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By R. R. Sayers

There is probably no industry , trade , or art in which mercury is used but what has produced some cases of mercury poisoning . This is true of the mining and smelting of mercury , where the hazard has long been recognized . When the ore contains free mercury or the more soluble salts , and when the workings are underground and are poorly ventilated , cases occur , but there are a far greater number of cases among the employees about the reduction works . 3 In 1863 William V. Wells visited the mines at Almaden , * Spain , which were worked by convicts . He reported that the men at the furnaces suffered severely , being able to work only about one week out of four , when it was necessary to transfer them to places where the exposure was less . He states that "pale cadaverous faces and leaden eyes are consequences of even these short periods . " Mercury , like lead , when absorbed in small amounts at intervals , as daily, over an extended period of time will result in symptoms of poisoning . This is due to the fact that the mercury is eliminated from the body more slowly than it is absorbed . The frequency and severity of cases of mercury poisoning are far less with modern methods of mining and recovery of the metal than formerly . However , further reduction is possible and much can be done by both the workmen and the operators by following the proper precautionary measures , some of which are described in this chapter .

May 1, 1922

By Clarence Karr

AN EXTENSIVE characterization was conducted on the neutral oil components in a low-temperature bituminous coal tar. A total of tai individual compounds identified with respect to individual isomers, and at least 55 other compounds were indicated to be present. The amounts were determined in all instances. A comparison of isomeric distribution in the tar with thermo-dynamic equilibrium distribution, and kinetic distributions indicated that the composition of the tar largely reflected the structure of the coal from which it was formed. Detailed descriptions are presented for the separatory and qualitative and quantitative procedures for the characterization of the neutral oil component. These include micro fractional vacuum distillation, displacement liquid chromatography, gas-liquid chromatography, countercurrent distribution, and infrared and ultraviolet spectrophotometry. Descriptions are given for the synthesis of authentic specimens of alkylindenes, The ultraviolet and infrared spectra of 134 polycyclic compounds, ranging from alkylindenes to alkylphenanthrenes, either found in the distillable neutral oil, or thought likely to be present, are also given.

Jan 1, 1967

By Kyei-Sing Kwong

The U.S. Bureau of Mines investigated the synthesis of advanced ceramics (SiC+AlN, SiAlON, SiC+A1203, and Si3N4+AlN) from natural clays (kaolin, halloysite, or montmorillonite) by an intercalation and heat treatment method. This process includes the steps of refining a clay, intercalating organic chemicals into its layered structure, drying the intercalated mixture, firing the treated structure at certain temperature ranges in controlled atmospheres to form desired compounds, and grinding the loosely agglomerated structure. Focus of this research is to economically process advanced ceramic structures from abundant natural resources. The advanced ceramic phases produced in this simple treatment are homogeneously distributed at the nanostructure level, and may potentially lead to cost effective manufacturing processes. The intercalation of clay was confirmed by X-ray and BET analyses. The evolution of chemical compositions during carbonization reactions and carbothermal reduction was investigated. The characteristics of refined clays and synthesized powders were studied. Advanced ceramic composites/solid solution have been produced from intercalated clays, without the presence of other compounds.

Jan 1, 2010

By Jack C. White

This U.S. Bureau of Mines report assesses the resource potential of trace metals present in commercial Ti mineral concentrates. Metals of greatest interest: are those defined as "strategic and critical" by the U.S. Congress in 1981. Metals of interest in Ti mineral concentrates are Cb, Cr, Ta, Th, U, V, and Zr. Commercially available Ti mineral concentrates were studied. Characterization and analysis of major and minor constituents were performed by X-ray diffraction, neutron activation, inductively coupled plasma emission, atomic absorption, and classical wet chemical techniques. Of the metals investigated, the Cb, Ta, and V content of some concentrates may be a significant potential resource, depending on their amenability to recovery.

Jan 1, 2010

By Raymond L. Carpenter

The thermal conductivity, electrical resistivity, and Seebeck coefficient for nine compounds, based on the formula for enargite Cu3AsS3, were measured in a search for efficient materials to be used in thermoelectric generators or refrigerators. Results indicate that one of these compounds, Cu3SbSe4, has thermoelectric properties approaching those of bismuth telluride. An investigation of the effect of adding small quantities of tellurium to Cu3SbSe4 and Cu3SbS4 in order to improve their properties also was made. A figure of merit of 2.1 x 10-4 °C-1 was obtained for Cu3SbSe4 + 0.1 percent tellurium.

Jan 1, 1963

"Research on the control of exposure to respirable contaminants in mine atmospheres is conducted in five areas; 1) control of dust generation, 2) dilution, dispersion and collection of dust in mine airways, 3) characterization of dust particles, 4) interaction of dust and lungs, 5) relationship of mine environment, geology, and seam characteristics to dust generation and mobility. The distribution of research findings to the mining industry, to government agencies, and to scientists at other universities is accomplished in several ways.A data bank of respirable dust samples displaying a wide range of characteristics (low volatile, medium volatile, high volatile, silica fireclay, rockdust) has been established by the Center. This data bank is being utilized by Center researchers in a suite of medical, scientific, and engineering tests (FIGURE 26).The Center has honored requests for educational and informational materials from several sources, including MSHA and CANMET who received information on Center generated software and used the Center's expertise in developing a computer program for particle distribution model (DISFIT).The Generic Mineral Technology Center for Respirable Dust has organized two dust conferences on respirable dust, the Coal Mine Dust Conference, held at West VirginiaUniversity, Morgantown, West Virginia from October 8-10, 1984 and Respirable Dust in the Mineral Industries: Health Effects, Characterization and Control, an international symposium on Respirable Dust in the Mineral Industries held at The Pennsylvania State University, University Park, Pennsylvania from October 14-16. 1986. These conferences were co-sponsored by the U.S. Bureau of Mines, Mine Safety and Health Administration, National Institute for Occupational Safety and Health (NIOSH), and the American Conference of Governmental Industrial Hygienists (ACGIH). On August 23-26, 1988, the VIIth International Pnuemoconioses Conference was held in Pittsburgh, Pennsylvania. While not a sponsor of this conference, researchers in the Generic Mineral Technology Center for Respirable Dust had significant participation with sixteen (16) papers presented (see Volume 8 of this series for abstracts and papers). These conferences provided a significant forum for the exchange of ideas on dust research and the interchange of research findings. The proceedings from these conferences are available from NTIS and ACGIH.In sum, significant benefits to mine worker health have resulted and should continue to result from the synergistic scientific, engineering, and medical research in respirable dust (FIGURE 27). As always, an important objective is the rapid dissemination of the results of this research to industry. Video tapes and the Bureau's Technology News series have been a very effective means of USBM technology transfer. Individual no-cost subscriptions to the Technology News series are available from the U. S. Bureau of Mines, Branch of Technology Transfer, 2401 E Street, N.W., Washington, DC, 20241."

Aug 31, 1989

By James L. Eirls

The objective of this project was to improve a driver's field of view for large trucks used in the mining industry. Rearward viewing was enhanced by improving the rear-view mirror designs. Rear vision was accomplished using a closed circuit television system. Views ahead,, to the right, and downward were obtained with a blind area viewer (BAV). The BAV is a unique combination of fresnel lenses housed in a shielded, environmentally protected enclosure that produces an image of the area in front of and downward 70° and to either side of the BAV 300. The improved visibility devices were evaluated by long-term, in-mine testing. The right Bide mirror (RSM) and BAV provide the greatest improvements for the least cost and are commercially available. Application of the RSM and BAV should achieve a reduction in accident potential and greater vehicle productivity by enlarging and improving the equipment operator's visibility and making priviously blind areas and hazardous situations detectable.

Jan 1, 1982

By Donald W. Mitchell, John Nagy, Edwin M. Murphy

To increase safety and productivity in mining , the potential uses and hazards of rigid foam were investigated by the Bureau of Mines Experimental Coal Mine . This research resulted in the development of chemical formulations , spraying equipment , and application procedures that permit safe and effective use of urethane foams for improving mine ventilation , for reducing weathering of mine rock and steel , for constructing seals in fire areas , and for thermal insulation .

Jan 1, 1964

By Robert L. Grayson, Syd S. Peng

"An airborne dust study was undertaken at a Southwestern Pennsylvania underground bituminous coal mine by the Pennsylvania Department of Mines and Mineral Industries in 1964 for the purpose of making recommendations and requirements regarding compliance with health and safety aspects of The Bituminous Coal Mining Laws of Pennsylvania, approved by the legislature on July 17, 1961. The study was designed to accurately represent the airborne dust conditions of the subject mine. Sampling by midget impinger of specific worker locations throughout the mine was accomplished. Sample analyses yielded dust concentrations to mppcf, particle size determinations in cumulative per cent less than specified cut-off diameters, and determinations of free silica percentages in total dust samples. The data from this study is further analyzed, and the results are presented.INTRODUCTIONThe Bituminous Coal Mining Laws of Pennsylvania, enacted in 1961, prompted a study of respirable coal mine dust by the Department of Mines and Minerals Industry in 1964. In recognition of their obligation for ensuring the health and safety of bituminous coal miners, the department set out to characterize the airborne dust of mines throughout the commonwealth. The purpose of the studies was to make recommendations and requirements for compliance with the law and for control of airborne coal mine dust in Pennsylvania mines.One such study was undertaken at an underground bituminous coal mine operating in the Pittsburgh Seam in Southwestern Pennsylvania. The study was desig11ed to sample specific worker locations throughout the mine site and characterize the respirable dust relative to each of them. A midget impinger was used to gather respirable range dust samples during an 8-hour shift. Continuous miner operator, roof bolter, stoper bolter, loading machine operator, shuttle car operator, gathering motorman, mainline motorman, and rotary dumper jobs were sampled underground. In addition, barge mover, coal sampler, fine coal operator, heavy media operator, and boiler room attendant occupations were sampled on the surface. The surface sampling was over a 71-hour shift because of UMWA contract provisions."

Jan 1, 1988

By Terry S. Cory

This report covers antenna design, analysis, and development work suited for use with a wireless radio communication system operating at medium frequency. The work includes the test and evaluation of prototype vehicular antennas developed during the program.

Jan 12, 1978

By R. J. SHAW

Oil shale has been defined as, "a compact, laminated rock of sedimentary origin yielding over 35 percent of ash and containing organic matter that yields oil when distilled but not appreciably when extracted with the ordinary solvents for petroleum." The oil-yielding organic matter in oil shale, commonly called kerogen, decomposes upon application of heat to form bituminous materials that are soluble in organic solvents and may be extracted from the inorganic residue. However, separation usually is accomplished by continuing the heating and thereby cracking the primary bitumens to gas and oil, which distill, leaving a carbonaceous material on the mineral residue. It has been suggested that this conversion takes place only at relatively high temperatures - 750°F or higher. On the other hand, other workers have found that transformation may take place to some extent at temperatures as low as 400°F. In either a solvent extraction or a destructive distillation process for separating organic material from the inorganic portion of oil shale, the quantity of heat required to raise the temperature of the oil shale sufficiently to induce a satisfactory rate of conversion of kerogen to oil is important in determining the design of an economical process. Likewise, the quantity of heat recoverable from a spent shale is important in determining the overall heat balance of the process. Published data on the specific heat of American oil shales are meager. Gavin and Sharp present data for two samples of Colorado oil shale, one from near DeBeque and one from Parachute Creek, and for a sample of spent shale over a temperature range of 68°F to 1940°F. McKee and Lydor present data on the specific heat of two samples of oil shale from near DeBeque, Colorado. Additional thermal data on various grades of oil shale over a wider range of temperature are needed in order to apply sound engineering practices to the design of equipment for processing oil shale.

Nov 1, 1947

By Oliver W. Keener

The operation described herein differs from the usual practice in the Tri-State district in two important respects: (1) the ore is loaded into cars which are tramped to the shaft and hoisted on self-dumping cages, and (2) about 30 per cent of the ore is loaded by power shovels. The four-month period covered by the cost data appended at the end of the paper immediately followed a period of about one year during which the mine was shut down, and the expense incident to the resumption of operations is reflected in the costs. The author acknowledges the assistance of C. F. Jackson, mining engineer, U. S. Bureau of Mines, in the preparation of this paper and the compilation of the data.

Jan 1, 1929

By J. G. Donaldson

Binary alloys of molybdenum and tungsten were prepared by the Bureau of Mines in laboratory-scale experiments by hydrogen reduction of their vaporized hexafluorides. Near-optimum deposition parameters were determined, and the nature of the deposited alloys was investigated. Dense, homogeneous alloys were codeposited between 650° and 750° C with a reduction efficiency of more than 75 percent. The alloy composition was uniform when the hydrogen ratio in the gas feed mixture did not exceed 3 times the stoichiometric requirement. Regulating the proportions of the metal hexafluorides in the gas feed provided a large degree of control over the composition of the deposit. Hardness of the deposits varied directly with the proportion of excess hydro,,,, in the gas feed and with the weight-percent of tungsten in the alloy. Hardness was not affected by deposition temperature over the range 650° to 750° C for specimens of similar composition. Extreme brittleness and unsuitable physical shapes of the alloys prevented tensile strength measurements.

Jan 1, 1966

By Jon I. Voltz

The U.S. Bureau of Mines has conducted fundamental coal fragmentation studies to evaluate the effects of impact energy and direction of bedding planes on dust generation, size distribution, and impact-output energy relationships. Product size distributions were obtained for the fragmented samples by screening to minus 150 mesh. The minus lS0-mesh fines were analyzed with a light scattering photometer with a measurement range of 176 to 1.9 /.tm. Increased input energy produced a significant increase in the weight of plus 3/8-in material for impact perpendicular to the bedding planes. No significant trend was observed for parallel impact. Impact direction had little influence on dust size distribution, and input versus output energy relationships. As expected, total airborne dust measured at time of impact and percent particulates below 11 /.tm in size generally increased with increased input energy for both directions of impact. Energy used for sample fragmentation increased with increased energy input.

Jan 1, 1989

By Young W. A.

The Eagle Silver mine is in the Rush Valley mining district, Tooele County, Utah, and is now operated by the Hampton Mining Co. The property, originally referred to as the Argent, is reported to have been one of the first discoveries in the district. The early operators mined ore to a depth of 850 feet, at which point the property was abandoned because of excessive water. During 1905 the Honerine tunnel was driven into the area approximately 1,800 feet below the collar of the Argent shaft. This tunnel served to drain the levels above and operations were resumed. Ore deposits in the Eagle Silver mine occur in the Galena King lime-stone, a 20-to 60-foot member of interbedded quartzite and limestone in the Oquirrh formation of Pennsylvanian age. This member has been faulted along the bedding, forming the Galena King gouge. Mineralization commonly occurs in or near this gouge area in a brecciated, highly altered, pipelike zone. The known ore shoots occur in association with the breccia pipe, commonly adjacent to cross faulting and porphyry intrusions. In general, two ore shoots have been mined on the upper levels of the mine, one lying to the east and the other to the west of the breccia zone. The Bureau of Mines diamond-drilling program was begun during the latter part of 1948 and completed early in 1949. Nine holes were drilled, aggregating 852.8 feet. Sludge and core samples from mineralized sections were analyzed in the Salt Lake City laboratories. A total of 87 sludge, 71 core, and 11 chip samples was submitted for analysis.

Jan 1, 1950

By R. V. Ramani, K. V. K. Prasad, M. Swaminathan

"Engineering design involves, in addition to numerical calculations, considerable amount of expertise and judgement. The expertise and judgement is required to conceptualize and idealize the problem, select a suitable mathematical model for the problem and to interpret the model results in terms of stipulated design constraints. In recent years, knowledge based systems (KBS) have provided the capability to integrate the qualitative experiential and expert knowledge with ~he quantitative knowledge for improved analysis and design of systems. A possible KBS architecture for mine ventilation system design was discussed by Ramani and Prasad · (1987). The expert system (ES) component of the KBS supports the analysis and interpretation phases of the ventilation design process with an algorithmic program used for the solution of alternate designs. The purpose of this paper is to discuss the data and knowledge needs for developing such a system and a formal means of their representation on the computer. A number of ES shells were evaluated to explore possible development and delivery environments for the system. A brief summary of this evaluation is also provided.INTRODUCTIONLuxbacher and Ramani (1979) have discussed the design process of mine ventilation systems and have provided the interrelationships that exist between ventilation, strata control, drainage and material handling systems and mining methods. They have also outlined the importance of correct analysis of the problem, choice of the right solution method and a rigorous interpretation of the solutions. The expertise required for analysis and interpretation phases was identified as the key element in developing effective and efficient ventilation system designs. Such expertise is embedded in the right choice of questions to be asked of the user as well as in directing the user to a wide array of alternative methods that may satisfy the design requirements. With advances in artificial intelligence applications in recent years, particularly expert systems, the integration of expertise into traditional mine planning and design algorithms has been facilitated. These planning and design aids, employing the integration of numeric and symbolic logic and called coupled systems, are powerful tools for engineers to tap the benefits of experts (Kitzmiller and Kowalik, 1985; Fenves, 1985). The purpose of this paper is to discuss the means of representing knowledge for the design of mine ventilation systems through the use of a coupled system. The KBS is visualized as consisting of the following components:"

Jan 1, 1989

By Robert T. MacMillan

A process has been developed in the laboratory and expanded to semi-pilot-plant scale for recovering titania, iron, and byproducts from two types of titaniferous iron ores. A reducing roast with coke and soda ash followed by grinding and magnetic separation produced powdered iron and slag from which titania and byproducts were recovered by H2SO4 decomposition. Based on the steps tested on a. semi-pilot-plant scale supplemented by the results of the laboratory investigations, enough data are available to make a balanced flow sheet. Combined data from the laboratory and semi-pilot plant indicated that 85 to 9O percent of the titania content of the ore was recoverable and that approximately 90 percent of the iron could be recovered as a metallic-iron powder. Tahawus magnetite from the Maclntyre mine at Tahawus, N. Y., was successfully treated as follows: (1) The ore was roasted at 1,050° to 1,080° C. with carbon and soda ash, thereby reducing the iron to metal sponge and retaining the titania in the slag. (2) The metallic iron was separated, after wet grinding, by magnetic or gravity means. (3) The slag fraction was air-roasted at 850° C. and leached with NaOH to recover Na3VO4. (4) The leached solids received a dilute-H2SO4 leach to remove interfering impurities, chiefly Na2O and SiO2. (5) Titania was dissolved from the leached solids of step (4) by a H2SO4-bake followed by a water leach. (6) Titania was precipitated by seeding and boiling the resulting solution. The spent liquor was used for the dilute-H2SO4 leach in step (4). The following scheme was found to be technically feasible for recovering other byproducts of the process. (1) The gelled filtrate from the dilute-acid leach step was washed and dehydrated to produce a commercially acceptable silica gel. (2) The wash liquor containing sulfates of Na2O, Al2O3, Fe2O3, and TiO2 was combined with the highly alkaline filtrate from the wet-grind and metallic iron-separation steps, precipitating iron and titanium hydroxides, which were separated for special treatment. (3) Anhydrous Na2SO4 and Al2O3?3H2O were recoverable from the alkaline filtrate from step (2) by evaporation and carbonation, respectively, and the barren liquor was recycled to the magnetic-separation step.

Jan 1, 1952

By B. H. Clemmons

A field method has been devised for rapid determination of heavy minerals occurring in the unconsolidatod beach and dune sands. The method has been proved practical by usage in field evaluations of several hundred beach- and dune-sand samples in the Florida area. The simple equipment required and the techniques involved are described. Other data show that the method is relatively insensitive to variations in the mineralogical content or size distribution of the mixed heavy minerals contained in the samples tested. A modification of this procedure, found to be suitable for plant use in determining the relative purity of heavy-mineral flotation concentrates, is also described. A specific application is determination of the amount of feldspar-quartz in spodumene flotation concentrates. The results of the rapid evaluation techniques closely approximate those obtained by more precise laboratory procedures.

Jan 1, 1957

By J. W. Adams

Measurements of surface magnetic field noise were made at various locations over the Geneva Coal Mine near Price, Utah, on June 12, 1973. The locations selected were on the surface over emergency locator beacons underground at depths between 3S0 meters (1150 ft.) and 488 meters (1600 ft.). The surface terrain where these measurements were made was mountainous, and access was difficult. There were no power lines within several miles, and the weather was clear; therefore, the magnetic noise levels were about as low as will normally occur. Results of measurements of distant sferics indicate rather sharp cutoff frequencies below which broadband, impulsive noise is attenuated. The mechanism of propagation for this noise above the daytime cutoff frequency of 3500 Hz and the nighttime cutoff frequency of 1700 Hz is deduced to be a waveguide formed by the D or F layers of ionosphere as an upper plane and the earth as a lower plane.

Jan 1, 1974

By L. A. Stinnett

An investigation of hazardous surface openings of abandoned and inactive underground mines in the Black Hills area of South Dakota has revealed: (1) tracing legal ownership of mineral claims via county courthouses is confusing, complex, and oftentimes misleading, (2) in general, the selected mine openings in this investigation are to be considered relatively high in risks and hazard potential which poses a threat to the general public, (3) mine closure procedures and designs can generally be categorically implemented depending on the overall situation of the particular mine opening with subsequent unit costs estimates, (4) few preventive state or federal legal measures exist to date concerning mine closures, and (5) liability damages relating to mine opening accidents usually involve expensive and complex common law cases.

Jan 1, 1979