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Improve the dust control effectiveness of dry collection systems on surface coal mine drills. Approach Use a dust pelletizer to convert the respirable dust particles discharged by the dry collector into dust pellets that present no health hazard. Background Blasthole drills are well-known sources of respirable dust that can contain significant amounts of quartz. The drills frequently use a dry cyclone-filter type collector that can obtain dust reductions theoretically greater than 95 pct. However, surface mine drills using dry collectors typically have three major dust sources that significantly reduce the overall effectiveness of the collection system: (1) the dust collector dump cycle, (2) drill shroud leakage, and (3) leakage around the drill stem seal in the drill table.

Jan 1, 1989

By J. E. Meacham

The U.S. Bureau of Mines investigated recovery of manganese from basic oxygen furnace (BOF) steelmaking slags because the slags represent a large potential resource of a metal for which there is no domestic production. BOF slags were leached using fluosilicic acid, a byproduct of the fertilizer industry. Manganese and iron were extracted as soluble manganous and ferrous fluosilicates while the calcium and magnesium remained in the tailings as insoluble fluorides. Treating the pregnant liquor with sodium chloride, precipitated sodium fluosilicate (Na2Sif6) which was recovered as a byproduct. Manganese and iron were precipitated as hydroxide-carbonate salts with the addition of sodium carbonate to the treated liquor. Recoveries for manganese and iron were 73 to 83 and 67 to 70 pet, respectively.

Jan 1, 1991

By R. L. Montgomery

Electronegativities of the rare-earth elements were calculated from heats of formation. The values obtained from different compounds varied widely. The postulates of Pauling's electronegativity theory were interpreted for bonds that are primarily ionic; the study showed that many compounds obey rules of the form expected. Revised electronegativity values are given for the more electropositive elements, including the rare-earth metals (which are near magnesium in electronegativity). Estimates of un-known heats of formation are made from electronegativities and are compared with other estimates. INTRODUCTION Calculation of the electronegativities of the rare-earth elements is interesting to show how these metals stand relative to the other metals and to each other, and also possibly to systematize the thermochemical data on them.

Jan 1, 1960

By Mary H. Brown

The heats of formation of oxalic acid and sodium, potassium oxalates, and lithium oxalates were related by solution calorimetry to the heat of formation of (COOH)2.2H20, a value believed to be reliable as reported in the literature. The following heats of formation were determined: (COOH)2(a), -198.1±0.1; (COOH)2(ß), -197.8±0.1; UAW,, -328.7±0.4; Na2C204 -316.2±0.1; K2C204, -321.9±0.2; and K2C204-H20, -393.5±0.2 kcal/mole. The heat of the crystalline transformation (COOH)2(a) ? (COOH)2(ß) was determined to be 0.30±0.02 kcal/mole at 298.15° K.

Jan 1, 1970

Improve the accuracy of commonly-used mine air velocity measurement techniques. Approach The Bureau of Mines, through a contract with Ketron, Inc., conducted a detailed study to establish appropriate, generalized correction factors for commonly-used air velocity measurement techniques. The techniques used were centerline readings, continuous traverse and split traverse vane anemometer readings, and smoke cloud readings (see Bureau of Mines Bulletion 589 for details on the proper use of these techniques). The various measurement techniques were used at different mine test sites to measure different air velocities. The data collected from the test sites were used in a statistical analysis which determined a generalized correction factor for each measurement technique. The correction factor multiplied by the measured velocity was used to provide the true velocity.

Jan 1, 1984

Minimize airborne respirable quartz dust produced by continous mining machines. Approach Install a shovel-mounted underboom water spray system on the off-curtain side of the mining machine. Dusty air containing quartz is momentarily trapped under the boom, where it is captured by fine spray mist. The remaining dust cloud is directed immediately behind the curtain before it can migrate back to the machine operator's location. How It Works Previous studies have shown that most of the dust generated by continous mining machines occurs under the boon as the cutter head shears down. The primary source of respirable quartz dust on many continous mining operations is cutting or trimming roof rock immediately prior to shearing. This results in very high concentration , of

Jan 1, 1989

By Richard J. Bielicki

Poor mixing of methane and air at coal mine working faces causes fluctuating methane concentrations. If these fluctuations are large enough, methane levels can periodically exceed safe limits, even though the time average methane concentration may be satisfactory. Concentration fluctuations measured underground can result both from variations in methane emission rate and poor mixing. The present paper reports on a statistical analysis of fluctuations at a constant methane emission rate, that is, on fluctuations due only to poor mixing. A full-scale model of a working face was used. Both peak heights and elapsed times between peaks were evaluated. Good mixing was indicated by normal, Poisson, and exponential distributions while poor or incomplete mixing was indicated by log-normal or gamma distributions.

Jan 1, 1974

By J. R. Ruark

This report presents results of mining operations and of research and development work done during stage I of the gas combustion retorting research program conducted by the Colorado School of Mines Research Foundation and six major oil companies at the Bureau of Mines Anvil Points Oil Shale Facilities. A brief description of the gas combustion process is given and the experimental program is discussed. Included in this discussion are (1) air-gas distributor development, (2) results of gas and shale distribution studies, and (3) effects of other process variable studies. The report concludes with a statistical evaluation of experimental results. Two appendixes present a chronological account of the experimental work and tabulations of data for all retorting runs conducted during stage I.

Jan 1, 1969

By Craig M. Jensen

A laboratory assessment of prompt and delayed neutron activation analysis with 252Cf and 14MeV neutron sources, for use as an in-situ method of determining low-level copper concentration has been performed. A simulated borehole using porphyry ore was constructed and varying copper concentrations were simulated using copper rods. Prompt neutron activation analysis experiments were consistant with earlier work and do not appear to be feasible fur copper concentration of 1.5% or less. Delayed neutron activation analysis experiments indicate that copper ore concentrations of less than 0.1% are detectable using either the 511-KeV gamma-ray of copper-64 or the 1039-KeV gamma-ray of copper-66, with high resolution detectors such as Ge (Li) or intrinsic germanium.

Jan 1, 1977

By Scott W. Hazen

This report describes the design, analysis, and results of a special experimental mine-sampling project conducted as part of the Bureau of Mines continuing program on sample-methods research. The experimental project was conducted at the Bureau?s Denver Mining Research Center and at the Climax molybdenum mine within the framework of a cooperative research agreement between the Bureau and Climax Molybdenum Co., Division of American Metals-Climax, Inc. The primary objective of the project was to investigate the interrelation-ship between sample volume, number of samples, the standard deviation of an assay distribution, and the precision required for an estimate of grade of ore, and to develop this interrelationship into a relatively simple method of application for use in mine sampling.

Jan 1, 1962

Introduction Research has shown that when an emergency occurs, work-ers often do not get the information they need to take appropriate action. Important information about incidents is either not com-municated effectively or not at all to those affected by the event. The "Emergency Communication Triangle" safety talk focuses on the content of emergency warning messages. It presents a procedure using mental cues that can be used by senders and receivers of emergency warnings. The talk includes graphics for use during the presentation, as well as references for more information. Background Interviews with 48 miners who had escaped one of three different underground mine fires revealed that warning information provided to them was inadequate. Either insufficient information was provided to miners inby the fire areas or they failed to ask the questions needed to let them plan and execute an effective escape. Most of the miners who evacuated from these three mines did not have information that would allow them to make decisions about efficient escapes. The communication breakdown came from two directions: (1) the individuals providing the warning did not offer details about the situations even though some were known and (2) the individuals who received the warnings did not ask for clarification of the situation. The lack of information allowed miners to continue attempting to place cues into normal frameworks after they should have evaluated the situation as abnormal and threatening. The uncertainty created by the lack of information influenced their decision-making and therefore their actions. Approach Researchers at the NIOSH Pittsburgh Research Laboratory have developed a training intervention that can be used by senders and receivers of warnings during a mine emergency. This material was developed for use in short safety training sessions such as start-of-shift safety talks. The information can be presented in about 15 minutes. Although the illustrations were taken from the underground coal mining industry, the training can be tailored to any work setting by substituting appropriate examples. How It Works During the safety talk, miners learn about the six categories of critical information that should be provided during emergency communications: Who, Where, What, Miners, Event, and Response. • Who: When reporting an emergency or receiving a warning, the first thing a miner must do is identify himself or herself. This is important because people react differently based on who gives them information. • Where: Giving or finding out the location of the problem is important. Of the 48 miners interviewed about their escape, only 2 knew where the fire was located. However, this information was known by either the dispatcher or the person who discovered the fire. • What: Miners must tell or ask exactly what is happening. At one mine fire, miners near the phone heard the message to evacuate and went to gather the others on their crew. One worker shouted to a machine operator: "Come on down to the mantrip. We're going out." Because it was close to quitting time, the machine operator thought they were just leaving the section a little early and went through his normal end-of-shift routine, wasting valuable time. After giving or obtaining the three initial pieces of critical information, miners can then give or obtain details about the response in progress. • Miners: Is anyone hurt? Has everyone been accounted for? When and where was a missing person last seen?

Sep 1, 2004

By J. H. Johnson

The report references reports and publications from 1975 to the present related to diesel underground mine air quality research undertaken by Michigan Technological University. Research results obtained on this contract are summarized in 5 different sections as follows: Section 1 - Development of a Systematic Approach to Monitoring, Data Analysis, and Interpretation for Diesel Mine Air Quality Control, Section 2 - Experimental Evaluation of LHD On-Board Air Quality Control Systems, Section 3 - Development of a Portable Self-Contained LHD Tailpipe Emissions Measurement Apparatus for NO , N0, CO, CO , and Particulate Matter, Section 4 Quantitative Analysis of Diesel and Coal particulate Matter by Laser Raman Spectro¬scopy and Section 5 - Development and Application to Detector Tubes of a Laboratory Method to Assess Accuracy of Occupational Diesel Pollutant Concentration Measurements.

Jan 1, 1985

By J. H. Field

Synthesis of hydrocarbons by the Fischer-Tropsch reaction in a hot-gas- recycle system was demonstrated to be technically feasible. This project was undertaken, by the Bureau of Mines, to determine if the system was operable and to ascertain the optimum conditions for the production of gasoline. Carbon steel turnings packed with a void volume from 88 to 90 pct. were satisfactory catalysts, but steel catalysts with greater void volume, either turnings or steel wool, were not as active. Good temperature control with a pressure drop of less than 0.5 pounds per square inch (p.s,i,) per foot of catalyst bed of turnings was obtained by operating with a recycle to fresh feed ratio of 20 and by splitting the total gas flaw and injecting portions into the reactor at different entry ports.

Jan 1, 1961

By A. Gene Collins, Cynthia A. Pearson, Cathy J. Waters

The chemistry of selenium and tellurium is discussed , along with a method of preparing a synthetic oilfield brine , an oilfield brine sampling method , and methods for determining selenium and tellurium in complex oilfield brines . Selenium either can be reduced to the elemental form with sulfur dioxide and determined semiquantitatively by color comparison of the red amorphous form or can be converted to selenite and determined quantitatively by reacting it with 3,3 ' - diaminobenzidine and obtaining its spectral absorbance at 420 mu . Tellurium can be reduced to the elemental form with hypophosphorous acid , and the spectral absorbance of its red hydrosol can be measured at 400 mu . Less than 0.05 mg / 1 of selenium and 0.1 mg / 1 of tellurium can be determined by the described methods .

Jan 1, 1964

By W. I. Garms

This paper, describing the milling practices at the Hayden concentrator of the Nevada Consolidated Copper Co. is the first of a Series being prepared by the Bureau of Mines on milling methods and costs in various districts of the United States. The Hayden concentrator is located at Hayden, Gila County, Ariz., 20 miles from the mine at Ray, Pinal County, Ariz., and approximately 1-1/2 miles north of the junction of the Gila and San Pedro Rivers. During the fourth quarter of 1928 the concentrator treated daily by flotation an average of 10,336 tons of ore containing 1.25 per cent of copper. The average recovery during this period amounted to 87.84 per cent of the total copper. The concentrates contained 19.88 per cent of copper.

Jan 1, 1930

By S. C. Termes

To help develop the basis for new fine-particle separation methods, the Bureau of Mines has investigated the use of cross-linked starches containing four chelating groups--carboxylate, iminodiacetate, dietha-nolamine, and xanthate--as flocculants for selected metal oxide and hydroxide mineral fines. It was found that those starches capable of interacting with the mineral surface by a chemisorpti,on mechanism (as indicated by zeta potential measurements) produced the highest recover-ies and'grades of the metal oxide or hydroxide when flocculated from a binary mixture with quartz. The effects of pH, dispersing agent, stirring rate, stirring time, and starch dosage on selective flocculation were studied for binary mixtures of hematite and chromite with quartz. Floc strength becomes important in achieving maximum recoveries by mechanical postflocculation separations.

Jan 1, 1985

By Clarence O. Babcock

This Bureau of Mines publication presents guidelines for mining near surface and underground bodies of water. The guidelines were based on information developed under contract in three phases of study, as follows: (1) Collection and documentation of data from worldwide sources; (2) application of existing guidelines, foreign, Federal, and State, to case histories of previous inundations; and (3) development of recommended guidelines for underground coal mining near bodies of water aimed at maximum efficient utilization of underground coal resources consistent with minimizing inundation hazards. While the contract guidelines were for the mining of coal seams, they may also be used for mining any tabular sedimentary mineral deposit. Tables are given for the determination of the size of coal pillars needed; for other bedded deposits, similar tables could be determined based on their strength properties.

Jan 1, 1977

By O. T. Barrett, R. F. Aberethy, H. N. Cooper, Thomas Fraer, William L. Crentz

"INTRODUCTION The object of the techniques described in this report is to determine the possibilities of separating the components of a raw coal into such grades as may be necessary to recover some exceptionally clean functions for special purposes.To do this commercial gravity methods would require separation at very low specific gravities, entirely outside the range of conventional practice. Hence, a technique has been developed for breaking down cool ample, into very close fractions within the gravity range of the (-lean coal matter as well as for separating it from the refuse and particles.Such data on the fundamental specific-gravity consist of the clean-coal matter will serve to appraise the difficulty of the problem and to chow be accomplished if and when effective methods of making such separations commercially are developed."

May 1, 1945

By James R. McVey

Tests during pillar robbing, longwall operations, and other mining activities indicate that roof-floor convergence rates can be used as an indicator of imminent roof failure. A large number of electrical-mechanical devices have been built to measure convergence as well as convergence rates, but most obstruct mine traffic and are costly and time consuming to install. The Bureau of Mines has designed and is evaluating three types of small ultrasonic units to make these measurements. The new instruments provide nonobstructing measurements up to 35 ft away. The ultrasonic transducers can be attached to a roof bolt, placed in an unsupported area (by means of a toss basket), or handheld. Total distance to the target and rate of closure are displayed digitally to 0.001 ft and 0.01 ft/min, respectively.

Jan 1, 1984

By Agnes Y. Lee

The Bureau of Mines has developed an effective hydrometallurgical method to recover high-purity Pb metal and elemental S from concentrates. This low-temperature process eliminates S gases and Pb emissions, in contrast to the current high-temperature smelting technology. The method consists of (1) oxidative leaching with H202, Pb02, and waste fluosilicic acid at 95° C to produce a solution of PbSiF6 and a residue containing elemental S, (2) electrowinning the PbSiF6 solution at 35° C to produce 99.99 pct Pb metal and H2SiF6, and (3) solvent extraction to recover S, leaving a residue containing Cu, Ag, and other metal values. Spent electrolyte was recycled repeatedly, with impurity buildup controlled by controlling the leach parameters.

Jan 1, 1986