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By A. W. Henderson

This investigation was performed to develop chlorination methods for extracting tungsten from scheelite and from an ore concentrate containing a mixture of scheelite and wolframite. On a laboratory scale with proper temperature control using elemental chlorine, over 90 percent extraction of tungsten is achieved. Carbon and sulfur dioxide were studied as reducing agents. The effects of salts such as calcium fluoride and sodium chloride were studied as additives to increase extraction and to reduce impurities in the volatile tungsten chloride product. Sodium chloride reacts with ferric chloride to form a nonvolatile double salt; whereas the chlorides and oxychlorides of tungsten are volatile and consequently condense free of iron. Separation of tungsten from molybdenum from an equal molar mixture was successful by fractionally distilling the oxygen-free chlorides and by selectively condensing the oxychlorides. Yields of 60 and 80 percent, respectively, were achieved for separating the less volatile tungsten chlorides containing less than 0.5 percent molybdenum.

Jan 1, 1965

By P. G. Clites

This study was undertaken to determine the effect of consumable-electrode vacuum arc melting on the properties of copper and to determine the applicability of the process to the production of cast shapes of copper. Ingots and castings were produced from electrolytic tough pitch copper (ASTM designation ETP), from electrolytic cathode copper (ASTM designation CATH), and from oxygen-free copper (ASTM designation OF). The products of this study were evaluated to determine the effect of the melting process on the removal of impurities from the copper and on the physical properties of the copper. The results indicate that consumable-electrode arc melting can be satisfactorily applied to the melting and casting of copper. Ingots prepared directly from electrolytic cathode copper contained slightly higher levels of impurities than are found in commercial oxygen-free copper, Excellent results were obtained with centrifugal castings of unalloyed copper, and reasonably successful static castings can be produced if proper mold and gating systems are employed.

Jan 1, 1963

By L. C. IlsLey

Minin,g Qr col-cu.ttint till:I chines are 1?;\i9ng the _m9t wideiy .used de1sses ()f mining equipment.· These 1T:.i:1Chines ,.--re practicaily t-tl\·operc1_ted eiyher_by compressed .iir or by electric. ·motors. According to &.ta• compiled _ from the 122. issue COAL CATALOG\JE. OJMEINED WITH; OOAL "FIELD 'pf!:fC'TOTl1, bf 7,088. mnes from which reports were obttiined there -are 3895 mines that u.se coal-cutting eql;lipmen:ts,, 'f'hi report lists 20,031: r.ct:lchines, 17,&75 being operated by·elct:i.c.m<;>_tors··:r;id :the remtiinder by compressed i.r motors,· ,-. · ', .. . · .. ··, .. _ ,· .,, .. .. . . . . . : ; "'l t:: On tl.Ccou-nt .. of the wide· use of coc:11-cutting -.:i"cliine_- any Stat!;ls have issued regulationa as "to their operation dnd be to safety precautions that.should be observed J especially in gaseous mines.

Oct 1, 1922

By James W. Myers

The Bureau of Mines studied factors affecting ignition of coal mine refuse and on methods for control of burning. Laboratory experiments showed that air permeates more readily through segregated than through nonsegregated refuse and that air permeability is greater through coarse than through fine particle refuse. Minus 3-1/4-inch refuse ignites spontaneously more readily than minus 1/4-inch refuse. The burning of a 1,000-pound conical coal pile was con-trolled by capping with an 18-inch-thick layer of minus 1/4-inch refuse containing 37 percent combustible. In field trials, the burning of refuse at operating mines was controlled by capping with a layer of fine refuse. Water, applied as a spray or by injection, quenched surface flames and cooled the burning waste. Inspection of refuse piles at operating mines showed that the spontaneous ignition tendency is affected by the exposed surface relative to the total volume and the segregation of particles during dumping.

Jan 1, 1966

By Richard F. Link

The objective of this report is to explain a statistical method for the summarization, organization, and classification of multivariate assay and other data from the mineral industry. Multivariate data are those characterized by several measurements at each data point, such as assay data from a mixed metal mine, or blast furnace data. A specific method of linear discriminant analysis, the Mahalanobis d2 procedure, is explained, starting from elementary principles; the d2 procedure enables many measurements at many data points to be studied by investigating the interrelationships among the data. The relation of linear discriminant analysis to other statistical methods for treating multivariate data, in particular the eigenvalue technique of factor analysis, is also explained. Example analyses are made on data from the Frisco mine, San Francisco del Oro, Chihuahua, Mexico. The data comprise assay values for silver, lead, copper, and zinc taken at some 19,000 sample points distributed into 91 groups.

Jan 1, 1967

By Aarne Visnapuu

Dissociation and vaporization of gold chlorides and bromides were investigated by a static pressure method and by Knudsen cell mass spectrometer. Two distinct chlorine and three distinct bromine pressure-temperature relation-ships were observed for the respective salts. The chlorine pressures are attributed to the dissociation of Au2Cl6 and Au2C12, and the bromine pressures to the dissociation of Au2Br6, Au2Br4, and AU2Br2, These pressure-temperature relationships were used to calculate dissociation pressure equations, enthalpies, and entropies of dissociation for each salt. Mass analysis of the vapors over AU2Cls between 83° and 152° C confirmed the existence of gaseous AU2C16. Ionization potential of this molecule is 11.0±0.1 ev and enthalpy of vaporization is 28.l±2.0 kcal/mole. Mass analysis of the vapors over the gold bromides detected only Bra in the temperature range 15°-150° C.

Jan 1, 1971

By D. R. Mathews

The Bureau of Mines investigated the effects of tungsten and chromium, separately and combined, on improving the mechanical properties and oxidation resistance of vanadium. Binary and ternary vanadium-base alloys were prepared and tested for oxidation resistance and tensile strength. Softening occurred with less than 1 weight-percent of either tungsten or chromium, followed by strengthening with higher alloying contents. Vanadium alloys containing up to 9.8 weight-percent chromium or 14.1 weight-percent tungsten were more resistant to oxidation in air at 600° C than unalloyed vanadium. For the alloys with 12.20 weight-percent chromium or 14.56 weight-percent: tungsten, the maximum concentrations used, the lower yield strengths were about twice that of 38,600 psi for the unalloyed vanadium. Recrystallization temperatures for these alloys were 100 and 150° C higher, respectively. Alloys containing both chromium and tungsten had properties similar to those of the vanadium-tungsten alloys.

Jan 1, 1967

By Allan F. Smith

The Bureau of Mines studied toxic products produced by burning eight fire-resistant mines conveyor belts, a brattice cloth, and an electrical cable insulation obtained from laboratory-scale burning experiments under various air-flow conditions. Generally, CO product concentrations for most materials were noticeably higher then the NO2 and HC1 levels that were measured; also, no phosgene was detected. However, several of the fire-resistant belt samples yielded HC1 concentrations that were above the reported lethal level for 1/2 to 1-hour exposures, although these data were limited to flow conditions where air dilution effects were small; the belt materials that showed this behavior included samples of polyvinyl chloride, styrene butadiene, styrene butadiene blends, and a British neoprene which yielded the greatest amount of toxic vapor. In addition, some results are presented on the phosphoric acid concentrations that may be produced from the decomposition of ammonium dihydrogen phosphate when dispersed on a burning coalbed.

Jan 1, 1973

By D. J. Bauer

The Bureau of Mines has conducted extensive studies on the recovery of alumina from kaolinitic clay by a HCI leaching-HCI sparging process. The current study reports a modification of the process, which involves a double-leaching system. The first leach of the calcined clay is made at as high a HCI acid strength as possible so that the dissolution of aluminum chloride hexahydrate (AlCI3*6H20) is suppressed, Most of the impurities, but very little aluminum, are soluble in the strong acid. After liquid-solid separation and washing, the solids are leached with recycled weak HCI, which dissolves the AICI3&apos;6H2O. The pregnant liquor is separated from the gangue, and AICI3&apos;6H2O is crystallized from solu-tion by injecting HCI gas. A proposed flowsheet is presented, and the effect of bleedstream size on AlC13&apos;6H20 purity is discussed.

Jan 1, 1984

By B. J. Scheiner

Extraction of silver from silver mill tailings by an electrolytic oxidation procedure was investigated by the Bureau of Mines. Various parameters affecting silver extraction, such as electrolysis time, particle size, and dissolution of the silver as the tetrachloro or cyanide complex, were studied at 30° C with an electrolyte concentration of 20 weight-percent sodium chloride. Resulting silver extractions ranged from 77 to 90 percent, depending on the tailings being treated. Concomitant extraction of mercury ranged between 90 and 95 percent. Power consumption was 52 to 90 kilowatt-hours per ton for the tailings investigated. Comparative experiments using direct cyanidation resulted in extraction of 46 to 82 percent of the silver and 20 percent of the mercury. Cyanide consumption ranged from 3.3 to 9.4 pounds per ton of tailings, depending on the tailings being treated. Silver and mercury were recovered from leach solutions by precipitation on iron powder, followed by conventional distillation and fire refining steps.

Jan 1, 1972

By C. M. K. Boldt

The Bureau of Mines surveyed waste disposal sites at 18 metal and non-metal mines and conducted laboratory and full-scale field tests to de-termine the effects of tailings deposition techniques on physical properties of tailings pond beaches. Survey data included measurements of beach slopes, descriptions of deposition techniques, and measurements of beach physical properties taken at various distances from the point of discharge. Laboratory tests involved depositing two types of tailings, each with different grain-size distributions, into a settling trough and determining the resultant physical properties of settled materials along the length of the beach. Side confinement and the closeness of the water pool to the point of deposition caused the laboratory results to be inconclusive. Full-scale field deposition tests conducted at the tailings pond of a cooperating mine showed that there were similarities in relationships between exit velocities of tailings slurry and physical properties of the settled tailings on the beach.

Jan 1, 1988

By S. D. Maksimovic

The use of vertical surface degasification boreholes with bleeder systems and the use of a timbered bleeder system to degasify gob areas were studied by the Bureau of Mines. This report describes three gob degasification studies conducted in the Pittsburgh coalbed. One study was conducted to determine the number of panels degasified with one large borehole. The study showed that the borehole provided degasification for three panels. Another study was conducted during the retreat of a 35-acre panel with a single-entry and a two-entry bleeder system and a large surface borehole. A major portion of methane emitted from the panel was carried away by the bore-hole, leaving the bleeder entries relatively free of methane. The last study was made to determine the effectiveness of a timbered bleeder system. The bleeder entries successfully degasified the gob area when enough entries were available and adequate pressure was available to force the air through roof falls.

Jan 1, 1980

By Blair Burwell

This paper describing the method of mining a deposit of vanadium ore near Rifle, Colo., is one of a series of similar papers on metal-mining methods and costs being issued by the United States Bureau of Mines. This vanadium deposit probably is the largest yet found in North America. It is situated 12 miles northeast of Rifle, Colo. (see fig. 1), on the southern flank of tae White River plateau, and is at an altitude of 6,500 feet. Between 150 and 200 tons of ore are mined daily and trucked to the mill at Rifle. The product of the mill is fined vanadium oxide, which is shipped to the company&apos;s plaits at Columbiana, Ohio, and Niagara Falls, N. Y., for the electric manufacture of ferrovanadium. HISTORY The deposit was discovered about 1909 by men prospecting for carnotite. Its outcrop on the bola cliff of Rifle Canon had been known to stockmen for many years.

Jan 1, 1932

By C. N. Adams

The purpose of this investigation was to evaluate the physical and mechanical properties of high-purity titanium made by two processes. Sodium-reduced metal with 58 Brinell hardness number (B.h.n.) and electrorefined metal with 60 B.h.n. and 70 B.h.n. were used. Titanium of these hardness levels did not work-harden excessively, and beyond 40 percent cold work the hardening effect was not great. Rapid softening occurred when the metal was annealed at temperature between 300° and 600° C. Full annealing, as determined by property and microstructure studies, was accomplished after 30 minutes at 700° C. A recrystallization diagram is presented which is based on determinations of annealed grain size as a function of rolling reduction and annealing time. For reductions of less than 20 percent, exaggerated grain growth occurred during annealing; for reductions greater than 20 percent, the variation in grain size for each annealing temperature was minor.

Jan 1, 1961

By Alla D. Mah

Relatively pure aluminum nitride (AIN) recently has been prepared in sufficiently large amounts to permit a variety of experimental studies.4/ Several mechanical and chemical properties have been investigated, which show that this substance has good potentialities as a container for liquid aluminum, gallium, and boric oxide. The present work by the Bureau of Mines was undertaken to obtain thermo-dynamic data pertinent to the calculations regarding thermal stability and reactivity of aluminum nitride. The following measurements were made: (1) determination of the heat of formation from the elements at 298.15° K.; (2) determinations of the heat capacity over the temperature range 51° to 298.15° K. and the evaluation of the entropy at 298.15° K. therefrom; and (3) determinations of the heat content over the temperature range 298.15° to 1,800° K. These data are combined to obtain free energies of formation from the elements between 298.15° and 2,000° K.

Jan 1, 1961

By Jr. Taylor

The following heats of solution have been measured in 1.160 molal H2SO4 at 25° C: AH298, kcal./mole Be(c) + 77.44(H2SO4?47.849 H2O) H2(g) + BeSO4 (soln) -92.83 ± 0.11 BeSO4 ?(c) + 77.44 (H2SO4?47.849 H2O) BeSO4(soln) -16.45 ± 0.02 BeSO4?2H2O(c) + 77.44(H2SO4?47.849 H2O) BeSO4?2H2O(soln) -5.395 ± 0.019 BeSO4?4H2O(c) + 77.44 (H2SO4?47.849 H2O) BeSO4?4H2O(soln) 1.513 ± 0.010 Combining these data with other experimental results and data taken from National Bureau of Standards information yielded the following heats of formation at 298° K:

Jan 1, 1966

By K. R. Van Doren

The polynomial method for estimating virial coefficients from experimental data suffers from three serious defects: (1) There is no known relationship between the polynomial coefficients and the virial coefficients, (2) the values of the estimates depend upon the degree of the polynomial and the particular set of values used for the independent variable, as well as the random errors in the dependent variable, and (3) the variances calculated for the estimates do not represent the mean square errors of estimation. Attempts to overcome these defects have thus far been unsuccessful; these attempts have also failed to account for the fact that none of the virial coefficients are uniquely determined by the values of the dependent variable for a finite set of values of the independent variable. The conclusion is that virial coefficients cannot be reliably estimated from experimental data unless additional information about the virial expansion itself, such as its rate of convergence, is available.

Jan 1, 1969

By Edward F. Divers

This Bureau of Mines report describes a new type of scrubber (dust collector) and ventilation system built into the auger support frame (boom) of a Jeffrey 120L continuous mining machine. With this twin scrubber arrangement, one scrubber is mounted into each side of the boom. Each scrubber includes a 2,500-cfm fan, a flooded fibrous-bed scrubber panel, and a water droplet eliminator. The system was designed for minimum size and adds only a few inches to machine height. Exhaust duct design allows flexibility with various airflow configurations to suit both blowing and exhaust fare ventilation systems and brattice distances ranging up to 20 feet. Full-scale tests with exhaust ventilation were conducted at a Mine Safety and Health Administration surface facility at Bruceton, Pa., to determine the scrubbers&apos; methane dilution capability. Several configurations of the twin scrubber-ventilation system produced striking improvements in face methane dilution when compared with conventional systems.

Jan 1, 1981

By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine if primary gas toxicities that evolve during the early (~300° C) and later (~.400° C) combustion stages of polyvinyl chloride and chlorinated brattices could be predicted by a smoke particle characteristic, which could be used as a simple and inexpensive test parameter. The experiments were conducted in an approximately 20-L furnace at set furnace temperatures of 2500 and 1,0000 C, for 14 min duration, with an airflow through the furnace of 10 L/min. The variables studied, as a function of time, were the hydrogen chloride (HCl) and carbon monoxide (CO) concentrations, sample and furnace temperatures, the sample mass weight loss, the average smoke particle diameter (dg and number concentration (no), and the product of the average smoke particle diameter and concentration (dgno)&apos; Results show that the inverse of the smoke particle diameter-concentration (l/dgno) correlates directly with the primary gas toxicities evolved during both stages of combustion.

Jan 1, 1989

By Potter G. M.

Ore-dressing tests were conducted on a sample of ore submitted by the Richmond Hill Mining Co. of Lead, S. Dak. as a part of the Bureau of Mines program for investigating potential domestic sources of manganese. Half of the sample was taken from the 300-foot level and half from surface cuts. The problems involved were liberation and rejection of silica and iron and removal of lead, Silver, and gold from the manganese concentrates. Although a portion of the silica and iron oxides was too intimately associated with manganese minerals for rejection by ore-dressing methods, thus limiting recovery of high-grade concentrates, the Richmond Hill ore was found amenable to simple gravity methods of concentration for producing intermediate-grade products. By jigging and tabling, 73.8 percent of the total manganese was recovered in a product that, when sintered, assayed plus 40 percent Mn. Lead, silver, and gold were successfully removed from gravity concentrates by a chloridizing roasting treatment.

Jan 1, 1948