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By Vernom F. Swanson, George E. Fish

A study was made during 1959-60 of reported nelsonite occurrences in Nelson and Amherst Counties, Va. The investigation was limited to core drill- ing on one deposit and beneficiation studies on three deposits. Three diamond-drill holes totaling 562 feet were drilled on the E. M. Hughes property to determine subsurface continuity. Although outcrops as much as 30 feet wide were present on this property, the only nelsonite intersected in the holes ranged from 4 to 18 inches thick. The ilmenite content of the core ranged from 50 to 75 percent. These nelsonite deposits are of secondary importance as a source of titanium, being small, rarely exceeding 1,500 feet in length and 30 feet in width, but they are high grade. Due to the proximity of some of the bodies it might be possible to mine several of them as one operation feeding one mill. Electromagnetic separation on composited samples recovered 83.0 percent of the Tio as an ilmenite concentrate in 68.5 percent of the weight. Two flotation procedures were developed. The first method, using oleic acid as a collector and fluo silicic acid as an apatite depressant on deslimed feed, produced an overall recovery of 59.3 percent in batch tests. The second procedure eliminated desliming. Laurylamine hydrochloride removed silicates in an acid pulp followed by an alkaline apatite flotation with oleic acid as the collector and dextrine as the ilmenite depressant. The ilmenite-rich tailing represented a 66.2-percent recovery of Tio in the batch tests.

Jan 1, 1964

By J. J. Demeter

A tube-wall reactor with a Raney nickel catalyst deposited on the outer wall of the tube by flame spraying is effective in the practically complete conversion of 3H2+1CO synthesis gas to a high-Btu gas (methane) at an hourly space velocity of 7,000 volumes of gas (NTP) per hour per volume of annular volume. Partially reacted synthesis gas containing an appreciable amount of methane can also be treated in this reactor to increase the heating value to over 900 Btu per cubic foot. Excellent heat removal through the metal wall to a coolant and temperature control were obtained. The heat transfer co-efficient from the catalyst to the coolant was about 275 Btu per hour per square foot per ° F. Synthesis tests were conducted with tubes 1.2 inches in ad by 6 inches long, and 1.3 inches in od by 36 inches long. When operating at a synthesis gas rate of 100 to 120 scfh per square foot of catalyst-coated tube, catalyst life was long enough to realize a catalyst cost for the raw Raney nickel alloy of about 0.3 cent per 1,000 cubic feet of pipeline gas (900 to 950 Btu per scf). Gas recycling at ratios of 1:1 to 3:1 was effective in increasing conversion and in extending the life of the catalyst to about 16 weeks. In cost and in operating characteristics the tube-wall reactor compares favorably with the fluidized-bed and hot-gas-recycle reactor systems for the synthesis of high-Btu gas from H2+CO.

Jan 1, 1967

By G. R. Peterson, K. E. Porter

The U.S. Bureau of Mines has estimated the potential availability of copper from 204 mines and deposits in market economy countries (MEC's). The evaluated properties have demonstrated resources totaling 436.4 million metric tons of contained copper and account for 90% of the Bureau of Mimes reserve base for copper in market economy countries. Total recoverable MEC copper resources are 340.8 million metric tons, 69% of which is from producing mines and 31% from nonproducing mines and deposits. Chile had the lowest estimated average total cost from producing mines of W.48 per pound of recoverable copper at a 0% discounted cash-flow rate of return (DCFROR), with estimated average total costs ranging from $0.40 to $0.81 per pound. The estimated average total cost of production, per pound of copper, for producing mines in the United States amounts to $0.57 in January 1988 dollars at a Wo DCFROR, with estimated total costs ranging from $0.36 to $0.85 per pound. In both real and nominal terms, the United States has, on average, significantly lowered its copper production costs since 1981. Rationalization of the industry and significant increases in productivity have made a strong improvement in the competitiveness of the U.S. copper industry to the extent that the United States should no longer be considered as a marginal producer of copper.

Jan 1, 1992

By S. J. Hussey

The Bureau of Mines investigated the applicability of carbon-in-pulp pro-cess for recovering silver from low-grade ores. The reasons for the research were (1) to illustrate a practical procedure for the process design of carbon-in-pulp adsorption circuits using leach slurries and simple equipment; and (2) to illustrate how equations of adsorption theory relating rate data and equilibrium adsorption curves can be helpful in process design. Carbon-in-pulp silver adsorption tests were made on Banner, Idaho; mine-run ore samples with silver contents ranging from 2.0 to 8.5 oz/ton and variations in cyanide leach extraction from 48 to 93 pet. The lower recoveries were attributed to the presence of complex silver sulfide minerals. Carbon-in-pulp batch adsorption tests provided rate data for the estimation of a silver equilibrium adsorption curve. Process design procedures in which the rate data were related to an equilibrium adsorption curvey by equations of adsorption theory were used to plan a four-stage pilot plant cascade. The pilot plant was successfully operated for 45 hr of countercurrent flow, producing a carbon product containing a mean silver loading of 571 oz/ton from a pregnant solution of 1.7 oz/ton of silver. Virtually all of the dissolved silver was recovered on the carbon.

Jan 1, 1978

By A. C. Fieldner

The Bureau of Mires in its investigations of gas masks for use in mines and allied industries has studied and developed various types of masks for protection against noxious uses and furies that may be present in atmospheres encountered in mines, metallurgical works, chemical and other industries. As a result of these investigations, the Bureau issued a schedule5 of tests under which manufacturer who voluntarily submit masks for examination and test, are issued an approval certificate for masks that meet the Bureau's specifications. In the Bureau's schedule, masks arc classified by types of gases removed, as type A masks for protection against acid gases; B; organic vapor; C, ammonia; D, carbon monoxide; E, smoke, dust, and mist; F, special gases; combination types, and type N, for protection in air against all gases, vapors, and smokes. The purpose of this paper is to describe the physical and chemical tests that were conducted on a type N mask, the protective principles and construction of the essential elements of the canister and attachments, and the uses and limitations of this type of mask. The mask tested is known as the all-service mask, manufactured by the Mine Safety Appliances Co., Pittsburgh, Pa;, and was approved (approval No. 1403) by the Bureau on July 1, 1924, for protection from all classes of poisonous vapors, gases and smokes in air.

Jan 1, 1925

By Sean Gallagher, Thomas R. Battenhouse, August J. Kwitowski, John R. Bartels, Dean H. Ambrose

Problem: Incident investigation reports do not usually contain enough information to aid in studying boom arm vertical speed for roof bolting machines to determine the impact that appendage speed had on an operator's risk of experiencing a contact. Laboratory experiments with human subjects are also not feasible because of safety and ethical issues. Method Researchers successfully developed a three-dimensional computer model that uses virtual human simulation software as the primary means to gather contact data when the boom arm touches the operator's hand, arm, head, or leg. Results: Data analysis of roof bolter simulations shows that the speed of the boom arm is the most important factor in determining the risk of an operator making contact. Regardless of other variables, contact incidents were always greater when the bolter arm was moving up, greater on the hand, and greater for the boom arm part of the machine. The reason why the subject experiences more contacts when the boom arm is moving up rather than down is that more risky behaviors occur during drilling and bolting when the boom arm is ascending. Based on the data collected, boom speeds greater than 13 in/sec result in a substantial increase in risk to the roof bolter operator of making contact. Speeds less than or equal to 13 in/sec are associated with a more modest relative risk of making contact, which represents a decrease in potential hazard. Impact on Industry: The use of such information can be quite helpful in making recommendations to machine design and task procedures to reduce the likelihood that roof bolter operators will experience injury due to contact with a moving roof bolting machine's boom arm.

By John P. Harmon

A group of organic chemicals, known as wetting agents, has been developed, primarily for use in the textile industry. These chemicals have the property of reducing the surface tension of water when mixed with it in very dilute solutions. The advantage of lowered surface tension is recognized in dust-control work, and several wetting agents, have been tried by dust-control engineers with varying degrees of success. It is well-known that certain solids, coal for instance, are extremely hard to wet with plain water because of the high surface tension of water and the water-repellent action of coal. If the surface tension of the water is reduced, it can be demonstrated that the coal can be wetted easily. This is accomplished practical and at law cost by dissolving a very small percentage of wetting agent in the water that is to be used for wetting purposes. (Care should be exercised in using a wetting agent to be sure that it will not interfere with a subsequent process.) For some time, the comparative efficiency of various wetting agents has been the subject of considerable work by dust-control men at coal mines, as well as by members of the Bureau of Mines 3/, 4/, 5/, 6/. In this connection, a number of samples of air-borne dust have been collected in the mines. With the exception of dust-control measures conditions of dust generation and dissemination were maintained as, nearly uniform as possible. Samples were collected when water alone was sprayed on the cutter bar of a mining machine; various wetting agents were then successively added to the water and more samples of air-borne dust were-collected.

Jan 1, 1946

By C. L. Brown

Coal has been transported by belt conveyors in mines for many years; however, only since the beginning of the general mechanization period have complete transportation system of this type been employed. Aside from my complete belt-conveyor transportation systems, belt conveyors are frequently used in conjunction with other transportation. Many early installations, for the most part, were made without standards as a guide. As a result, some States have outlined certain requirements based more or less on experience following mine fires. Correlation of these regulations should result in more uniformity in connection with standardization of regulations. The National Electrical manufacturers Association has published standards for mining-belt-conveyor installations2/ that should be helpful to the coal-mining industry generally. Bureau of Mines Schedule 2F3/ requires certain controls for permissible-belt- conveyor drives, and similar requirements are listed in Bureau of Mines bulletin 514.4/ Committees of the American Mining Congress have prepared much valuable information concerning operation of belt conveyors, and a subcommittee on fire-resistant belting has been active. 5/

Jan 1, 1956

By M. A. Reyes

This experiment investigated the effects of different machine mounted area lighting technologies on visual performance. The primary objective was to conduct a comparative evaluation of the lighting technologies based on the visual performance of thirty-six human subjects in a simulated underground mine environment. Incandescent (Incand), fluorescent (Fluor), and light-emitting diode (LED) technologies were used to create four lighting combinations. Visual performance was quantified for the detection of movement in the peripheral field of view and the identification of ground hazards. Measurements were made of the speed [response time measured in milliseconds (ms)], the accuracy (the number of targets and objects missed), and the subjective discomfort rating of the glare experienced for each lighting combination. A secondary objective explored the effects of aging on visual performance. The results indicate that lighting combinations which consisted of LED area lights significantly improved visual performance for the detection of hazards found in the peripheral field of view, as well as those found on the ground. They furthermore, indicate that age plays a significant role in visual performance.

Jan 1, 2009

By Fred D. DeVaney

Copper sulphate is a common flotation reagent for blonde ores. Metallic iron also is present in the mill circuit, and a reaction between the iron and the salt would be in accord with well-known chemistry. The abundance of metallic iron in a flotation food may be noted by even perfunctory examination. First of all the mine contributes metallic iron, then the coarse-crushing machines add their share, and finally the fine-grinding medium its portion. If the grinding is with cast-iron balls the amount of metallics is greater than when steel is used. Thus it, is that much more metallic iron is present than would be indicated by noting the ball consumption. An estimate that the total amount of metallics is twice that supplied by the balls and liners might not be far amiss. That copper sulphate plates out on iron in an acid solution is well known, but since flotation is practiced commonly in solutions where acid has not been added this reaction has not been given sufficient thought.

Jan 1, 1929

By M. H. Chetrick

An important factor in the design and operation of a lignite-gasification plant is knowledge of the thermal requirements. These not only vary with different-size plants but also with the operating conditions for a plant of given capacity. Thermal data have been collected since 1945 from a commercial-scale lignite-gasification pilot plant operated by the Bureau of Mines at Grand Forks, N. Dak. The description and operation of this plant and a study of the gas-composition data have already been described in previous reports (1, 2, 3, 4, 5).2) / This investigation was made to review the thermal data taken in tests and to correlate them in terms of the fraction of undecomposed steam and the H2:CO ratio.

Jan 1, 1953

By L. R. Burdick

Anthracite barley is considerably cheaper than rice. Its use, therefore, is attractive from a cost standpoint, - but its smaller size (through 3/16 inch over 3/32 inch round-mesh screen) makes it more difficult to use on some equipment when fairly high combustion rates are necessary to carry plant loads. Tests wore made in one plant to determine the performance of rice and various types of barley on a chain-grate stoker in a two-arch refractory furnace. In general, the efficiency and capacity increased with increased fuel size and volatile content. This performance is presented in tabular and curve form, together with a short review of the ignition and burning process on chain-grate stokers and a discussion of the operating procedures and limitations during the tests. In this particular installation, higher combustion rates and efficiencies could have been obtained with barley if the grate links had been designed for more uniform air flow through the grate surface. Careful maintenance and operation are particularly necessary for satisfactory results with barley on equipment not especially designed for its use.

Jan 1, 1950

By R. Hogg, T. F. Dumm, L. G. Austin, M. Yekeler

"Dedicated to Professor Kurt Leschonski on the occasion of his 60th birthdayAbstractThe kinetics of batch grinding quartz from a feed of 600 by 425 Jim to a product of 80% less than 10 µm have been determined using screening and laser diffractometer sizing for size analysis. The specific rates of breakage decreased by a factor of about three when the material became less than about 100 µm in size, but the primary breakage distribution function also changed to give proponionately more fine material, so that the grinding efficiency expressed as the development of surface area (B.E:T.) per unit of energy input did not decrease. Analysis of the shape of the particles in the 2S x 38 µm size range showed that particles of this size produced by roll crushing or by 8 minutes of grinding of a 42S x 600 µm feed were not different but at long grinding times the particles were rounded. This suggests that the breakage mechanism changes to give more chipping and abrasion and less disintegrative fracture. As the material approached the ultrafine size range it adhered to the mill case and there was no further size reduction. However, a technique for striking the mill case to dislodge the particles was successful in allowing further grinding to 400Jo by weight less than 2 µm.1 IntroductionIt has long been known that it is difficult to accomplish ultrafme grinding in a tumbling ball mill. It has been reported [12, 13] that there is no further size reduction after some hours of grinding cement clinker in laboratory ball mills. Austin and Bagga (1] and Shah and Austin [16] have given an analysis of the kinetics of dry grinding in a laboratory ball mill, introducing the concept of a slowing-down factor K, which is the ratio of the specific rates of breakage at some long time of grinding to the normal specific rates of breakage. They showed that this factor decreased as fine material accumulated in the mill charge. Cottaar and co-workers [8-10] showed that the movement of solid in a dry laboratory ball mill was influenced by the fineness of the solid and by the presence of air, and that evacuation of air from the mill caused particle sedimentation and low rates of breakage.The concept of the slowing-down factor has also been used in wet grinding [17, 18]. At very .high slurry concentrations it appears to be correlated with a steady decrease of mill power caused by the build up of a layer of deposit sticking to the mill case. This reduces the effective mill diameter and, eventually, the balls start to adhere in the layer and centrifuge. A decrease of mill power always indicates less lifting and tumbling of the media and, hence, less breakage. However, slowing-down of breakage rates was also observed at lower slurry concentrations where there was no change in mill power."

Jan 1, 1990

By R. V. Ramani, S. Shankar

"The phenomenon of re-entrainment is seen in environments such as sand dune formation, soil erosion, fugitive dust emission and the spread of radionuclides from accidents involving nuclear weapons. A thorough review of existing literature reveals that work on re-entrainment of dust in mine atmospheres is scant. The present study was undertaken as a part of ongoing research at the Generic Mineral Technology Center on Respirable Dust at the Pennsylvania State University on the development of methods to predict ambient dust concentrations in mine atmospheres (Ramani, 1983). The contribution of re-entrainment to the spatial and temporal concentration of dust in mine airways is being studied. The research has included wind tunnel and in-mine studies.A set of seven experiments was performed under controlled conditions in the US Bureau of Mines' Lake Lynn Laboratory mine. Two types of source coal dust, anthracite and bituminous, were subjected to various airflow rates and were subjected to walking by two different individuals. Six sets of instruments were used along the test section for sampling airborne particles. The average air velocity just above the coal dust bed varied between 2.1 to 3.2 m/sec.Due to re-entrainment as a result of the airflow conditions, the average respirable dust concentration in the center of the mine airway increased to 0.09 mg!m3 (standard deviation= 0.03 mg/m3)from an initial value of 0.02 mg/m3. The concentration of all (total) airborne dust increased to 0.17 mg/m3 (standard deviation = 0.10 mg/m3) from an initial value of 0. 02 mg/m3. The action of people walking, however, caused higher amounts of re-entrainment. The average concentration of respirable and total dust at the center of the mine airway increased to values of 0. 28 mg/m3 (standard deviation of 0.12 mg/m3) and 1.53 mg/m3 (standard deviation of 1.0 mg/m3), from initial values of 0.03 and 0.05 mg/m3, respectively. Jr was observed that the dust concentrations were much higher near the floor, immediately at the end of the coal-dust bed.Depending on the level of activity and the amount of dust deposited in the mine airways, re-entrainment may become an important source of airborne dust in areas away from the point of actual mining."

Dec 1, 1996

By H. Dale Nichols

[The growing importance of the Sundence (Jurassic) formation an a source of oil, in the Rocky Mountain area has prompted the making of a series of porosity determinations of core samples collected. from the reservoir sands of the Lance Creek oil field, Niobrara. County, Wyo. These analyses are preliminary to a stud of fluid and energy relations in the Basal Sundance reservoir of that field, and the determinations of porosity will be used in subsequent studies requiring, calculations of the volumetric capacity of the reservoir and estimation of the reserves of oil and gas. However, the porosity characteristics an of the Sundance sands in the Lance Creek field are factory that affect the solution of many current practical problems of development and operation. Primarily for that reason but also because it is recognized that porosity values of different oil-production sands are of widespread interest throughout the industry, the results of the initial work have been presented in tabular and graphic form with no attempt to evaluate their significance as they relate to the production history of the field.]

Jan 1, 1938

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) spin trapping methodology has been used to study the reactions of manganese dusts with glutathione, employing a-{4-pyridyl-1-oxide)·N-tert-butyl-nitrone (PBN) and 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as spin traps. The results show evidence for the glutathionyl radical formation in the reactions of both MnO2 and manganese (Ill) acetate with glutathione. Based on these experimental observations, we hypothesise that the mechanism of neurotoxic effects of manganese might be due to the fact that the generation of glutathionyl radicals depletes the glutathione pool and reduces the glutathione shield against free radical products of dopamine metabolism and manganese induced reactive oxygenated species. IntroductionExposure to manganese compounds often occurs as the result of foundries and mining operations (1. 2). Other significant sources of environmental manganese include coal-fired power plants and burning of residual and crude oil (3, 4). Lately gasoline combustion has also started to contribute since manganese (methyl cyclopentadienyl manganese tricarbonyl. 0. 125 g/gallon) is being used instead of lead as an antiknock ingredient in automobile fuels (5. 6). Although manganese is an essential element in certain biological processes it is toxic in excessive amounts. The manganese toxicity is mainly associated with the nervous system (7-9). Symptoms frequently observed in manganese poisoning or manganism are disorientation, memory loss, anxiety, compulsive laughing and crying, mask-like faces, akincsia rigidity and tremor (10). In spite of numerous investigations to understand the mechanism of manganese induced injury. it has not been possible to localize the initial chemical lesion responsible for altered physiology and ultimate cell death. This may perhaps he the reason for failure in developing a successful therapy for manganese intoxication."

Jan 1, 1990

By Lloyd R. Michels, Burke Cartwright, S. F. Ravitz

"INTRODUCTION Frequent attempts have be,made in the electrolysis of molten magnesium chloride to regenerate the electrolyte by allowing the chlorice generated at the anwdo to read with magnesium oxide and carbon within the melt according to the following reactions: (1) MgO + C + CL2 = MgCl2 + CO,(2) 2MgO + C + 2C12 = 2MgC12. + CO2.The principal advantages of such a procedure are that (1) the direct source of magnesium is magnesium oxide rather than the more expensive dehydrated magnesium chloride and (2) it is not necessary to handle or dispose of large quantities of chlorine or hydogen chloride.Grätzll 5/ proposed the use of an MgO carbon feed in a more or,less compact form in the anode compartment, of the cell. In a patent issued to Magall Aktiengecellschaft, 6/ a compact mixture of MgO and carbon is used as the anode itself. Kato 7/ and Backer 8/ add the feed in finely divided form to the surface of the anode compartment. The Bureau of Mines 2/ recently made a pilot-plant investigation of the electrolysis of suspension of MgO and carbon from chloride melts, in which it was found that although,current efficiencies of 60 to 70 percent were obtainable, the formation of sludges containing MgO, carbon, and magnesium seriously interfered with the operation of the cell,"

Apr 1, 1945

By M. Townsend, E. L. Petsonk, H. Abrons, E. Daniloff, K. Kinsley

Workers exposed to certain inhaled dusts may show increased levels of nonspecific airways responsiveness (AR). In some studies, cigarette smokers have also been reported to have increased levels of AR. As part of an ongoing study, we compared the results of preshift methacholine inhalation challenge, spirometry, and smoking and occupational histories, in 191 under-ground bituminous coal miners (M) and 215 non-mining control workers· (C) . All M and c were selected to have normal baseline% predicted FEVI (PPFEV). Mining tenure was recorded as years worked underground (YRUG) and at the coal face (YRFC). AR was assessed as the% decrease in FEVI from baseline divided by the dose of methacholine delivered. M reported similar years smoked (YRSM) but fewer pack-years* (PY) than c~ Overall, both increasing YRSM and PY were associated with more AR*. Smoking C* but not M showed increased AR with increasing PY. In smoking and nonsmoking M, baseline AR and PPFEV showed no association with YRUG. The level of AR was inversely related to YRFC*, possibly representing selection away from dustier jobs. AR was inversely correlated with PPFEV*. In this study, AR and baseline PPFEV were not significantly associated with mining tenure, but cigarette smoking was related to both baseline lung function and level of AR. * p < 0.05 (Supported in part by Grant Gll35142, us Bureau of Mines, Generic Mineral Technology Center for Respirable Dust.)

Jan 1, 1989

By William G. Gruzenaky

The separation of yttrium and the individual rare-earth elements (lanthanons) from mixtures in which they occur has been a difficult problem through-out the years. Because of the increased interest in the various uses of these metals, the economy of their production may become of great importance. Studies relative to this problem, undertaken at the Federal Bureau of Mines Albany Metallurgy Research Center, resulted in the development of a solvent extraction method by which yttrium can be separated from the rare-earth metals. A separation factor of 10.93 was obtained between yttrium and cerium from a single-stage extraction, and a factor of 1.78 was obtained between yttrium and erbium from a multistage system. The valuable metals were extracted from euxenite by caustic soda fusion or by chlorination, and several separation methods were investigated. Partial separation of the yttrium and rare-earth element fraction was made by chemical methods and by solvent extraction. Thermal decomposition of aqueous rare-earth nitrates or selective ignition of yttrium and rare-earth oxalates yielded a fraction enriched in cerium. A fraction enriched in the light rare-earth elements resulted from a double sulfate precipitation, whereas a potassium ferrocyanide pr cipitation yielded a fraction enriched in yttrium. Precipitation with dimethyl phosphate yielded a fraction enriched in yttrium and heavy rare-earth elements. Enriched fractions were obtained with several solvent extraction systems. A system consisting of rare-earth nitrates, nitric acid, and tri-n-butylamine-3 methyl-2-butanone favored the separation of yttrium from the heavy as well as from the light rare-earth elements.

Jan 1, 1961

By John J. Mulligan

Lead-silver deposits in the Omilak area, on the western slopes of the Darby Mountains, Seward Peninsula, Alaska, were investigated by the Bureau of Mines, during the 1953 and 1954 field seasons, as a part of the U.S. Department of Interior&apos;s continuing program for the development of Alaska&apos;s resources. The Omilak area was the scene of early day prospecting and mining activity. The Omilak mine, which operated from 1881 to 1890, was the second producing lode mine in Alaska; the first was a small gold mine near Sitka. Several hundred tons of ore were produced at the Omilak mina; as an indication of grade, 41 tons shipped from Omilak in 1889 contained 75 percent lead and 142 ounces of silver per ton. A prominent, nearby occurrence of lead-silver minerals, found but not explored during this period, has since become known as the Foster prospect. Subsequent exploration of this prospect revealed an abundance of massive galena occurring on an outcrop and as float scattered through limestone talus. Evidence of lead deposition, together with the generally high silver content of lead ores previously shipped from the district, indicated that deposits might be found which would be commercially valuable even in this remote area. To investigate the possibility, the Bureau of Mines made a reconnaissance of the Omilak area and did bulldozer trenching, diamond core drilling, and sampling at the roster prospect. Data resulting from the investigation are presented in detail in this report and are summarized in the following paragraphs.

Jan 1, 1962