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By Paul Biggs

This Bureau of Mines report contains information on 63 water flood projects in Colorado. Water was injected in 10 formations located in 58 oilfields. Specific field data presented include location, discovery, development, water supply, fluid injection, oil and water production, oil reserves, and oil recoveries by primary and secondary methods. An estimated 3.5 billion barrels of water has been injected to recover approximately 533 million barrels of oil, a ratio of 6.57 to 1. Most of the injection water is from alluvial deposits, although produced water is used in many fields. Injection water treatment is not a major problem. Appraisal of project success or failure in this report is based on technical, rather than economic, information.

Jan 1, 1974

By Bowles Oliver

"Modification of Quarry Process.Limestone beds are formed by processes of nature, processes that have been in operation for thousands and perhaps millions of years. Therefore, their com- position and physical properties are long-established and unalterable features over which man has no control. He must take them as he fields them.It is undoubtedly true that the character of lime depends largely on the nature of the parent limestone. A high-calcium lime cannot be manufactured from a dolomite, nor can a pure lime result from the calcination of an impure raw material. However, in the process of turning limestone into lime man is not entirely helpless in his control of quality. Even though a deposit is variable in character a single lime product of uniform quality may be produced by judicious quarrying. A single grade of product may not always be desired, the producer may wish to supply the needs of a variety of users each demanding U different grade or quality of lime such a series of graded products may be produced in part at least by modifying the quarry method. Thus, by changes in quarry practice a single product or a variety of products may be made. The latter problem will be considered at a later time, and the present paper devoted to the first named question' that of producing a single grade of lime from a deposit of variable rock,It is realized of course that uniformity in the product is influenced greatly by manufacturing processes such as calcining' hydrating' grinding or storage, but the present discussion is confined to the influence of raw materials only. In considering the various devices that may be employed it is realized that much remains to be learned, and it is hoped that many operators will contribute to the discussion as they have already done in connection with previous papers of this series."

May 1, 1923

To enhance safety and efficiency when moving large mining equipment under energized trolley lines, and to assist in compliance with Section 75.1003.2, 30 CFR. Approach A system was designed, using established technology, that permits a remotely located circuit breaker to be controlled from the cab of a mine locomotive moving large mining equipment under energized trolley lines. This control consists of setting the desired trip current, automatic or manual tripping, resetting, and voice communications between the locomotive and a remote Circuit breaker location. How It Works According to 75.1003.2, 30 CFR, whenever a piece of off-track equipment (such as a longwall chock or a continuous miner) is moved by rail under energized trolley or feeder lines, power for the locomotive that is moving the equipment must come from only one' circuit breaker. This circuit breaker must be adjusted to permit no more than one-half its rated short-circuit current to flow. The intent is to lessen the danger if an accident should occur, and if the equipment contacts the trolley line. Even so, the danger is great. This half setting can still represent many hundreds or even thousands of amperes, enough to endanger personnel, the equipment, or the mine. The Remote Control System reduces this danger substantially by giving the personnel associated with the move total control over the associated circuit breaker. The system as designed, is intended to be used with portable circuit breakers that are pulled on a small flat car by a mine jeep, and either precede or follow the equipment, depending on the direction of the power. This portable circuit breaker is equipped with a commercially available solid state overcurrent relay and associated shunt. This circuit breaker is connected via heavy duty clamps around an open trolley line tie breaker such that the current through the shunt is also the current in the trolley line. A receiver, interfaced with the overcurrent relay and shunt, completes the remote system.

Jan 1, 1981

By Dorsey A. Lyon, Robert M. Keeney

This bulletin is one of a series dealing with the application of the electric furnace to the smelting of ores and the manufacture of alloys, and is published by the Bureau of Mines in the endeavor to increase efficiency in metallurgical processes. The bulletin presents, first, a critical discussion of the possibility of smelting copper ores in the electric furnace; second, the results of the experimental work of other investigators on the electric smelting of copper; third, the results of experiments by the authors on the electric smelting of native copper concentrates and sulphide copper ores; and, fourth, a comparison of the electric furnace with the blast furnace and reverberatory furnace for copper smelting. Before considering the electric smelting of copper ores the reader should understand that the electric furnace was not developed as a competitor of the combustion furnace, but for the purpose of doing high-temperature work that can not be done in the combustion furnace, and for the treatment of ores from deposits that are in regions where fuel is scarce and costly but hydroelectric power is comparatively cheap, as in Chile, and in certain parts of Canada, the United States, and Mexico. Furthermore, it is not the object of this report to try to prove that the electric furnace should replace the reverberatory or the blast furnace, as used at present in smelting copper ores, but to show that the electric furnace may be used with advantage in localities where conditions are not favorable to the use of the reverberatory or the blast furnace. For example, otherwise valuable ore deposits may be situated in a district so remote from, or inaccessible by, railway that the cost of get- ting coke for smelting, or of transporting the ore to a smelter, is pro- hibitive. If there is sufficient water power at hand, from which electric power can be developed at a reasonable cost, and this electric power is used for smelting the ore in an electric furnace, with subse- quent bessemerizing, if necessary, the concentrated product may be

Jan 1, 1915

By Joseph T. Singewald

The term "titaniferous magnetite" is used to designate those mag- netic ores of iron that carry more than 2 or 3 per cent of titanium. Large and easily workable deposits of these ores occur in different parts of the world, and have attracted attention for many years. Under present furnace practice, however, the smelting of these ores is both difficult and expensive, and for that reason they are not accepted by furnaces, so that the deposits are practically worthless. The problem of finding a feasible method of utilizing these ores has naturally been attractive, and numerous attempts have been made to solve it. Experiments to that end embrace two lines of investigation. The one that has been the more frequently tried is the elimination of the titanium from the ores, so as to make possible their smelting in the usual way. The other is the devising of a method of smelting by which titaniferous ores may be reduced as economically as are non- titaniferous ores. The former method involves a physical process, the latter a chemical process. The measure of success attainable by the first method depends entirely on the relations between the iron and the titanium in the ore. Views in regard to these relations have been divergent. Some investi- gators have believed the titanium to occur as a part of the magnetite molecule, in which case, of course, any process of mechanical separa- tion would be impossible. Others have believed that the titanium occurs as the mineral ilmenite, and that the ores are aggregates of magnetite and ilmenite. In this case a separation of the two minerals is theoretically possible. Magnetite is highly magnetic; ilmenite is nonmagnetic or only feebly magnetic. Crushing and magnetic con- centration should separate them. Numerous experiments in mag- netic separation have been made with various degrees of success, but rarely has more than a very imperfect separation been obtainable. In other words, some of the titanium exists in a separable form and some in an inseparable form, and the ratio between the two forms is

Jan 1, 1913

By K. Robert Dorman

This Bureau of Mines report describes laboratory and field experimentation in building mine ventilation stoppings, air-door frames, and fan bulkheads with a civil construction technique. Shotcrete is applied to a free-standing, three-dimensional wire-truss panel, which is easily cut and rapidly erected. In mines where shotcrete equipment is available, this technique should be faster and cheaper than conventional block-and-mortar or monolithic concrete construction.

Jan 1, 1980

Continuously separate mixture of non-magnetic materials (such as scrap, precious metals, or certain ores) at a reasonable cost. Approach Nonmagnetic materials of different densities are rapidly float/sink separated by an augmented lifting force produced In a magnetic fluid (liquid) by the effect of an external magnetic field. The magnetic fluid is a colloidal suspension of magnetite In kerosene, prepared by a low-cost process. How It Works Separation is accomplished in an open trough filled with magnetic fluid. A magnetic field is established in the fluid, by energizing an electromagnet having poles on each side of the trough. Due to the design of the magnet poles and air gaps, the magnetic field is strongest at the bottom, about 10,000 oersteds, and uniformly decreases in strength to about 2,000 oersteds at the top of the fluid. Therefore, the magnetic field gradient increases with depth. The magnetic force attracts the entire separation medium (magnetic fluid) creating a reaction force of equal magnitude and acting in the opposite direction. This reaction created within a magnetic fluid/magnetic field combination is called a magnetic levitation force. It increases with the field strength. In this case because the magnetic field is strongest at the bottom of the trough, the magnetic levitation force will quickly float lighter material while heavier material sinks.

Jan 1, 1980

By R. F. Abernethy

A chemical method of determining microgram quantities of arsenic in coal was investigated by the Bureau of Mines to supplement a semiquantitative spectrographic method of determining arsenic in coal ash. In accordance with a method recommended by the International Organization for Standardization, 1-gram samples of coal are decomposed by wet oxidation with boiling sulfuric acid (H2S04) and nitric acid (HN03) to remove the organic matter. After heating to fumes of SO3 to remove HN03, the arsenic is separated as arsine by the action of zinc in H2S04 solution. The arsine is absorbed in dilute iodine solution in which the arsenic is determined colorimetrically by the molybdenum-blue reaction. Two modifications of the method for obtaining the arsenic in solution, in addition to the wet oxidation method, give satisfactory results. The modifications are (1) furnace ashing with MgO added to the coal, followed by treatment with H2S04, and (2) extraction of arsenic from the coal by dilute HNO3 without ashing. Float-and sink-tests show that arsenic is associated mainly with mineral matter in the three coals examined. High-temperature ashing tests show that very little arsenic is volatilized from coal ash below 1,000° C, but it is virtually all removed from the ash at 1,300° C.

Jan 1, 1968

By G. S. Scott

The flammability of trichloroethylene vapors in air has been determined in a 7-inch cyclindrical vessel. Saturated flammable mixtures were formed with air at atmospheric pressure between 30° C (86° F) and 82° C (180° F); the trichloroethylene concentrations at these temperatures are 12.5 (lower) and 90 (upper) volume-percent, respectively. Further study is necessary to assess the effects of different variables on the flammability of this material. INTRODUCTION Trichloroethylene (TCE) (ClHC = CCl2), sold under various trade names (Blacosolv, Perm-A-Clor, Tri, Triad, Triclene, Trivec, Tromex, Vapoclean, Vapoclor, Westrosol, etc.), is an important industrial chemical. A summary of its physical and chemical properties is given in table 1. It is used to degrease metals, leather, and textiles, to extract residual oils from vegetable oil cakes, for dry cleaning, and in soap. It is a powerful solvent for fats, resins, bitumens, rubber, sulfur, and phosphorus. Several explosions in which trichloroethylene was involved prompted an investigation by the Bureau of Mines to determine the conditions under which such accidents can occur.

Jan 1, 1963

By Launa G. Mallett, Charles Vaught

This report is intended to help mine safety trainers better prepare to teach the influx of new underground coal miners who are entering the industry. This is done by identifying two different approaches to instruction and discussing the ways they may affect how well prepared new hires are to deal with a dynamic and hazardous workplace. One approach is based on the use of a syllabus. Those using a syllabus are more likely to rely on lecturing or direct instruction. This is a good way to get across factual information, but does not provide a context within which miners can fit the discrete facts so that they form an integrated whole set of concepts, principles, and skills. The other approach is based on the use of a curriculum. Those using a curriculum may be more likely to help miners integrate concepts and skills that give them an overall picture of the complex mining environment and how they fit into the workplace. This will better prepare them for the decision-making and problem-solving activities that will help them work safely and productively

Jan 1, 2008

By Philip W. Holland

The U.S. Bureau of Mines has developed an improved method for determining dissolved helium in water in the concentration range of 4.0 x 10-8 to 270 X 10-8 cm3 He (STP)/cm3 H2O. The method is a modification of a previously reported method that was developed for analrzing surface and subsurface waters in geochemical survey work. Water samples are collected in SOD-cm stainless steel cylinders, and the dissolved gases in a sample are extracted into an evacuated cylinder of equal volume. After addition of 30 psig of nitrogen containing less than 2 ppb helium to the extracted gases, the resulting mixture is analyzed for helium using a helium-tuned mass spectrometer. The helium content of the water sample is determined from an empirical calibration that is established by analyzing standard solutions of helium in water. The accuracy of the method is ±7 pct for helium-in-water concentrations above 10 x 10-8 cm3 He (STP)/cm3 H2O.

Jan 1, 1989

Enhance the critical skill of hazard recognition among miners by providing quality training that can help jot performance and lead to a higher degree of safety in the workplace. Background In mining, as in many other occupations, the safety of the worker depends on his or her ability to recognize hazards in the workplace. Some of the information needed by the miner for recognizing potential areas of danger is available in the form of visual cues found throughout the mine. One aspect of the dynamic mine environment it which the task of hazard recognition is critical for al workers is that of ground control. Regardless of job responsibilities, every worker is continuously exposed to roof rib, and floor hazards. Fatality injury data for the "underground coal" segment of the mining industry continue to show that about half of all fatalities are due to falls of ground each year. It is hypothesized that some of these accident, can be prevented if miners are better able to recognize visual cues that forewarn of potential roof and rib problems.

Jan 1, 1992

To precondition a stope in advance of mining and thus reduce or prevent rock bursts. Approach Drill deep holes from a mine opening in a radial pattern in the vein and load and blast to fracture, the rock prior to production mining How It Works Preconditioning of a sphalerite galena vein in a hard gangue of quartz and quartzite creates a zone of softer rock that fails by displacement rather than violently as an elastic-battle mass. However, the entire area must he analyzed carefully so that the stress transfer does not cause problems in other workings of the mine A typical drill hole pattern and explosive loading is shown in the sketch. Hole diameter is about 4 inches and a down-the-hole, type drill is used. Drilling speed in hard quartzite is about 12 inches per minute High pressure compressed air (250 psi) is used to run the drill. An overhand cut-and-fill stoping area on the 7700 level of Hecla Mining Company's Star Mine in Burke, Idaho was preconditioned above and below the

Jan 1, 1981

Develop a method for recovering phosphate from a wide variety of complex western phosphate materials, including low-grade ores, tailings, and unused fines. Approach A flotation technique is used for this broad type of extraction. The method includes depression of phosphate minerals and anionic flotation of carbonate minerals, followed by cationic flotation of silicate minerals. How It Works A slurry is prepared for flotation by sizing to remove a low-grade, high-impurity slime fraction. Depending on the material, further sizing and/or grinding steps may be used to produce a size concentrate or to remove gangue. The flotation feed is conditioned with H2SiF6 and a fatty acid emulsion. The H2SiF6 is absorbed chemically to the phosphate mineral surface, making it strongly attracted to water and preventing adsorption of the fatty acid. Under these conditions, the fatty acid is a selective collector for carbonate minerals, which are removed as a froth product. Next, the silicates are floated with an amine reagent added directly to the slurry without additional pulp preparation.

Jan 1, 1982

By Charles Zahn

Gas chromatography is a method of separating mixtures of gases and volatile materials by entraining their vapors in a gas stream, which passes over an appropriate stationary phase. Two techniques are in common use: Gas-Liquid Chromatography, in which the stationary phase is a liquid supported on an inert solid, and Gas-Solid Chromatography, where the stationary phase is a solid adsorbent, such as charcoal or alumina. In both techniques components emerge from the column after a characteristic residence time. Gas chromatography is applicable as a qualitative or quantitative tool in a wide variety of problems in chemical research and processing. It may also be employed for purification and separation. A running bibliography on gas chromatography has been maintained at the Bureau of Mines synthetic liquid fuels laboratories, Bruceton, Pa., for several years for the benefit of research workers, who use chromatography as an analytical tool. Since the number of references grew and interest in the technique became more wide-spread, the Bureau is publishing this list rather than maintain it as a purely internal source.

Jan 1, 1958

By P. W. Jeran

The Stereonet Analysis Program (SNAP) is a mathematics tool which, by means of a computer, reproduces mathematically the manual techniques of pre- paring stereograms. This computer program was developed to provide a fast, accurate, and economical means of analyzing fracture orientation data. It is mitten in FORTRAN IV for use on a UNIVAC 1108 operating under an Exec II system, but can be adapted to other systems. SNAP is currently being used to aid in the analysis of cleats and other geologically induced fractures associated with coalbeds that are being mined underground, Methane flows through the coalbed and into these mine workings predominantly through the fracture system. Therefore, knowledge of fracture orientation is an invaluable aid in the development of methane control technology.

Jan 1, 1970

By Fun-Den Wang

A new approach for evaluating pit slope stability by the limiting equilibrium method has been developed by the Bureau of Mines. The finite element method of plane strain analysis is used to find the stress field of the pit slope structure. This stress field is then used to find the normal and shear stresses along a potential failure surface. The normal stresses are used with the Coulomb equation to calculate the shear resistance. The shear stresses are integrated to determine the total driving force. The factor of safety is evaluated from the ratio of the resisting force to the driving force along a failure surface, and is found to be affected by the elastic material properties, modulus of elasticity, and Poisson's ratio.

Jan 1, 1970

By Thomas J. Peters

In 1988, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 5,640-acre Soda Mountain Wilderness Study Area (OR-011-017), in order to evaluate its identified mineral resources. The study area is located in Jackson County, OR, about 30 miles south-east of Medford. The study area covers most of the south-facing slope of 6,071-ft Soda Mountain. Geologically, the area is underlain by Oligocene to Pliocene basaltic andesite flows and less extensive intrusive rocks of the western Cascade Mountains. In addition, there is a 3/4-mile-diameter area of kaolinized and silicified rhyolite tuff, which appears to have intruded the andesite, and is host to epithermal gold mineralization.

Jan 1, 1989

By Sidney Katell

This report is an economic evaluation of the production of hydrogen in a continuous system by the steam oxidation of partially reduced iron oxide in a fluidized bed at 7 atmospheres using producer gas to reduce the iron oxide. The oxidation-reduction step is based on experimental data obtained by the Bureau of Mines at the Pittsburgh Coal Research Center. The estimated capital requirement for a plant producing 30 million std. c.f.d.3 of 99.8 percent purity hydrogen at a discharge pressure of 450 p.s.i.g. is $13,100,000, using January 1961 equipment cost data. Based on a 330-day operating year, the operating cost before profit and taxes with coal price as a variable is estimated to be:

Jan 1, 1962

The first steps in the process of mine evacuation are the recognition of a problem and an attempt to communicate the problem to miners who may be affected. This chapter will focus on the way that a problem, fire, came to the attention of mine personnel and the messages that were sent to miners in the affected areas. The concept of information uncertainty, which was introduced in chapter 4, will be discussed as it influences problem perception and diagnosis. Sociotechnical and interpersonal communications will be explored and suggestions for improving these systems will be offered. It might seem that the first indication of a dangerous fire would motivate individuals to take self-protective action, to evacuate the affected area or structure, and to provide clear warning to others who are in danger. Research has actually shown that in most situations this does not occur. Instead, time is taken to gather more information, confirm information that is provided, and consider possible alternative explanations that could account for the given circumstances [Canter 1990; Scanlon 1979; Bickman et al. 1977]. This process of confirmation can lead to the loss of critical time. Canter [1990] summarizes the problem in his book, which reports studies of a number of fire events: "As discussed throughout this book, ambiguity and confusion, incoherent instructions and time-wasting actions, lack of appropriate instructions and misunderstanding of the nature of the event that is unfolding, are all hallmarks of fires and emergencies that kill people." In this chapter, the detection of each mine fire and the communication of warning to endangered miners will be reviewed with an emphasis on how those processes were affected by the availability and use of information. Information can become available through a variety of mechanisms during an emergency situation. First, cues may be taken directly from the environment. Smoke is an obvious example. Secondly, mechanical devices, such as smoke detectors, may provide warning messages. A third source of information is interpersonal communications. These can occur face-to-face or through some mechanical device such as a telephone. With all three methods there is a possibility of miscommunication, misunderstanding, and misinterpretation. All of these means of communication were used with varying degrees of success in the three mine fires analyzed here. A fire, like any nonroutine situation, engenders uncertainty about a diagnosis and understanding of the problem [Mead 1938]. This uncertainty leads to delays in realization of the seriousness of the situation and therefore in the proper response to it. Delay in action is an important concern in any fire setting, but is even more at issue in underground coal mine fires. Mine fires are qualitatively different from structural blazes: workers' escapeways may be miles long; the seam height at many operations is so low that it is impossible to walk upright; access to underground workings is always limited to a few (sometimes only two)

Jan 1, 2000