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By Gerald T. Homce, Michael R. Yenchek, H. Kenneth Sacks, James C. Cawley

Accidents occur when least expected, from sources that we rarely anticipate and with outcomes that can vary greatly. Anyone who has ever been involved in an automobile accident knows, the transition from driving comfortably and safely down a highway to being involved in a potentially life-threatening situation can occur in a heartbeat. Accidents on the job are no different. The mining industry has a relatively small number of electrical injuries, compared to industries such as construction or agriculture, due to the small total employment in mining. Mining does, however, have one of the highest occupational electrocution rates of any U.S. industry, at 2.8 for every 100,000 workers per year. This is approximately four times the average for all industries. Data from the Mine Safety and Health Administration (MSHA) shows that 75 electrical fatalities occurred in the mining industry between 1990 and 1999. Of these, at least 17% involved high-reaching mobile equipment that contacted overhead power lines.

By R. L. Hopkins, H. T. Rall

A continuous method has been developed for preparing thiolacetic acid . Acetic anhydride and hydrogen sulfide are passed concurrently over an amine ion- exchange resin , under 20 - psi pressure . The thiolacetic acid , a product of the reaction , is flashed continuously from the crude reaction mixture and is purified by fractional distillation . The yield of thiolacetic acid is in excess of 80 percent based on the acetic anhydride charged . INTRODUCTION In the synthesis of reference compounds needed in the identification of sulfur compounds in petroleum , thiolacetic acid has become an important reagent because of its use in the synthesis of thiols by addition to appropriate olefins : R - CH = CH₂ + CH3 - COSH R- CH2 - CH2 - S - COCH R - CH2 - CH₂ - SH + CH3COONa NaOH (1 ) The commonly used procedures for its preparation , as described by Clark and Hartman (1 )4 and by Ellingboe (2 ) , are based on the batchwise reaction of acetic anhydride with hydrogen sulfide :

Jan 1, 1964

By F. D. DeVaney

An examination of the physical properties of manganese ores is being made at the Mississippi. Valley Station of the United States Bureau of Mines in cooperation with the Missouri School of Mines and Metallurgy, Rolla, Missouri. The object of the study is to find out how much these ores can be beneficiated by such processes as jigging, tabling, magnetic separation, and flotation. Some. of the results were given in an earlier report.4 Eighty samples obtained from various prospects and mines throughout the country have been examined; this is a very small part of those that should be examined before the work can be a definite factor in-the appraisal of manganese ores or the guide in beneficiation which the operators seek. The ore deposits are not expected to reach to great depths vertically, after the manner of copper and gold, but in lateral distribution their greater extent is notable. This applies particularly to the residual and replacement deposits of manganese.

Jan 1, 1929

By G. W. Grove, G. L. FreAS

One of the chief hazards in mining bituminous coal is the accumulation of coal dust in the mines . When coal dust is thrown into suspension , it can be ignited and exploded by electricity through short -circuiting of mining machinery and trolley wires , or by arcs and sparks . The Bureau of Mines has endeavored to assist the coal -mining industry in preventing disasters from this cause by urging that all bituminous -coal mines be rock -dusted . As it has been difficult to convince some mining men of the danger of ignition of coal dust and of the effectiveness of rock dusting in preventing widespread explosions , a small , portable , coal -dust - explosion gallery has been designed to demonstrate the explosibility of bituminouscoal dust . Such galleries are furnished to Bureau engineers , inspectors , and safety instructors to illustrate visually and impressively the Bureau's accident -prevention educational work on the causes and prevention of dust explosions in bituminous -coal mines .

Jun 1, 1949

By Robert S. Sanford

The Broughton and Ring magnetite deposits in Essex County, N. Y., are thought to be in a mineralized belt that extends from the Lake Sanford mining district to Lake Champlain and passes through the Mineville district. The country rook is syenite-gneiss, similar to that in the Mineville area. The Bureau of Mines conducted a vertical magnetometer survey of the area. On the Broughton properties there are no indications, magnetically, of magnetite in any degree of concentration. 'On the ding properties a number of sharp, localized magnetic anomalies were observed. One core-drill hole was bored to a, depth of 48.3 feet, also, to test one of the strongest anomalies. The field work was in progress from December 1943 to July 1944. Although no iron ore was intersected by' the drill hole, it showed that the amphibolite rook, at a depth of 6 to 100 feet below the surface, contained enough magnetite and iron sulfides to account for the anomalies recorded by the magnetometer survey.

Jan 1, 1949

By E. L. Garton

The United Status Bureau of Mines has recently collected samples of crude petroleum from well] in the newly developed Joiner, Kilgore, and Longview fields of Rusk and Gregg Counties in the East Texas district, and from the Van field of the East Central district of Texas. East Texas Cruder The four samples of crude oil from the East Texas fields are all typical "intermediate base" crudes according to the classification given by Smith and Lane. 3 Sample 31,063 is from the discovery well in the Joiner field. This well came in on October 3, 1930, with an initial production of 400 barrels per day. Sample 31,062 was obtained from a well that was completed on February 1, 1931, with an initial production of 3,500 barrels per day. The 32 East Texas crudes are produced at an average depth of approximately 3,600 feet. which is the deepest Woodgine-sand production so far encountered in any of the Texas or Louisiana fields.

Jan 1, 1931

In the interest of safety ii: coal mining, the Bureau of Mines recommends: That all active underground coal mines, whether working or idle, have one or more fans in continuous operation. The capacity and installation shall be such that the entire mine workings are adequately ventilated at all times. Main fairs shall be located on the surface in fireproof housing offset from the line of any mine opening. The housing shall be provided with ample pressure-relief doors or other devices easily opened by the force of an explosion. The installation shall permit prompt reversal of air flow. For mines that liberate gas, the fan shall have at least two independent sources of rower immediately applicable. Ventilation of underground workings in coal mines is needed whether or not explosive gas is present. Natural ventilation is unreliable and often uncontrollable. Main fans should be on the surface; if they are in the mine, fire or explosion may make access difficult or dangerous and render the installation inoperative.

Jan 1, 1939

By Barbee J. Scheibner

This Bureau of Mines report describes the geology and physical properties of core samples at the Sunnyside coal mine No. 1, Sunnyside, Utah, and was written in conjunction with the Single-Entry Program conducted at the mine. The objective of this program was to test the hypothesis that the single-entry system in the Sunnyside mine, supported in the center by open cribs and divided by a fire-resistant partition, is equivalent to or better than a two-entry sys-tem. Drill cores, taken underground at 15 sites in the single-entry study area, facilitated the construction of geologic cross sections of the entries. Physical property data obtained from the drill cores was used in a three-dimensional finite element analysis program to evaluate the stability of the openings, the support requirements, and the de formation characteristics of the roof and floor material. Data on 10 physical property parameters for 5 rock types plus coal are also tabulated and discussed.

Jan 1, 1979

Improve the effectiveness of face ventilation systems in coal mines by minimizing leakage around line and check curtains. Approach In-mine surveys were conducted to determine current curtain construction techniques, their effectiveness and associated costs. In addition, performance characteristics of extensible curtains were evaluated. A total of 77 conventional curtains in 10 mines was examined for 12 important characteristics. Extensible curtains were erected in a full-scale model and examined for operational difficulties, effects of leakage, and air pressure. Survey Results The underground mine study identified four categories of face brattice construction ranging from simple to complex: 1. Simple suspension of the curtain from roof bolts with the bottom edge lying on floor. 2. Spadding of the curtain to the roof on about 12-inch centers and stabilization of the bottom edge with wood or rock. 3. Use of vertical props and spads with a base board for support on the bottom. 4. Use of vertical props with caps and bottom boards plus horizontal brattice support boards.

Jan 1, 1984

By McHenry Mosier

Although local conditions at each mining property affect the percentage of increase in drilling speed for a given reduction in gage of bit, the results of drilling tests conducted at the Mount Weather testing adit show such a large advantage in favor of the smaller gages that they should be indicative of the possibilities at most mines. GENERAL DISCUSSION Although it is common knowledge among miners that drilling speed increases with reduction in gage of bit, the large amount o this increase is not so universally realized, A recent Bureau of Mines4/ survey of drilling practices in 28 metal mines showed that the maximum gage of starters is 3 inches and that at 50 percent of the mines starters are 2-1/4 inches or larger, Because this size appears too large for conditions at most mines where abrasion is moderate and where powder distribution permits, the use of smaller bits presents a favorable opportunity for reducing drilling costs.

Jan 1, 1939

By Richard F. Link, George W. Gladfelter, George S. Koch

Contour maps, useful in mineral industries, for example, in analysis of trends in mineralization, may be constructed through statistical methods of regression analysis programed for an electronic computer, For many applica­tions, the resulting maps are more useful and objective than conventional contour maps that are necessarily subjective because they are drawn by hand methods. In principle, an equation is found that fits a quadratic surface to observed elevations of points referred to a datum plane, The quadratic sur­face, represented by a contour map may take the form of a ridge, valley, dome, or basin, Once an equation has been derived, its coefficients may be used to construct a contour map--showing lines of equal value that are derived from the original observed data points by the averaging process of fitting the quadratic surface. Methods employed are illustrated by an example analysis, based on data from a large vein of the Fresnillo mine, Zacatecas, Mexico. Computer programs to implement the methods are described in an appendix,

Jan 1, 1964

The National Institute of Occupational Safety and Health has classified diesel exhaust as a potential human carcinogen. Though standards for diesel particulate matter (DPM) in the work place have not been established, concern for the health of miners is prompting mine operators to consider methods for reducing worker exposure to diesel exhaust. Approach One of many methods for reducing DPM being investigated by the Bureau of Mines is the use of additives in diesel fuel to improve combustion. Research Results Three fuel additives have been tested in Caterpillar and Deutz diesel engines which are similar to types used in underground mines. One iron-based additive containing ferrous picrate had no effect on emissions. A second iron-based additive containing ferrocene reduced DPM between 5 and 45 pet depending on engine operating conditions. The 37-pct reduction for an 8-minute duty cycle, which includes a wide range of transient loads and speeds, is considered to represent in-mine performance.

Jan 1, 1990

By Oliver C. Ralston

OUTSTANDING TRENDS of the year included the following: 1. Concentration and beneficiation of iron ores to provide improved blast-furnace feed and extend ore reserves. 2. Successful development of pelletizing and sintering procedures for fine iron ores. 3. The realization that cyclone separation could replace existing classifiers in many grinding circuits. 4. The rapidly blossoming metallurgy of ultrapure silicon and improvements in zone melting. 5. The rapid increase in the use of liquid-liquid extraction and ion exchange in hydrometallurgy. 6. The industrial application of vacuum melting on the 100-ton scale. 7. The hope for developing a columbium (noibium) base alloy for high-temperature use. The technologic advancement in metallurgy that had the greatest effect on the American economy was the beneficiation of iron ores to give improved feed for blast furnaces and indirectly extend our ore reserves. This was not a sudden development but rather culmination of a decade of intensive effort.

Jan 1, 1958

Measure the daily exposure of individual miners to alpha particles emitted by radon daughters (radioactive decay products of the radon gas present in the mine atmosphere). Approach A dosimeter worn by a miner counts alpha particle emissions from radon daughters, RaA (Polonium 218) and RaC (Polonium 214), collected on a filter, and stores the gross count for later readout. How It Works A pump draws air into the detector assembly where radon daughters are collected on a filter. The detector, a solid state surface barrier type, is mounted in the filter head behind a thin mylar disc which serves as a moisture barrier. When a radon daughter decays and its alpha emission strikes the detector, the alpha particle causes a pulse of electrical charge in the detector. The circuits used to condition and count the electrical pulses generated in the detector are represented by the other blocks shown in the simplified block diagram. Each pulse is first amplified.

Jan 1, 1979

By J. K. Whyatt, B. G. White

Various methods of monitoring slip movements on bedding planes, as well as examination of rock burst damage in stopes, suggest that many rock bursts in the Lucky Friday Mine are closely associated with these movements. Slip displacements along bedding simultaneously reduce the physical dimensions of stopes and increase compressive stress along stope margins. Such changes, in turn, contribute directly to sudden failures of rock and cemented sandfill surrounding stopes. We believe that the reduction of rock burst hazards must be based on a clear understanding of the basic mechanisms involved. The current work emphasizes the mechanical role of wall rock movement and seismicity in generating conditions that promote rock burst damage. Based on our interpretations of these mechanisms, we briefly address several hypothetical practices that could influence rock burst hazards in similar mining situations. The overall goal of this research is to advance the NIOSH mission of improving the health and safety of the nation’s workers.

By B. W. Madsen

As part of a program to maintain an adequate supply of minerals and metals to meet national economic and strategic needs, the Bureau of Mines conducted research to determine the diffusion coefficients for ferric ions in synthetic copper leach solutions. Determination of ferric ion diffusion coefficients in typical dump leach solutions is necessary for predicting leaching rates of copper from large-scale leaching operations and for optimizing concentrations of ferric iron in solutions to maximize leaching efficiency. Derivative chronopotentiometry, an electroanalytical technique, was used to determine ferric ion diffusion coefficients. The diffusion coefficient decreased dramatically with increasing concentration of iron in solution. An empirical model was used to relate the ferric ion diffusion coefficient to the total amount of sulfate in solution. Measuring the diffusion coefficient dependence on temperature yielded an activation energy of 5.5 kcal/mole of ferric ion. Activity coefficients of ferric ions as a function of concentration were calculated from diffusion coefficient data.

Jan 1, 1981

By Ronald S. Conti

Fire is a major concern for those who work in underground mines. A mine fire can occur at anytime and often results in a partial or total evacuation of mine personnel and could result in the loss of lives. Therefore, having a workforce that is well trained to prevent, detect, and fight a fire is important. This paper focuses on responders’ preparedness for fire. Responders in this context are considered the entire workforce and are categorized as first, second, and sustained responders and evacuating miners. Quality training enhances ones awareness of mine fire hazards and promotes self-confidence in combating fires and responding to emergencies. Early warning systems and other escapeway aids such as a through-the-earth signaling and communication system, lasers and strobe lights are also addressed. The technological advancements that have been made can improve the state-of-preparedness for responders to underground emergencies and increase the chances of survival for escaping personnel.

By D. E. Shanks

As part of its effort to produce cell-grade alumina from clay, the Bureau of Mines investigated the hydrogen chloride gas-sparging crystallization of aluminum chloride hexahydrate (ACH) from aluminum chloride liquor, to provide information for optimizing the crystallization operation. Four parameters important in controlling the crystallization of the aluminum chloride hexahydrate and the concentration of impurities, particularly phosphorus and magnesium, in ACH crystals are (1) aluminum chloride concentration in the feed solution to crystallization, (2) hydrogen chloride gas flow rate, (3) temperature, and (4) concentration of phosphorus and magnesium also in the feed solution. Parameters 1, 2, and 3 affect crystal formation. The combined effects are very important because the phosphorus and magnesium concentrate in the crystals during the early stages of crystal growth. Aluminum chloride hexahydrate of cell-grade purity was crystallized from saturated aluminum chloride solutions containing less than 0.003 wt-pct P205 and 0.010 wt-pct MgO. Crystallization temperatures less than 600 C decreased crystal purity.

Jan 1, 1981

By W. A. Cole

The sulfur shortage that existed during the Korean conflict stimulated interest in coal measures as possible sources of sulfur. One of the areas brought to the attention of the Bureau of Mines was in Marion County, Iowa, where comparatively high-sulfur coals and other marcasite-bearing strata were known to occur. A Bureau of Mines engineer inspected the marcasite occurrence on December 4, 1954; this prompted further work on the Iowa coals and associated formations as a source of iron sulfides. An investigation of the Iowa high-sulfur coals was undertaken including core drilling, field reconnaissance, and compilation of data pertinent to consideration of the following: 1. Upgrading Iowa coal by mechanical cleaning and the feasibility of recovering sulfur from coal brasses. 2. Possibility of processing the high-sulfur coals by adaptation of methods employed in processing industrial gases to produce sulfur and sulfur products. 3. Possibility of finding concentrations of iron sulfides in associated rock formations in sufficient quantity for economical recovery.

Jan 1, 1957

By Jalna R. Zatko

The Bureau of Mines, U.S. Department of the Interior, has developed a novel method of flocculation dewatering of phosphatic clay wastes using polyethylene oxide as the flocculant. Research was conducted to determine whether ethylene oxide gas was present in the air in the vicinity of disposed waste materials which had been flocculated with polyethylene oxide. Samples of clay waste materials containing polyethylene oxide were prepared in stoppered glass bottles in simulated disposal environments. Gaseous samples, removed over a 75-day period using an airtight syringe, were injected into a gas chromatograph that was capable of separating ethylene oxide from air. The presence of ethylene oxide gas was not detected in any sample. To determine possible degradation products of polyethylene oxide, the properties and reactions of ethylene oxide and its polymers were reviewed. Based upon the literature survey and experimental study, it was concluded that adverse environmental effects were not likely to result from the use of polyethylene oxide for flocculating phosphatic clay waste products.

Jan 1, 1980