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By R. August Heindl

A process for recovering manganese from open-hearth steel-plant slags was investigated. The proposed method of accomplishing this is indicated by the flow diagram in figure 1. Mixtures of open-hearth, steel-plant flush slags and limestone, so proportioned as to have molar [CaO -3P205] ratios of approximately 2, were fired at approximately 2,400° F. in an oxidizing atmosphere and then cooled slowly. This treatment produced a clinker consisting principally of two solid phases comprised of (1) various combinations of the oxides of manganese, iron, aluminum, and magnesium, probably in spinel complexes, and (2) a dicalcium silicate phase, which contains the phosphorus. Reduction of these clinkers with hydrogen or with gaseous mixtures containing CO, CH4, and other hydrocarbons at about 1,300° F. formed manganous oxide as well as varying amounts of ferrous oxide and iron. Carbon monoxide and mixtures of hydrogen and carbon monoxide effectively reduced the clinkers but also gave higher proportions of soluble iron when the manganese was extracted from the reduced clinkers by leaching at about 80° F. with ammonium carbonate solutions containing 26 to 28 percent ammonia and 15 to 26 percent carbon dioxide. It is believed that the manganese is in solution as an ammonia-manganese complex. Concentrations of about 90 grams of manganese per liter were obtained by batch countercurrent procedures. By distilling 50 percent of the ammonia, the ammonia-manganese complex was decomposed, and approximately 90 percent of the manganese was precipitated as the carbonate with the simultaneous precipitation of 15 to 30 percent of the iron, the larger amounts of iron precipitating in the continuous tests. The manganese-iron ratio in the product could be increased either by recycling more manganese from the distillation to the extraction or by aerating the liquor to purge it of iron before, rather than after, the distillation step. Calcination of the pelletized manganese carbonate in an oxidizing stmosphere at 2,000° F. or above gave a final product, Mn304, resistant to crushing and apparently possessing the other physical properties essential in a ferromanganese blast-furnace feed.

Jan 1, 1955

By E. D. Gardner

Ore and concentrate are transported on, the surface at western mining districts by (1) railroads, (2) surface trams, (3) aerial trams, (4) trucks, and (5) wagons, and (6) on the backs of animals. The daily and ultimate tonnage to be moved is the principal factor governing the selection of the method of transportation. Railroads are preferred when large tonnages are to be hauled over relatively long distances. The mine-haulage system may be extended or surface trams built to the mill or shipping point if a practical track grade is possible and if the distance is relatively short. Aerial trams have a special field of usefulness for transportation over steep or excessively rough terrain.

Jan 1, 1936

By M. F. Dunn

A handbook to provide a quick reference guide for selecting and using jet fans in a variety of conditions was prepared. The document is intended for use by front-line supervision, ventilation engineers, and mine planners. Included are discussions of jet fan characteristics, selection and use critieria, and do's and don't's for easier operation, safety, and performance. The handbook is based on research at three underground metal/nonmetal mines having cross-sectional areas of 900 to 2,000 ft2.

Jan 1, 1983

By W. W. Adams

This bulletin covers all mines in the United States that were operated in 1936 to produce metallic ores and all mines that were operated to produce nonmetallic minerals other than coal, stone, sand, gravel, or their products. Reports from mine operators revealed a better safety record for fatal accidents in 1936 than in any other year except 1934 during the 26 years for which annual surveys of accidents in the mineral industries of the United States have been conducted by the Bureau of Mines. On the other hand, the record for nonfatal injuries, although better in 1936 than in any year prior to 1930, was not as good as it was from 1930 to 1935, inclusive.

Jan 1, 1939

Develop geophysical techniques suitable for enhancing miner safety. Specifically, to use geophysical methods to detect hazardous conditions in a rock mass in deep underground mines as well as to assess the mechanical integrity and monitor changes of the rock.

Jan 1, 1997

By Joan C. Biordi

A molecular beam-mass spectrometer-low pressure flat flame apparatus has been constructed for the purpose of examining the chemical microstructure of normal methane-oxygen-argon flames and those inhibited with Halon extinguishants. Details of construction and performance of this apparatus and of related flame temperature measurements are given. Particular attention is paid to the empirical characterization of the perturbation to the flame caused by the sampling probes. The composition profiles obtained for normal flames are compared to those of flames inhibited by CF3Br. In addition to the usual stable species (CH4, O2, CO, CO2, H2O, H2, and H2CO), the inhibitor, its products and intermediates associated with its reactions could be followed. In particular, hydrogen bromide, bromine atoms, hydrogen fluoride, and carbonyl fluoride were observed. The relatively rapid disappearance of inhibitor and early appearance of fluorinated reaction products suggest a short lifetime for the CF3 radical in this system. Observation of COF2 suggests that CF3Br is effective as an inhibitor, at least in part, by virtue of its interference with the oxygen containing species of the normal chain reaction. Profiles of the 17+ peak at low electron energy suggests that the hydroxyl radical may also be sampled, but the profiles obtained are not yet sufficiently accurate to determine the effect of inhibitor on this important flame radical.

Jan 1, 1973

By J. G. Kirby, F. S. LOTT

The mmber of petroleum refineries in the United States decreased during 1949 from 375 to 367 while the total crude-oil charging capacity of refineries continued to increase. A gain in the through-put capacity of 257,305 barrels daily raised the total to a new high level 6,696,300 as of January 1, 1950. The capacity of the average refinery to process crude-oil increased during 1949 from 17,171 barrels daily to 18,246. The four coastal refinery districts accounted for 178,900 barrels or 70 percent of the total capacity increase and the Illinois-Indiana- Kentucky district 57,950 barrels, or 23 percent. Slight declines in capacity were reported in the Texas Inland and the Arkansas-Louisiana Inland districts. The capacity building on January 1, 1950, 145,600 barrels daily, was less than half the amount under construction a year earlier. Most of the new construction involved enlargement of existing refineries and was confined to the East Coast and Indiana-Illinois-Kentucky districts. Two new refineries, however, were under construction, one in Oklahoma and the other in Texas. The shut-down capacity increased for the first time since 1946, and the 473,302 barrels daily reported on January 1, 1950, was the largest recorded since January 1, 1938. The only refining district showing a decline in the shut-down capacity was the Appalachian No. 2 district. The largest increases were reported in the Texas Gulf, Indiana-Illinois- Kentucky, California, and East Coast districts. The operating ratio of the petroleum refining industry, as indicated by dividing the January 1950 runs to stills of 5,483,000 barrels daily by the total installed capacity January 1, 1950, was 81.9 percent, compared with a ratio of 87.8 percent at the beginning of 1949.

Aug 1, 1950

By J. B. Rosenbaum

This report presents new findings and consolidates previously published data to provide a single reference containing a concise and comprehensive description of the Bureau's work on electrolytic chromium. Two separate systems for electrolytic-chromium recovery were developed, one designated as the oxidized system the other as the reduced system. The electrowinning of chromium metal follows the dissolution of chromium from the ore or from ferrochrome and its separation from gangue and metallic impurities. Chromite was first solubilized by pressure digestion at slightly elevated temperatures in an oxidized acid solution using Na2Cr2O7 as an oxidizing agent. Later it was found that a sodium-free electrolyte was preferable, using return-cell anolyte containing H2SO4 and Cr03 as the oxidizing agent. Gangue materials were separated from the soluble metallics by filtration; and, after the Cr+3 had been stabilized, the metallic impurities were separated as crystalline ammonium salts by vacuum crystallization.

Jan 1, 1957

By M. Kanda, W. D. Bensema, J. W. Adams

Two different techniques were used to make measurements of the absolute value of electromagnetic noise in and above an operating coal mine, McElroy Mine, located near Moundsville, Nest Virginia. The electromagnetic environment created by 300 volt dc and 480 volt ac machinery was measured. In one technique noise was measured over the entire electromagnetic spectrum of interest for brief time periods. The noise was recorded using broadband analog magnetic tape. The noise data was later transformed to give spectral plots. In the other technique, noise amplitudes were recorded at several discrete frequencies for a sufficient length of time to provide amplitude probability distributions. The specific, measured results are given in a number of spectral plots and amplitude probability distribution plots.

Jan 6, 1974

By John Nagy

Tests were conducted in the Experimental coal mine to study some of the factors that should be considered in fighting mine fires and to obtain data on the effectiveness of different types of extinguishing agents. The investigation was confined to class "A" fires in a zone 20 feet long, involving coal burning on the floor, on the floor and ribs, and on the floor, ribs, and roof of the mine entry. It was determined that the time elapsed between ignition and attack of the fire is very important. A fire in the early stages was found to be controlled more easily and quickly than a similar fire that had burned longer. It was also found that, under suitable conditions, a fire in the floor, ribs, and roof develops very rapidly and consequently might spread over a considerable area if not brought under control quickly. The ventilating current affects fire-controlling operations markedly. Attack in intake or fresh air is highly advantageous, the chief inconvenience being the radiant heat from the fire. Attack in direct return air was impossible for the fires tested in this investigation, because of the high temperature. Universal-type gas masks for noxious gases and smoke offered no protection against the intense heat. Approach to a fire in the return air behind a water-fog curtain is not feasible unless the direction of air flow can be reversed. In one" test fresh air was carried to the fire area with a line brattice. Although the entire controlling operation was in fresh air and masks were not necessary, it was considerably more difficult to control the fire than when a similar fire was attacked in intake air.

Jan 1, 1950

By Gerald M. Bandholz

Exxon Minerals Company, a division of Exxon Corporation, has been exploring for base metal deposits in the Precambrian volcanic rocks in northern Wisconsin since 1970. Aerial electromagnetic surveys of the area, conducted in 1974, reported an anomaly, near Crandon, in Forest County. In the summer of 1975, the first diamond drill entered the anomaly, representing the 25th prospect Exxon had drilled in Wisconsin. This first hole revealed significant mineralization containing zinc and copper. Subsequent drilling confirmed the discovery of a sizeable zinc-copper massive sulfide are body. 1.1.2 Location The deposit is located in northeastern Wisconsin within a topographical high called the Northern Highlands region. The deposit lies about 5 miles directly south of Crandon and about 2 miles east of State Highway 55 on Sand Lake Road (see fig. 1). Other local communities include Rhinelander 28 miles west, Antigo 45 miles south, and Iron River and Iron Mountain, in Michigan, 75 and 44 miles east and north of Crandon respectively. In relation to the lakes and streams, the deposit lies 0.25 miles north of Little Sand Lake, and about 1 mile south of Swamp Creek.

Jan 1, 1981

By THEO L. JOHNSTON

In preparing for war , Japan built an iron and steel industry that ranked high with other industrial nations . Deficient in raw materials for making iron and steel , it had to acquire the bulk of its iron ore and much of its coal and scrap iron from foreign sources . Steel manufacture, and fabrication , however , were reserved mostly for the Home Islands , where modern integrated plants produced the implements of war . The vulnerability of relying on imports during the war was recognized early, and steps were taken to exploit iron-ore deposits and develop treatment processes on the Home Islands in order to be as self - sufficient as possible . Although the industry had expanded considerably, the capacity of the large plants still was insufficient for military requirements, so other meth- ods of producing iron and steel were adopted, which in some ways illustrate the desperate effort made to supply the war machine. In developing the iron and steel industry, modern practices of other countries were studied and followed with modifications to suit Japanese con- Aitions. German and American technical ability and equipment played a large part in the program; however, the Japanese had competent furnace technologists capable of obtaining proper equipment performance. For the most part, the standard practice consisted of smelting iron ores in blast furnaces and then refining the pig iron to make steel in open-hearth furnaces. Electric furnaces played an important part, especially in the manu- facture of alloy steels. Various other methods yielded minor but significant production. Among the various other treatment processes used, the production of sponge iron in rotary kilns 'probably was the most important in producing melt- ing stock for steel making. Of special importance was the fact that sponge iron made from low-grade ores contained critical metals, such as nickel and chromium, so that the results were more significant than was generally believed.'

Mar 1, 1948

By R. Y. Williams

The investigative work described in this report was undertaken by the Bureau of Mines under a cooperative agreement with the department of mining engineering of the University of Illinois and the Illinois State Geological Survey." The purpose of this agreement was to provide for a comprehensive investigation of coal-mining conditions in the State, with especial reference to the possibility of lessening waste in the mining and preparation of coal and of reducing the dangers to which miners are exposed. The Bureau of Mines paid particular attention to those phases of the investigation that were of general interest from their bearing on safety and efficiency in the coal-mining industry as a whole. Thus, it studied the occurrence of gas (methane) in the mines of the southern part of the State," tested the inflammability of the coal dust from many mines, examined the efficiency of the control of ventilating currents, and investigated the factors affecting the humidity of mine air with respect to their bearing on the occurrence of mine explosions. Following the establishment of the fact that under certain conditions dry bituminous coal dust is inflammable, there arose the problem of finding efficient methods of preventing or limiting coal-dust explosions. Experiments in the gas-and-dust gallery at the Pittsburgh testing station of the Bureau of Mines verified the fact that certain dusts that explode violently when dry are rendered inert by proper humidi- .fication of the atmosphere within the gallery, and the importance of humidity as a factor in limiting the inflammability of coal dust in a mine is demonstrated by the fact that there has never been in Illinois a dust explosion during the summer months, whereas the records show a number of dust explosions during cold weather. It is easy to see that the warm moisture-laden air that enters a mine in the summer must deposit moisture on cooling, whereas the cold and relatively dry air that enters in winter must take up moisture as it becomes heated in traveling through the mine.

Jan 1, 1914

By L. C. IlsLey

Explosives have been fired electrically for several decades. Mountains have been tunneled, deep shafts sunk, extensive coal and metal mine workings excavated and, in times of war, railroads, buildings, bridges, and fortifications have been destroyed by means of electrically fired explosives. Modern engineering depends so much on explosives that their safe and efficient handling and especially their detonation are of prime importance to all those connected with the use of explosive agents. Electric shot-firing is only one method of igniting explosives, but it is rapidly spreading and because of certain inherent safety features should be encouraged. Data collected by the Bureau of Mines indicate that in the United States a large percentage of the blasting in quarries, shafts, and tunnels, and from 15 to 25 per cent of the blasts in mining operations, are set off electrically. The Bureau of Mines is interested in electric shot-firing because of its use in mining, and especially because electric methods, when properly applied, are undoubtedly safer than other methods commonly used.

Jan 1, 1926

By Northcutt Ely

This volume- summarizes mining and petroleum legislation in 18 European jurisdictions. Within these jurisdictions, primary attention is given to requirements that must be met in each country for acquisition of rights to permit development of mineral resources. Coverage includes: First, identitication of the controlling laws or statutes governing minerals acquisition and reference to the administrative authority; second, analysis; of the laws governing mines and quarries and their products; third, analysis of laws applicable to natural gas, petroleum, and related materials; and fourth, mention of laws regulating offshore operations. Where pertinent, sections dealing with historical background or administration have been added in countries where minerals are subject to control of States or Provinces, those areas are considered separately from the central government.

Jan 1, 1974

[This Report represents the culmination of work perfomed under Contract No. .,JG1551A8 for the U.S. Bureau of Mine.The &apos;.:o-< embeded a site evaluation, engineering E:-y- ,, esign, and preparation of specifications for construction of a Transport Research 7 :4 (HTRF)The HTRF is designed as a research facility J evaluate the hydraulic transport of large lump coal at a prototype ;e scale. The HTRF is to be constructed and operated by the Pittsburgh and Safety Research Center of ;. re U.-AN a*, their Bruceton, Pennsylvania test center. In terms of technical capability, the HTRF will have transport pipeline:: of -, twelve-, and eighteen-inch diameter _&apos; with supporting coal handling n , water forage a.^ &apos;d conveyance, mixing, pumping, and dewatering equipment, plus instrumentation and controls. Maximum design velocity 13 20 ft/sec.; solids concentration, by, volume, will; 1 be a maximum-- of sixty, percent. Each test loop is designed to accommodate solids of up to one-third the diameter e - of the pine. The Final Report Pr.-&apos;I-rents information of t HTHF,. including the site evaluation, design criteria, a description of the a description of the procedure to be used for operation of the facility, an estimate of the cost to construct the f^Cilit:r, 1 p el_~lli.&apos;iU construe`, icn Schedule, and a construction suicJ_iicaT.l_ccn&apos;. T e c011SLr?Jc&apos;.ion soecl_ i.on _ccnta_i:s technic.&apos;..i re7,uir: (-n`,s for !&apos;urr1S~ &apos;~latcr..al. and ec-uipr,ent for :":C1 C_`:_C ti on of ti,_ H ice&apos; u:&apos;.:i ._II u s(-.6 for ~.Iir: .3!7 soliciting bids. `.l_o included n cc&apos;;,art_- c?r~.air sV:et..: :s ^nd rr^.?]

Jan 1, 1976

By Welby G. Courtney

This publication reviews recent U.S. Bureau of Mines studies of frictional ignition of a methane-air environment by coal mining bits cutting into sandstone and the effectiveness of remedial techniques to reduce the likelihood of frictional ignition. Frictional ignition with a mining bit always involves a worn bit having a wear flat on the tip of the bit. The worn bit forms hot spots on the surface of the sandstone because of frictional abrasion. The hot spots then can ignite the methane-air environment. A small wear flat forms a small hot spot, which does not give ignition, while a large wear flat forms a large hot spot, which gives ignition. The likelihood of frictional ignition can be somewhat reduced by using a mushroom-shaped tungsten-carbide bit tip on the mining bit and by increasing the bit clearance angle; it can be significantly reduced by using a water spray nozzle in back of each bit, which is carefully oriented to direct the water spray onto the sandstone surface directly behind the bit and thereby cool the hot spots formed by the worn bit. A bit replacement schedule must be used to avoid the formation of a dangerously worn bit.

Jan 1, 1990

By S. S. Cole, C. E. Wood, T. L. Joseph

"INTRODUCTION Iron ore containing titanium was first used in blast furnaces over a century ago. It is well known that TiO2 is a slag-forming material that will increase the amount of slag produced by the usual gangue materials, silica and alumina. Increase in the volume of slag due to the presence of TiO2 and a lack of information concerning its effect on the properties of the slag have prevented the general use of titaniferous ore. Also rather com¬mon belief among furnace operators that the bottom of the furnace builds up when ores containing TiO2 are smelted has militated against the use of titaniferous ore. This building up of the hearth has been attributed to the formation of copper-colored crystals of titanium cyanonitride, which have been observed in the salamanders of blast furnaces. Until recently the availability of nontitaniferous iron ore has left little incentive to use ore containing titanium.The presence of vanadium in certain deposits of titaniferous magnetite in New York State has created new interest in problems connected with the use of titanium-bearing ore. It appears that most of the vanadium in this ore can be recovered in pig iron, which can be blown in a converter to produce a slag containing vanadium in amounts suitable for the production of ferrovanadium.The Titanium Division of the National Lead Co. recently erected a largo mill to treat ore from Sanford Hill, in Essex County, New York, about 50 miles west of Port Henry. The ore deposit was acquired from the MacIntyre Iron Co. and is often referred to as Sanford ore. It is one of the largest deposits of Iron-bearing material to be found east of the Lake Superior region and is being mined by open-pit methods."

Jan 1, 1943

By T. A. Henrie

One objective of Project Gnome is to study the feasibility of a phase of the Plowshare program recovering thermal energy from an underground nuclear explosion. The test will be conducted in an underground salt deposit. It is anticipated that some of the energy thus released will be stored as thermal energy in molten salt. This report describes the pre-Gnome experiments conducted at the Federal Bureau of Mines Metallurgy Research Laboratory, Boulder City, Nev. The objectives of this study were to determine the problems involved in the recovery of thermal energy from molten salts to assist in planning the experimental program for the Gnome project.

Jan 1, 1961

By D. Harrington, B. W. Dyer

"Two recent occurrences in Western metal mines in each of which 3 men were killed due to breathing fumes from explosives, have aroused keen interest among mining men not only as to the exact cause of such accidents, but also as to possible preventive measures.In sinking the forty five degree incline Marsh *haft near Burke, Idaho, on May 13, 1920, a round of holes containing about sixty pounds of 40 per cent gelatin explosive was blasted by the night shift upon leaving at 11:30 P.M. It was customary for the night shift to leave compressed air blowers open at bottom of abaft until the compressor was shut down slightly before midnight. Presumably this was not done on the night of the lath as the fumes were so heavy in the shaft bottom on the morning of the 14th that at about 8 o'clock, Superintendent Bergen and one of the shaft men, on reaching the shaft bottom, were overcome and fell from the bucket into the sump containing about six feet of water; and when two other men went down in the bucket a few minutes later to investigate, one also fell into the sump and the other was barely able to roach the shaft collar. The three bodies were later on recovered from the sump.At 400 P.M., June 10, 1920, at the Dominion Mine, Colville, Washington, a round of 11 holes containing about fifteen pounds of 60 per cent nitro¬glycerine explosive was blasted in a fifty degree raise about fifty feet above the main tunnel level by the shift going off for the night. in this mine it was the practice not to try to blow out the fumes until just before the shift went to work the next morning, Although no work was being done on the night shift, one of the raise men, curious to ascertain the effect of the shots, about 7:45 P.M., wandered into the mine (which was a tunnel only a few hundred feet in length), and was missed by one of his companions about an hour later. When three men tried to remove the body of the inquisitive miner, two of them were also overcome; ultimately these two and the first man were removed from the point at which all were asphyxiated, which was practically at the foot of themaise."

Jul 1, 1920