6 in their initial paper presenting data on the properties of Texas polyhalite demonstrated the desirability of calcination and subsequent hot extraction with water as a satisfactory pronedure for treatment of this potash-bearing salt. Their preliminary data have been supplemented by an additional report7 dealing more particularly with the leaching of raw and calcined polyhalite with water and with saturated sodium chloride solu¬tions. Further data8 have been reported as a result of experiments made in a small labora¬tory rotary-tube furnace under various calcination and extraction conditions. Hot water was used as the leaching solution in all of these tests.In addition to the data on calcination and extraction, two processes as proposed by Storch and Clarke have been published by Wroth,9 and more recently a number of very promising processes have been proposed by Storoh and Fragen.10"

Apr 1, 1932

By G. D. Bakulev

Economic Importance of Gasification of Fuel and Brief Outline of Development of Underground Gasification of Coal in the U.S.S.R. The underground gasification of fuel offers a number of economic and social advantages, principally the following: 1. Full automation of labor-consuming coal-mining processes, which resist complex mechanization and automation, particularly shaft mining. 2. Elimination of hard, dangerous, and often unhealthful mining work. 3. Creation of hygienic conditions for personnel employed in gas production, as well as for those in boiler rooms using the gas. 4. Possibility of automation of complex production processes of thermal-electric powerplants using underground gas with economic installations for steam production. 5. Economic operation of thermal-electric powerplants constructed in the areas of underground-gas production. 6. Release of railroads from the burden of transporting fuel. 7. Extension of the power base of some areas in need of fuel and of the economy as a whole due to use of fuel deposits not amenable to normal mining practices. 8. Reduction of capital investments per unit of energy produced in the form of fuel. 9. Substantial increase in general labor productivity. 10. Possibility of substantial reduction in the cost of fuel produced and of electric power produced from underground gas.

Jan 1, 1962

By L. H. Adami, E. G. King

The heats of formation of four sulfides --MnS ( alabandite ) , FeS ( hexagonal pyrrhotite ) , ZnS ( wurtzite ) , and CdS ( greenockite ) -- were determined by hydrochloric acid solution calorimetry . The heats of formation from the metals and rhombic sulfur at 298.15 ° K are , respectively , -51.01 ± 0.19 , -23.81 ± 0.24 , -45.86 ± 0.20 , and -35.70 ± 0.30 kcal /mole . The corresponding free energies of formation were calculated from the heats of formation and the pertinent entropy values .

Jan 1, 1964

By Ralph B. Adair

The Bureau of Mines conducted laboratory and continuous pilot plant flotation tests to determine the feasibility of recovering commercial-grade mica from an Alabama graphitic-mica schist. Preconcentration of the ground ore on a Humphrey's spiral was employed to reject the heavy minerals and part of the quartz in a product virtually free of mica. The acid-cationic mica flotation process recovered over 89 percent of the mica in a product containing 98.7 percent mica. Grinding of the mica concentrate in a fluid energy mill produced a product with a bulk density of 12 lb per cubic foot.

Jan 1, 1969

By W. E. Wallace, P. S. Raghootama, M. S. Seehra, C. A. Hill, M. J. Keane, P. Mike

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte hemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz, kaolin, and alumina dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect cf lecithin adsorption. Dust hemolytic potential versus media pH are presented. Fourier transform infrared spectroscopy and photoacoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis.Introduction Quarts dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and' progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction. In the alveolar spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, sagas other functions, mechanically stabilises the lung from collapse by reducing the surface tension of water in the alveolar sacs.(1) This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11% in dog lavage fluid). and phospholipids (about 88%).(2) Fhosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalaitoyl lecithin (DPL).(2) Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occuring upon deposition of a particle in a pulmonary alveolus.(3)"

Jan 1, 1988

By Allen S. Smith

Analysis of the helium content of a natural gas presents more than the usual difficulties encountered in applying the thermal--conductivity method because of the relatively small amounts of this inert gas present and the wide variation in the other constituents. However, the numerous advantages of this method and its adaptability to continuously recording and control instruments make it worthy of consideration. A specific application of the method described yields quantitative results only when used with gas mixtures of known qualitative compositions which vary within predetermined limits. Periodic analyses for the helium content of a producing gas well may be conveniently made by an absorption method3/ and a continuous analytical method is not necessary for this purpose. Natural gas containing 1.75 to 1.90 percent of helium produced from Government-owned wells is processed in the Amarillo (Texas) Helium Plant of the Bureau of Mines. The helium extracted in the plant is supplied to the Army and Navy, and the processed natural gas is sold to a commercial gas company4/. As complete recovery of the helium in the raw material is not economically practicable, the processed gas contains 0.1 to 0.3 percent of helium, depending upon conditions of operation;- Production is checked against the helium removed from the gas, which before the installation of the thermal--conductivity apparatus was calculated from the analysis of a cumulative sample of the processed gas. As conditions of operation affect the residual helium content to a large extent, a composite sample was an uncertain index of the efficiency of the process.

Jan 1, 1934

By Wilbur I. Duvall

A linear array of shot and gage holes 30 feet deep in a granite outcrop was used to compare the size and shape of radial strain pulses produced in the rock when short cylindrical charges of cast composition B were detonated axially or at one end. The axially detonated charges produced radial strain pulses that had shorter rise times and larger peak strain than the strain pulses produced by end detonated charges.

Jan 1, 1965

The applicability of borehole assaying techniques, both conventional and advanced, to orebody evaluation in the mining industry is reviewed and assessed, and the research, development, and demonstration programs necessary to apply the various logging techniques to mining are outlined. At present, the principal method of orebody evaluation in the mining industry is coring. However, coring is costly and time-consuming, and potentially great savings can be realized if all or part of d coring program is replaced by a borehole logging suite specialized to the needs of the particular mining industry. Using a set of 12 minerals, most of which are essential to the U. S. economy, an algorithm is presented for calculating the priority of developing suitable borehole assaying technology to replace all or part of the coring in each mineral industry, The priority is expressed in terms of dollars currently spent for that portion of present orebody evaluation techniques which may eventually be replaceable by in-situ assay techniques. The orebody assay requirements (grades, accuracies, etc.) of the 12 selected mineral industries, as determined from mining industry interviews and published literature, are compiled and represent performance criteria for borehole assaying instruments for the particular industry. Current logging techniques, applied chiefly in the petroleum industry, and advanced assay techniques which are or may be packageable for borehole use are evaluated to determine their performance characteristics. The performance characteristics of the various conventional and advanced techniques are then compared with the performance criteria in each of the 12 mineral industries in order to determine the potential benefit derivable from each technique. Finally, the benefit available from each technique, averaged over the 12 mineral industries, is compared with the cost of development of the technique, to determine the overall priority for investment in research to develop the technique for use in mining. The technology assessment and cost-benefit analysis shows neutron activation analysis in its various forms to have the highest priority for research and development as a borehole logging technique. Other techniques found to be promising include x-ray fluorescence, x-ray diffraction, photoluminescence (optical fluorescence), and infrared spectroscopy. Of the 12 industries considered in the study, those where the need for advanced borehole logging technology is greatest are uranium, copper, gold, and iron.

Jan 1, 1976

By Ernest Ph. Hérivel

The mine and treatment plant of the Teziutlan, unit of the Mexican Corporation, S. A., are located at Aire Libre, in the District of Teziutlan, near the northwest edge of the State of Pueblo, Republic of Mexico. The property is leased from the Teziutlan Copper Co. The town of Teziutlan is the terminus of a branch railroad starting from Oriental Junction or the Mexico-Jalapa-Veracruz narrow-gage system of the National Railways of Mexico. A branch line 18 km in length from Teziutlan to Aire Libre belongs to the Teziutlan Copper Co. and is leased and operated in conjunction with the mine.

Jan 1, 1933

By J. E. Pahlman

Spontaneous oxidation and combustion of sulfides and resultant fires are serious problems in underground mines. The Bureau of Mines has con-ducted fundamental thermal gravimetric analysis (TGA) research to deter-mine the mechanisms and factors governing the rate of low-temperature pyrite oxidation, and to identify possible inhibitors to spontaneous oxidation and combustion. The mechanism of low-temperature pyrite oxidation was found to be topochemical, meaning that the oxidation process is controlled by the chemical reaction at the interface between pyrite (FeS2) and iron sulfate (FeS04)' An activation energy of 8.9 kcal/mol FeS2 was obtained for oxidation of minus 500-mesh pyrite in an atmosphere of 60 vol pct water vapor and 40 vol pct . Water-vapor content of the atmosphere was found to be the critical factor in the rate of spontaneous oxidation of pyrite, with a water-vapor content greater than 20 vol pct needed for accelerated oxidation. An atmosphere of pure oxygen resulted in negligible oxidation. The rate of pyrite oxidation is also greatly affected by the particle size of pyrite. Pyrite-oxidation rate increased drastically for particles less than 40 ~m. Room-temperature pyrophoric behavior was observed for freshly ground unoxidized pyrite (55 pct minus 5 ~m) upon exposure to air. Addition of water-adsorbing materials such as activated alumina (Alz03) decreased the rate of pyrite oxidation.

Jan 1, 1986

By Wils L. Cooley

The report covers several aspects of mine safety ground systems, primarily for underground coal mines. The design of a combined ground fault-ground check monitoring system is presented. An analysis is made of grounding systems for dc shuttle cars. Complete resistance data and results of physical inspections of self-salting ground rods are presented. A detailed resistance and economic analysis is presented for the use of composite materials for building inexpensive and effective ground beds in high-resistivity areas. The desireability of penetrating the coal seam with a borehole safety ground is investigated. A report is made of a Mine Substation Grounding and Bonding Workshop.

Jan 1, 1980

By R. L. Hopkins

Fifteen alkyl cycloalkyl sulfides and three dicycloalkyl sulfides were synthesized to provide reference compounds in the search for these classes of sulfur compounds in crude oils. In synthesizing sulfides by alkaline alkylation the order in which the reactants were added was shown to determine the yield and purity of the product.

Jan 1, 1966

By T. A. Henrie, E. K. Kleespies

Electrolytic studies were conducted to determine the transfer rates of the alloying constituents from molten titanium anodes to solid titanium cathodes in molten salt systems . The metals , nickel , tin , copper , bismuth , and manganese , were selected on the basis of thermodynamic data and the melting point of the alloy system . The transfer of nickel , tin , and bismuth was very low . The content of these elements in the cathode was in the range of less than 0.01 to 0.001 percent . The copper transfer was 0.6 to 0.8 weight - percent in electrolytes containing titanium chlorides and 0.12 weight - percent in titanium fluoride salt systems . The manganese transferred at rates comparable to that of titanium . Highpurity titanium and titanium- manganese alloys of uniform composition were produced by electrorefining molten titanium alloys in chloride electrolytes . Comparisons are made between the calculated and the actual quantities of metal transfer .

Jan 1, 1964

By W. M. Myers

[Utilization of small stone is recognized as one of the important problems of the lime industry. The term ?small stone' is used to designate material that is too small for calcination in tie shaft kilo. The maximum dimension A such stone rosy be placed at four inches. The introduction of any considerable quantity of stone having demensions lee: than this into the charge of a kiln impedes the draft and readers successful operation of the kiln difficult on impossible. Attempts design a shaft kiln which would calcine stall stone satisfactorily have not been successful to date. Thousands of tons of this small stone arc produced daily, and while part of it finds a market, for it has many uses, the profit is usually small an competition is teen and prices are low. Production of the material is, however, so greatly in excess of market that surplus of hundreds or possibly thousands of Jose axe place daily in stock piles and classified as waste. in a few instances a fortunate combination of circumstances, such as a program of or other work requiring large quantities of concrete aggregate, may mate it possible some quarries to market this stone later at a profit, teat in general the chances A profitable utilization are slight, and the quarry operator has the expense of handling this waste stone and providing a storage site for it. The brittle nature of limestone makes it impossible to quarry the stone and crush, it to size suitable for the shaft kilns without producing an excess of undesirable fines. Elimination of fines by changes in quarrying or crushing practices cannot lee expected. On the contrary, the adoption of more modern methods of quarrying in recent years has increased the proportion of small material. The tendency is to blast the roan with large charges of explosives and crush it with mechanical crushers, which produces more fines than the older methods of careful blasting with small char yes and sledging the rock by hand.. We increasing use of underground mining of limestone has also increased the production of small stone, as blasting in the confined space of an underground stope shatters the rocs more completely than quarrying in the open. The use of the very friable limestones, such as the limestone of Florida for the manufacture of lime adds a new factor to the calcination of small stone. These friable lime limestones have a low tensile strength and crumble in the kiln, causing trouble. Successful calcination of these stones is accomplished in specially]

Jan 1, 1926

By John L. Miller

The synthetic fluormicas may be divided on the basis of silicon content into tetrasilicic, trisilicic, and disilicic. Properties of lead and barium disilicic fluormicas were determined to characterize these two representative members of the disilicic group. Properties described include unit-cell parameters from X-ray diffraction, optical data, chemical composition, density, melting point, and mechanical and dielectric properties. Both the lead and the barium micas were typically monoclinic; neither was sufficiently cleavable to yield usable mica splittings. Both yielded polycrystalline, machinable ceramics with excellent mechanical and dielectric properties.

Jan 1, 1963

By W. E. Wallace

Volume-rate-of-flow measurements were made of the flow of mercury through porous samples under conditions of no field, magnetic field transverse to the direction of flow, and transverse magnetic field and electric current to determine if a magnetic method might be potentially useful in the study of pore-size distribution. No change was observed in the flow rate from the application of a magnetic field alone. The application of both field and current produced an electromagnetic pumping action with or against the direction of flow, depending upon the direction of the electric current. This pumping effect was observed to be greater in a rectangular porcelain sample than the calculated value for an equal-Sized open channel.

Jan 1, 1969

By G. W. Reimers

Metastable pyrophoric wüstite (FexO, with x between 0.89 and 0.95) was found to be much easier to grind to colloidal state than were its stable disproportion products magnetite or iron. The grinding of polycrystalline magnetite appears to be complicated by the magnetic flocculation arising from interparticle attraction. This is superimposed on the attraction of a fluctuating electric dipole for a neighboring induced dipole. More than 85 pct of the tumbling time was saved by grinding antiferromagnetic wüstite instead of the ferrimagnetic oxide of iron (Fe304). Disproportionation of colloidal wüstite to the stable ferromagnetic and ferrimagnetic colloidal particles of alpha-iron and magnetite, respectively, was accomplished rapidly at temperatures above 250° C but below 570° C, the eutectoidal stability point of the wüstite phase.

Jan 1, 1972

By Daryl E. Radcliffe

The Bureau of Mines, as part of an agreement with the Bear Coal Co., Somerset, Col o., evaluated the response of a coal mine roof to time lapse. Time lapse, the interval between exposure and support of the roof, was studied using both instrumentation and statistics. Instrumentation studies were designed to equate displacement and rates of displacement with areas of roof left unsupported from 15 minutes to more than 4 days. A statistical study was completed to compare roof fall occurrence with time lapse intervals encountered during normal room-and-pillar mining. Results from this investigation show time lapse, in the Bear mine, to he insignificant with respect to roof stability after installation of permanent support.

Jan 1, 1980

By A. Adams

The quality of hafnium metal produced by the Kroll process depends upon the purity of the hafnium tetrachloride. This investigation of methods for purification of hafnium tetrachloride was undertaken to aid in producing a higher purity hafnium metal than is currently produced by the Kroll process, The quantities of metallic impurities in hafnium metal were decreased by contact with molten alkali-metal chloride salt. Contact was achieved by a semicontinuous process of bubbling gaseous hafnium tetrachloride through a molten salt bath or by a batch process, first fusing the tetrachloride with a combination of alkali chlorides and then heating the mixture to sublime the hafnium tetrachloride. Low-melting mixtures of sodium, potassium, and lithium chlorides were used to purify hafnium tetrachloride. About 30 percent of the initial hafnium tetrachloride was trapped during purification with alkali- metal chloride salts. The 95-percent confidence limits (6)4 for the amount of oxygen decrease 60 and 34.3 parts per million when the batch purification is combined with a reduction so that both take place in the same equipment,

Jan 1, 1961

By F. E. Armstrong

A program with the objective of developing a fast, accurate instrumental method of analyzing mine dust for incombustible content has been underway in the Bureau of Mines for several years. Several prototype instruments making use of a gamma-ray backscatter technique have resulted. Although extensive laboratory testing has shown that these instruments are accurate under laboratory conditions, only extensive field testing will prove their ultimate practicality and usefulness. This report shows that under most conditions these devices are at least as accurate as the volumetric method and much faster in use. Other data obtained during the same study concerning mine dust are presented; these concern moisture content, sample bulk density distribution, and some particle size distribution information.

Jan 1, 1973