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By C. B. DUTTON, W. F. RITTMAN, E. W. Dean, M. S. HOWARD

NOMENCLATURE USED IN THIS REPORT. In this report the ending ene has been used throughout, except in the bibliography and in quotations from the writings of previous investigators, for all aromatic hydrocarbons, as, for instance, benzene, toluene, xylene. The ending ol, though largely used in technical description, is not correctly applicable to these hydrocarbons, and should be used to designate the impure mixtures of commerce, as distinguished from pure chemical compounds. PRESENT STATUS OF PETROLEUM-REFINING INDUSTRY. Although petroleum is widely distributed, being found in many parts of the world, and although information as to its occurrence and general characteristics seems to have existed from vcry early times, our knowledge of the chemical nature of this substance has been acquired largely within the past 40 years. Within this period a voluminous literature has accumulated, which records work as painstaking as has ever been undertaken in the whole field of chemistry, such as that of C. M. Warren, F. H. Storer, S. P. Sadtler, S. F. Peckham, and C. F. Mabery. Despite this fact, the commercial method of treating crude petroleum for the purpose of procuring marketable products is, in the main, essentially empirical. Much knowledge has been acquired as to methods of separating from crude petroleum such products as are desirable commercially, but little has been done to attain the maximum recovery of such products.

Jan 1, 1916

By Larry Patts, Michael J. Brnich

Approximately 45% of U.S. coal is produced from underground mining. The use of diesel engines to power under- ground mining equipment has steadily increased over the past four decades in an effort to improve mine safety and productivity. Several advantages realized with the use of diesel-powered mining equipment in underground coal mines are listed in Table I. The primary disadvantage of using diesel equipment in underground coal mines is that diesel exhaust emissions can contaminate mine ventilation air. The major constituents of diesel exhaust are gaseous emissions (which include carbon monoxide, carbon dioxide, oxides of nitrogen, sulfur oxides and unburned hydrocarbons) and diesel particulate matter (DPM). The Mine Safety and Health Administration (MSHA) has incorporated threshold limit values for all gaseous components of diesel exhaust into their regulations. These have been established by the American Conference of Governmental Industrial Hygienists.

By Alla D. Mah

Heat content and entropy data at high temperatures were obtained for cuprous oxide (Cu2O) and cupric oxide (CuO). Experimental results and smooth values are reported. Equations are given for heat content increments and heat capacities above 2980 K. Low-temperature heat capacity data were obtained for cuprous oxide. Evaluation of the 2980 K entropy gave, S°298.15(Cu2O) = 22.08 ± 0.10 cal/deg mole. Heat of formation values were determined for cuprous and cupric oxides. The values are: AH°298.15(Cu2O) = -40,830 ± 300 cal/mole, and AH°298.15(CuO) = -37,230 ± 150 cal/mole.

Jan 1, 1967

By M. Jaffe

The data developed in this study establishes the technical and economic feasibility as well as the improved health and safety characteristics of a novel mining concept. The mining concept is a modified longwall technique using prestressed tendons for roof control, longhole blasting for fragmentation, and remote mucking. The technical feasibility was found to be dependent on the state of the art, while economic feasibility was found to be dependent on particular minerals and on supply and demand. Since these two conditions are not necessarily coincident in time the data is presented in the report in a manner that enables the mining engineer to perform a rapid preliminary technical and economic analyses for a specific property.

Jan 1, 1977

By Robert L. Lagace

An investigation is made of the feasibility of developing compact transmit antennas and/or other means to efficiently couple VLF to MF band radio energy between portable wireless communication units in coal minus. The completely wireless communication ranges between two portable radios equipped with practically-sized reference loop antennas in representative coal mine environments are estimated. Antenna technology is assessed with respect to transmit moment, range, intrinsic safety, battery and wearability requirements to determine the most suitable antenna types for use by miners. It is concluded that air-core bandolier loop antennas, and perhaps ferrite-loaded loop antennas, having peak transmit moments of about 2.5 ampere-m2 will be the most effective antenna choices for portable units. This choice, however, will not allow the range goal of 1350 feet to he attained in mines having unfavorable signal attenuation and noise environments. Rectangular air-core loops are compared with grounded horizontal-wire and vertical-wire mode exciters for fixed station applications. The potential for significantly increasing the wireless communication range by inductively coupling to communications and power lines in a mine is evaluated and found to be considerable based on theoretical coupling equations. Lastly, the theoretical performance of a hybrid noise cancelling diversity receiving technique that utilizes both the electric and magnetic field components of the ambient noise to improve the receiver output signal-to-noise ratio under certain adverse conditions is estimated and shown to be favorable when the magnetic and electric field noise components are highly correlated.

Jan 1, 1977

By Thomas L. Vandergrift

To significantly increase the stability of underground excavations while exploiting the full advantages of confined rock strength, methods must be developed to actively control the distribution of stresses near the excavation. This U.S. Bureau of Mines study examines theoretical and practical aspects of rock pres¬surization, an active stress control concept that induces compressive stress in the wall rock through repeated hydraulic fracturing with a settable fluid. Numerical analyses performed by incorporating the rock pressurization concept into a variety of boundary-element models indicate that rock pressurization has the potential to improve underground excavation stability in three ways: (1) by relocating stress concentrations away from the weak opening surface to stronger, confined wall rock; (2) by inducing additional stresses in a biaxial stress field to reduce the difference between the principal stress components near the surface of the opening; and (3) by counteracting the tensile stresses induced in the rock around internally loaded openings. Practical aspects of the rock pressurization concept were investigated through a series of hydraulic fracturing experiments. The use of sulfur as a settable fluid for hydraulic fracturing was demonstrated, although problems related to sulfur viscosity suggest that other molten materials, such as wax, may be better suited to practical field application of the rock pressurization concept.

Jan 1, 2010

By C. P. Mishra

The Bureau of Mines performed a study of the availability of cobalt from market economy countries. The study entailed the detailed analysis of 97 deposits which contain 3.9 billion lb of cobalt at the demonstrated level; in 94 of the deposits cobalt is recovered as a byproduct, and in 3 it is considered the primary product. Since 97 pet of all recoverable cobalt is derived as a byproduct from copper and nickel deposits, the report focused on these two sources. At an assumed market price of $0.89flb for copper, $3.45/lb for nickel, $475/tr 021 for platinum, and $7/lb for cobalt, 1,330 million lb of cobalt at the demonstrated level are potentially available. This total includes 1,105 million lb of cobalt from copper properties, 190 million lb from nickel, 29 million lb from platinum, and 6 million lb from primary cobalt. This analysis indicates that the production cost for 589 million lb of cobalt can be totally covered by the revenues obtained from the other metals produced. The impacts of increases in capital investment and energy costs are also discussed.

Jan 1, 1985

By Richard A. Allwes

This U.S. Bureau of Mines report presents the results of structural analyses and full-scale physical tests conducted on a steel-set arch and tri-set. The purpose of the analyses and tests was to evaluate the suitability of these structures for use in roof-fall prone areas. The arch canopy test and design procedures previously developed by the Bureau were utilized in this evaluation. Theoretical resistance functions were established for the steel-set arch and tri-set and were representative of the experimental behavior of the structures. The resistance functions were used to determine the energy absorption capacity of the structures and to predict their dynamic response to impact loading. The dynamic tests demonstrated that the arch canopy design procedure is appropriate for tri-sets and yields conservative designs for both steel-set arches and tri-sets. As a result of this work, it is recommended that these two structures may be considered for use in roof-fall prone areas and for rehabilitation work, provided the arch canopy design procedure is utilized for each application and the principles underlying the design procedure are understood.

Jan 1, 2010

By R. C. Hickman

Preliminary evidence indicated that the Chattanooga Shale might constitute a potential vast low-grade source of uranium. Investigation by core drilling indicated that while the Chattanooga Shale may constitute a resource for the future, the very low (0.006 percent) average uranium content is not economic when compared with the relatively higher grade western ores. A total of approximately 12,000 feet of test drilling was done in 72 drillholes, and large samples were mined for extractive and metallurgical testing. An experimental mine site was selected on the basis of the drilling project.

Jan 1, 1967

By W. W. Adams

This bulletin covers all mines in the United States that were operated in 1936 to produce metallic ores and all mines that were operated to produce nonmetallic minerals other than coal, stone, sand, gravel, or their products. Reports from mine operators revealed a better safety record for fatal accidents in 1936 than in any other year except 1934 during the 26 years for which annual surveys of accidents in the mineral industries of the United States have been conducted by the Bureau of Mines. On the other hand, the record for nonfatal injuries, although better in 1936 than in any year prior to 1930, was not as good as it was from 1930 to 1935, inclusive.

Jan 1, 1939

By A. R. T. Denues

This investigation was made under a cooperative agreement between the United States Department of the Interior, Bureau of Mines, and the Pittsburgh Testing Laboratory. Funds were supplied by the Chile Exploration Co., whose executive offices are in New York City. The support, cooperation, and services of these agencies made the work possible and are acknowledged gratefully. The writer wishes to express his particular indebtedness to the staff of the Explosives Division of the Bureau of Mines for services and assistance, particularly Dr. Wilbert J. Huff, consulting explosives chemist, J. C. Holtz, J. E. Tiffany, and A. B. Coates; to F. O. Gardner, treasurer of the Pittsburgh Testing Laboratory; to G. B. Holderer, consulting engineer in connection with liquid-oxygen explosives for the Chile Exploration Co.; to the Enos Coal Mining Co. of Oakland City, Ind., particularly to G. H. Utterback of the staff of the mine for providing facilities that made field tests possible; and to full-time assistants J. W. Rothhaar and J. G. P. Weinheimer and to W. S. Hiller, part-time assistant, who were employed under the cooperative agreement.

Jan 1, 1940

By Kenneth G. Skinner

The rapid growth of the metallurgical, chemical, and allied industries on the Pacific coast just prior to and during the war caused a sudden increase in the demand for refractories, which was the immediate cause of a revival in interest in refractory clays available on the Pacific coast, particularly in the Pacific Northwest. Population increases and shortage of shipping facilities caused an increase in the amount of various ceramic materials and products used and produced on the Pacific coast, with accompanying demand for information regarding sources of clay. In an effort to supply part of this information, the Bureau of Mines, in cooperation with the College of Mines, University of Washington, started a program in 1944 to test the refractory and other properties of clays from seven Pacific Northwest deposits that had been drilled and sampled as part of the Bureau of Mines alumina from clay investigation. Figure 1 shows the location of these deposits.

Jan 1, 1949

By Gerald T. Homce, James C. Cawley

Problem: CFOI and SOII data show that 2,287 U.S. workers died and 32,807 workers sustained days away from work due to electrical shock or electrical burn injuries between 1992 and 1998. Method: The narrative, work activity, job title, source of injury, location, and industry for each fatal electrical accident were examined. A primary causal factor was identified for each fatality. Results: Electrical fatalities were categorized into five major groups. Overall, 44% of electrical fatalities occurred in the construction industry. Contact with overhead power lines caused 41 % of all electrical fatalities. Discussion: Electrical shock caused 99% of fatal and 62% of nonfatal electrical accidents. Comprising about 7% of the U.S. workforce, construction workers sustain 44% of electrical fatalities. Power line contact by mobile equipment occurs in many industries and should be the subject of focused research. Other problem areas are identified and opportunities for research are proposed. Impact on Industry: Improvements in electrical safety in one industry often have application in other industries.

By Eleanor Abshire

This bibliography is the result of a cooperative project undertaken by the Bureau of Ships and the Bureau of Mines to accumulate literature published to date on zirconium and hafnium and to establish an information center on these metals for the use of any interested research organization or library. This bibliography, which will be supplemented as additional information is accumulated, consists of references, with abstracts, to pertinent literature on the subject published from 1907 to date.

Jan 1, 1957

By R. Hogg

"Agglomeration processes and agglomerate characteristics are largely controlled by the forces of interaction between particles. The nature and typical magnitude of these interaction forces are evaluated relative to the external forces commonly present in agglomeration systems. The specific roles of the interaction forces in the various stages of agglomerate formation and growth and their effects on the integrity and mechanical strength of agglomerates are briefly reviewed. Because the interaction forces affect different aspects of agglomerate development in different ways, conflicting requirements can arise. Examples of such conflicts are given and used to demonstrate the importance of evaluating the effects of interaction forces etc., in the context of the overall agglomeration process and its ultimate objectives.INTRODUCTIONThe term agglomeration is generally used to refer to processes whereby discrete particles are caused, or allowed, to associate into clumps in which the individual particles retain their identity but are held together by relatively weak, usually physical forces. Various other designations are given to these processes, depending on the specific circumstances under which agglomeration occurs. The terms balling and pelletizing are often used to describe agglomeration in dry or semi-dry powders; coagulation and flocculation are used to refer to agglomeration of particles dispersed in fluids. Common to all of these cases is the fact that the formation, growth and integrity of the agglomerates depend primarily on the forces acting on and between particles. The same forces are, of course, responsible for manyaspects of the behavior of colloidal systems and their study and evaluation constitute the,basis for colloid and interface science.FORCES ACTING ON FINE PARTICLES AND AGGLOMERATES It is convenient to classify the forces acting on and between particles into two general types: external forces and interaction forces. It should he recognized, however, that a sharp distinction is not always possible.External Forces Gravity and inertial forces act on all particles and their magnitude is proportional to particle mass, i.e. they vary with the cube of particle size. Such forces are oftensignificant for large agglomerates but may be negligible for individual, fine particles.Hydrodynamic (""drag"") forces are important, for particles suspended in fluids. For very small particles, the drag force is directly proportional to size (Stokes' Law) while for very large particles or agglomerates it varies with approximately the square of size (Newton's Law). A useful procedure for estimating drag forces over a broad range of particle sizes and physical conditions has been given by Concha (1)."

Jan 1, 1989

By E. P. Youngman

Titanium ranks as one of the more abundant elements, is widely distributed, and occurs in concentrated form in numerous deposits. This substance was discoveres 140 years ago; but despite the efforts of metallurgists and chemists to find a place for it in industry, only within the last 10 or 15 years has the increased use of titanium pigments provided any extensive outlet for titanium ores. Even to-day titanium is confined to a few highly specialized industrial applications. The metal itself is now quoted regularly in trade journale, but scarcely yet can it be said that the production or use of the metal. has progressed very far beyond the laboratory stage. Ferroalloys containing the element were largely used for a time, especially in connection with the manufacture of Bessemer steel rails; but as American rail- ways adopted open-hearth rails in preference to Bessemer rails, the demand for the alloys in the rail manufacture gradually dwindled into insignificance. New outlets for ferrotitanium have been found in the steel industry; and the production of titanium alloys, both in the United States and in Europe, has increased in recent years. By far the largest use of titanium at the present time, however, is in pigments. The manufacture of titanium white began in Norway, but at present the United States is the leading producer. One of the two companies now operating in the United States is also the leading factor in European production. Although titanium occurs, in many minerals, the principal commercial sources are rutile (the natural oxide, Ti02) and ilmenite (iron-titanium oxide, FeO. TiO2). The latter is a coal-black mineral, but it is the one used in the manufacture of the titanium white of commerce, as well as in the manufacture of ferroalloys and arc-lamp electrodes. Rutile, the natural oxide, is not pure white and, being less common in nature, costs more; it is, therefore, reserved for use in the manufacture of titanium chemicals employed in relatively small amounts in dye works and bleacheries and for sundry minor purposes. This paper summarizes the titanium industry, with special reference to its economic aspects. It is offered as a survey of current trade literature and as a digest of material in the files of the bureau and is presented in response to numerous inquiries from prospective producers as to ways and means of exploiting deposits. (At present, much of the ilmenite consumed in this country comes from overseas, principally from British India..). A forthcoming circular, devoted to deposits of titanium-bearing ores, deals with foreign and domestic sources of supply.

Oct 1, 1930

By M. J. Spendlove

A progress report is presented on a research program in which an attempt was made to develop a practical sulfide-volatilization process for recovering tin from low-grade Bolivian ores. Shaft-furnace designs and operating techniques were studied in a series of experiments in which the objective was to sulfidize cassiterite to stannous sulfide, remove the stannous sulfide by volatilization, reconvert the stannous sulfide to stannous oxide, and collect the resulting fume. A shaft furnace was developed and operated in a final test in which many of the previous difficulties were surmounted. Since the supporting funds were exhausted at this point, the project was discontinued; recommendations for further improvements in furnace design and operation were made on the basis of interpretation of experimental results obtained in shaft-furnace experiments and other related studies.

Jan 1, 1955

By D. J. Hawk

The mechanical properties of coal are often represented by the orthotropicmaterial model, which consists of nine elastic constants. The material symmetries involved are found in coal primarily because of the natural process by which it was formed. In this thesis the material properties of five U.S. coals, as obtained from cubical testing, are examined, using as a basis for comparison the assumption of the orthotropic material model. An analysis is performed on each set of coal material data in order to examine its conformability to other, less complex material models, these being the transversely isotropic model consisting of five elastic constants and the 'isotropic model consisting of two elastic constants. In addition, the material properties of two American shales are analyzed, based on the assumption that they comply with the transversely isotropic model. An analysis similar to that performed on the coal material is applied to the shale in order to determine the conformity of its material properties to the isotropic model.

Jan 1, 1980

By Donald R. Corson

The Bureau of Mines is conducting research on the effects of various established and potential soil-stabilization additives to hydraulic backfill. This initial phase is an evaluation of the effect of inclusion of varying amounts of Portland cement and combinations of cement and a dispersant on the bearing strength of backfill. Results of unconfined compression tests are given for over 200 sample cylinders incorporating a fill material with cement or cement and dispersant. Inclusion of a minor amount of dispersant (0.2 percent by weight) is found to yield a significant increase in strength for 20-to-1 and leaner sand-cement mixes. An apparent optimum concentration of dispersant exists beyond which no further increase in strength is achieved. A dispersant-cement ratio of l.8- to-1 yielded a strength increase of 515 percent over the strength of untreated 40-to-l sand-cement mixes.

Jan 1, 1966

By R. L. Grant

"Carbon dioxide has been used for extinguishing electrical fires of many kinds (1, 3, 4) 3/ and more recently has been applied to some extent in fighting coal-mine fires (5). This report is concerned with the possibility of an electric current being conducted from a live power source, such as a trolley wire, across the impinging spray of carbon dioxide gas, to a metallic discharge nozzle, and then being grounded through the body of the person holding or touching the container. Rose and. Skinner (5) have described a case in which a fall of roof coal had brought down the trolley without creating a dead shot. The current was conducted in part through the loose coal to the rail, causing ignition of the coal. The fire was successfully extinguished with carbon dioxide.Dielectric data on pure carbon dioxide gas and liquid have been reported by Quinn and Jones (2). For the gas, the dielectric constants range from 1.00971 (35°C., 10 atmospheres) to 1.3072 (70°C., 151 atmospheres); for the liquid, 1.6016 (0°C., 50 atmospheres). Compared with the dielectric constant of air (1.0006, 1 atmosphere), these data, indicate that carbon dioxide in both gaseous and liquid forms is a very poor conductor of electricity, of the same order as air. 4/"

Aug 1, 1942