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By Ronald D. Hill, Elmore C. Grim

The removal of overburden often exposes pyritic materials (iron disulfide). As shown in equations 1 and 2, the oxidation of this material results in the production of ferrous iron and sulfuric acid. The reaction then proceeds to form ferric hydroxide and more acid, as shown in equations 2 and 4. [ ] Consequently a low pH water is produced (pH 2-4.5). At these pH levels, the heavy metals such as iron, manganese, copper, and zinc are more soluble and enter into the solution to further pollute the water. Water of this type supports only limited water flora, such as acid-tolerant molds and algae; it will not support fish life, destroys and corrodes metal piers, culverts, barges, etc., increases the cost of water treatment for power plants and municipal water supplies, and leaves the water unacceptable for recreational uses. The amount, and rate of acid formation, and the quality of water discharged are a function of the amount and type of pyrite in the overburden and coal, time of exposure, characteristics of the overburden, and amount of available water(l). Crystalline forms of pyritic material are less subject to weathering and oxidation than amorphic forms. Since oxidation by oxygen is the primary reaction during early acid formation, the less time pyritic material is exposed to air, the less acid is formed. Thus, a positive preventative method is to cover pyritic materials as soon as possible with earth, which serves as an oxygen barrier. In terms of mining, this step is accomplished by current reclamation techniques and small open pits.

Jan 1, 1974

By Thomas E. Marshall, Timothy Batchler, Anthony T. Iannacchione

As the amount of new fractured surfaces or "damaged rock layers" within roof rock increases, the stability of the rock mass decreases. While direct measurements of this phenomenon are not easily made, there is good circumstantial evidence to support this hypothesis. For example, it is common to observe increased cracks or fractures in the immediate mine roof rock before a roof fall. Likewise, roof drill holes placed in areas that later fail often reveal increased numbers and/or separations of fractures within the rock column through time. And finally, the frequency of microseismic activity, representative of rock fracturing, increases before a roof fall. For this study, more than 700 microseismic emissions were collected from two underground limestone mine roof fall areas in southwestern Pennsylvania. Microseismic events were located and magnitudes determined using the moment magnitude technique. Moment magnitude is based on the event seismic moment, which is a measure of the seismic deformation. The amount of new fracture surface length was calculated based on the stored strain energy within the rock prior to fracture. In the two case studies presented, a significant amount of microseismic activity was observed as much as two days before the first signs of failure in the roof fall areas. Additionally, results from this analysis reveal much about the behavior of strata prone to failure and allows for the construction of hazard maps based on microseismic emissions. The potential use of this technique as a means of anticipating roof falls is analyzed and discussed.

Coaxial cable structures form the subject of substantial theoretical and experimental investigations either directly related, or which can be extrapolated, to the communications needs and environments of U.S. coal mines. Communication systems based on "guided" waves, of which "leaky" coaxial cables are one implementation, are attractive candidates for providing a range of communication functions primarily along haulage ways, and possible also within sections up to the working face. (However, there are still strong reservations as to whether a practical coaxial cable sys tem could provide sufficient communications coverage within a section. ) In this Part, we present the results of some theoretical calculations of the performance of leaky coaxial cable communication systems. We also analyze the applicability of the theoretical and experimental results obtained by other researchers to the needs of U.S. coal mines. In particular, this investigation has been focused on the utility of relatively low cost, conventional, flexible, coaxial cable at frequencies covering the LF through HF bands and extending into the lower part of the VHF band, as opposed to relatively high cost, special semi-rigid, coaxial cable* at frequencies in the VHF and UHF bands. There are three major design alternatives for coaxial cable communication systems considered in this chapter: • Base station feeding a coaxial cable with high surface transfer impedance (holes in outer conductor, e.g., braid construction). • Base station feeding a coaxial cable with repeaters (U.K. experiments). • No base station, direct communication via a coaxial cable with periodic radiative structures.

Jan 1, 1974

By James H. Aase

Selected glacial lake clay deposits in Minnesota were sampled, tested, and evaluated to determine their suitability for use as a bonding agent in iron ore pellet manufacturing. Preliminary tests conducted on clay samples obtained from five ancient glacial lake basins identified the clays in the Lake Agassiz glacial lake basin near Cook, Minn., as having the greatest bonding potential. An auger drilling program was conducted to obtain substantial quantities of representative material for detailed testing. The drilling indicated the presence of large clay reserves in excess of 500 million tons within the 12-square-mile area investigated. Bench scale tests indicated that the bonding properties of Cook area clays, when activated with relatively small quantities of sodium carbonate monohydrate (Na2C03?H2O), imparted excellent strength characteristics to iron ore pellets. Larger scale continuous pelletizing tests were made to confirm the bench scale results. These tests indicated that use of 1 percent activated clay alone as binder gave the iron ore pellets an overall strength slightly lower than with 0.75 percent bentonite, considered the industry standard. Use of 0.5 percent activated clay plus 0.5 percent bentonite produced better pellet strength qualities than use of 0.75 percent bentonite alone, without increasing the silica plus alumina content. The data from both bench scale and larger scale continuous tests suggest that the Cook, Minn., clays can be utilized after activation either alone or in combination with bentonite at an economic advantage over present pelletizing practice with bentonite.

Jan 1, 1968

By G. F. Kuncir

The funding tables included in this report were defined in support of an evaluation of the Advancing Oil Sale Mining Technology Program undertaken by The Aerospace Corporation. Because of the sensitive nature of the fiscal planning information, the tables have been separated from the main analysis report and given a limited distribution.

Jan 1, 1977

By Donald J. Frendzel

The post-World War II expansion of the Soviet petroleum industry has established the U.S.S.R. as a major oil-producing nation and has led to Russian reentry into the international petroleum trade. The rapid growth of Soviet petroleum production will allow the U.S.S.R. to displace Venezuela as the world's second largest oil-producer in 1960 and to narrow further the gap between Soviet and U.S. crude-oil production. U.S.S.R. crude oil output was only a tenth of U.S. production in 1946, but it will be more than a third at the end of 1960 and more than half in 1965. The Soviet Seven-Year Plan (1959-65) for oil provides for substantial increases in petroleum production, refining, storage, and distribution facilities. Crude oil production and primary distillation capacity are to double, considerable storage capacity is planned, and pipelines for crude oil and petroleum products are to increase threefold. According to the Soviets, the initial phases of this plan (1959 and 1960) have been completed successfully. However, this progress has been achieved with difficulty.

Jan 1, 1961

By GEORGE T. Harley, Walter R. Storms

This paper, which describes mining mothods at International Minerals & Chemical Corp, 'e. potash mine. in. Eddy. County, N. Mex., is one of a sories being prepared by the Mining Branch of the Bureau of Minos. on mining method a and practicos in, various mining districts of the United States. The mine shafts and. surface plant or International Minerals & Chemical Corp. are situated. in. sec.. 12, T. 22 S., R. 29 E., N. M. P. M., about 26-1/2 miles by paved highway east of the city of Carlsbad (figs. 1, 2, and 3). A spur line of the Atchison, Topeka & Santa Fe Railroad connects the mine with the Clovia-Pecos branch of the same road near Loving, a few miles south of Carlsbad. This spur also serves the refinery of United Staics Potash Co. This report gives. the history and describes the geology of the district. Methods of prospecting, exploration, sampling, and estimation of tonnage and values are explained; development and mining methods are discussed in con- siderable detail; transportation, ventilation and drainage are outlined; safety measures are noted; and the wage scale and organization are mentioned.

Jun 1, 1949

By B. J. Scheiner

Oxidation procedures based on the chlorine-hypochlorite system were investigated for improving gold recovery from carbonaceous gold ores. The oxidation pretreatment prior to cyanidation was accomplished by (1) addition of sodium hypochlorite to ore pulp, (2) by addition of chlorine to ore pulp, and (3) by generation of hypochlorite in situ by electrolysis of a brine solution used to pulp the ore. Gold extraction of 90 pct was achieved by cyanidation of carbonaceous ore that had been pretreated with 20 Ib per ton sodium hypochlorite at 50° C for 4 hours. Similarly, pretreatment of the ore pulp with 35 1b chlorine per ton at 24° to 30° C and 15 hours reaction time resulted in 89-pct gold extraction by subsequent cyanidation. Concomitant studies showed that electrolyzing the pulp prepared with a brine solution was equally as effective as electrolyzing hypochlorite and chlorine for oxidizing carbonaceous ore constituents that are deleterious to cyanidation. Gold extraction of 90 pct was obtained by electrolysis when 275 lb of are was treated at 200 amp for 7 hours in an 8-to 10-pct salt solution. Power consumption was in the range of 60 kwhr per ton.

Jan 1, 1972

By John J. Mulligan

The creeks draining Cape Mountain, on the western tip of Seward Peninsula, Alaska, comprise the Cape Mountain tin-placer district. Because of the war-caused shortage of tin, the Bureau of Mines in 1943 conducted a churn-drill placer reconnaissance to explore the district. Favorable indications were found, and plans were made for further investigation of the deposits; the plans were abandoned when tin again became plentiful. In July 1951 the Zenda Gold Mining Co. was granted a Defense Minerals Administration (Defense Minerals Exploration Administration after October 1951) loan to continue exploration of the more favorable areas indicated by results of the Bureau's investigation. Equipment was moved to the area in the fall and winter of 1951-52. During the 1952 field season, 209 churn-drill holes totaling 7,521 linear feet and 10 test shafts totaling 96 linear feet were sunk on the Cape Creek drainage. Work was resumed in 1953, when 56 churn-drill holes totaling 3,157 linear feet were drilled on Boulder Creek. The company planned to drill Goodwin Gulch and Goodwin Creek, but no further work was done owing to lack of capital.

Jan 1, 1959

By Clyde M. Pearce

The Lake Superior iron-mining district includes parts of the States of Michigan, Minnesota, and Wisconsin. The laws of each State provide for an industrial commission and for inspection of mines. The following extract from the General Orders on Mines, effective October 25, 1937, issued by the Industrial Commission of Wisconsin, is the only reference to the use of safety catches on mine cages or skips found in the laws and regulations in the Lake Superior iron-mining district: Order 316 - Cages for Hoisting Men. (c) Sides, Gates, and Safety Catches. ***Every cage shall be provided with safety catches of sufficient strength to hold the cage with its maximum load at any point in the event the hoisting cable should break. (d) Testing Safety Catches. The safety catches of cages and skips used to hoist men shall be kept well oiled and in good working order. They shall be tested at least once each month by tying up the cage or skip with hemp rope, lowering a few feet of hoisting cable on top of cage, then cutting the hemp rope, provided that any other system of testing, which is equally effective, may be used.

Jan 1, 1945

By D. Bienstock

The Fischer-Tropsch synthesis is practicable in a reactor where the exothermic heat of reaction is removed by circulating large quantities of recycle gas through a catalyst bed of high-voids content. At an hourly space velocity of 1100, the feed gas, a mixture of 1.5 parts hydrogen to 1 of carbon monoxide, was converted 90 percent, producing hydrocarbons predominantly in the gasoline range. At these conditions a recycle-to-fresh gas ratio of 40:1 was enough to give excellent temperature control with a pressure drop of 1.5 p.s.i. per foot of bed using a steel catalyst in the form of lathe turnings. Steel parallel plates, although offering lower resistance to gasflow, were less reactive and less durable. INTRODUCTION The Federal Bureau of Mines has been engaged in a research and development program since 1944 on the synthesis of gasoline from coal. Gasification of coal with steam and oxygen to yield a synthesis gas--a mixture of carbon monoxide and hydrogen--is being investigated at Morgantown, W. Va.; and the synthesis of gasoline by catalytically reacting the carbon monoxide and hydrogen over iron by the Fischer-Tropsch reaction is being investigated at Bruceton, Pa.

Jan 1, 1960

By Henry G. Dorsett

This report is a description of equipment and test procedures used by the Federal Bureau of Mines in laboratory studies on the explosibility of dusts. The principal tests concern ignition temperature, minimum explosive concentra¬tion, minimum electrical energy for ignition, limiting oxygen concentration, pressure, and rates of pressure rise. As new materials often present unique problems, variations in the general procedure and special tests performed are indicated, The general procedures for handling a dust sample from its receipt at the laboratory to the preparation of the report are described. The repro¬ducibility of the respective tests are shown. A brief history of laboratory studies on dust explosions by the Bureau of Mines and a description of current equipment and test procedures used are presented in this report. Its purpose is to facilitate interpretation of data previously published and those proposed to be published on the numerous mineral, agricultural and industrial dusts that have been studied. Through understanding and interpretation of the laboratory data obtained for the parameters of explosibility, preventive measures can be adopted for alleviat¬ing the hazard of dust explosions arising in manufacturing and processing industries.

Jan 1, 1960

By William L. Crentz

Early in the nineteenth century, coal from Clearfield County entered the eastern commercial market. Ashley reports that coal was moved down the Susquehanna River by ark from Clearfield to Columbia, a distance of 260 miles, as early as 18o4. Around 1850, the famous Moshannon or Lower Freeport bed was discovered. Several years later the Moshannon Basin was developed extensively, and the coal from this area soon acquired an enviable reputation as a high-quality industrial fuel. Today much of the original Moshannon Basin coal is worked out, and the Lower Kittanning bed has replaced the Lower Freeport bed as the principal source of production in southeast Clearfield County. With depletion of the thick underground deposits, the importance 'of Clearfield County as a coal Producer would have diminished rapidly, if it had not been for strip mining the thinner beds. About 60 percent of the coal produced in the county is strip-mined, and the trend toward this mining method is expected to continue as the older underground operations are exhausted. Many strip mines are working in beds that are too thin to be recovered economically by any other method.

Jan 1, 1952

By Richard N. Spencer

This report describes investigations of the economic merits of multiple zone mining and beneficiation versus selective mining of altered Western phosphate rock. The same deposit was considered in both instances and it was assumed that the grade of selectively mined ore was comparable to the grade of the concentrate from beneficiation. The beneficiating scheme used for the investigation was one proved by small continuous circuit operation. All economic factors were found to favor multiple zone mining plus beneficiation. Capital requirements and production costs were lower, and production life of the deposit was extended 4.5 times. The concentrate from beneficiation would be a uniform high-quality feed for acidulation and would be low in stable metallic oxide (R203) content. Such a feed would permit improved plant operating control, and the low R203 would promote more rapid filtration and minimize sludge formation in the phosphoric acid. With the proposed treatment, the concentrate produced by flotation from this deposit would cost about 1.5 times as much per ton as the concentrate produced by classification sizing. Therefore, inclusion of a flotation step in treatment schemes requires an economic analysis for each ore deposit.

Jan 1, 1971

By Stephan Stecura

One of the principal objectives of the Bureau of Mines program for development of superrefractory ceramic materials is to obtain fundamental data on the physical properties of refractory oxides. Elements of particular interest to research workers in the Bureau include groups III and IV of the Periodic Table and the rare-earth group. This report contains thermal expansion and phase inversion measurements on oxides of scandium, yttrium, lanthanum and 12 lanthanide series elements (promethium and terbium omitted) up to 1,350°C, made by high-temperature X-ray diffractometer techniques. Thermal expansion values were calculated from unit cell dimensions measured at selected temperatures; with anisotropic oxides expansion was determined parallel to each major crystallographic axis. The combined random and systematic errors in the thermal expansion values are considered to be less than 3 percent of the total expansion at 500° C, and approximately 2 percent at 1,000° C, No difference in expansion coefficients was observed between heating and cooling cycles for oxides that did not undergo phase inversion. Tabular data of linear expansion, in percent, linear expansion coefficients, and graphical presentation of linear expansion as a function of temperature are presented.

Jan 1, 1961

By O. C. Blade

Diesel fuel is being used in greater volume than ever before in the United States. During 1950 railroads used 43 percent of the total volume of Diesel fuel sold, smelters, mines, and manufacturing plants used about 13 percent, highway vehicles such as trucks and busses, and equipment such as tractors and bulldozers accounted for approximately 20 percent, about 12 percent was used by water craft, and the remaining 12 percent by gas and electric utilities, the military forces, and oil companies. These figures were calculated from data issued by the Bureau of Mines. 2/ Comparable figures for 1951 and for 1952 to date are not available, but recent information indicates that well over 11,000,000 barrels of Diesel fuel per month are produced by the country's refineries. 3/ More information on this increasingly important type of engine fuel is needed by the petroleum industry, engine manufacturers, and consumers, particularly on the grades and qualities of the Diesel fuels being marketed. To supply this information the American Petroleum Institute and the Bureau of Mines, United States Department of the Interior, under cooperative agreement, are conducting annual surveys of Diesel fuel oil produced in refineries in this country.

Jan 1, 1952

By Robert W. McKibbin

The Bureau of Mines conducted laboratory tests to determine the slurry transport and deposition properties of coal waste. A 188.5-ft pipe test loop was constructed with instruments to measure density, flow, and power and discharge, suction, and differential pressures. A 20-ton ample of Western coal waste was crushed and screened to 100 pct minus 1/2 in. Eight loop tests using this graded waste were run at slurry densities ranging from 1.15 (25 wt-pct solids) to 1.46 (60 wt-pct sol-ids) 0 The resultant friction-'pressure gradients ranged from 0,06 to 0.24 ft of water per foot of 4-in standard steel pipe. Particle-size degradation was significant.. In a typical loop test lasting 25 min, the minus 200-mesh fraction increased from 19 pct to 34 pct. Deposition tests showed that without the use of a flocculant, the slurries would not dewater when left to stand for 1 week. With flocculant, additional water was releas2d; however, the settled slurries remained thixotropic. Further testing is necessary to determine their suitability for use as backfill material in active mines.

Jan 1, 1983

By H. R. Shell

Of three known compounds in the ternary system K20 - PbO - SiO2, one having the composition K2Pb4Si8021 crystallizes into a structure with asbestiform properties. This compound, whose silicon-oxygen ratio is between that of the layer silicates (for example, mica) and the double-chain amphiboles, crystallizes in the tetragonal system. It malts, apparently congruently, at 779° C. The fiberized product prepared from crystals is fluffy and closely resembles natural asbestos in appearance, but is more brittle and has less strength. However, potassium-lead silicate may be separated into fibers with a uniform diameter of 200-300 A.U., and the fibers show with the electron microscope the s criteria that have been interpreted as indicating a hollow tube structure in chrysotile asbestos. Since very few inorganic crystalline compounds have such a structure, the material has unusual scientific interest. Microcrystalline potassium-lead silicate was rapidly and completely formed when powdered glass of the same composition was heated to 650° - 700° C, but macrocrystals grew only slowly from the viscous massive glass. Maximum growth rate was 0.12mm. per hour at 700° C.

Jan 1, 1957

By M. A. Elliott, F. W. Brown

"INTRODUCTION During the recent war the Bureau of Mines, at the request of one of the armed services, investigated the hazards that night be encountered 5n handling perchloric acid, particularly if spilled on certain materials. The hazardous nature of perchloric acid when mixed with reducing agents had been known qualitatively, but it was desired to obtain quantitative data on the explosion hazards of such materials. Accordingly, tests were made to determine the sensitivity of mixtures of perchloric acid and oxidizable materials to initiation by heat, impact, sparks, flame, and explosive impulses. This report summarizes the results of those tests.PROPERTIES OF PERCELORIC ACIDAnhydrous perchloric acid is a colorless,hygroscopic, volatile, mobile liquid that fumes in the air. The anhydrous acid is unstable at ordinary temperatures, and therefore the commercial acid is a water solution containing either 60 percent or 70 percent by weight of the anhydrous acid. The commercial acid is widely used in chemical analysis, frequently to oxidize organic material. If proper precautions are not observed, such an oxidixation may become exceedingly rapid and result in an explosion. Several such explosions involving the acid are mentioned in the literature. 4, 5, 6/"

Jan 1, 1948

By Harry D. Jumper

This paper describing the methods of ruining a sand, gravel, and bowlder deposit 20 miles east of Los Angeles, and the classification and preparation of these materials for market, is one of a series being prepared for and published by the United States Bureau of Mines on methods and cost of mining sand and gravel. These papers are designed to disseminate technical information regarding, the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion anti study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations stall ensue. The description contained herein is typical of this industry in Southern California. ACKNOWLEDGMENT The author acknowledges tine assistance of L. L. Rogers, vice-president and manager of production and distribution for the Consolidated Rock Products Co., in the preparation of this paper.

Jan 1, 1933