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By Walter G. Dupree

When the original version of this study was published in 1972 it was evident that a problem was developing on the energy scene. The ability of the United States to find the energy supplies it needed within its own boundaries--at least in the forms desired--was declining. Production of crude oil in the United States had peaked in 1970 and was declining slowly; environmental restrictions had begun to hamper the production and consumption of high sulfur coal; natural gas reserves were beginning to dwindle; and the development of nuclear power was proceeding more slowly than originally planned. Shortfalls in energy supply were being met through the importation of increasingly larger quantities of petroleum, but supplies were adequate and the price of the imports was below that of domestic production. The energy problem was more prospective than current. In October of 1973 the prospective problem became the "Energy Crisis' when the Arab petroleum exporting countries reduced crude oil production, imposed an embargo on the shipment of crude oil to the United States, and then raised the price of crude oil in a series of large steps. This crisis was a clear demonstration of the dangers of the dependence of the United States on imported petroleum, and of the Nation's vulnerability to the actions of the oil exporting countries. After the embargo was lifted, attention shifted to the immediate hardships resulting from the higher prices for gasoline, fuel, and electricity,

Jan 1, 1975

By E. D. Eastman

"The factors that determine the efficiency of reduction of iron oxides by gaseous reducing agents may be considered in two classes; those which effect the equilibrium between the reacting substances end their products, and those which affect the rete of reaction. Both sets are of prectical importance, the former as influencing the maximum possible efficiency and the latter as determining what fraction of the maximum yield may be readily or profitably obtained. In addition, the thermal changes attending the reduction greatly affect the chance of successful industrial application of any such process, and knowledge of them is necessary for the intelligent design of apparatus and control of the reaction. Some aspects of each of these three divisions of the problem are discussed below.I. The Maximum Reducing Power of Fuel Gases on the Oxides of IronsThe gases that heve been considered specifically in this work are coal gas, water gas and producer gas, typical analyses” of which are given in Table 1 Of the various hydrocarbons represented in Table 1, (several being grouped or averaged as C2R4), methane is the only gas assumed to be capable of existence at appreciable pressures under the conditions of interest here. The equilibria in the several systems which may ensue when one of the above gases is allowed to react with the iron oxides, may therefore be represented in the most general case by equations of the type of the following arbitrarily chosen ones:"

Jun 1, 1923

By Daryl R. Tweeton

The Bureau of Mines compared the effects of surface-active chemicals with those of pure water on core-drilling rock and quartz and on fracturing quartz. The objectives were to determine if these chemicals assist drilling and fracturing rock and if zeta potential control was worth pursuing as an aid to full-scale drilling. All tests were performed in the laboratory. No significant increases in drilling rates were observed for 1 to 10,000 ppm Al (as AlC13) in flushing water when drilling microcline or serpentine, nor for 1 to 10,000 ppm Mg (as MgC12) when drilling microcline or marble. Concentrations near those giving a zero zeta potential were used with microcline and marble. A 50-pct rate increase was observed for drilling quartz in 0.7 ppm oleylammonium acetate, which gave a zero zeta potential. No other concentrations were used. No effect on the tensile strength of quartz thread in 0.05 ppm Al (as AlC13), which gave a zero zeta potential, was observed. Heptanol, reported to give a zero zeta potential on quartz, did not reduce the bending strength of small quartz bars below that in water. These generally negative findings raise doubt about the usefulness of zeta potential control in full-scale drilling. The results, combined with previous studies, suggest that controlling physical properties of drilling fluids, such as viscosity, is more useful than altering chemical properties.

Jan 1, 1976

By L. R. Fisher

The purpose of this investigation was twofold: (1) To devise a rapid method for determining quantitatively the porphyrin-carboxylic acid content of a particular crude-oil porphyrin aggregate, and (2) to isolate porphyrins in the crystalline state from crude-oil porphyrin aggregates. The first purpose was accomplished by applying adsorption chromatography. In fulfillment of the second aim three different crystalline porphyries were isolated by methods which involved both adsorption chromatography and fractionation of benzene solutions with hydrochloric acid of varying strength. The three porphyrins had etio, rhodo-, and phyllo-type absorption spectra, respectively. INTRODUCTION Many samples of petroleum have, as interesting minor constituents, chemical compounds known as metalloporphyrins. Their presence in crude oil and other bituminous materials was first discovered by Treibs a quarter century ago. Much experimental work has been done on metalloporphyrins because of their importance to the petroleum industry. They have a deleterious effect on refining catalysts. The ash resulting from the burning of heavy fuel oil is very reactive, We to the presence of metallic constituents, particularly vanadium. In oil-fired gas turbines, the ash may build up on the blades, causing imbalance of the rotors and, in addition, severe corrosion. In industrial boilers, the ash residue is responsible for severe damage to boiler tubes and to the refractory brickwork (15).4 Through study of the chemical constitution of the various metalloporphyrins found in petroleum, much can be learned concerning the origin, migration, and history of crude oils.

Jan 1, 1961

By H. R. Appell

The Bureau of Mines studied the conversion of a variety of cellulosic wastes, for example, sawdust, bovine manure, sewage sludge, urban refuse (free of metal and ceramics), etc., to heavy oils. The objective of the investigation was to determine the scope of the reaction and elucidate the chemistry involved. The reactions took place in the presence of synthesis gas and water or carbon monoxide and water under conditions of elevated temperatures and pressures. Waste conversions above 90 pct, often near 99 pct, with oil yields in the range of 40 to 60 pct, were obtained in the temperature range of 250° to 425° C and pressure range of 1,500 to 4,000 psig. Because mild conditions were sought, most of the experiments were conducted at temperatures of 250° to 350° C and pressures of 1,500 to 3,000 psig. In general, lower viscosity products were obtained at higher reaction temperatures. Conversions and oil yields were significantly increased by operating in the presence of a high-boiling oil; either anthracene oil or oil recycled from the process was satisfactory. Synthesis gas containing 50 pct carbon monoxide gave satisfactory results as a replacement for carbon monoxide. Cobalt molybdate on alumina catalyst, used with sodium carbonate, gave a product of lower viscosity and lower oxygen content than sodium carbonate used as the sole catalyst. The waste-to-oil process has been successfully investigated in continuous flow equipment as well as in batch autoclaves.

Jan 1, 1975

By W. L. O'Brien, E. A. Rowe

Electrorefined vanadium with additions of up to 5 percent by weight of yttrium, cerium , lanthanum , praseodymium, neodymium, and samarium was melted to ingots in a nonconsumable electrode arc in a helium atmosphere . The ingots were rolled into strips and evaluated for the effect of the alloying elements on hardness , tensile strength , ductility , recrystallization temperature , and microstructure . Except for samarium , average additions of alloying elements of 1 to 2 weight - percent resulted in the retention of 0.12 to 1.05 weight - percent in the alloys and reduced the ultimate tensile strength from about 48,000 to approximately 30,600 psi . The corresponding yield stress (0.2 percent offset ) was reduced from about 40,700 to approximately 20 , 200 psi . Diamond pyramid hardness (DPH) was reduced from 117 to an average of 62 kg /mm² . Increased malleability at room temperature resulted with yttrium and all rare - earth- metal additions , except samarium , particularly with more than 0.25 weight - percent additions . Decreasing oxygen contents corresponded with the changes noted in the mechanical properties of the alloys . The recrystallization temperature of electrorefined vanadium was reduced from approximately 950 ° to 800 ° C. Yttrium or a rare- earth metal content , except samarium , in excess of 0.1 weight - percent in vanadium produced a second phase suggestive of an eutectic which indicated a possible maximum solubility of less than 0.1 weight - percent for both room and elevated temperatures .

Jan 1, 1964

By G. W. Jones, I. Spolan

"INTRODUCTION The operation of internal-combustion engines at high altitudes and the general aspects of combustion processes in rarefied atmospheres have created considerable interest in the problem of ignition and flame propagation at low pressures. Nuckolls, Matson, and Dufour 4/ have published results on the effect of low pressures on the propagation of flame in gasoline vapor-air mixtures in vessels of large capacity. The volumes of their test equipment varied in capacity from 0.425 to 125 cubic feet. Various sources of ignition were employed. These authors found that the explosive range of gasoline vapor in air decreases with decreasing pressure at pressures considerably below atmospheric, until a limiting absolute pressure of about 33 mm. mercury at ordinary temperature is reached, at which point no appreciable flame is propagated.Experiments carried out at the Bureau with natural gas-air mixtures at reduced pressures have shown 5/ that the limits of inflammability are but little affected at reduced pressures down to 175 mm. mercury. As the pressures of natural gas-air mixtures are reduced below atmospheric, the mixtures become more difficult to ignite; however, if a suitable source of ignition is employed, the limits of inflammability are as wide at 175 mm. mercury absolute pressure as they are at atmospheric pressure. In view of these observations with natural gas-air mixtures, it appears important to investigate gasoline vapor-air mixtures for possible similar behavior. For this reason the tests herein described were carried-out."

Oct 1, 1946

By BUREAU OF MINES

The cheapest method of handling gravel in placer mining operations is by hydraulic mining . In working gravel deposits by hydraulic mining , it is essential that an abundant supply of water under sufficient head can be economically developed and that there is sufficient grade for sluice boxes and for disposal of the tailing . Without dumping facilities , simple hydraulic mining is an impossibility . The cost of hydraulic mining may range from 2 cents a yard under favorable condıtions to 12 or even 20 cents under less favorable conditions and to 35 cents or more a yard in Alaska , according to conditions of operation , and if frozen gravel is encountered . When it is necessary to elevate gravel , the costs may exceed 60 cents a cubic yard . When the natural conditions do not permit of hydraulic pining proper , other methods of elevating the grade are employed , some of which are described below . Bucket dredging has replaced hydraulic mining in importance in California and other states where hydraulic mining was once extensively carried on , and is by far the cheapest method of elevating gravel when mechanical methods are required and the physical conditions are suitable for dredging . Dredging costs vary greatly under the different conditions encountered , and the total amount of gold to be recovered must of course be enough to warrant the cost of a dredge installation . Gold dredging operations in the United States are fully described in Bull . 127 , U.S. Bureau of Mines .

Jan 1, 1922

By Clyde E. Williams

[As a results of work conducted during the past three years, the Northwest Experiment Station of the Bureau of Mines, in cooperation with the University of Washington at Seattle, Washington, has developed a process for the production of sponge iron. Commercial operation of this process in a 3 to 4-ton scale has been so satisfactory that its use on a large scale (20 to 100 tons per day) can be safely considered. Description of Process. The process consists in passing a mixture of iron ore and coal through a rotating kiln heated at one end to a temperature sufficient to convert iron oxide to metallic iron, discharging, cooling, and separating the sponge iron from the residual coke and silicious material on a magnetic separator. Both the coal and the ore should be crushed to peso as 6-meth scream, tans producing particles finer then 1/12 of an inch. Seventy-five parts of coal or other carbonaceous material arc charged with every 100 parts of ore), This large amount of coal is required in order to supply sufficient carbon to maintain a strongly reducing atmosphere in the charge, but may be reduced to about 65 parts per 100 parts of ore by recovering and using tae carbon that remains in the discharge product. Large-scale operation and refinements in furnace design should lower this ratio to perhaps 56 or 60 parts of coal to 100 parts of ore.]

Jan 1, 1924

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

A. 3 Program Description The computer program developed to simulate events in the case of fire in the mine is described in this section The description is divided into three parts. 1. Program Capabilities This part summarizes what inputs can be changed, what outputs can be obtained and demonstrates program flexibility through suggested uses.

Jan 1, 1976

To improve electrical safety and lengthen light bulb life on trolley haulageways. Approach A resistor inserted in series with each pair of light bulbs, decreases the voltage applied to the bulbs and eliminates heavy arcing when voltages rise. How It Works Under certain conditions, incandescent light bulbs connected directly to a 300-volt d-c trolley wire can be a hazard, particularly during weekends when electrical equipment is nut in use. When little electrical power is being used, the voltage (on the trolley lines and at the substation) can rise to a value which will destroy the bulb filament, cause arcing, and damage the bulb holder. In one coal mine where light bulbs in certain locations fre¬quently failed, the problem was overcome by inserting a 100-ohm, 50-watt resistor in series with each pair of light bulbs. The light bulbs are rated at 300-volts and 100-watts. Figure 1 shows the light bulbs and resistor circuit. This resistance was added in order to reduce the current through a short circuited bulb holder, from several hundred amperes to a much safer value of 3 amperes. However, the resistor in series with each pair of light bulbs, also reduces the voltage across the lighted bulbs to approximately 240 volts during periods when the trolley line voltage is up to 300 volts. With this arrangement, no light bulb failures occurred over a 6-month period. The resulting light reduction has not been objectionable.

Jan 1, 1976

By C. S. Compton, T. E. Marshall, D. R. Dolinar, R. Grau, L. J. Prosser, A. T. Iannacchione, D. C. Oyler

Unrecognized roof beam failures resulted in 69% of the falls of ground injuries occurring in underground U.S. stone mines from 1990 to 1996. Field investigations at 45 underground stone mines suggest that excessive beam sag or deflection is the principal unstable roof behavior characteristics associated with miner injuries. Laminated roof structures, common in most underground stone mines, allow the immediate roof to separate into distinct beams. The timely determination of roof beam deflection could provide stone miners with advanced knowledge of potentially hazardous roof. Existing methods to assess roof conditions consist of observational and monitoring techniques. Observational techniques include open drillholes, sounding, wedging, and borescopes. Monitoring techniques include scratch tools, extensometers, telltales, Miners Helpers, and Guardian Angels'. Miners have difficulty utilizing these techniques because roof beams are located an average of 8 m (26.5 ft) above the miner's head in environments that are dark, dusty and noisy and these deflections are measured in millimeters of movement. To help mitigate the potential for falls of ground injuries to underground stone miners, the National Institute for Occupational Safety and Health (NIOSH) has developed the Roof Monitoring Safety System (RMSS) to aid in monitoring dangerous levels of roof beam deflection. If enough site-specific information is collected and placed on highly visible maps, individual mining operations could establish general guidelines for responding to specific roof beam deflection occurrences. This would help in implementing a pro-active, comprehensive roof control plan for reducing falls of ground injuries.

By Van H. Manning

PETROLEUM INVESTIGATIONS. The work of the petroleum division of the Bureau of Mines during the period of the war was under the supervision of Chester Naramore, chief petroleum technologist. In its petroleum investigations the bureau cooperated freely with other Government bureaus and acted as a source of information on petroleum matters. COOPERATIVE WORK ON INTERALLIED PETROLEUM COMMISSION. On July 15, 1918, Mr. Naramore and W. E. Perdew, chemical en- gineer of the bureau, left for London to act as representatives of the United States Fuel Administration and the United States Shipping Board on the Inter-allied Petroleum Commission. Numerous con- ferences were held with representatives from France, England, and Italy on specifications and requirements of the various allied Govern- ments for petroleum products, and for this purpose meetings were held in London, Paris, and Rome. EXAMINATION OF PETROLEUM FACILITIES IN FRANCE. The storage facilities and the transportation system in France were studied, and recommendations based on the information gained were made to the director of the oil division of the Fuel Administra- tion and to the chairman of the Shipping Board. Refinery plants in France were inspected, as well as filling stations and shipping facilities from ports in France and Italy to the various fronts and the petroleum base of the American Expeditionary Force at Romorantin. France. At the request of Ambassador Sharp, a re- port was prepared on the advisability of developing the petroleum resources in France.

Jun 1, 1919

By Lon D. Santis

This paper presents data and theorem to calculate the risk of experiencing undesirable lightning related events while blasting or while engaged in other lightning sensitive activities. The paper provides an overview of lightning hazards in blasting operations and a brief history of lightning related blasting accidents. Lightning continues to be the primary cause of premature initiations of explosives in mining, on average, over two such incidents are reported to the Mine Safety and Health Administration (MSHA) each year. The energy contained in lightning discharges and how this energy sets off explosives in mining is presented. Three categories of lightning warning methods: public media, lightning detectors, and atmospheric electrostatic field measurement are discussed. The remainder of the paper presents recently acquired data on the spatial characteristics of lightning development. This data is used to estimate the risk assumed by blasters under certain conditions. Risk estimations are made for electric and nonelectric blasting if persons are evacuated when cloud-to-ground (c-g) lightning approaches within a certain distance. For example, about 0.6% of all c-g lightning strikes have no other c-g lightning strikes within 25 miles in the previous 30 minutes. The paper shows that a typical blaster using nonelectric initiation in a high lightning density area with a 100% accurate lightning detector set to alarm at 25 miles would have a lightning caused unplanned detonation every 14,000 years

By Lloyd A. Morley, Robert Stefanko

In the context of the following report, an hazardous location can be described as any industrial area in/which flammable or explosive gases, vapors, and dusts can be encountered. When electrical apparatus is used in such hazardous atmospheres, the chance of a dust or gas ignition is ever present. Consequently, in an effort to reduce the ignition hazard, several protection systems have been devised. Such systems are termed electrical hazard reduction techniques. The most widely accepted and used of these, the explosion-proof enclosure, is the principal subject of this report. However, other techniques are briefly mentioned. Hazard reduction techniques used in coal mine atmospheres (which can contain methane, coal dust, and air mixtures) are classified as Group I. The explosion-proof enclosure commonly used in mines is defined by the USBM Schedule 2G as a device that can contain internal explosions of methane-air mixtures without undergoing damage or excessive distortion and without an ignition of a surrounding methane-air mixture or discharge of flame. (100) Internationally, the definition remains the same except the words "discharge of flame" are not present. (4,5,31,42,52,76,102) The latter description often refers to flame-roof enclosure construction, but the terms "flameproof: and "explosion-proof" commonly have the same connotation. These enclosures which may not be vapor tight, are distinguished by heavy-wall cast or welded construction and bolted or threaded close fitting flanges. Explosion-proof enclosure techniques have been utilized in U.S.

Jan 1, 1974

By P. Kovalchik, S. Peng, G. Cole, R. Matetic

Previous studies conducted by the National Institute for Occupational Safety and Health (NIOSH) have shown that approximately 90 percent of coal miners and 49 percent of metal/nonmetal miners had a hearing impairment by age 50 (Franks, 1997). Mine workers are exposed to additional noise levels underground due to the reflection of machine-generated noise that would otherwise dissipate in an aboveground setting. Determining the sound-absorption coefficients is essential in modeling the sound field in an underground mining environment. Sound absorption is a measure of the amount of acoustic energy that strikes a surface and is absorbed rather than being reflected. The acoustic environment that mining machines operate in is a critical factor affecting the sound pressure level exposure for mining machine operators. Impedance tube testing is an inappropriate method for determining underground absorption coefficients due to the brittle composition of materials such as coal and slate. Classic absorption coefficient estimation using T60 measurements will not work well in an underground environment because the theory assumes a finite room, a diffuse field and a relatively uniform absorption. None of these assumptions are true in an open-ended mine entry. This paper presents a method using a ray-tracing technique to determine absorption coefficients for underground mines. Absorption coefficients are determined and presented for octave bands from 63 Hz to 8 kHz. The absorption coefficients are essential for determining and predicting potential overexposure to machine operators in different mine environments.1

By Frank J. Susko

The U.S. Bureau of Mines is developing a process for removing metals from mining and mineral processing waste streams by precipitation. The precipitation process is accelerated by flocculation when a high molecular weight polymer is added. Infrared (IR) studies were performed on zinc hydroxide [Zn(OH);J, copper hydroxide [Cu(OH);J, and zinc sulfide (ZnS) flocculated with both non ionic and anionic polyacrylamide (PAM) and polyethylene oxide (PEO). The IR data were compared with general trends in the performance of the polymers observed during flocculation. These studies will help to understand the bonding between the precipitate and polymer and indicate the effectiveness of a flocculant for dewatering. Two types of bands showed up on the IR spectra; one type described the interlayer water of the flocs, the other described the organic bonds of the polymers. A general decrease in the areas of the three water bands, hydroxyl (O-H) stretching (3,200-3,500 cm-1), water bending (1,610-1,630 cm-1), and torsional oscillations (600-700 cm-1), indicate interlayer water being driven off, which is a favorable condition in flocculation. Shifts in the O-H stretching band indicate water bridging between the precipitate and polymer. Shifts in the amine (N-H) deformation, carbon-nitrogen (C-N) stretch band (1,600-1,610 cm-1) indicate the amine group of the PAM is involved in the bonding. Evidence suggests that ether oxygen of PEO is also involved in the bonding process.

Jan 1, 1990

To develop a system which will effectively detect and extinguish fires in underground fueling areas while also providing a warning for nearby miners. Approach A system involving optical fire sensors. automatically-released dry chemical and aqueous film-forming fluid (AFFF) fire suppressants, and automatic alarms was designed from off-the-shelf, state-of-the-art components, and was in-mine tested at two mines in the two typical underground fueling area situations: fuel transfer areas and fuel storage areas. How It Works As mines become more mechanized, the number of fire hazards increases since fueling areas are more abundant. Fire hazards are especially serious in deep mines, since escape time is longer. To help solve this growing problem, the Bureau of Mines, in cooperation with the Mine Safety and Health Administration (MSHA) and the National Fire Protection Association (NFPA), has developed and in-mine tested a cost-effective fueling area fire protection system. The system was designed to be rugged enough for reliable, long-term use, yet to utilize state-of-the-art, off-the-shelf components to maintain cost-effectiveness. The system consists of cross-zoned, ultraviolet flame sensors used for quick response to fire, and a dual-agent fire suppression subsystem. A dry chemical is used for fast fire -knockdown," and AFFF (or "light water") is used for long-term, fire-securing capability. The basic components of the system are shown in the schematic illustration.

Jan 1, 1982

By A. J. Kraemer

For a number of years the Bureau of Mines has conducted semi-annual survey to determine the changes in the characteristics of the rotor gasoline being sold in the United States. Certain cities have been decided upon as points of origin of samples. Tare choice of these cities has been governed by their situation as the representative of a more or less definitely bounded marketing territory. Samples have been taken on or about the fifteenth day of January and July of each year. In the collection of the samples an attempt has been made to get a representation of the important types of motor fuel being sold, and also to tame into consideration the proportion of tie total consumption that is supplied by the different marketers. It is therefore felt that the survey affords a reliable indication of the quality of the gasoline being sold throughout the United States at the time of sampling. The figures in Table I, below, were obtained by averaging the end points of the least volatile and most volatile samples of gasoline. For example, of 850 samples analyzed in 1919, the 10 per cent (85 samples) having the highest end points, and the 1C per cent having the lowest end points were averaged. These averages are represented in the table as the "Maximum 10 per cent" and the "Minimum 10 per cent", respectively. The same scheme was used in the succeeding surveys.

Jan 1, 1925

By Charles A. Sorrell

This Bureau of Mines publication reviews the structural characteristics of crystalline phases and phase equilibria data for the system NaC1-KC1-AlC13-NaF-KF-AlF3, which encompasses a large number of molten salt fluxes currently used in aluminum recycling. Its purpose is to provide guidelines for research into the relationships between molten salt compositions and their physical properties, notably vapor pressures, densities, surface tensions, and viscosities, knowledge of which is essential to maximizing fluxing efficiencies and metal recovery and minimizing hazardous emissions and disposal problems. In addition, this report describes experimental determinations of sub-solidus compatibility relationships in the system, which is of the quaternary reciprocal type, containing 12 different stable 4-phase assemblages in the solid state. The compatibility diagram serves to define the important compositional planes across which important changes in properties are likely to occur.

Jan 1, 1986