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By Xavier B. Starnes

"SUMMARYThe J. D. Price property is in Crittenden County, Ky., about 5-1/2 miles west of Marion. The Levias-Crittenden Springs fault system traverses the property. Mines on 3 miles of the same fault system immediately northeast have produced about 250,000 tons of fluorspar ore. The Keystone property, adjacent on the northeast, has produced about 150,000 tons of ore. 3/About 1934, lessees, sank a shaft upon the Price property to a depth of 111.5 feet and crosscut from the bottom of the shaft to the principal fault. No ore was found. Later, in 1942-43, they explored the same fault by core-drilling, but this project also was unsuccessful in finding ore.The author visited the property in September 1944, and subsequently the Bureau further explored the property by core-drilling three holes. No ore was found.ACKNOWLEGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. This ex¬ploratory project was under the general supervision of E. D. Gardner, regional engineer of the Central Region, and 0. M. Bishop, district engineer, Bureau of Mines. The mining branch is under the direction of L. B. Moon. The work on the project was under the direct supervision of Xavier B. Starnes, mining engineer."

Jun 1, 1947

By Paul Hopkins

The following methods have been selected from a large number tried while assaying several hundred samples of placer concentrates. It is thought that some of these methods may be useful to those who are required to assay similar products containing large quantities of metallic articles, such as jeweler's sweepings. No great difficulties will be encountered in assaying black sand from beaches or river bars. Such samples require care in grinding and sifting so that no oversize particles of gold or platinum are lost. It is also necessary to have sufficient silica in the flux to form a fluid slag with the excess of iron, magnesium, or chromium which such samples contain. It is much more difficult to assay black sands, or concentrates, produced in large-scale placer-mining operations. These products are usually much harder and more abrasive than the beach black sands. They also contain numerous metallic particles resulting mainly from wear on the mining machinery. These particles consist chiefly of iron or steel but also contain lead, copper, and alloys such as babbitt, solder, brass, ferrosilicon, etc. Fairly large particles of gold are often found. Some samples will contain as much as 10 percent of such metallic particles. It is not feasible to remove the particles of iron with a magnet and discard them, as they invariably contain gold, sometimes a considerable amount. This gold is attached to the iron particles by rust or wedged into cavities. Scraps of sheet iron are often found which have become tightly folded or rolled and contain gold or amalgam within the folds.

Jan 1, 1934

By Russell. Paul L.

"INTRODUCTION Preliminary reports by Bureau of Mines engineers 3/ and by the Federal Geological Survey 4/ suggested that exploration would discover substantial reserves of minable ore in the Contact mine, Grant County, New Mexico. During February and March 1943, a sampling program was conducted on this property under the direction of the author. This was art of a general survey of the manganese districts of southwestern New Mexico.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources, to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as practicable soon as after its conclusion. The Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocer, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. S. Dean, assistant director. With respect to this report, special acknowledgment is due to C. H. Johnson, district engineer for New Mexico, and E. D. Gardner, regional engineer, and his staff, of the Central Region of the Bureau of Mines at the time of this work in 1943; also to Kenworthy, metallurgist at the Rolla. Mo., Laboratory of the Bureau of Mines, for work on beneficietion of the ore, and Sherman K. Neuschel, geologist of the Federal Geological Survey, for assistance in interpreting geological data at the project."

Oct 1, 1946

"The Generic Mineral Technology Center on Respirable Dust was established in August 1983, at the request of the Bureau of Mines, to conduct research that affords ""...each miner the opportunity to work underground during the period of (his/her) adult working life without incurring any disability from pneumoconiosis or any other occupational disease"". The Center consists of the Mining and Mineral Resources Research Institutes (MRI) of The Pennsylvania State University (PSU) and West Virginia University (WVU) in association with the MRIs of the Massachusetts Institute of Technology (MIT) and the University of Minnesota (UMN). (FIGURE 34) Michigan Technological University (MTU) is also affiliated with the Center in the area of diesel particulates.The Center brings together experts concerned with particles causing potentially disabling or fatal diseases including pneumoconiosis (""black-lung""), silicosis, and asbestosis. The latter is of deep concern not just to workers in the mineral sector of the economy but also to the general populace. The primary goal of the Center is to reduce the incidence and severity of respirable dust disease through advancing fundamental understanding of all aspects of respirable dust associated with mining and milling, and the interaction of dust and lungs. The research program of the Generic Mineral Technology Center explores these scientific, engineering or medical concerns with the objective of refining existing strategies and developing new respirable dust control techniquesand technology that are consistent with the fundamental dust-lung interaction processes that lead to mine worker disability. The work concentrates on five areas (FIGURE 35):"

Nov 1, 1988

By R. C. Hickman

"INTRODUCTION The most productive area of the eastern Virginia pyrite belt lies to the north of the village of Mineral., in Louisa County. The largest producers of pyrite ore in the area were the Armenius, Boyd Smith, and the Sulphur mines.The Boyd Smith mine started production about 1890 and operated more or less continuously until 1922, when competition from the Gulf States and Spain closed the pyrite mines in Virginia. There are no reliable records of production or value of minerals produced.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the most effective utilization of our mineral resources to the end that they take the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, Oliver C. Palston, chief, analyzes samples and performs beneficiation tests.The project was under the immediate supervision of Mitchell H. Kline, chief, Raleigh Division, Mining Branch, Bureau of Mines.LOCATIONThe Boyd Smith property is reached from Mineral, Va., by traveling north on State Route 522 about 2-1/2 miles. An unsurfaced road, winding in a northwesterly direction, loads to the Boyd Smith headframe, which is about half a mile from State Route 522 (fig. 1). The tract comprises 181 acres."

Aug 1, 1947

By C. B. Manula, R. L. Sanford, R. A. Rivell

This report describes the development and application of a rail haulage simulator that is readily adaptable for the analysis of a wide variety of operating problems. Various gaming, options have been integrated into the model structure which permit trial and error solutions from a computer terminal prior to capital committment in the actual operation. The high level of information retrieval available allows engineers and managers to develop production data which fit individual needs. In this report, emphasis was placed on the problem of organizing and performing the sequence of operations that are necessary to accomplish a complete mine materials handling simulation. Here, the Rail Haulage Sub-assembly was linked to the Production Sub-system to mine and move coal from seven operating sections to the intermediate and main-line track. The analysis was devoted to the problems associated with how the operating system performs and what alternatives were available to minimize idle times and hence increase productivity. In order to have some objective means of evaluating which of the alter- native methods for production was most appropriate, the choice was to replace the intermediate track with belt conveyors. Since the attempt here was to demonstrate model flexibility and not to establish the goals or trade-offs between computing objectives with which systems judgement must contend, no further alternatives were tried. This is left to management with the data and a problem to solve. Rail haulage simulation is not new, and several, operationally tested models are being used in practice (Bucklen, et. al., 1968).

Jan 1, 1974

By Edmond Chin

The area encompassed by the political entities included in this study com-prises 11 million square miles or about 15 percent of the total Earth's land area. The bulk of the region is contained on the Asian continental land mass. Australia, the world's largest is-land or the world's smallest continent, alone is almost as large as the continental United States. The islands of New Zealand, New Guinea, Borneo, Sumatra, and Honshu are among the largest in the world. Collectively, they constitute a land area of 1.1 million square miles or an area about one-fourth the size of the United States. The region is noted for its great rivers. The Chang, Huang, Amur, and Mekong are respectively the fifth, sixth, eighth, and eleventh longest rivers in the world. The Ganges-Brahmaputra has created the world's largest delta, which covers 30,000 square miles. Abutting East Asia are the Sea of Japan, Dong Hai, Nan Hai, Bay of Ben-gal, and Arabian Sea. In the Southern Hemisphere, there is the Indian Ocean and the South Pacific Ocean. The Continental Shelf adjacent to the region constitutes a large proportion of the world's readily accessible shelf area. On the other hand, the Philippine and Java trenches and, further out, the Mariana Trench reach to formidable, abyssal depths, downward to 6,000 fathoms. Contrasting to this is Mount Everest, which reaches a lofty height of 29,028 feet. And then there is Xizang, whose high plateaus have been called the roof of the world.

Jan 1, 1992

By W. P. Yant

The hazard to health from contamination of air by a noxious gas depends not only on the potential harmful response attending exposure., but also on the warning properties, which in effect may be termed the "accompanying warning response," This warning may be manifested as an odor, taste, irritation of the eyes, nose, or throat, or perhaps headache, vertigo,, or nausea. These manifestations may be painful and even slightly harmful, but to a much lesser degree than the primary injury of exposure. The warning response mitigates hazards directly in proportion to the degree of intolerability which -accompanies injurious exposure, and accordingly its absence augments hazards. This accounts for the fact that the actual health hazards from a nonodorous or non-irritating gas or vapor of comparatively low toxicity sometimes equal or exceed the hazard from a considerably more toxic substance, but one which possesses a marked odor or produces eye, nose, or throat irritation in advance of harmful exposure. When a substance lacks the properties for giving warning, it is often possible to impart them by the addition of a small amount of another substance which has an exceedingly high warning intensity. The vapors of this substance, commonly termed a "warning agent" or "tracer gas," escape and mingle with the gas or vapor which lacks warning properties and thereby apprises persons of the latter's presence. The amount of the warning agent added is that which will give adequate warning in advance of serious physiological harm from the dangerous gas or vapor.

Jan 1, 1930

By Kray Luxbacher, Erik Westman, Peter Swanson

Three-dimensional time-lapse velocity tomograms were generated to image stress redistribution around a longwall panel to produce a better understanding of the mechanisms that lead to ground failure. Mining-induced microseismic events provided passive sources for the three-dimensional velocity tomography. Surface-mounted geophones monitored microseismic activity for 18 days. Most similar studies have utilized active sources including longwall shearers, controlled explosions, and hammer blows. These active sources generally require a person to initiate and measure the location and time of the source, and are not conducive to continuous monitoring. This method utilizes mining induced microseismic events as passive sources and lends itself well to continuous monitoring. Two event location methods were compared in order to move toward quantification of tomographic results in terms of ground conditions. Additionally, LAMODEL was utilized to determine the expected stress distribution around the longwall panel and compare these images to the velocity tomograms. Eighteen tomograms were generated, one per day, and high velocity regions in the set of tomograms generated from the initial location algorithm correlated with abutment stress redistribution predicted by numerical modeling. This research is significant as it has the potential to improve safety in underground mines and is the only example of long term passive velocity tomography implementation for the purpose of inferring stress redistribution around an area of active mining. Though still immature, this technology has the potential to allow mine personnel to image areas of active mining on a regular basis and detect areas with anomalous velocity distributions indicating potential safety hazards.

By John D. Foulkes, David A. Curtis, Robert L. Lagace, John L. Rothery

An investigation is made of the feasibility of developing compact transmit antennas and/or other means to efficiently couple VLF to MF band radio energy between portable wireless communication units in coal mines. The completely wireless communication ranges between two portable radios equipped with practically-sized reference loop antennas in representative coal mine environments are estimated. Antenna technology is assessed with respect to transmit moment, range, intrinsic safety, battery and wearability requirements to deter- mine the most suitable antenna types for use by miners. It is concluded that air-core bandolier loop antennas, and perhaps ferrite-loaded loop antennas, having peak transmit moments of about 2.5 ampere-m5 will be the most effective antenna choices for portable units. This choice, however, will not allow the range goal of 1350 feet to be attained in mines having unfavorable signal attenuation and noise environments. Rectangular air-core loops are compared with grounded horizontal-wire and vertical-wire mode exciters for fixed station applications. The potential for significantly increasing the wireless communication range by inductively coupling to communications and power lines in a mine is evaluated and found to be considerable based on theoretical coupling equations. Lastly, the theoretical performance of a hybrid noise cancelling diversity receiving technique that utilizes both the electric and magnetic field components of the ambient noise to improve the receiver output signal-to-noise ratio under certain adverse conditions is estimated and shown to be favorable when the magnetic and electric field noise components are highly correlated.

Jan 1, 1977

By C. B. Manula, R. L. Sanford, R. A. Rivell

A central requirement for using simulation models is the need for retrospect testing to validate experimental conclusions. Acceptance of a model by managers and safety practitioners is more likely to depend on its tested performance in-the field rather than on the underlying logic or the validity aspects of the model itself. It is here that simulation bridges the gap between theory and useful design procedures. The original version of the rail haulage sub-assembly was success¬fully tested in the field (Sanford, 1969). However, the case studies that were described here involved single-stage haulage and restricted jobtypes from UGMHS. Since this report together with Volume VI (Production Subsystem) describes extensive changes and modifications to the rail haulage sub-assembly and UGMHS, field tests were necessary to verify both the rail model and the linking concepts to the Produc¬tion Sub-system. Mine Description The candidate mine selected for model verification works the 6 1/2 foot Pittsburgh seam. Shaft openings are used for manways and ventilation and a dual compartment slope for materials handling. In the bottom half of the slope, a hoist with track handles supplies and equipment. In the upper half, a 42 inch belt conveyor travelling at 450 fpm moves coal from a rotary dump to the surface. The immediate roof is shale with the first 12 inches taken during development mining. About 4500 raw tons are produced daily from seven face units and one spare working three shifts. At seven of the sections,

Jan 1, 1974

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

UNIT OF MEASURE ABBREVIATIONS USED IN MFIRE FT foot FT3/MIN cubic foot per minute LBM•MIN2/FT4 pound mass times minutes squared over feet to the fourth FT2/HR square feet per hour BTU/HR*FT*F British thermal unit divided by hours times fimes feet times degree Fahrenheit IN W G inches water gage FT3/MIN cubic feet per minute FT2 square feet FT3 cubic feet LBM, pound mass F Fahrenheit IN W G /CFM2 inches water gage per cubic foot per minute squared PERCENTAGE percent BTU/MIN British thermal unit per minute MFIRE BAT PROGRAM cls echo off echo MFIRE activated mfire0 echo Wait a moment for loading the program if EXIST zheng chg mfirel if EXIST zheng chg mfire2 if EXIST zheng chg mfire1 if EXIST zheng chg erase zheng chg if EXIST hang chg erase hang chg if EXIST yunzhi fan copy yaodong.ion+yunzhi fan yaodong ion if EXIST yunzhi fan erase yunzhi fan if EXIST xintan chg copy yaodong xin+xintan chg yaodong ion if EXIST xintan chg erase xintan chg if EXIST yaodong xin copy yaodong.xin mfire out if EXIST yaodong.xin erase yaodong.xin if EXIST net erase net echo Your output is saved in file MFIRE OUT MFIRE0 FOR PROGRAM CHARACTER•50 A OPEN (10,FILE='NET',STATUS='UNKNOWN',FORM='UNFORMATTED') NETWW=0 WRITE (10) NETWW OPEN (21,FILE='ZHENG CHG',STATUS='UNKNOWN',FORM='UNFORMATTED') A=) ' B=0.0 WRITE (21) A WRITE (21) A,B

Jan 1, 1990

By Martin H. Stanczyk

Two methods of recovering zinc from zinc ammonia complex solutions were investigated. One method studied was distillation of the ammonia from the solutions to recover a basic zinc sulfate, which after calcining to zinc oxide was reduced to metallic zinc using hydrogen at 900° C. The second method tested was electrolysis. The tests were made of synthetic and leach solutions analyzing about 80, 100, and 115 gpl (grams per liter) of Zn, NH3, and SO4, respectively. The leach solutions were prepared by oxidation leaching of a sphalerite flotation concentrate, assaying 55 pct zinc at elevated temperature and pressure. The distillation method recovered about 98 pct of the zinc in a product analyzing 97 pct zinc. Ammonia losses incurred during the leaching and distillation operations were about 0.1 lb per lb (pound per pound) of metallic zinc produced. Electrolysis of the solutions at a cathode current density of 25 amp per sq ft (ampere per square foot) yielded zinc deposits assaying in excess of 99.9 pct zinc. About 1.5 kwhr (kilowatt-hour) of power were consumed per pound of zinc deposited; the current efficiency was 72 pct. Other electrodeposition tests revealed that small amounts of ferric iron in the cell liquor were deleterious to electrolysis unless about 5 lb of glue per ton of zinc were present in the electrolyte. The use of glue and vigorous agitation of the electrolyte gave smooth zinc deposits from solutions containing as much as 0.1 gpl iron.

Jan 1, 1962

By Mark Colwell, Russell Frith

This paper summarizes the results of a research project whose goal was to provide the Australian coal industry with a chain pillar design methodology readily usable by colliery staff. The project was primarily funded by the Australian Coal Association Research Program and further supported by several Australian longwall operations. The starting point or basis of the project was the Analysis of Longwall Pillar Stability (ALPS) methodology. ALPS was chosen because of its operational focus; it uses tailgate performance as the determining chain pillar design criterion rather than simply pillar stability. Furthermore, ALPS recognizes that several geotechnical and design factors, including (but not limited to) chain pillar stability, affect that performance. There are some geotechnical and mine layout differences between United States and Australian coal fields that required investigation and, therefore, calibration before the full benefits offered by the ALPS methodology could be realized in Australia. Ultimately, case history data were collected from 19 longwall mines representing approximately 60% of all Australian longwall operations. In addition, six monitoring sites incorporated an array of hydraulic stress cells to measure the change in vertical stress throughout the various phases of the longwall extraction cycle. The sites also incorporated extensometers to monitor roof and rib performance in response to the retreating longwallface. The study found strong relationships between the tailgate stability factor, the Coal Mine Roof Rating, and the installed level of primary support. The final outcome of the project is a chain pillar design methodology called Analysis of Longwall Tailgate Serviceability (ALTS). Guidelines for using ALTS are provided.

Jan 5, 1999

By Mark Larson, Doug Tesarik, Joe Shoemaker, Brad Seymour

In cooperation with Cyprus Twentymile Coal Co., researchers from the National Institute for Occupational Safety and Health (NIOSH), Spokane Research Laboratory, conducted a study at the Foidel Creek Mine, an underground coal mine near Oak Creek, CO, to evaluate the stability of underground working conditions as a longwall advanced through a series of backfilled cross-panel entries. Instruments installed in the cross-panel entry pillars, backfill, longwall panel, and adjacent headgate entry were continuously monitored by a computerized data acquisition system as the longwall approached and advanced through the backfilled section of the panel. Data collected from these instruments were analyzed to determine the magnitude and direction of the secondary principal stress changes ahead of the longwall face, deformation and closure of the headgate entry, and stability of the cross-panel entry pillars and backfill. A three-dimensional, boundary element model was calibrated to accurately predict mining-induced stress changes and the distance they occurred ahead of the longwall face. As the longwall advanced through the backfilled entries, most of the mining-induced load was supported by the cross-panel entry pillars. The backfill provided stability for the roof and floor of the in-panel entries and also confined the entry pillars significantly improving their load-carrying capacity. Comprehensive information derived from backfill material property tests, instrument data, underground observations, and numeric modeling results document the safety and stability of the 8-Right mine through and should provide beneficial case study information for other longwall backfilling applications in the future.

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

The Federal Coal Mine Health and Safety Act of 1969 has dictated major changes in mine ventilation with regard to both air quantity and quality. Requirements have also been placed on the ventilation of beltlines, gob and face areas, and air velocities on trolley haulage roads are limited. Escapeways, separate from trolley haulage roads and on an intake split of air, must be maintained continuous to the surface. These and other similar requirements have not only precipitated several modifications to existing ventilation systems but also have greatly increased the complexities of new mine ventilation planning. It is apparent that the use of computers in ventilation system analysis and design is a necessity. SUMMARY Although computer oriented analysis of mine ventilation systems was introduced over two decades ago, it has yet to receive widespread acceptance in the United States. Central to this problem is the fact that, while many computer programs for network analysis have been developed, no attention has been paid to the development of computer input data. Consequently, without this foundation, program applications have been infrequent. This thesis has directly attacked this problem and has presented all pertinent information basic to the development of good computer input data. The areas that were covered include quantity measurement, pressure measurement, fan testing, survey data balancing, and the development of a network schematic from the ventilation survey results. These discussions on data collection and the corresponding reduction to computer coding have been illustrated by an application of a ventilation simulation program to an existing mine in Southwestern Pennsylvania. The use of a ventilation

Jan 1, 1977

By Richard V. Ageton

"Everyone admits that there are more accidents in metal mines than there should be but there is much difference of opinion as to the causes of accidents, whether avoidable or unavoidable, and the amount of responsibility attaching to the miner and the mine operator, respectively. However, it seems that one of the main reasons why there are so many accidents, is that there is so little general knowledge regarding their causes and costs. Some information regarding the costs and causes of metal-mine accidents is presented in this paper.The data contained were obtained from a study of the complete accident and medical reports of two large metal-mining companies, which carry their own insurance. Path maintain hospitals with competent medical attendants. One of these companies also maintains a very efficient safety bureau, consisting of a safety engineer, with two assistants who work in connection with the medical department, and with the safety committee made up from among the miners themselves.Daring the year of 1920, ""A"" Company employed approximately 900 men, and these men worked more than 270,000 shifts. There were 373 minor and major injuries, among these 900 men, hence assuming that each injured man was hurt cut once, 41 per cent of the men who worked in this mine received some kind of time-losing injury during the year. On account of these injuries the injured men lost 3731 shifts, and thus the time lost due to injuries amounted to approximately 1.4 per cent of the total number of shifts worked,"

Oct 1, 1923

By Wm. C. Dean

The location of trapped miners from their seismic signals will be in- accurate if we assume the P-wave propagation velocity is a constant. P- wave velocities are anything but constant in regions about mines, so some calibration is necessary to obtain more accurate seismic locations. The reference event method compares the time arrivals of signals generated by the miners with those previously recorded from a reference or calibration event in the vicinity of the miners. This method locates the miners' position relative to the calibration source. Hence, the location of the miners is absolute if the reference event position is known absolutely, usually from surveys and mine maps. Advantages resulting from the system, besides greater accuracy, are locations independent of the velocity model assumed, the same solution from the full array and from any subset of four or more seismometers in the array (three if the miners' depth is known), fewer seismometers required, and no complex computers required for analysis. VELA Uniform experience shows that the accuracy of locations of teleseismic explosions and earthquakes is improved by an order of magnitude over locations computed from average travel time curves. Each calibration event is applicable only over a limited range. We recommend a field test of the method at a mine to measure its location accuracy, the range of effectiveness for each calibration event, the number of seismometers needed, and the number of reference events required per mine. From these experiments we could decide whether the reference event method was useful and, if so, what form a practical rescue system would take.

Jan 1, 1974

The Federal Mine Safety and Health Act of 1977* defines respirable dust as dust measured with a device approved by the Secretary of Labor and the Secretary of Health and Human Services [30 USC 842(e)]. The approved sampler for respirable coal mine dust is the coal mine dust personal sampler unit (CPSU) [30 CFR 74; Jacobson 1971; Jacobson and Lamonica 1969]. The CPSU is generally called the 10-mm nylon cyclone, although the 10-mm nylon cyclone is actually just one component of the CPSU. The CPSU may either be mounted on a worker (with the sampling head positioned in the breathing zone for personal exposure monitoring) or in a fixed location for area sampling [Tomb 1990]. The CPSU consists of a pump unit, a sampling head assembly, and a battery charger if rechargeable batteries are used in the pump unit [30 CFR 74.2]. The sampling head assembly contains two stages. The first stage is a 10-mm nylon cyclone, which has collection characteristics similar to an elutriator. The amount of dust penetration depends on the flow rate [Jacobson and Lamonica 1969]. The second stage is a membrane filter (vinyl, pore size 5 pm) that collects the dust passing through the cyclone. The dust collected on the membrane filter is weighed to a precision (standard deviation) of 81 pg [Parobeck et al. 1981], and the respirable dust concentration in the mine atmosphere is then determined from the mass of dust collected and the volume of air sampled [Tomb 1990].

Jan 1, 1997

By Isaac A. Zlochower, Kenneth L. Cashdollar

The Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health conducted a study of the explosibility of various metals and other elemental dusts dispersed in air, with a focus on the experimental explosion temperatures. The data are useful for understanding the basics of dust cloud combustion, as well as for evaluating the explosion hazards in the minerals and metals processing industries. The dusts studied included boron, carbon, magnesium, aluminum, silicon, sulfur, titanium, chromium, iron, nickel, copper, zinc, niobium, molybdenum, tin, hafhium, tantalum, tungsten, and lead. The dusts were chosen to cover a wide range of physical properties - from the more volatile materials such as magnesium, aluminum, sulfur, and zinc to the highly "refractory" (very low volatility) elements such as carbon, niobium, molybdenum, tantalum, and tungsten. These flammability studies were conducted in a 20-L chamber, using strong pyrotechc ignitors. The experimental data obtained included the minimum explosible concentrations, maximum explosion pressures, and maximum explosion temperatures. A unique multiwavelength infrared pyrometer was used to measure the temperatures. For the elemental dusts studied, all ignited and burned as air-dispersed dust clouds except for nickel, copper, molybdenum, and lead. The measured maximum explosion temperatures ranged from -1 550 K for tin and tungsten powders to -2800 K for aluminum, magnesium, and titanium powders. The measured temperatures are compared to the calculated, adiabatic flame temperatures. In general, the dusts whose experimental temperatures were closer to the adiabatic values were those with the finer particle sizes, those that were more easily vaporized, and/or those that were intrinsically more reactive.