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By V. R. Miller

The Bureau of Mines has developed a technique to separate and recover the three major components, Pb, Zn, and Cd, from lead smelter flue dust. This research was conducted as part of the Bureau's effort to reduce environmental conflicts and occupational hazards associated with mineral-processing operations and to recover valuable constituents in emissions and effluents. The laboratory process utilizes sulfation roasting of the flue dust followed by water leaching to extract over 95 pct of the cadmium and zinc. Ninety-nine percent of the cadmium was recovered from solution by cementing with zinc dust, and zinc was electrowon from the resulting solution after purification. Zinc electrolysis was carried out in a 1-liter cell at 35° C with a cathode-current density of 8 A/dm2 in a solution containing 65 g/l Zn++ and 180 g/l H2S04, Current efficiencies of 80 pct were obtained. The leached residue consisted largely of PbS04, which was converted to PbC03 and leached with H2SiF6 to produce PbSiF6 electrolyte. Ninety-five percent of the lead contained in the residue was converted to electrolyte. Lead was electrowon from solutions containing 70 gil Pb++ and 90 g/l H2SiF6 using a lead cathode, Pb02-coated titanium anodes at 28° C, and a current density of 1.6 A/dm2. Current efficiencies approaching 92 pct were obtained. Accessory minerals such as cobalt and nickel were separated into purification residues and liquor.

Jan 1, 1982

By W. W. Agey

Past investigations on waterborne impurities in the flotation process have been concerned primarily with the treatment of specific ores with particular local waters. Although some anions and cations present in water are known to react with flotation reagents, a definitive study has not been made on the effect of such common ions upon the flotation process. This report describes the fundamental research undertaken to define and measure the adverse and/or beneficial effects of different concentrations and combinations of several common anions and cations when oleic acid is used to froth-float limestone from a pulp of quartz and limestone. Research on the effect of waterborne impurities upon the flotation process was composed of two equally important phases. The first phase comprised development of a procedure for floating limestone from quartz that would give the same results in test after test. Some difficulty was encountered, but once such a procedure was developed, the second phase, comprising study and measurement of the effect of various ions c on to natural water upon the flotation of limestone, was quickly completed.

Jan 1, 1963

By W. D. Dietzman

This Bureau of Mines report presents a profitability analysis of producing crude oil by waterflooding. Included are the estimated costs of installation of water injection and producing equipment for waterfloods at 2,000 and 4,000 feet and the estimated annual operational expenses for each in west Texas. Using these cost estimates as a base for selecting a range of costs that are indicative of producing crude oil by waterflooding, a simulation technique was derived for determining the profitability under various conditions. Because of the large number of combinations of variables used in this study, a high-speed digital computer was utilized for the calculations. The variables include operational expenses, capitalized costs, price of the oil, annual production, and leasehold acquisition cost. The results obtained from the simulations are presented Fn the appendix. In addition, a nomographical approach was chosen for presentation of the profitability. Five nomographs are presented that can be used for fast estimation of the discounted cash flow (DCF) rate of return that might be expected from a prospective or active operation under various sets of assumed conditions.

Jan 1, 1974

By George R. Schottler

The objective of this research is to find the extent of the range of applicability of previously developed statistical methods for determining grade and tonnage of ore to bedded uranium deposits. Uranium assays obtained from gamma-ray logs of exploratory drill holes are used to compute grade and tonnage of ore in the deposit by a standard polygonal method and by statistical analysis. The results obtained by the two methods are compared. The uranium-assay frequency distributions are shown to be lognormal and a simple transformation permits the use of standard normal curve statistics. The effects on the assay frequency distributions of stratified sampling, a required minimum mining thickness, and increased assay-interval length are investigated. The addition of low-grade mineralization to make up the required minimum mining thickness results in a distinct change in the skewness of the assay frequency distribution. Any statistical inference regarding grade-tonnage relationships that will be produced, using the minimum mining thickness, should be made on the basis of this "revised" assay frequency distribution.

Jan 1, 1965

By C. T. Sheeran

The Bureau of Mines investigated a microprocessor-based real-time control and monitoring system for uranium mining applications. The system is capable of controlling and monitoring up to 768 stations within 3 km of the central processor on a common four-wire cable. It can be used in conjunction with detectors to continuously monitor and display radiation working levels at points throughout the mine. Surface alarms are sounded for critical situations such as rapid radiation buildup, loss of power to monitors or fans, and changes in air door position. Permanent records of all changes are automatically printed out with their time of occurrence. Printouts can also be obtained for shift reports or trend logs. The system can be used to remotely control fan startup and shut-down, and also can alert miners of underground conditions by blowing horns or turning on lights. Battery backup keeps the system operative for up to 4 h in case of a mine power outage. A special software feature permits automatic, time-delayed, sequential restart of fans.

Jan 1, 1984

By William O. Vanderburg

[This circular is one of two papers on the tungsten industry in the United States end contains general information on the subject. The second paper which will be issued in the near future deals with the methods ailed costs of mining and milling tungsten ores. These two papers are abstracts from the general bulletin on tungsten which will be issued at some future time Modern civilization and progress depend largely on tools wherewith the forces of nature are brought under control and directed toward human comfort. These tools are made chiefly from metals derived from the earth's crust. During the present century powerful tools have been made available through the development of ferrous and. nonferrous alloys containing such elements as molybdenum, vanadium, titanium, tantalum, and tungsten, which were little used before 1900. One of the most important of these so-called rare elements is tungsten; its use ins alloys for high-speed cutting tool is partly responsible for the era of mass production. So widespread has the use of alloys become that the period may be termed an "Alloy Age".]

Jan 1, 1935

By John Nagy

Large-scale tests in the U.S. Bureau of Mines Experimental Coal Mine show that the explosion hazard of coal dust on shuttle-car roadways can be con-trolled by proper application of water, dry rock dust, a saturated solution of ammonium phosphate, or mixtures of water or the water-phosphate solution with rock dust. The experiments were made with loadings of 1.0 and 5.0 pounds of mine size coal dust per linear foot of entry, and with a 3-or 4-inch-thick layer of coal rubble on the floor, The data from the tests with mine-size coal and rubble are comparable. The water contents of the dust loading were determined from samples collected just prior to initiation of a gas-air mixture in an ignition zone at the face Dust samples were collected 1 inch deep from the coal-rubble deposit. One experiment was made with the dust in the coal rubble bound with latex applied as a water solution by spray. The binding action was inadequate and explosion propagation was obtained.

Jan 1, 1970

By Kenneth D. Winters

This Bureau of Mines report presents a Fortran IV computer program for the structural analysis of (1) protective canopies used in underground mines to protect equipment operators from roof falls and (2) rollover protective structures (ROPS) used in surface mines to protect equipment operators during vehicle overturn accidents. The program, entitled PLASTIC CANOPY, permits rapid and inexpensive calculation of the ultimate strength and deformation characteristics of a canopy for a variety of static loading conditions. The structure is modeled as a series of interconnected beam and/or plate elements. Stresses in, and displacements of, each structural element are computed and printed out at the yield strength of the canopy, at several intermediate load levels between the yield and ultimate strength of the canopy, and at the ultimate strength of the canopy. Other features of the program include prediction of buckling of a beam member under combined axial compression loading and bending, plotting of the input geometry of the structure, and plotting of the deformed shape of the loaded structure. Program description, input instructions, program listing, and four example problems are included.

Jan 1, 1979

By William H. Pomroy

This report describes Bureau of Mines research that led to the design, prototype fabrication, and successful proof-of-concept testing of an improved stench fire-warning system for underground noncoal mines. Stench systems are the most widely used means of warning driers in underground noncoal mines of fires or other emergencies. A stench system alerts miners that an emergency condition exists by injecting an odorant into the mine air. Although stench warning systems have been used successfully for over 60 yr, present systems suffer several serious shortcomings, including odorant toxicity, unreliability of warnings, widely varying stench concentrations, and others. In 1980, the Bureau began a research program to upgrade the stench warning system. The resultant system overcomes the deficiencies of existing systems by substituting tetrahydrothiophene for the commonly used ethyl mercaptan stench odorant, and through the use of a specially designed stench injector. The improved injector reliably meters stench fluid into either ventilation-air or compressed-air streams at a precisely controlled rate. Prototype hardware has been fabricated and proof-of-concept tested under bath laboratory and in-mine conditions.

Jan 1, 1985

By Larry D. Nichols

Poroplastic membranes containing ion exchange liquids were studied for separating cobalt from nickel-containing solutions similar to ammoniacal laterite leaches. The driving force for cobalt transport was differences in pH and composition between the leach and extraction streams. Using a diketone ion exchange liquid, a leach pH of 6.5 to 7.0, and a strip pH of 2.3, cobalt was extracted from a 750 ppm solution containing 2500 ppm of nickel at rates ranging from 1 to 10 µg/cm2 .min in single membrane cells, and from 10 to 100 in more closely spaced multiple membrane cells. Rates were variable, with evidence that cross -membrane flow pasterns were a key factor; a reproducible rate of 30 pg/cm .min would be economically viable. Loss of transport observed after several days of continuous operation was restored by flushing membranes with fresh ion exchange liquid. A major effort was devoted to preparation of thin, leak-free membranes; the resulting membranes endured operating conditions without mechanical failure.

Jan 1, 1982

By Ralph L. Windrow

This paper is one of a series being prepared for and published by the United States Bureau of Mines describing methods and costs of mining and preparing sand and gravel for market at various plants throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. The Clowdy plant, with which this paper deals, is located 7 miles west of Dallas, Tex., and has a rail connection with the Texas and Pacific Railway. In addition to the rail outlet there is a paved road over which materials produced at this plant can be moved into Dallas by truck.

Jan 1, 1932

By R. L. Hopkins, H. T. Rall, H. J. Coleman, C. J. Thompson

Two methods were tested for separating sulfur compounds in certain petroleum fractions into types . Such separation is preliminary to identifying the compounds . Each method involved extraction of sulfides from petroleum sulfur concentrates . In the first method , the sulfur concentrate was reacted with methyl - ptoluenesulfonate to form sulfonium compounds from which unreacted portions of the sample were removed by washing with solvent . The sulfides then were recovered by heating the sulfonium compounds with anhydrous triethanolamine . The second method consisted of passing anhydrous hydrogen iodide into a n-butane solution of the sample cooled in dry ice , whereupon the hydrogen iodide adducted with the sulfides to form sulfonium compounds . These adducts separated as crystalline solids or , more frequently , as glassy viscous liquids . The sulfide was regenerated by adding water to the filtered sulfonium compound and was recovered by steam distillation or by extraction with pentane . These methods have been evaluated , using individual pure sulfur compounds and blends of sulfur compounds . They also have been applied successfully to separating sulfides from sulfur concentrates derived from petroleum fractions .

Jan 1, 1964

By M. I. Copeland

The investigation of the zirconium-gadolinium equilibrium diagram was part of a program to investigate rare:earth alloys for use as nuclear reactor control materials. Investigation of the zirconium-gadolinium equilibrium diagram revealed a eutectic system with limited terminal solubilities and one peritectoid reaction. The eutectic composition occurs at about 82 percent gadolinium, and the eutectic isotherm, which occurs at 1,220 ±5° C., extends from about 12 to 99+ percent gadolinium. A peritectoid isotherm occurs at 890 ±5° C. and extends from about 2 to 99+ percent gadolinium. The solubility of gadolinium in beta zirconium decreases from about 12 percent at 1,220 ±5° C. to about 2 percent at 890 ±5° C. The solubility of gadolinium in alpha zirconium decreases from approximately 5 percent at 890 ±5° C. to between 2 and 3 percent at 600° C. Vary little solubility of zirconium in gadolinium was indicated. An allotropic transformation of gadolinium was observed at 1,260 ±5° C. A change of the gadolinium transformation temperature on alloying with zirconium was not observed.

Jan 1, 1961

By Wilbur I. Duvall

Twelve millisecond delayed blasts in four limestone quarries in Iowa were instrumented with arrays of vertical velocity gages to determine if the direction of propagation through the rock or the method of initiation of the blast had any effect upon the level of vibration. Two gage arrays approximately 90° apart were used to test the effect of direction of propagation. The vibrations from blasts initiated by three methods were recorded. Vibration records from these tests were analyzed for peak particle velocity as a function of distance from the blast. The data are shown to fit a power Law equation. Direction of propagation is shown to affect the value of the exponent n. The effect of charge size per delay interval on the level of vibration is removed from the data by scaling the travel distance by the square root of the charge weight per delay period. The method of initiating the blasts is shown to have a strong effect upon the level of vibration and the spread in the data from one shot to another.

Jan 1, 1963

By Thomas A. Phillips

This publication is an economic evaluation of the Bureau of Mines electrolytic process for recovering lead from scrap lead-acid batteries. In this process, scrap batteries are crushed and separated into metal and sludge fractions. The metal fraction is cast as anodes and electro- refined. Lead in the sludge fraction is converted to lead carbonate by reaction with an ammonium carbonate-ammonium bisulfite solution. The lead carbonate is then dissolved in a fluosilicic acid electrolyte from which pure lead metal is electrowon. A cost estimate is presented for a plant capable of processing 10,000 scrap batteries per day. The fixed capital cost for this plant is estimated to he $14 million on a fourth quarter 1984 basis. Operating costs are estimated to be $0.15/lb Pb recovered. Assuming a lead selling price of $0.17/lb, the interest rate of return on investment after taxes is 11 pct. A lead selling price of about $0.21/lb is needed to obtain a 20-pct-interest rate of return.

Jan 1, 1986

By P. M. Sullivan

A physical beneficiation flowsheet was designed by the Bureau of Mines for reclaiming and recycling metal and mineral values contained in municipal incinerator residues, and a continuous processing plant was installed. Residue samples collected from incinerators located in various parts of the country were processed at a rate of 1/2 ton per hour. Continuous screening, shredding, grinding, magnetic separation, and gravity concentration techniques were applied to produce metallic iron concentrates, clean nonferrous metal composites, clean fine glass fractions, and tine carbonaceous ash tailings. Research to develop systems for refining and upgrading the reclaimed metals and glass into marketable products is also underway. From the engineering data developed in the continuous processing plant, evaluations of the capital and operating costs for plants with capacities of 250, 400, 670, and 1,000 tons of dry incinerator residues per day were made. Research on a parallel system to separate and recover the metals, minerals, glass, paper, and plastics from raw, unburned refuse it currently underway, as are studies on the use of air classification to separate the refuse into organic and inorganic fractions.

Jan 1, 1971

By A. Adams

The quality of hafnium metal produced by the Kroll process depends upon the purity of the hafnium tetrachloride. This investigation of methods for purification of hafnium tetrachloride was undertaken to aid in producing a higher purity hafnium metal than is currently produced by the Kroll process, The quantities of metallic impurities in hafnium metal were decreased by contact with molten alkali-metal chloride salt. Contact was achieved by a semicontinuous process of bubbling gaseous hafnium tetrachloride through a molten salt bath or by a batch process, first fusing the tetrachloride with a combination of alkali chlorides and then heating the mixture to sublime the hafnium tetrachloride. Low-melting mixtures of sodium, potassium, and lithium chlorides were used to purify hafnium tetrachloride. About 30 percent of the initial hafnium tetrachloride was trapped during purification with alkali- metal chloride salts. The 95-percent confidence limits (6)4 for the amount of oxygen decrease 60 and 34.3 parts per million when the batch purification is combined with a reduction so that both take place in the same equipment,

Jan 1, 1961

By H. R. Babitzke

The purpose of this investigation was to evaluate the potential of columbium-hafnium alloys as structural materials for use at elevated temperatures. The work described in this report was conducted to determine the properties of columbium-hafnium alloys and to select the more promising ones for further improvement. Properties determined in this report were machinability, hardness, workability, tensile strength, and oxidation resistance. Ten ingots, ranging from 100 percent columbium to 70 atomic-percent hafnium, were prepared and subjected to tests. The test results showed that the alloys with 33 and 50 atomic-percent hafnium were superior in workability, strength, and oxidation resistance. For the alloy series tested, the strength and hardness values increased with the increasing hafnium content. Maximum values were reached with 50 atomic-percent hafnium. The oxidation resistance was poorest at the 1 atomic-percent hafnium level but improved with increasing hafnium content through 70 atomic-percent. Eight of the ten ingots were fabricable at room temperature. The two remaining ingots, those with 5 and 10 atomic-percent hafnium, required hot-working.

Jan 1, 1962

By E. D. Gardner

This paper is one of a series on mining methods and costs being published by the United States Bureau of Mines. In April 19.74 the St. Joseph Lead Co., at Atlanta, Elmore County, Idaho, was mining and milling about 225 tons of gold ore daily with a total force of 150 men. The mine, which comprises the old Boise-Rochester and Monarch properties, is at an elevation of about 6,000 feet. Snow lies on the ground about 5 months each year but does net interfere greatly with local operations. However, the road to Mountain Home, the shipping point 80 miles distant, passes over a high range and usually is closed by snow from about November 15 to June 15. Heavy supplies are brought in and concentrates trucked out during the summer. In winter the district is served by a biweekly mail plane and a passenger and express plane making 4 to 6 trips weekly. Mine timber is cut locally. A plentiful supply of water is obtained from a stream brought to the property through 7,500 feet of plume.

Jan 1, 1935

By H. P. Hermance

Preliminary examinations of the Parker and Webb deposits were made by E. E. Maillott, Bureau of Mines engineer in July 1942. The chemical and spectrographic analyses included in this report wore made at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., under the general supervision successively of S. M. Shelton and of Paul M. Tyler, formerly regional engineer, Eastern Region. Beneficiation tests were conducted under the supervision of Frank D. Lamb. The mineral exploration was under the general supervision of J. D. Bardill, formerly district engineer. Acknowledgment is gratefully made to the St. Joseph Lead Co., in particular to John S. Brown and P. J. Mechin for their assistance. Special acknowledgment is made to the American Metal Co., Ltd., ,Ind to T. C. Moore for furnishing core-drill and assay data; to the Universal Exploration Co. and P. B. Jennings; and to the Northern New York Mining Corp. and C. H. Sprague for their permission to publish the core-drill dta. Excellent cooperation was given by Dr. W; M. Agar and C, L. Rogers of the Geological Survey.

Jan 1, 1949