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By Benjamin W. Haynes

The Bureau of Mines conducted research to devise technology for increasing the Nation's mineral supply by recovering valuable constituents from currently discarded waste materials. Municipal solid waste (MSW), presently a major disposal problem, represents a significant source of metals, glass, and a combustible fraction that can be used to supplement coal in generating heat and electricity. As part of the total metallurgical system to treat MSW, this study evaluates the combustible fraction of MSW to characterize the various combustible components and to identify the principal sources of elements that eventually may be objectionable from corrosive or environmental considerations. Several possible sources for cadmium, chromium, cobalt, copper, lead, nickel, and zinc have been tentatively identified. These sources are pigments, inks, paper stock, and additives to plastics. A correlation between industry consumption values and measured concentrations in MSW was found for several elements.

Jan 1, 1978

By J. R. Hauger, P. A. Romans, W. J. Niebuhr

With suitable instrumentation and techniques it is possible to determine the presence of tantalum in columbium to 20 ppm . This paper discusses the selection of X- ray spectrographic instrumentation and describes a technique for accomplishing the low level determination of tantalum . An ion- exchange method of separating tantalum from columbium is also described .

Jan 1, 1964

By Peter Grandone, Ludwig Schmict

The injection of oil-field brimJs into subsurface formations containing mineralized water ·now is .recognizud as the most satisfactory and effective means of disposal in Kansas.· Other disposal ·methods, such as impounding brines in evapOTation nonds and controlled diversion into surface streams, have not prov-ed entirely successful, principally. because the volumes of brine to be disposed of were large, the soil f;?xtr~~mely porous, the net evaporation is low, and the rairiiall insufficient fc)r adequati.:~ dilution of the brine. The disposal of brine by subsurfaCE) inj'ection is often: more. expensive than by either of the above surface methods; nevertheless, surface dis:pos?,l ow.ing to the damaging effe-c.ts of· salt water to plant, animal and aquatic life and to potable water supplies has been:a long-continuing problem with many technical, economic, and 'legal·complexiti,2s

Aug 1, 1943

By F. E. Armstrong

Tritiated water has been used as a tracer to follow the path of leach liquids as they flow through a copper-mine dump. Semipermeable layers, produced within the dump by compaction and "stratification" of deposized dump material, restrict the vertical movement of water. Knowledge of this restriction would aid in the optimization of the leaching process. The portion of the dump of particular interest was approximately 2,000 feet long, 800 feet wide, and 200 feet high. A total of 94 curies of tritiated water was injected into the dump at the rate of 650 gpm over a period of 39 hours. The leach liquid was sampled at natural surface outflows and through a series of wells, some drilled to the bottom of the dump and others to intermediate levels. More than 3,300 samples were analyzed, most by liquid scintillation counting, but a few hundred by gas counting. Data obtained permitted calculation of flow paths, recycle times, total fluid volume, and estimates of retention times in various portions of the dump.

Jan 1, 1971

By H. E. Hilliard

A method was investigated for detecting and counting filamentous iron bacteria in open recirculating cooling systems. It is simple and fast and does not require trained microbiologists. Samples from 26 systems were examined. Cells were cultivated on commercially prepared ready-to-use media. Cultures grew well on this medium and were identified as filamentous iron bacteria by microscopic examination and by their ability to deposit iron using the prussian blue reaction.

Jan 1, 1976

By E. R. Palowitch, A. W. Deurbrouck

The Bureau of Mines reviewed available data on the effect of crushing high - sulfur coals for the liberation of impurities in the light of increasingly stringent air pollution regulations . The survey , which provided information on Appalachian region coals only , indicated that such important coalbeds as the Upper and Lower Freeport and the Upper Kittanning show significant sulfur reductions when crushed to 14 - mesh top size . For many other coalbeds amenability to sulfur liberation by crushing was indicated , although too few samples were available to draw firm conclusions .

Jan 1, 1966

By Kenneth H. Johnston

Information on oil and water production, volume of water injected, core analyses, and well completion data was collected on 28 Red Fork sand water-flood projects for comparison and evaluation of results. An average water injection efficiency of 35 percent, an average water-injected to oil-produced ratio of 16.8:1, and an average loss outside the flood pattern of approximately 45 percent of the injected fluid resulted in an oil recovery to January 1, 1969, of only 5.6 percent of the pore volume, or 9.1 percent of the initial stock-tank oil in place. The principal causes of poor oil recovery from these projects are the losses of large quantities of injection water from the flood patterns through oriented, natural fracture systems or zones of high permeability and excessive channeling of injection fluids from input wells to oil wells. For more efficient operation and a higher percentage of oil recovery from the Red Fork sand and other low-permeability-sand waterflood projects, directional orientation of both induced-and natural-fracture systems should be determined during early development. The success of a low-permeability-sand waterflood project depends to a large extent upon the orientation of the injection wells with the fracture system.

Jan 1, 1970

By William J. Campbell

The columbite-tantalite mineral series was studied by various instrumental techniques to establish the relationship of density to composition. The samples used were carefully selected to obtain a mineralogical purity of at least 98 percent. Impurities were determined by optical microscopy, X-ray diffraction, and optical and X-ray spectroscopy. Each sample was analyzed by fluorescent X-ray spectroscopy for iron, manganese, columbium (niobium), and tantalum. The existence of a unique relationship in this isomorphous series permits a simple correlation of the intensity of a spectral line with the concentration of the analytical element.

Jan 1, 1955

By Donald P. Blasko

The Bureau of Mines investigated two areas of oil and gas seeps in the north-central Gulf of Alaska--Katalla River to Bering River and Cape Yakataga to Yakutat Bay to determine (1) whether previously reported seeps are still active, (2) the characteristics of the seeping hydrocarbons, and (3) the amount of bitumen contained in the drainage leaving the seeps and entering the Gulf of Alaska. Thirteen separate oil seeps, six bitumen deposits, and eight gas seeps were located, sampled, and analyzed. The oils ranged from 35.2° to 14.1° API gravity and had sulfur contents from 0.53 to 1.31 wt-pct. Bitumen samples had API gravities from 2.4° to 14.6° and sulfur contents from 0.28 to 0.88 wt-pct. Gas samples had specific gravities ranging from 0.577 to 0.883 and caloric values from 724 to 1,427 Btu/cu ft. A total of 63 water samples obtained from seep locations and seep drainages were analyzed by atomic absorption spectrophotometry for ionic content and by solvent extraction for hydrocarbon content. Although some of the water at the oil seeps had a bitumen content as high as 246,000 mg/1, the amount of hydrocarbons actually reaching the Gulf of Alaska averaged <0.2 mg/1.

Jan 1, 1976

By A. W. Deurbrouck

The Bureau of Mines reviewed available data on the effect of crushing high-sulfur coals for the liberation of impurities in the light of increasingly stringent air pollution regulations. The survey, which provided information on Appalachian region coals only, indicated that such important coal- beds as the Upper and Lower Freeport and the Upper Kittanning show significant sulfur reductions when crushed to 14-mesh top size. For many other coalbeds amenability to sulfur liberation by crushing was indicated, although too few samples were available to draw firm conclusions,

Jan 1, 1966

By Ralph B. Adair

The Bureau of Mines conducted laboratory batch and small-scale continuous tests on samples of silt from the Nolichucky Reservoir near Greeneville, Tenn., to develop a process for the recovery of commercial-grade muscovite concentrates. Using a combination of Humphreys spirals for preconcentration followed by cationic flotation, 94.5 percent of the muscovite was recovered in a product containing 96.5 percent muscovite.

Jan 1, 1971

By L. H. Wullstein

Bureau of Mines research on methods for reclaiming land disturbed by the minerals sector of the economy has produced a specific procedure for effectively germinating seed of Indian ricegrass, a drought-tolerant plant valuable for reclaiming arid and semiarid sites. This report describes the procedure which consists of acid-treating the seed followed by temperature and light cycling treatments. Use of the procedure resulted in an average germination rate of 29 percent, ranging from 18 to 56 percent. Seed subjected to long cold treatment but with acid treatment yielded an average germination rate of 9.2 percent, ranging from 6.6 to 14.7 percent. Untreated seeds (controls) gave germination rates less than 0.1 percent.

Jan 1, 1979

By Manuel Gomez

Carbon number distributions were obtained for tar acid fractions from five low-temperature tars by low-ionizing voltage mass spectrometry. Quantitative data for phenols representing seven structural compound types were examined by statistical analysis. It was shown that for the phenols discussed, the data could be represented by regression equations expressing phenolic concentration as a function of the reciprocal of the carbon number and the carbon-to-hydrogen ratio of the parent coal. The total concentration of each structural type present was found to depend on the molecular weight and boiling point of the initial member of the group. Carbon distribution data for the tar acid fractions studied support the view that low-temperature tars contain the same chemical compounds but in different proportions.

Jan 1, 1965

By F. D. DeVaney

The supply of manganese is a subject of much interest. The idea of obtaining it from rhodochrosite-MnC03 is attractive because the carbonate is supposed not to be so contaminated with impurities as the commonly utilized oxides. Large bodies of rhodochrosite-bearing rock have been known for a long while to exist at Butte, Mont. Hence samples were obtained from that place. In the two samples examined quartz was the chief diluting substance. The leaner sample was about one half quartz; some copper, lead, zinc, and iron sulphides were also present. The rhodochrosite amounted to about 40 per cent, so that the sample had a tenor of about 20 per cent manganese. This sample was the subject of the examination reported herein.

Jan 1, 1928

By Alan H. Goode

The advancement of high-temperature drilling fluid technology for application in geothermal environments is part of the Bureau of Mines program for more efficient development of our Nation&apos;s energy resources. The bentonite constituent of water-base drilling fluids is sensitive to destabilization by high-temperature and salinity. A substitute material for bentonite, phosphate slime, which is reported to be saline resistant, was considered. These studies show that spray-dried slime suspensions have more favorable rheological behavior, but poorer filtration properties, as compared with bentonite suspensions.

Jan 1, 1975

By B. Dimitriades

Experimental work has been done to refine and to confirm an analytical procedure by which gas-liquid chromatographic (GLC) spectra are interpreted from retention time data alone. The rationale of this spectra interpretation technique involves whether or not a given peak invariably represents the same component or component mixture; if not, what factors influence changes in peak identifications. To answer these questions, peak-identification procedures, based mainly on the use of subtractive columns, were developed and applied to interpret GLC spectra of several exhaust (and fuel) samples.

Jan 1, 1972

By Geoffrey G. Huggins

Discussions are presented of the three phases of the noise reduction program on flight-type coal conveyors. The three phases are identification of noise sources, evaluation of potential noise reduction concepts, and implementation of noise reduction which is intended to reduce conveyor noise to less than 90 dB(A) in the underground mining environment. The major noise sources are impacts of the chain on the tail roller and on the top and bottom decks. A total noise reduction of 11 dB(A) was achieved by using techniques which are applicable to retrofit. These are a vibration isolated tail roller and an isolated wear strip on the return deck. A theoretical model of isolation provided by the isolated tail roller is developed. Appendices are presented which contain information on other potential concepts and additional data generated.

Jan 1, 1976

By H. W. Kilau

Thermodynamic calculations indicate that an electrochemical cell might serve as an analytical device for determining the composition of high-purity metals. An equation, readily derived, for the cell voltage, E, is as follows: [E I RT In F NFe unknown sample T of L NFe standard] The cell, however, must come to equilibrium, must be reversible, and must have no thermal effects or complicating side reactions whose magnitude is indeterminable. This Bureau of Mines investigation explores the feasibility of an electrochemical technique for the analysis of high-purity iron. Experiments were conducted using room-temperature aqueous cells and high-temperature molten salt cells. The room-temperature cells proved to be irreversible. The high-temperature cells utilizing FeCl2 and a eutectic mixture of KC1-LiCl were reversible, but did not attain a constant voltage necessary for analytical considerations.

Jan 1, 1963

By Rolland L. Blake

Petrographic and mineralogical studies were made on unoxidized samples from the Cuyuna and Mesabi districts to study occurrence and properties of the iron phyllosilicate minerals . Examination of 96 thin sections from the thinbedded facies of the main iron - formation of the Cuyuna district indicates that the most abundant minerals are Mn - Mg - siderite , stilpnome lane , and minnesotaite . Reconstitution and recrystallization of minerals has occurred along certain beds , and textures indicate that some minnesotaite apparently formed at expense of stilpnomelane . Three samples of stilpnome lane and one of minnesotaite were concentrated from fracture - fillings within iron- formation . Results of chemical , optical , spectrographic , X- ray diffraction , and differential thermal analyses on these samples are reported . The detection of ammonia in stilpnome lane samples is the first such occurrence reported , and its significance is discussed . New mineral data are presented on greenalite and probable septechamosite from the Mesabi district .

Jan 1, 1964

By Henry H. Ginsberg

The effectiveness of 0.01 pct. molybdenum, as ammonium molybdate impregnated on coal, on the hydrogenation of a high-volatile bituminous C coal at 8,000 p.s.i.g. and 460° to 480° C. has been studied in a pilot plant by the Federal Bureau of Mines. Under these conditions, the Bureau obtained 98 to 99 pct. conversion5/ of coal to liquids and gases at throughputs of 29 to 101 lb. of m.a.f. coal per cubic foot of reaction space per hour. At 460° C. the indicated yield of oil ranged from 63 pct. (based on m.a.f. coal) at a throughput of 35 lb./c.f.h. (pounds per cubic foot per hour) to 68.5 pct. at a throughput of 58 lb./c.f.h., and the yield of gaseous hydro-carbons ranged from 25.5 to 19 pct. at the same throughputs. The maximum measured yield of oil boiling under 325° C. was 47 pct.

Jan 1, 1960